• Textile Coloration and Finishing
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• v.26 no.2
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• pp.71-78
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• 2014

This review paper is a state of the art report of the development of high performance nano-composites with carbon nanotube. We investigate the research and development (R&D) trends of high performance nano-composites with carbon nanotube by analyzing technical trends in research institutes and industry. We report the R&D and technology trends for the properties and applications of fabrication of hybrid composites with aligned carbon nanotubes, multifunctional fiber/carbon nanotube composites. We discuss the specific topics including unidirectional carbon nanotube, carbon nanotube forests, transfer-printing carbon nanotube technology, deposition of carbon nanotube by electrophoresis, vapor grown carbon fiber (VGCF), cup-stacked carbon nanotube, bucky paper and carbon nanotube yarns in this review paper.

• Composites Research
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• v.32 no.5
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• pp.296-300
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• 2019

Two dimensional transition metal carbides and/or nitrides, known as MXenes, are a promising electrode material in energy storage due to their excellent electrical conductivity, outstanding electrochemical performance, and abundant functional groups on the surface. Use of $Ti_3C_2$ as electrode material has significantly enhanced electrochemical performance by providing more chemically active interfaces, short ion-diffusion lengths, and improved charge transport kinetics. Here, we reports the efficient method to synthesize $Ti_3C_2$ from MAX phase, and opens new avenues for developing MXene based electrode materials for Lithium-Ion batteries.

• Composites Research
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• v.18 no.3
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• pp.7-13
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• 2005

This paper presents a study on the low velocity impact response of the woven fabric laminates for the hybrid composite bodyshell of a tilting railway vehicle. In this study, the low velocity impact tests for the three laminates with size of $100mm\times100mm$ were conducted at three impact energy levels of 2.4J, 2.7J and 4.2J. Based on the tests, the impact force, the absorbed energy and the damaged area were investigated according to the different energy levels and the stacking sequences. The damage area was evaluated by the visual inspection and the C-scan device. The test results show that the absorbed energy of [fill]8 laminate is highest whereas (fill2/warp2)s is lowest. The [fill]8 laminate has the largest damage area because of the highest impact energy absorption.

• Composites Research
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• v.19 no.1
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• pp.29-35
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• 2006

The avoidance of enemy's radar detection is very important issue in the modem electronic weapon system. Researchers have studied to minimize reflected signals of radar. In this research, two types of radar absorbing structure (RAS), 'C'-type shell and 'U'-type shell, were fabricated using fiber-reinforced composite materials and their radar cross section (RCS) were evaluated. The absorption layer was composed of glass fiber reinforced epoxy and nano size carbon-black, and the reflection layer was fabricated with carbon fiber reinforced epoxy. During their manufacturing process, undesired thermal deformation (so called spring-back) was observed. In order to reduce spring-back, the bending angle of mold was controlled by a series of experiments. The spring-back of parts fabricated by using compensated mold was predicted by finite element analysis (ANSYS). The RCS of RAS shells were measured by compact range and predicted by physical optics method. The measured RCS data was well matched with the predicted data.

• Korean Journal of Materials Research
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• v.30 no.10
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• pp.522-532
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• 2020

Conductive polymer composites with high electrical and mechanical properties are in demand for bipolar plates of phosphoric acid fuel cells (PAFC). In this study, composites based on natural graphite/fluorinated ethylene propylene (FEP) and different ratios of carbon black are mixed and hot formed into bars. The overall content of natural graphite is replaced by carbon black (0.2 wt% to 3.0 wt%). It is found that the addition of carbon black reduces electrical resistivity and density. The density of composite materials added with carbon black 3.0 wt% is 2.168 g/㎤, which is 0.017 g/㎤ less than that of non-additive composites. In-plane electrical resistivity is 7.68 μΩm and through-plane electrical resistivity is 27.66 μΩm. Compared with non-additive composites, in-plane electrical resistivity decreases by 95.7 % and through-plane decreases by 95.9 %. Also, the bending strength is about 30 % improved when carbon black is added at 2.0 wt% compared to non-additive cases. The decrease of electrical resistivity of composites is estimated to stem from the carbon black, which is a conductive material located between melted FEP and acts a path for electrons; the increasing mechanical properties are estimated to result from carbon black filling up pores in the composites.

• Journal of Adhesion and Interface
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• v.10 no.2
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• pp.90-97
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• 2009

Dispersion and self-sensing evaluation for single-carbon fiber reinforced in three different acid-treated CNT-epoxy nanocomposites were investigated by electro-micromechanical techniques and wettability tests. Self-sensing based on contact resistivity exhibited more noise for single carbon fiber/acid-treated CNT-epoxy composites than it did for untreated CNT. However, the apparent modulus was higher the acid treated case than the untreated case which is attributed to better stress transfer. The interfacial shear strength (IFSS) between carbon fibers and the CNT-epoxy was lower than that between carbon fiber and neat epoxy due to the increased viscosity associated with the addition of the CNT. The CNT-epoxy nanocomposite exhibited more hydrophobicity than did neat epoxy. Change in the thermodynamic work of adhesion was consistent with changes in the IFSS but disproportional to that of the apparent modulus. The optimum condition of acid treatment on the need can be obtained instead of the maximum condition.

• Composites Research
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• v.33 no.5
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• pp.296-301
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• 2020

Laminated composite materials have excellent in-plane properties, but are vulnerable in thickness directions, making it easy to delamination when bending and torsion loads are applied. Thickness directional reinforcement methods of composite materials that delay delamination include Z-pinning, Stitching, Tufting, etc., and typically Z-pinning and Stitching method are commonly used. The Z-pinning is reinforcement method by inserting metal or carbon pin in the thickness direction of prepreg, and the conventional stitching process is a method of reinforcing the mechanical properties in the thickness direction by intersecting the upper and lower fibers on the preform. In this paper, I-fiber stitching method, which complement and improve weakness of Z-pinning and Stitching method, was proposed, and the static strength of composite single-lap joints using I-fiber stitching process were evaluated. The single-lap joints were fabricated by a co-curing method using an autoclave vacuum bag process. The thickness of the composite adherend was fixed, and 5 types of specimens were manufactured with varying the stitching pattern (5×5, 7×7) and angle (0°, 45°). From the test, the failure load of the specimen reinforced by the I-fiber stitching process was increased by up to 143% compared to that of specimen without reinforcement.

• Journal of the Korean Society of Safety
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• v.19 no.4 s.68
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• pp.31-35
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• 2004

The A17075/CFRP multi-layered hybrid laminate material consists of the alternating A17075-T6 sheets and carbon/epoxy prepregs of M40 fade. The influence of volume fraction and fiber orientation of A17075/CFRP layer on flexural properties of A17075/CFRP laminate alternating A17075-T6 and carbon/epoxy prepreg was investigated. The results obtained from the experimental analysis are as follows: 1. In the $0^{\circ}$ fiber orientation, the mont of increase of the flexural rigidity was $20.5\%$ at the $26.5\%$ volume fraction and $38.0\%\;at\;the\;35.7\%$ volume fraction compared with the flexural rigidity level(20.0GPa) of the $10\%$ volume fraction of CFRP. 2. In the $\pm45^{\circ}$ fiber orientation the amount of decrease of the flexural rigidity was $23.5\%\;at\;the\;20.0\%$ volume fraction and $31.5\%\;at\;the\;33.3\%$ volume fraction compared with the flexural rigidity level of the $10\%$ volume fraction of CFRP. 3. In the $0^{\circ}$ fiber orientation, the flexural strength was 481.5MPa at the $10\%$ volume fraction of CFRP and 583.8MPa at the $26.5\%$ volume fraction and 653.7MPa at the $35.7\%$ volume faction. 4. In the $\pm45^{\circ}$ fiber orientation, the flexural strength was 354.0MPa at the $20.0\%$ volume fraction of CFRP and 340.5MPa at the $33.3\%$ volume fraction.

• Elastomers and Composites
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• v.38 no.4
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• pp.326-333
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• 2003

Even though many studies have been reported about rubber vulcanization, it is still remained difficult to find a quantitative relationship between the final states of vulcanized rubber and initial formulation or processing conditions. Dynamic differential scanning calorimetry (DSC) method is known as a comparatively easy method to research for the rubber vulcanization in both experimental and analysis. In the present research, a study on the vulcanization reaction of NR/CB composites modified by isoprene(IR) and chloroprene(CR) rubbers is carried out using dynamic DSC method. Thermograms with several different heating rates were obtained and analyzed using the Kissinger method. Analysis showed that the vulcanization reaction was progressed through the first order reaction mechanism. In addition, the reaction temperature was severely influenced by the kinds or rubber modifiers, in this case, more influenced by CR than by IR. Those effects were clearly verified in the values of activation energy. Kinds of carbon blacks, however, could hardly influence on the reaction mechanism.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.37 no.1
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• pp.1-8
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• 2013

Coolant rubber hoses for automotive radiators can degrade under thermal and mechanical loadings and thus fail owing to the influences of locally formed electricity. In this study, an advanced test method was developed to simulate the failure of a rubber hose. The aging behavior of carbon-black-filled ethylene-propylene diene monomer (EPDM) rubber used as a radiator hose material under a combination of electrochemical stresses and tensile strain was analyzed. The changing behaviors of the current and the resistance as a function of the aging time were analyzed in consideration of the tensile strain, voltage, and aging temperature. Sectioned specimens clarified the failure mechanisms of the aged skin layer under the combined electrochemical stresses.