• Title/Summary/Keyword: 캐스트필름

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Study on Poly(triazine bissulfide)s Derivatives being the Synthesized Optical Plastic Material (합성한 광학플라스틱 재료인 Poly(triazine bissulfide)s 유도체에 대한 연구)

  • Lee, Y.H.;Lee, D.H.;Kim, J.J.;Ha, T.W.;Cha, J.W.
    • Journal of Korean Ophthalmic Optics Society
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    • v.9 no.2
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    • pp.481-489
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    • 2004
  • Poly(triazine bissulfide)s were synthesized from 6-dibutylamino-1,3,5-triazine-2,4-dithiol with bis(4-chloro-3-nitrophenyl)sulfone in the presence of the phase transfer catalyst, and from m-dibromide xylene and p-dibromide xylene with 6-dibutylamino-1,3,5-triazine-2,4-dithiol in the presence of cetyltrimethyl ammonium bromide at $70^{\circ}C$ for 24h. We could acquire the good results about solubility, thermal property, and molecular weight to make cast film. These results are important as base for the synthesis of functionalization polymer material being optical plastic material. The maximum algebra viscosity was 0.57~1.40dl/g at the temperature more than $50{\sim}60^{\circ}C$.

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Synthesis and Properties of Block Copolymer Comprising of Poly(DL-lactic acid) and Poly(ethylene oxide) (Poly(DL-lactic acid)/Poly(ethylene oxide)을 포함한 블록공중합체의 합성 및 특성)

  • 이찬우;배기서
    • Polymer(Korea)
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    • v.26 no.5
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    • pp.582-588
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    • 2002
  • The block copolymers were prepared by the ring opening polymerizati on of DL-lactide by poly(ethylene oxide) (PEO) with diethylzinc (ZnE$_2$) as a catalyst. When the feed ratio of PEO was over 30% relative to DL-lactide, the polymerization of DL-lactide took place from the PEO hydroxyl terminals to provide the desired A -B-A or A-B block copolymer. The block copolymers were made of films by cast method and the films obtained was drawn to 2.5 times at 60 $\^{C}$. At the same draw ratio, the tensile modulus of the films was decreased with increasing PEO content in the block copolymers. It was therefore suggested that the block copolymers comprising of PDLLA and PEO, had high potentials as the biomaterials with improved flexibility.

Investigation of Physical Properties and Self Healing of Hardener-Free Epoxy-Modified Mortars with GGBFS (고로슬래그미분말을 혼입한 경화제 무첨가 에폭시수지 모르타르의 물리적 성질 및 자기치유 검토)

  • Jo, Young-Kug;Kim, Wan-Ki
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.1
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    • pp.80-87
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    • 2020
  • The purpose of this study is to investigate the physical properties and self-healing effects of hardener-free epoxy-modified mortars(EMMs) using ground granulated blast furnace slag(GGBFS). The EMMs with GGBFS were prepared with various polymer-binder ratios and GGBFS contents, and tested for strengths, adhesion in tension, water permeation and self-healing effects. The conclusions obtained from the test results are summarized as follows. The compressive strength of the EMMs with GGBFS is reduced with increasing polymer-binder ratios because of reduction of the degree of hardening in the EMMs, and is somewhat inferior to that of unmodified mortars. In the flexural and tensile strengths, the flexural strength of the EMMs is almost constant with increasing polymer-binder ratios. However, the tensile strength of the EMMs is gradually increased with increasing polymer-binder ratios. Regardless of the GGBFS contents, the adhesion in tension of the EMMs increases sharply with increasing polymer-binder ratios. The water permeation of the EMMs is remarkably reduced with increasing polymer-binder ratios and GGBFS contents. The self-healing effect of the hardener-free EMMs with GGBFS is improved with increasing water immersion period at a GGBFS content of 20%.