• Title/Summary/Keyword: 침적율

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Temperature Dependence of Cr Impurity in La0.6Sr0.4Ti0.3Fe0.7O3-δ Coated Ba0.5Sr0.5Co0.8Fe0.2O3-δ Ion Conducting Membrane for oxygen Separation (산소 분리를 위한 La0.6Sr0.4Ti0.3Fe0.7O3-δ가 코팅된 Ba0.5Sr0.5Co0.8Fe0.2O3-δ 이온전도성 분리막에서 Cr 불순물의 온도 의존성)

  • Park, Yu Gang;Park, Jung Hoon
    • Korean Chemical Engineering Research
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    • v.57 no.1
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    • pp.11-16
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    • 2019
  • $La_{0.6}Sr_{0.4}Ti_{0.3}Fe_{0.7}O_{3-{\delta}}$(LSTF) coated $Ba_{0.5}Sr_{0.5}Co_{0.8}Fe_{0.2}O_{3-{\delta}}$(BSCF) membranes which has properties of high oxygen permeability and stability to $CO_2$ were applied to a bench scale apparatus to conduct oxygen permeation experiments. Also, the membranes of the laboratory and the bench scale device were divided into three regions according to the temperature gradient in the membrane reactor for comparative analysis. While oxygen permeation experiment were conducted up to $900^{\circ}C$, temperature dependence of Cr deposition was investigated. As a result, it was confirmed that the oxygen permeability was $2.37ml/min{\cdot}cm^2$, which was significantly lower than $3.79ml/min{\cdot}cm^2$ measured in the laboratory apparatus. It was found through XRD and SEM/EDS analysis that the decrease in oxygen permeability was originated from the deposition of gaseous Cr on the membrane surface released from the alloy material of the housing. In particular, a large amount of Cr was found in the medium temperature region.

A Practical Methodology for Determination of Derived Intervention Levels on Relocation Following a Nuclear Accident (원자력 사고후 주민의 이주를 위한 유도개입준위 산정의 실용적 방법론)

  • Hwang, Won-Tae;Kim, Eun-Han;Suh, Kyung-Suk;Jeong, Hyo-Joon;Han, Moon-Hee;Lee, Chang-Woo
    • Journal of Radiation Protection and Research
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    • v.29 no.2
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    • pp.91-96
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    • 2004
  • A practical methodology for the determination of derived intervention levels (DILs) on relocation following an accidental release of radionuclides was designed based on dose rate on the ground. The influence of DILs was investigated with respect to the change of parameter values, which are dependent on socio-environmental characteristics in distinction from temporary and permanent relocations. The DILs on relocation showed a distinct difference depending on effective removal half-life of radionuclides following a deposition, delay time in measurement and residential characteristics. In particular, the delay time. In measurement was an important factor in determination of DILs in the case of an assumption that dose rate on the ground declines in a power function, not in an exponential function. The DILs showed lower numerical values as longer effective half-life, longer delay time In measurement and longer exposure time.

Characteristics of flowering, fruit setting and propagation of Callistemon citrinus (Curt.) Skeels (병솔꽃나무(Callistemon citrinus (Curt.) Skeels)의 개화결실 및 증식특성)

  • 김찬수;정은주;김지은;소인섭
    • Korean Journal of Plant Resources
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    • v.15 no.2
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    • pp.107-113
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    • 2002
  • This study was performed to obtain the information on fruit set, propagation and flowering habits of the exotic ornamental bottle brush tree (Callistemon citrinus). Trees have fruit capsules for four years since the fruit set and they have enlarged for three years. While 2 and 3-year-old capsules have similar seeds in number and size, 1-year-old ones have fewer and smaller seeds. Most dried capsules open when they have 75% relative water contents. Two year old seeds which they were dried at 30% germinated better than others. Removal of capsule bearing twigs resulted in greatly increased subsequent flower numbers (an average of 14 flowers per tree) compared with twigs where seed capsule were allowed to remain. In cutting for propagation, semi-hard wood branches dipped in 100mgι$^{-1}$ IBA for 24 hours rooted at 86.4 % and had an average of 12.6 primary roots.

Design and Characterization of Ascorbyl Glucoside loaded Solid Lipid Nanoparticles to improve skin penetration (피부 투과 개선을 위한 고형지질나노입자내 Ascorbyl glucoside 봉입 설계 및 특성화)

  • Yeo, Sooho
    • Journal of the Korean Applied Science and Technology
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    • v.38 no.3
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    • pp.662-668
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    • 2021
  • The aim of the present study was to design ascorbyl glucoside (AG) loaded solid lipid nanoparticles (SLNs) to improve skin penetration of AG. AG loaded SLNs were prepared using double emulsion method. The prepared AG loaded SLNs investigated particle characteristics (particle size, polydispersity index, zeta potential, loading capacity). Skin penetration study was carried out using SkinEthic RHE as one of the reconstructed human epidermis models. The mean particle size and zeta potential of SLNs were 172.65 - 347.19 nm and -22.90 - -41.20 mV, respectively. The loading capacity of AG loaded SLNs demonstrated that loading efficiency and loading amount were ranged from 44.18% to 57.77% and 12.83% to 16.15%, respectively. The results of penetration showed that all SLNs enhanced the skin penetration of AG and the amount of AG from SLNs were approximately 3.7 - 7.4 times higher than that from AG solution. Therefore, AG loaded SLN might be a promising topical drug delivery system.

Effects of NAA on Stem Cuttings of Varigated Aster glehni, Achillea sibirica and Solidago virga-aurea var. asiatica Nativ to Korea (한국자생 변이종 섬쑥부쟁이, 톱풀 및 미역취의 줄기 삽목시 발근에 미치는 NAA의 효과)

  • Lee, Jong-Suk
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.3 no.3
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    • pp.8-11
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    • 2000
  • The experiment was carried out in order to the effects of NAA on rooting of stem cutting of leaf variegated Aster glehni, dwarf type of Achillea sibirica and Solidago virga-aurea var. asiatica native to Korea. Higher rooting percentage(85%) of Aster glehni, promoted root number and root length of Achillea sibirica were obtained by basal dip treatment with $1,000mg{\cdot}L^{-1}$ NAA for 3 hours on late June. Percent rooting of the Solidago was not enhanced, but root number and root length were promoted by basal dip treatment with $100mg{\cdot}L^{-1}$ NAA.

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경수로 원자로 냉각재 CRUD 대표시료 채취 기술에 관한 고찰

  • Kim, Min-Jae;Kim, Jong-Bin;Gang, Deok-Won;Park, Jong-Seok
    • 대한방사선방어학회:학술대회논문집
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    • 2009.04a
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    • pp.254-255
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    • 2009
  • 국내 경수로 원전의 경우, 원전의 효율적, 경제적 운영차원에서 장주기 운전으로 패턴을 바뀌면서 핵연료봉 표면상에 크러드(crud)의 침적량은 점점 증가하는 경향을 나타내고 있다. 이러한 경향은 원자로의 출력 제어와 직결되면서 이에 대한 문제 해결을 위한 대표성이 있는 시료의 채취와 재현성이 있는 부식 생성물의 측정이 요구되어져 왔다. 원자로 계통 내에서 부식생성물의 농도변화에 대한 평가, 특히 입자농도가 증가되어지면 축방향 출력편차(Axial Offset Anomaly, AOA)가 발생될 수 있는 위험에 노출되거나, 핵연료 교체를 위해 발전소 정지시(shut down) 부식생성물의 방출이 급격히 증가되는 것으로 나타났다. 특히 입자성을 띤 물질은 존재의 특성상 이들 물질에 대한 대표시료의 채취가 어려울 뿐 아니라 grab 채취로 인해, 분석결과에 대한 재현성이 낮으며 계통 선량율의 제어와 작업자 피폭관리에 많은 어려움이 뒤따르고 있어 선진 원전 운영국에서는 앞 다투어 대표시료를 채취 할 수 있는 capillary sampling 법이나 integrated sampling법을 적용해 오고 있다. 본 논문에서는 국내 경수로 원전에서 일반적으로 사용하고 있는 grab sampling 법에 대한 문제점 파악과 해외 원전에서 사용 중인 capillary sampling 법의 국내 적용 가능성에 대해 살펴보았다.

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Growth and Optimal Environment Factors of Cockle Shell, Anadara granosa bisenensis, Spat in Laboratory Culture (실험실 사육에 의한 고막, Anadara granosa bisenensis 치패의 적정 환경요인 및 성장)

  • 강경호;박형욱;김재민
    • The Korean Journal of Malacology
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    • v.16 no.1_2
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    • pp.25-29
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    • 2000
  • In order to investigate the optimal environment factor for growth of the cockle shell, Anadara granosa bisenensis, tolerance experiment to the water temperature and salinity have been conducted. In the tolerance experiment to the temperature A. granosa bisenensis survived a very wide range from 3$^{\circ}C$ to 33$^{\circ}C$, but their survival rate was lower at higher water temperature up to 35$^{\circ}C$. In the case of salinity their tolerance range was from 0$\textperthousand$ to 100$\textperthousand$ and showed higher survival rate at lower salinity. Growth in shell length and total weight of the spat at the end of the rearing experiment was 13.17${\pm}$0.98 mm and 0.69${\pm}$011 g.

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Preparations and characteristics of the ceramic balls for heavy metals absorption and antibacterial activities in the drinking water (음용수중의 중금속흡착과 항균성용 세라믹 볼의 제조 및 특성평가)

  • Park, Chun-Won;Park, Ra-Young;Park, Sun-Min
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.15 no.6
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    • pp.263-268
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    • 2005
  • The ceramic balls impregnated with $20{\sim}40nm$ sized Ag colloid were examined for heavy metals absorption and antibacterial activities in the drinking water. The preparation conditions of ceramic ball that the porosity was excellent were as follows: starting material: 85 wt% $Ca_{10}(PO_4)_6(OH)_2$, binder: 5 wt% PVA and 15 wt% ${\alpha}-Ca_3(PO_4)_2$, heating temperature: $1000^{\circ}C$, duration: 3 hrs. The ceramic balls obtained under these conditions showed specific surface area of $110m^2/g$, pore size of $120{\mu}m$ and porosity of 80%. Also, as the results of a performance test on a rate of adsorbing and removing heavy metals in the drinking water by using the.AAS, heavy metals such as Zn, Mn, Fe and Cu were removed to the extent that their content became 0.03mg/l or lower after 1 day and they showed an excellent bactericidal activity that all coliforms were killed after 3 hrs.

Preparation of PVA/PAM/Zirconium phosphate Membrane for Proton Exchange Membranes (양이온교환용 PVA/PAM/Zirconium phosphate 막의 제조)

  • 임지원;황호상;김영진;남상용
    • Membrane Journal
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    • v.14 no.2
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    • pp.117-125
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    • 2004
  • Proton exchange membrane composed of PVA/PAM/ZrP was prepared and effect of PAM and ZrP contents on properties and performance of the membrane were investigated. PAM as a crosslinking agent was mixed into PVA solution with different concentration (7∼11 wt%) and the PVA/PAM solution was cast to prepare PVA/PAM crosslinked membrane. The membrane was treated in the solution of zirconyl chloride and phophoric acid to make a PVA/PAM/ZrP composite membrane. Methanol permeability, ion conductivity, swelling and ion exchange capacity of the membranes with different ZrP concentration were $10^{-8}∼l0^{-6}$ $\textrm{cm}^2$/sec, $10^{-3}~10^{-2}$ S/cm, 0.26∼1.17 g $H_2O$/g membrane and 2.59∼5.1 meq/g membrane, respectively. Hethanol permeability and ion conductivity of the PVA/PAM/ZrP membrane were improved by 18% and 23%, respectively, compared to those of the PVA/PAM membrane.

A Study on the Catalytic Reduction of Carbon Dioxide by Methane (메탄에 의한 이산화탄소의 환원반응에 관한 연구)

  • Hong, Seong-Soo;Yang, Jin-Seop;Kim, Byung-Kee;Ju, Chang-Sik;Lee, Gun-Dae
    • Applied Chemistry for Engineering
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    • v.8 no.4
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    • pp.685-693
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    • 1997
  • We have studied the reforming of carbon dioxide with methane over various supported nickel catalysts. The nickel supported on natural zeolite showed the highest activity and the nickel on acidic support showed higher activity and slow deactivation compared to nickel on basic support. The activity of nickel on natural zeolite increased with increasing loading ratio and showed almost constant activity above 10wt.% loading of nickel. The conversion and yield of products were affected by the mole ratio of reactants and the highest yields of CO and $H_2$ were obtained at $CH_4/CO_2=1$. The deactivation of catalyst was caused by deposition of coke which was formed by the decomposition of methane. The shape of coke was shown to be whisker tripe carbon, and it brought out the slow deactivation of catalyst.

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