• 제목/요약/키워드: 친환경 화학

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Electrochemical properties of AZ31, AZ61 magnesium alloy electrodes for eco-friendly Magnesium-air battery (친환경 마그네슘-공기 전지용 AZ31, AZ61 마그네슘 합금 전극의 전기화학적 특성)

  • Choi, Weon-Kyung
    • Journal of the Korea Convergence Society
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    • v.12 no.5
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    • pp.17-22
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    • 2021
  • Eco-friendly magnesium-air battery is a kind of metal-air battery known as a primary battery with a very high theoretical discharge capacity. This battery is also called a metal-fuel cell from the viewpoint of using oxygen in the atmosphere as a cathode active material and magnesium alloy as a fuel. Since battery performance is determined by the properties of the magnesium alloy used as a anode, more research and development of the magnesium alloy electrode as a anode material are required in order to commercialize it as a high-performance battery. In this study, the commercialized magnesium alloys(AZ31, AZ61) were selected and then electrochemical measurements and discharge test were conducted. Electrochemical properties of magnesium alloys were investigated by OCP changes, Tafel parameters and CV measurement, and the feasibilities of AZ61 alloy with excellent discharge capacity(1410mAhg-1) as electrode materials were evaluated through CC discharge experiments.

Development of Pore-Filled Anion-Exchange Membranes for High Performance Reverse Electrodialysis (고성능 역전기투석을 위한 세공충진 음이온교환막의 개발)

  • Kim, Do-Hyeong;Song, Hyeon-Bee;Yoon, Kyungseok;Kang, Moon-Sung
    • Membrane Journal
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    • v.32 no.5
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    • pp.336-347
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    • 2022
  • Reverse electrodialysis (RED) is one of the promising eco-friendly renewable energy technologies which can generate electricity from the concentration difference between seawater and freshwater by using ion-exchange membranes as a diaphragm. The ion-exchange membrane is a key component that determines the performance of RED, and must satisfy requirements such as low electrical resistance, high permselectivity, excellent durability, and low manufacturing cost. In this study, pore-filled anion-exchange membranes were fabricated using porous polymer substrates having various thicknesses and porosity, and the effects of ion-exchange polymer composition and membrane thickness on the power generation performance of RED were investigated. When the electrical resistance of the ion-exchange membrane is sufficiently low, it can be confirmed that the RED power generation performance is mainly influenced by the apparent permselectivity of the membrane. In addition, it was confirmed that the apparent permselectivity of the membranes can be improved through IEC, crosslinking degree, membrane thickness, surface modification, etc., and the optimum condition must be found in consideration of the trade-off relationship with electrical resistance.

Understanding Thermodynamics of Operating Voltage and Efficiency in PEM Water Electrolysis System for Carbon Neutrality and Green Hydrogen Energy Transition (탄소중립과 그린 수소에너지 전환을 위한 PEM 수전해 시스템에서 작동 전압 및 효율의 열역학적 이해)

  • HyungKuk Ju;Sungyool Bong;Seungyoung Park;Chang Hyun Lee
    • Journal of the Korean Electrochemical Society
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    • v.26 no.4
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    • pp.56-63
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    • 2023
  • The development of renewable energy technologies, such as solar, wave, and wind power, has led to the diversification of water electrolysis technologies, which can be easily coupled with renewable energy sources in terms of economics and scale. Water electrolysis technologies can be classified into three types based on operating temperature: low-temperature (<100 ℃), medium-temperature (300-700 ℃), and high-temperature (>700 ℃). It can also be classified by the type of electrolyte membrane used in the system. However, the concepts of thermodynamic and thermo-neutral voltages calculations and are very important factors in the evaluation of energy consumption and efficiency of water electrolysis technologies, are often confused. This review aims to contribute to a better understanding of the calculation of operating voltage and efficiency of PEM water electrolysis technologies and to clarify the differences between thermodynamic voltage and thermo-neutral voltage.

Control of Powdery Mildew on Cucumber by Using Oleic Acid in the Greenhouse (올레산을 이용한 오이의 흰가루병 방제)

  • Lee, Moon-Haeng;Kim, Young-Shik
    • Korean Journal of Organic Agriculture
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    • v.22 no.4
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    • pp.695-703
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    • 2014
  • We experimented with the effect of oleic acid and its appropriate concentration to prevent powdery mildew eco-friendly in a cucumber greenhouse cultivation. 'Baekbongdadaki' (Nongwoo Bio. co. Korea) was treated in the plastic greenhouse at Sangmyung University. We treated four levels of concentration of oleic acid, which were 0, 2000, 4000, 6000, and 8000 ppm. There were investigated diseased severity, diseased leaf area, control value, and pesticide injury. The degree of control values by oleic acid treatments was investigated at 3 days after treatment. The recurrence of powdery mildew was checked for 55 days. The day and night temperature in the greenhouse were controlled to 23 and $15^{\circ}C$ respectively. The humidity inside the greenhouse was not controlled to prevent outbreak of the disease. From the experimental results, oleic acid was very efficient to control powdery mildew. 2000 ppm of oleic acid was shown to be the most control efficiency without any pesticide injury. The recommended method to treat it was to spray three times every 3 weeks.

Survey the Occurrences and Establishment of Environment-friendly Control System of Ricania shanthungensis in Jeonnam Province (전남지역 갈색날개매미충 발생현황과 친환경 방제)

  • Choi, Duck-Soo;Ma, Kyung-Cheol;Kim, Hyo-Jeong;Lee, Jin-Hee;Oh, Sang-A;Kim, Seon-Gon
    • Korean Journal of Organic Agriculture
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    • v.26 no.3
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    • pp.439-452
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    • 2018
  • This study was carried out to establish of environment-friendly control system and to survey the occurrence status of Ricania shanthungensis in Jeonnam province from 2016 to 2017. R. shanthungensis occurred at 1,344 ha in 61 towns of 15 cities in Gwangju and Jeonnam province. At four sites in the stationary area, the densities of eggmass and pupae were lower in 2017 than in 2016, the hatching rate decreased, and the first hatching time, emergence of adults, and the start of spawning tended to be slower. Telenomus sp., an egg parasitoid of R. shanthungensis, was found in most areas. Sunchon had the highest rate of 46.1%, followed by Muan 40.6, Goksung 29.2, Gurye 25.8, and Gwangju 17, respectively. The optimum spraying time for the control of R. shanthungensis was early March. The spraying material and the dilution multiples are 10 times of the machine oil at environmental friendly cultivation and 500 times of the chlorpriphosphate wp. at normal cultivation. When sprayed these materials, 95% of egg prohibited to hatch. There was more than 80% of the insecticidal effects on the organic materials of the machine oil emulsion, the Sophora root extrect + microbial extract agent, and the castor emulsion. For adults, Sophora root extrect + microbial extract, neem extract, and machine oil were better. Four kinds of chemical pesticides such as dinotefuran wp were effective for nymph and adult control. We have developed an adult catching device using the most preferred daylight color and behavioral habits of R. shanthungensis. The capture device consisted of two daylight compact lamps (30W and 20W), a yellow plate, and a catcher using water, and caught about 700 individuals a day. Based on the above results, we have established a system for controlling and life cycle of R. shanthungensis in Jeonnam province.

Development of Metabolic Engineering Strategies for Microbial Platform to Produce Bioplastics (바이오플라스틱 생산 미생물 플랫폼 제작을 위한 대사공학 전략 개발)

  • Park, Si Jae;David, Yokimiko;Baylon, Mary Grace;Hong, Soon Ho;Oh, Young Hoon;Yang, Jung Eun;Choi, So Young;Lee, Seung Hwan;Lee, Sang Yup
    • Applied Chemistry for Engineering
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    • v.25 no.2
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    • pp.134-141
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    • 2014
  • As the concerns about environmental problems, climate change and limited fossil resources increase, bio-based production of chemicals and polymers from renewable resources gains much attention as one of the promising solutions to deal with these problems. To solve these problems, much effort has been devoted to the development of sustainable process using renewable resources. Recently, many chemicals and polymers have been synthesized by biorefinery process and these bio-based chemicals and plastics have been suggested as strong candidates to substitute petroleum-based products. In this review, we discuss current advances on the development of metabolically engineered microorganisms for the efficient production of bio-based chemicals and polymers.

Prediction of Reaction Performance of Isobutane Alkylation Using Ionic Liquid (이온성액체를 이용한 이소부탄 알킬레이션 반응성능에 대한 예측)

  • Kim, Soo Jung;Yoo, Kye Sang
    • Applied Chemistry for Engineering
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    • v.26 no.3
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    • pp.347-350
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    • 2015
  • In this study, ionic liquids have been employed as a green catalyst in the alkylation of isobutane with 2-butene. One of acid ionic liquids, 1-octyl-3-methylimidazolium-bromide-aluminum chloride, was used in the reaction. Effects of the liquid hourly space velocity (LHSV), reaction temperature and composition of ionic liquids on the reaction performance were investigated in order to optimize reaction conditions. Under identical reaction conditions, the optimum reaction temperature was $80^{\circ}C$ and the ionic liquid with the anion composition of 0.56 showed an excellent reaction activity. Moreover, a correlation model was developed with a statistical approach to predict the product yields.

The Flow analysis and the Flame structure of Turbulent Premixed Flat Burner (난류예혼합 플랫버너의 유동해석과 화염구조)

  • Kim, Hun-Ju;Yun, Bong-Seok;Heo, Su-Bin;Park, Jae-Min;Lee, Do-Hyung
    • Journal of Advanced Marine Engineering and Technology
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    • v.35 no.4
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    • pp.397-405
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    • 2011
  • Hydrogen energy, as part of eco-friendly alternative energy, is made mostly through reforming of fossil fuels. The turbulent premixed combustion type of metal-fiber flat burner which is recently used in industry was tested in this paper. We measured the mean temperature distributions, CO, HC, $CO_2$ and $O_2$ concentrations to observe the flame structure and flame stability in some kind of experimental conditions. And also PIV and several flow analysis methods were compared to establish the numerical analysis model. The results of this paper will be the basis of the burner design of steam reformer.

Eco-Friendly Drying Technology using Superheated Steam (과열 증기 이용 친환경 건조기술)

  • Kim, Og Sin;Lee, Dong Hyun;Chun, Won Pyo
    • Korean Chemical Engineering Research
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    • v.46 no.2
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    • pp.258-273
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    • 2008
  • For being recent high oil price age, the interest in superheated steam drying technology is increasing as the method to enhance the energy efficiency of drying process consuming a lot of energy. This technology uses the superheated steam as drying medium to dry the materials and has advantages that can save the energy by recycling the evaporated high-temperature steam, enhance the quality of dried products, and minimize the exhaust of environmental pollution materials. In this work, it has been introduced from general drying principle to the principle and related studies of drying technology using superheated steam, using examples of superheated steam with dryer types, and industrial applications.

Manufacturing and Application of Natural Surfactants for Cosmetics (화장품용 천연계면활성제의 제조 및 이용 최신기술)

  • Kim, Hyung-Won
    • Journal of Adhesion and Interface
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    • v.14 no.4
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    • pp.197-211
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    • 2013
  • Surfactants which have ability to decrease surface tension through surface activation between the interfaces are used as essential major raw materials for detergents and cosmetics. Typical synthetic detergents such as EO (ethylene oxide), LAB (linear alkylbenzene) are made from chemical surfactant derived from petrochemicals, therefore, they are responsible for major environment contaminations and ecosystem destruction, especially of rivers and also cause atopic dermatitis through strong skin stimulus of these small molecular's powerful permeability and lead to cancers if they get into organs through capillary. Now worldwide interest is increasing to develop new natural surfactants and biosurfactants as ecological, biodegradabl, harmless and multi-functional new amphiphillic materials which replace these synthetic surfactants.