• Title/Summary/Keyword: 콘크리트 중성화

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Weatherability of Epoxy Cement Mortars without Hardener (경화제를 첨가하지 않은 에폭시 시멘트 모르타르의 내후성)

  • Jo, Young-Kug
    • Journal of the Korea Concrete Institute
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    • v.18 no.6 s.96
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    • pp.801-809
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    • 2006
  • Epoxy resin has widely been used as adhesives and corrosion-resistant paints in the construction industry for many years, since it has desirable properties such as high adhesion and chemical resistance. Until now, in the production of conventional epoxy cement mortars, the use of any hardener has been considered indispensable for the hardening of the epoxy resin. However we have noticed the fact that even without any hardener, the hardening process of the epoxy resin can proceed by the action of hydroxides in cement mortars. As a result the disadvantages of the two-component mixing of the epoxy resin and hardener have been overcome. The purpose of this study is to evaluate the mechanical properties and durability of epoxy cement mortar without a hardener exposed at indoor and outdoor for one year. The epoxy cement mortars without and with a hardener were prepared with various polymer-cement ratios, and tested for weight change, flexural and compressive strengths, water absorption, carbonation depth and pore size distribution. Especially, the basic properties of the epoxy cement mortars without hardener are discussed in comparison with ones with the hardener. From the test results, it is concluded thai the epoxy cement mortars without a hardener exposed at indoor and outdoor for one year have higher strength and better durability than ones with the hardener within the polymer-cement ratios of 10 to 20%.

Aging Deterioration for Electric Power Transmission Tower on Offshore Through Periodic Inspections (해상송전철탑 구조물의 주기점검을 통한 경년열화 변화특성)

  • Lee, Ho Beom;Jang, Il Young
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.16 no.4
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    • pp.25-33
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    • 2012
  • In electric power transmission tower structures on offshore, implementation of life management using the event data of regular safety inspections for structural and material damages is strongly recommended. In this study, six tower structures in Sihwa Lake around Yeoungheung island were target bodies for the safety inspections. safety inspections for deterioration about each of six towers were performed about three items for steel member, five items for concrete foundation, and four items for steel-pipe pile in seawater and seawater itself. Safety inspections for steel members included the visual observations of surface appearances, the measurements of member thicknesses, and the checks of painting states. Also safety inspections for concrete foundations comprised the estimation of crack features, the evaluation of non-destructive compression strengths, and the measurements of neutralization depths and chlorides contents. For steel-pipe piles in seawater the inspections comprised the surveys of corrosion states in accordance with potential levels tests and anode tests, the analyses of photos taken on surfaces of the piles as well as the evaluation of seawater quality. A set of deterioration inspections was performed at the same positions around october of each year for three consecutive years. As a result in this study, Newly developed deterioration indexes have been applied profitably to maintain structural safety for electric power transmission towers by utilizing these event data systematically.

Evaluation on the Basic Properties of Phosphate Modified Portland Cement Paste for Potential Application of Geologic CO2 Sequestration (이산화탄소 지중 격리용 인산염 혼입 시멘트 페이스트에 관한 기초물성 평가)

  • Yoon, Ju-Han;Kim, Seong-Geun;Kim, Ji-Hyun;Lee, Jae-Yong;Chung, Chul-Woo
    • Journal of the Korea Institute of Building Construction
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    • v.17 no.3
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    • pp.253-260
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    • 2017
  • As global warming became a worldwide issue, a significant effort has been made on the development of technology related to $CO_2$ capture and storage. Geologic sequestration of $CO_2$ is one of those technologies for safe disposal of $CO_2$. Geologic sequestration stores $CO_2$ in the form of supercritical fluid into the underground site surrounded by solid rock, and concrete is used for prevention of $CO_2$ leakage into the atmosphere. In such case, concrete may experience severe damage by attack of supercritical $CO_2$, and especially in contact with underground water, very aggressive form of carbonation can occur. In this work, to prevent such deterioration in concrete, calcium phosphates were added to the portland cement to produce hydroxyapatite, one of the most stable mineral in the world. Temperature rise, viscosity, set and stiffening, and strength development of cement paste incorporating three different types of calcium phosphates were investigated. According to the results, it was found that the addition of calcium phosphate increased apparent viscosity, but decreased maximum temperature rise and 28 day compressive strength. It was found that monocalcium phosphate was found to be inappropriate for portland cement based material. Applicability of dicalcium and tricalcium phosphates for portland cement needs to be evaluated with further investigation, including the long term compressive strength development.

Watertightness and Durability Properties of Ultra Rapid Hardening Grout using Bottom-ash (잔골재 대체재로서 바텀애쉬를 이용한 초속경 그라우트재의 수밀성 및 내구특성)

  • Lee, Gun-Cheol;Oh, Dong-Uk;Cho, Byoung-Young;Kim, Young-Geun;Cho, Chung-Ki
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.3
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    • pp.102-109
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    • 2011
  • In this study, in order to develop ultra rapid hardening mortar(URHM) for tunnel repairs using bottom ash of low recycle ratio and Admixture as Eco concept, watertightness and durability properties of URHM on temperature condition of construction field were performed. Test result, seepage quantity and water absorption coefficient regarding watertightness of URHM were as in the following : series II > series I. Seepage quantity for the standard condition were smaller than low temperatures. all specimens were satisfied below 20g as standards of seepage quantity on KS F 4042. Because of the decrease of unit cement content by to replacement of blast furnace slag, the neutrlization resistance for durability properties was reduced. The result of alkali resistance and acide resistance, compressive strengths for specimens soaked in calcium hydroxide solution of seriesI were lower than compressive strengths for specimens not soaked. On the other hand, the case of series II show that the deterioration of compressive strengths for specimens was not almost showed. Compressive strengths of specimens soaked were similar with specimens not soaked except series II-C in $5^{\circ}C$. Therefore, specimens using both blast furnace slag and bottom ash were good in alkali resistance and acide resistance.

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Performance Improvement and Durability Evaluation of Shotcrete for Permanent Tunnel Support (터널 영구 지보재로서의 숏크리트 고성능화 및 내구성 평가에 관한 연구)

  • Lee, Sang-Pil;Ryu, Jong-Hyun;Lee, Sang-Don;Jeon, Seok-Won;Lee, Chung-In
    • Tunnel and Underground Space
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    • v.17 no.4
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    • pp.266-284
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    • 2007
  • Recently, many efforts have been made to construct the first unlined tunnel, without in-situ concrete lining, in Korea. However, the lack of reliability in the performance of shotcrete as permanent tunnel support prevented from its realization. Shotcrete has been regarded to have significant problems in field application and long term performance because of unsatisfactory strength level and durability compared to those of European countries. In this study, the high strength shotcrete satisfying compressive strength over 40 MPa and flexural strength over 4.5 MPa was developed from optimized mix design. The type of accelerators and the amount of silica fume were selected as the main factors in mixing process and the analyses were carried out up to the elapsed time of 2 years. In order to evaluate the short term durability of shotcrete, an array of laboratory test consisting of freeze-thaw, carbonation chloride penetration and permeability test was performed. For long-term durability tests, specimens have been put in an operated highway tunnel to expose them to the similar environment when they are actually used as an unlined tunnel support. From the strength and durability tests, it was found that only alkali-free based accelerator satisfied the target strength of this study and also, the developed shotcrete showed very high performance in its durability.

Reduction of pH of Recycled Fine Aggregate due to Natural and Artificial Treatment Method (자연 및 인위적 처리방법 변화에 따른 순환잔골재의 pH저감)

  • Han, Cheon-Goo;Han, Min-Cheol;Han, Sang-Yoon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.1
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    • pp.103-110
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    • 2011
  • This study is to comparatively analyze the characteristics of pH decrease in recycled fine aggregates for embankment and landfill produced from waste concrete by using natural process and artificial process. The result was as follows In case of recycled fine aggregates left outdoor, it was found that pH level was decreased if the thickness of embankment becomes thinner, or the materials left outdoors owing to high concentration of $CO_2$ in atmosphere caused by respirations of people. When the air was permeated, pH level was decreased more effectively. It was analyzed that this phenomenon was caused by efficient supply of $CO_2$ in the recycled fine aggregates owing to high-pressure ventilators. In case of water spraying treatment, sprayed water facilitated hydration of unhydrated cement to dissolve calcium hydroxides which neutralized $CO_2$ in the atmosphere during desiccation process and decrease pH level by a considerable margin. In case of Immersed treatment, decrease of pH was not sufficient. When facilitating the supply of $CO_2$, pH level of the recycled fine aggregates was decreased by the largest margin. It was analyzed that this phenomenon was caused by efficient supply of $CO_2$. From the above results, it was analyzed that the most effective method of reducing pH level of the recycled fine aggregates from the aspects of pH reduction performance, economic efficiency and workability was repeated wet-dry cycles of spraying water to the aggregates in the proportion of 1:0.5 by weight and then treating by forcefully blowing $CO_2$ gas into the aggregates.

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