• 한국산학기술학회논문지
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• 제4권3호
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• pp.218-222
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• 2003

본 연구의 목표는 난연화를 위한 기존 공법의 단점 보완과 환경 친화적인 난연제를 사용한 비 난연 XLPE 케이블의 난연화 방법과 최적의 난연 코팅액 배합에 있다. 전력용, 통신용 둥과 같이 고난연성이 요구되는 경우 기존 컴파운드 방법으로는 난연제를 다량으로 첨가하여 사용하며, base polymer와의 혼합성, 기계적인 물성에도 영향을 끼쳐서는 안 되는 등 여러 가지 요구 조건을 만족시켜야 하는 문제점을 가지고 있다. 각 난연 코팅액에 따른 코팅 표면을 고찰한 결과 모든 코팅의 표면은 깨끗하였으며, 코팅층의 두께는 약 10-20㎛로 일정하게 코팅이 되었다. TBBA/Sb₂O₃, TBBA/Zinc Borate의 무게비(wt%)가 1:0.7 이상부터 난연 효과를 보였다. 또한 Mg(OH)₂/Zinc Borate의 경우는 무게비(wt％)가 1:0.5, 1:0.6에서 난연효과를 보였으나, 1:0.7 이상에서는 난연 효과가 떨어지는 현상을 보였다. Mg(OH)₂/AF100 S/Zinc Borate의 경우는 AF100 S의 첨가량이 증가할수록 난연성이 향상되었다. 난연 코팅액의 열 분해 거동을 비교한 결과, Mg(OH)₂/Zinc Borate의 경우 초기 분해 온도가 유기계 난연제를 사용하였을 경우보다 늦어졌으며, 최종 잔류 탄화물 양도 많이 생성되었다. Mg(OH)₂/AF100 S/Zinc Borate의 경우 난연 효과를 상승을 위해 인계 난연제(AF100 S)를 첨가하였으나. 오히려 초기 분해온도가 빨라졌으며 잔류 탄화물의 양도 적게 나타났다. 그러나 연소 테스트 결과 가장 우수한 난연 효과를 보였다.

• 한국재료학회지
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• 제27권4호
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• pp.221-228
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• 2017

Various morphologies of copper oxide (CuO) have been considered to be of both fundamental and practical importance in the field of electronic materials. In this study, using Cu ($0.1{\mu}m$ and $7{\mu}m$) particles, flake-type CuO particles were grown via a wet oxidation method for 5min and 60min at $75^{\circ}C$. Using the prepared CuO, AlN, and silicone base as reagents, thermal interface material (TIM) compounds were synthesized using a high speed paste mixer. The properties of the thermal compounds prepared using the CuO particles were observed by thermal conductivity and breakdown voltage measurement. Most importantly, the volume of thermal compounds created using CuO particles grown from $0.1{\mu}m$ Cu particles increased by 192.5 % and 125 % depending on the growth time. The composition of CuO was confirmed by X-ray diffraction (XRD) analysis; cross sections of the grown CuO particles were observed using focused ion beam (FIB), field emission scanning electron microscopy (FE-SEM), and energy dispersive analysis by X-ray (EDAX). In addition, the thermal compound dispersion of the Cu and Al elements were observed by X-ray elemental mapping.

• 한국기계가공학회지
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• 제20권4호
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• pp.94-105
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• 2021

A graphical user interface (GUI) program for steam tracing system selection was developed by using a theoretical model. We derived the model on the basis of the one-dimensional heat transfer theory of conduction and convection through a composite wall. Computational fluid dynamics (CFD) and experiments were performed for validation at steam temperatures of 120.4[℃] and 158.9[℃]. The temperature of a pipe's outer surface obtained through CFD matched well with that predicted by the proposed model for both conditions. By contrast, the experiment results showed a small error at 120.4[℃] and a large error at 158.9[℃] because of the melting of the heat transfer compound and water phase transition. Thus, the steam temperature range of the proposed model is below 120.4[℃].

• 대한전기학회:학술대회논문집
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• 대한전기학회 1999년도 하계학술대회 논문집 D
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• pp.1593-1595
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• 1999

Effects of carbon black species and concentration on the mechanical and electrical properties of alumina trihydrate filled EPDM compounds were investigated. Mechanical properties improved with increasing carbon black concentration, and these effects were prominent in carbon blacks haying large specific area. In the case of non-conductive carbon black. tracking resistance improved when a small amount of carbon black was added to EPDM. Conductive carbon black showed detrimental effect to dielectric losses, volume resistivity and tracking resistance of EPDM compound.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1999년도 하계학술대회 논문집 D
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• pp.1587-1589
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• 1999

초고압 XLPE(가교 폴리에틸렌) 절연 케이블의 절연사고를 방지하기 위해서는 여러열화 조건하에서 절연체의 수명을 예측하는 것과 아울러 절연체(XLPE)의 성능향상을 모색하는 것이 바람직하다. 이러한 노력의 일환으로 절연재료의 열화현상을 화학반응의 법칙으로 가정한 Arhenius 모델과 같은 열화이론이 확립되어지고 있다 하지만, 실제 케이블을 만드는 과정에서 절연체의 성형 조건에 따른 절연 성능 평가와 관련된 연구는 그렇게 많지 않다. 본 연구에서는 XLPE의 성형 조건(가교, 건조, 냉각)에 따른 화학적 물성의 변화와 절연성능 사이의 상관관계를 알아보기 위해 LDPE에 가교제(DCP)를 첨가한 컴파운드를 이용해 만든 몰드 시편의 물성을 DSC, 가교도 분석 및 전기 트리 개시 전압을 측정해 살펴보았다. 그 결과 가교나 건조 조건에 비해 냉각 조건에 따른 가교 폴리에틸렌의 결정화도가 트리 개시전압에 보다 큰 영향을 미침을 알 수 있었다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2008년도 Techno-Fair 및 추계학술대회 논문집 전기물성,응용부문
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• pp.167-168
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• 2008

The permeation of $Ca^{2+}$ ions through the materials such as polyvinyl chloride (PVC) and non-halogenated flame retardant cross linked polyolefin (FR-XLPO) used for CN-CV underground distribution power cable jackets was investigated. The permeation of $Ca^{2+}$ ions was found to increase with the increase of time. The FR-XLPO showed higher permeation of $Ca^{2+}$ ions, by a factor of about two, than the PVC. This was explained by the destruction of structural integrity caused by mixing a large amount of mineral flame retardant such as $Mg(OH)_2$ used to impart non-flame ability to the jacket material.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1995년도 추계학술대회 논문집
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• pp.289-292
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• 1995

In this experiment the specimen is selected for epoxy resin used in the molding compound materials for the power semiconductors. The specimen was divided into the two parts. one is a specimen without irradiation, the other is irradiated with electron beam, of which dose is 1[Mrad], 2[Mrad], 4[Mrad], 8[Mrad] and 24[Mrad], respectively. From the analysis for the physical properties of the specimen, the carbonyl group which is asffact the electrical properties is decreased according to increase the dose of the electron beam. In the measurement of dielectric characteristics among the electrical properties, the frequency dependance of the dielectric characteristics is confirmed that its ${\beta}$-peak is represented by one peak due to attribute to the main chain below 50[$^{\circ}C$], and two peak above the temperature 100[$^{\circ}C$].

• 대한전기학회:학술대회논문집
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• 대한전기학회 1998년도 추계학술대회 논문집 학회본부 C
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• pp.864-865
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• 1998

Permeation of $Ca^{2+}$ ions in PVC and flame-retardant polyolefin (FR) compounds for the sheath of medium voltage underground cables was studied. At $70^{\circ}C$ ion permeation increases fast at times of up to a few tens of hour and then at a relatively slow rate. The first fast increase was attributed to the diffusion of ions in the samples while the second slow increase of ion permeation was attributed to the permeation of $Ca^{2+}$ ions through the samples. It was also found that the diffusivity of $Ca^{2+}$ ions in FR compounds is much higher than that in PVC compounds.

• 한국전기전자재료학회논문지
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• 제15권8호
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• pp.687-694
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• 2002

In order to replace the jacket material for URD power cables, the 6 kinds of polyethylene compounds were manufactured and evaluated. The characteristics of the compounds were investigated by water vapor transmission (WVT) test, thermal and mechanical test. In WVT test, all the polyethylene compounds showed the superior water resistance to conventional PVC. The molecular structure and density of polyethylene play an important role in WVT. Also, the polyethylene compounds showed the suitable characteristics in thermal and mechanical test. Especially, the linear polyethylene compounds showed the superior characteristics to LDPE ones. Due to the fillers in compounds, the abrasion resistance was decreased and the cut-through resistance was increased. From this study, it can be considered that the polyethylene compounds may be suitable to jacket material for URD power cables.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2004년도 추계학술대회 논문집 Vol.17
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• pp.293-296
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• 2004

초고압 케이블의 절연물질로 널리 사용되고 있는 가교 폴리에틸렌의 전기적 특성은 라멜라 결정 조직의 밀도와 라멜라 조직의 성장방향과 밀접한 관련이 있는 것으로 알려지고 있다. 본 연구에서는 반도전 물질에 2종의 첨가제를 이용하여 처방한 3종의 반도전 컴파운드에 대하여 시편 제작 조건에 따른 미세 조직을 제어하여 폴리에틸렌의 미세 조직을 변화시킴으로써, 라멜라 조직이 전기적 특성에 미치는 영향을 분석하였다. 전기적 특성은 AC 절연파괴 전압을 측정하였으며, 미세 조직 변화를 조사하기 위하여 TEM 이미지 분석 통하여 라멜라 밀도를 통계적으로 정성 분석하여 상관관계를 규명하였다.