• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
• /
• v.29 no.3
• /
• pp.153-161
• /
• 2023

The worldwide effects of COVID-19 have led to a surge in online shopping and contactless services. The consumption pattern has caused the issues such as the environmental pollution together with the increase of plastic waste. Reducing the reliance on the petroleum based plastic use for the package and replacing it with environmentally friendly material are the simple ways in order to solve those problems. Paper is an eco-friendly product with high recyclability as the food packaging materials but has still poor barrier properties. A barrier coating on surface of the paper can be achieved with the proper packaging materials featuring water, gas and grease barrier. Polyethylene (PE) or polypropylene (PP) coatings which are generally laminated or coated to paper are widely used in food packaging applications to protect products from moisture and provide water or grease resistance. However, recycling of packaging containing PE or PP matrix is limited and costly because those films are difficult to degrade in the environment. This study investigated the recyclability of modified acrylic emulsion coating papers compared to PE and PP polymer matrixes as well as their mechanical and gas barrier properties. The results showed that PE or modified acrylic emulsion coated papers had better mechanical properties compared to the uncoated paper as a control. PE or PP coating papers showed strong oil resistance property, achieving a kit rating of 12. Those papers also had a significantly higher percentage of screen reject during the recycling process than modified acrylic coated paper which had a screen rejection rate of 6.25%. In addition an uncoated paper had similar value of a screen rejection rate. It may suggest that modified acrylic emulsion coating paper can be more easily recycled than PE or PP coating papers. The overall results of the study found that modified acrylic emulsion coating paper would be a viable alternative to suggest a possible solution to an environmental problem as well as enhancing the weak mechanical and poor gas barrier properties of the paper against moisture.

• 기계와재료
• /
• v.21 no.4
• /
• pp.16-22
• /
• 2010

고온에서의 내열, 내산화, 내부식 등의 한계성을 극복하기 위하여 새로운 고온재료의 개발과 함께 표면특성 향상을 위한 코팅기술에 대한 연구가 계속 되어 왔다. 현재 선진국에서는 C/C복합재료를 비롯하여 $Si_3N_4$, SiC 및 SiC/SiC계 CFCC등의 규소계 비산화물 세라믹재료 등에도 표면에 내식, 내마모, 열차폐 및 내산화성에 견딜 수 있는 코팅층을 형성시켜, 표면에서의 산화, 열응력, 및 내산화성 등에 대한 특성평가 및 최적의 코팅층에 대한 연구가 진행중에 있으며 향후 국내에서도 육성해야할 중요한 기술분야이다.

• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 2017.05a
• /
• pp.104-104
• /
• 2017

유럽의 폐차 처리 지침, RoHs 및 국내 친환경 소재 부품의 개발이 날로 가속화 되면서 종래 사용해 오던 인산염 피막 등 중금속이 함유된 코팅 재료는 점차 친환경 코팅 용액으로 전환이 되었다. 최근 자동차 산업 등에서 종래 중금속인 $Cr^{+6}$을 함유하지 않는 다양한 코팅 용액이 상용화 되고 있다. 그 중 가장 효율적으로 적용되고 있는 용액이 아연 flake를 첨가하여 희생 양극효과를 가능하게 하여 내식용 코팅 용액으로 상용화 하고 있다. 이 용액에는 내식성을 확보하기 위하여 희생양극이 가능한 소재 인 아연 분말을 첨가하며, 이 분말의 분산성이 소재와 코팅 층의 밀착성, 내식성에 결정적인 영향을 미친다. 특히 산업 현장에서는 아연 분말의 효율적인 분산을 위하여 24시간 이상 교반해야하기 때문에 생산성을 감소시키는 결정적인 요인으로 작용을 한다. 아연 분말의 분산은 용액 내에 첨가하는 각종 첨가제의 종류와 첨가량에 따라 현저하게 분산성이 다르기 때문에 첨가 원소에 대한 연구가 매우 중요하다. 본 연구에서는 서로 다른 이종 합금을 첨가하여 각종 첨가제의 종류 및 첨가량이 분산에 미치는 영향을 조사하였고, 첨가량이 코팅 층의 밀착성 및 내식성에 미치는 영향에 대하여 연구하였다. 분산제 첨가량이 낮을 경우 용액은 두껍게 코팅이 되며 분산 거리가 짧아졌다. 이 경우 코팅 층의 박리가 쉽게 발생하며, 코팅 층이 불균일하였다. 1.7% 첨가량에서 최적분산효과를 얻을 수 있었으며, 1,000시간 이상의 내식성을 확보할 수 있었다. 분산성과 동시에 유동성 확보가 중요하며, 유동성 확보를 위하여 점증제의 첨가량에 대한 변화를 주었다. 최적의 첨가량은 1.5% 이상으로 이 경우 부식 발생시간을 억제할 수 있었다.

• Korean Journal of Food Science and Technology
• /
• v.40 no.6
• /
• pp.621-625
• /
• 2008

Squid oil is an abundant source of polyunsaturated fatty acids. This is particularly true for eicosapentaenoic acid and docosahexaenoic acid. The principal objective of this study was to extend the stability and improve the process aptitude of squid liver oil. Fluidized bed coatings were employed for coating with microencapsulated oil. The efficiency of the fluidized bed coating of the microencapsulated powder was over 90%. The apparent density with zein-DP was 0.6 g/mL, thereby indicating that flow ability had been improved as the result of an increase in specific gravity. The solubility of artificial gastric and enteric fluids with HPMC-FCC was 59.9 and 0%, respectively, whereas with zein-DP solubility was 0 and 31.0%, respectively. Polyunsaturated fatty acid retention results demonstrated that zein-DP coating was higher than HPMC-FCC, followed by the microencapsulated squid liver oil method. These results demonstrated that the application of microencapsulation and fluidized bed micro-coating techniques improved the stability and processing compatibility of squid liver oil.

• Journal of Korean Association for Spatial Structures
• /
• v.11 no.1
• /
• pp.97-104
• /
• 2011

This paper contains of descriptions of deterioration diagnosis of the surface and a coating layer for maintenance managements of large spatial structures with membrane structure. Membrane is a roofing material of the structures that its performance of durability including its performance of chemical resistance and corrosive resistance is considered to be highly important. In general, the items of diagnosis for maintenance managements such as membrane extensively include the diagnosis of deterioration of the membrane surface, of a coating layer of membrane, the diagnosis of deterioration between a coating layer and fiber, of overall surface of membrane, of the class of ropes, of reinforced belts, and of the cover of rubber. The object of this study that needs maintenance managements of the membrane with PVC and FIFE which are commonly used and shows the diagnosis results of deterioration of the surface and a coating layer.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2011.02a
• /
• pp.281-281
• /
• 2011

산업 환경에서 친환경 및 에너지효율성을 중요한 조건이 되면서 고효율성 및 다기능을 가진 재료에 대한 연구가 활발히 진행 되고 있다. 특히 Al-Ti-N 코팅은 이미 경도 측면에서 우수 하여 고속 공구 부품에 널리 사용되고 있고 최근에 Al-TiN에서 Si 첨가는 40GPa이상의 고경도와 1000도 이상의 산화온도를 지닌 나노 혼합물 코팅을 형성 시키는 것으로 알려져 있다. 본 연구에서 Al-Ti에 Si, Cu, Cr 을 첨가하였을 때 코팅을 형성하였을 때 바뀌는 물성 변화을 확인하였다. 이러한 연구를 위해 Al-Ti 합금 조성 중 가장 우수한 것으로 알려진 60:40으로 타겟을 만들어 스퍼터 장비를 이용해 코팅을 형성하여 기초 실험을 진행하였다. 그 근거로 하여 3원계인 Si, Cu, Cr 을 첨가하여 각각의 단일 타겟으로 만들고 코팅을 형성하였다. 타겟과 코팅의 성분이 동일한지 확인하기 위해 EPMA분석을 하였고 그 결과 오차 범위 내에 동일한 것으로 확인하였다. 또 내산화성 테스트를 위해 400도에서 1000도로 가열된 대기 중에 코팅 층을 1시간씩 노출시키는 공정을 통해 확인하였고 내식성 테스트는 SUS 304계열 위에 코팅을 하여 Potentiodynamic polarization scan 장비로 비교해 보았다. 표면경도는 3원계 코팅인 경우 질소비율이 증가할수록 30GPa ~ 35GPa까지 증가하였고 XRD 분석 결과와 비교 시 (111), (200) peak가 명확할수록 경도 값이 높은 것으로 확인하였다. 마모테스트 결과 3원계인 코팅 층이 dry상태에서 감소하는 경향을 보였다. 특히 0,26까지 감소한 Si 을 첨가한 코팅 층은 H/E지수도 좋아 마모트랙의 길이도 짧아 우수한 것으로 알 수 있었다. 이런 결과에서 보듯 3원소 이상 첨가 시 특성변화가 차이가 있다는 것을 알 수 있었다.

• Food Science and Preservation
• /
• v.14 no.4
• /
• pp.364-368
• /
• 2007

The purpose of this study was to improve the stability and the processing property of vitamin C. Vitamin C was coated according to particle size(80-100 mesh, 100-140 mesh) and mixing ratio(1:1.6, 1:2.5, 1:3(w/w)) with coating solution(8% Zein-DP, 6% HPMC-FCC), and then the quality characteristics of fluidized bed micro coated vitamin C were investigated. The coating efficiency and the thickness of coating film were higher in $80{\sim}100$ mesh particle than in $100{\sim}140$ mesh particles, and coating efficiency was decreased as the coating material was increased. The distribution range of particle was more narrow in mixing ratio of 1:3(w/w) than in the other. DPPH radical scavenging activity was not affected by the particle size and the mixing ratio. There was no difference between the coating materials in terms of the quality characteristics. The optimum coating condition for fluidized bed micro-coating of vitamin C powder was selected as the particle size of $80{\sim}100$ mesh and the mixing ratio with coating solution of 1:3(w/w).

• Applied Chemistry for Engineering
• /
• v.18 no.2
• /
• pp.183-187
• /
• 2007

$SiO_2/TiO_2$ core-shell particles with controlled shell thickness were prepared using large silica particles. The thickness of titania coating layer was varied from 8 nm to 38 nm depending on the number of coating steps from 1 to 3 times. After titania coating, the core-shell particles showed textured surface due to the titania coating layer, resulting in 3~25 times increase of specific surface areas. The properties of titania coated silica particles were characterized by FE-SEM, Zeta potential meter, BET, and XRD.

• Proceedings of the Korean Institute of Surface Engineering Conference
• /
• 2014.11a
• /
• pp.225-225
• /
• 2014

텅스텐 카바이드(WC) 모재와 CrZrN 코팅 사이의 밀착력을 향상시키기 위해 다양한 Cr-N 중간층이 합성되었다. 질소 분압을 조절하여 Cr-N 중간층 내의 질소 함량을 변화시켰으며, 그 결과 다양한 조성을 갖는 Cr-N 중간층이 합성되었으며 중간층의 물성이 변화하여 밀착력에 영향을 주었다.

• Korean Journal of Materials Research
• /
• v.25 no.5
• /
• pp.226-232
• /
• 2015

High temperature plasma coating technology has been applied to recover damaged aluminum dies from wear by spraying pure aluminum and alumina powder. However, the coated mixed powder layer composed of aluminum and alumina often undergoes a detachment from the substrate, making the coated substrate die unable to maintain its expected life span. In this study, in order to increase the bonding strength between the substrate and the coating layer, a pure aluminum layer was applied as an intermediate bond layer. In order to prepare the specimen with variable bond coating conditions, the bond coat layers with a various gun speed from 10 cm/sec to 30 cm/sec were prepared with coating cycle variations ranging from three to nine cycles. The specimen with a bond coat layer coated with a gun speed of 20 cm/sec and three coating cycles exhibited ~13MPa of adhesion strength, while the specimen without a bond coat layer showed ~6 MPa of adhesion strength. The adhesion strength with a variation of bond coat layer thickness is discussed in terms of coating parameters.