• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2009.11a
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• pp.157-157
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• 2009

다층카본나노튜브(MWCNT) 를 첨가한 전력케이블용 CNT 반도전 컴파운드를 용융혼합법을 사용하여 제조하였다. 카본나노튜브, 카본블랙, 분산제, 가교조제 함량변화에 따른 초고압 CNT 반도전 컴파운드의 특성을 조사하였다. 카본나노튜브 단독, 카본나노튜브와 전도성 카본블랙을 혼용함에 따른 상승효과, 분산제와 가교조제 사용에 따른 초고압 전력케이블용 CNT 반도전 컴파운드의 우수한 물성을 확인할 수 있었다.

• Elastomers and Composites
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• v.34 no.5
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• pp.391-398
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• 1999

Di-2-ethyl hexyl phthalate (DOP) and di-2-ethyl hexyl adiphate (DOA) were mixed with poly(vlnvl chlorides) [PVC] which have different degrees of polymerization (DP). Tensile strength, elongation, density, abrasion resistance, and hardness of these compounds were measured, High molecular weight PVC(DP 2500) was superior to that of DP 1300 for tensile strength, Hardness. But elongation and abrasion resistance of P1300 systems were better than those of P2500 systems. The densities of both systems were almost same. On the other hand, DOP Plasticized PVC was superior to DOA plasticized one for tensile strength, elongation, hardness. In cases of density, abrasion resistance, and flexual resistance, DOA systems were better than those of DOP systems.

• Polymer(Korea)
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• v.35 no.3
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• pp.228-231
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• 2011

The rate of vulcanization of nonpolar ethylene-propylene-diene terpolymer(EPDM)/carbon black compounds was investigated by using hot air and microwave as a heating source. The present study parameters such as heating source, sample thickness, and loading of an additive. The compound thickness was the main factor in the hot air vulcanization. It was due to the poor thermal conductivity of EPDM; that is, the thicker thickness, the lower vulcanization rate. For 100% vulcanization, the compound with 3 mm thickness required 7 min at $250^{\circ}C$ in the hot air system. However, the vulcanization of EPDM compounds by microwave system was not affected by the thickness while strongly dependent on the amount of a polar additive, carbon black. A compound with 80 phr of carbon black was perfectly vulcanized within 30 sec. These results suggest that the use of microwave as a heating source is an effective method for the vulcanization of compounds including a polar component.

• Elastomers and Composites
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• v.44 no.4
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• pp.401-407
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• 2009

Commercial grades of solution styrene-butadiene rubbers extended with high aromatic oils having high polycyclic aromatic compounds (PCA) and low PCA oils were used to study the effect of the processing oil particularly on the crack propagation resistance and frictional wear resistance of the vulcanizates. The aromatic oil based vulcanizates exhibited superior fracture behavior over the low PCA oil extended vulcanizates based on tensile and trouser tear tests. Compounds with aromatic oil showed superior crack propagation resistance compared with those containing low PCA oil, especially at the lower ranges of tearing energy. In terms of frictional wear resistance, the aromatic oil extended compounds showed superior performance particularly in the lower frictional work ($W_f$) range but in the higher $W_f$ range the low PCA oil extended vulcanizates performed better.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.12 no.9
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• pp.4261-4266
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• 2011

Polypropylene (PP)/talc compounds with talc content of 20wt% were fabricated by master-batch (MB) and direct compounding method using injection molding. The MB was prepared by mini compounder at $200^{\circ}C$ and the content of talc was 50wt%. The talc dispersion of the PP/talc compound was investigated by SEM-EDS. The talc was well dispersed within PP matrix in case of the MB-PP compound using MB. The rheological properties of the PP/talc compounds were measured by dynamic Rheometer. The MB-PP compound indicates higher shear thinning and elastic property than direct compound. The disperion of talc was certified by G'-G" plot, and Van Gurp-Palmen analysis was applied in order to certify an increase in elasticity.

• Composites Research
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• v.28 no.6
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• pp.389-394
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• 2015

The sound absorption coefficient and sound transmission loss of graphite intercalation compound (GIC) included epoxy composites were investigated. Epoxy resin was infused into the expanded GIC and the impedance tube method was employed to measure the sound absorption coefficient and sound transmission loss. Scanning electron microscopy photographs showed uniform distribution of the GIC in the epoxy matrix. The surface density of epoxy/GIC (20 wt%) composites decreased about 56% compared to that of pure epoxy. The sound absorption coefficient of composites increased about 3 times at the frequency range of 500~1000 Hz compared to the pure epoxy. The sound transmission loss of composites decreased with increasing the GIC content and it is attributed to the increase of pores in the composites.

• Journal of the Korean Magnetics Society
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• v.11 no.4
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• pp.157-162
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• 2001

Rheological characteristics of Sm-Co type plastic magnet compound for powder injection molding process were investigated with the variation of the magnetic powder size, their relative contents and volume fraction using the mixture of fine and coarse powder. Shear viscosity of Sm-Co type compound was decreased with increasing the size of coarse powder due to the increase of powder packing density. However, the smaller the average size of fine powder resulted in the higher viscosity of compound due to the increase of agglomeration force. In case of mechanically milled Sm-Co type powder, the viscosity of compound with the mixture of coarse powder of 125∼75 ㎛ and fine powder of average size of 4.9 ㎛ greatly depends on their relative contents and shows a minimum value at the 60 % coarse powder fraction. This means that the compound shows a maximum packing density at the 60% coarse powder fraction. Compound viscosities satisfied well the rheological model with the volume fraction of magnetic powder, and maximum volume fraction of magnetic powder in Sm-Co type compound for powder injection molding was about 66%.

• Elastomers and Composites
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• v.47 no.1
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• pp.54-64
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• 2012

Acrylonitrile was introduced in the emulsion SBR to increase compatibility between silica and rubber. AN-SBR/silica compounds showed faster vulcanization time and higher delta torque values than SBR 1721/silica compounds because interaction between nitrile group of AN-SBR and silanol group on the silica surface could make hydrogen bond that prevented adsorption of the accelerator on the silica surface, which improved the vulcanization reaction efficiency and enhanced the degree of crosslinking. AN-SBR/silica compound showed higher values in minimum torque than SBR 1721/silica compound during the vulcanization because AN-SBR has higher molecular weight than SBR 1721 in the raw material. When PEG was added to the SBR 1721 and AN-SBR compounds, vulcanization time was faster than SBR 1721 and AN-SBR compounds without PEG because PEG has a large number of ether linkages which show high compatibility with silanol group on the silica surface that prevented the adsorption of the accelerator and the ingredients on the silica surface, which improved the vulcanization reaction efficiency. In the mechanical properties, AN-SBR compounds showed higher modulus values at 100%, 300% than SBR 1721 compounds because interaction between nitrile group of AN-SBR and silanol group on the silica surface enhanced the degree of crosslinking. In the dynamic properties, AN-SBR compounds showed lower tan ${\delta}$ values at $0^{\circ}C$ than SBR 1721 compounds in accordance with the $T_g$ values. AN-SBR compounds showed lower tan ${\delta}$ values at $60^{\circ}C$ than SBR 1721 compounds because interaction between acrylonitrile and silica caused strong filler-rubber interaction that induced low energy dissipation by the filler-filler interaction.

• Elastomers and Composites
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• v.44 no.1
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• pp.47-54
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• 2009

EPDM(Ethylene-propylene-diene-terpolymer) compound reinforced with carbon black having four different particle size, acetylene black(thermal conductivity carbon black), and silica were manufactured by internal mix and open mill. To investigate the effect of particle size of filler and filler type on far-infrared vulcanization, intermal temperature of compound, degree of curing, infrared spectroscopy, and thermal analysis were measured. The thermal conductivity of far-infrared vulcanized EPDM compound increased with increasing particle size of carbon filler, but hot air vulcanized EPDM compound is not affected by particle size. The thermal conductivity was increased in the order of carbon black < silica < acetylene black(thermal conductivity carbon black).

• Proceedings of the KIEE Conference
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• 1997.07d
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• pp.1615-1617
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• 1997

절연재료로서 널리 쓰이는 XLPE(Crosslinked Polyethylene)의 경우, 내부에 발생하는 수트리에 의해 절연체로서의 성능 및 내구성이 많은 영향을 받게 된다. 이에 대한 연구가 진행되어 왔지만 수트리 발생과 진행에 관한 메커니즘은 아직까지 정확하게 알려지지 않은 상태이다. 이 논문에서는 몇 가지의 수트리 억제 컴파운드를 선정하여 시간과 온도에 따른 수트리 발생을 관찰하고, 컴파운드 내의 공간전하 및 전도전류가 수트리 억제에 미치는 영향을 조사하였다. 수트리가속을 위하여 주파수가속열화 방법을 사용하고 온도와 시간에 따른 발생 및 진전을 관찰하였다. 실험에서는 압축성형된 평판형 시편을 사용하였으며 상부전극으로는 $AgNO_3$ 수용액을, 하부전극으로는 금속전극을 사용하였다. 그리고 컴파운드 내부의 공간전하 분포 및 전도전류 측정을 하기위해 PEA(Pulsed Electro Acoustic) 방법을 이용하였다.