• Title/Summary/Keyword: 치환비율

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Effect of Adding of II-Anhydrite and Superplasticizer on the Fluidity of Cement Paste (II형 무수석고 및 고유동화제 첨가가 시멘트 페이스트의 유동성에 미치는 영향)

  • Kim, Jae-Ho;Kim, Do-Su;Lee, Beom-Jae;Rho, Jae-Seong
    • Applied Chemistry for Engineering
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    • v.9 no.3
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    • pp.336-341
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    • 1998
  • A comparative study on the effects of mean particle diameter and substitutional ratio of II-anhydrite on the fluidity of cement paste has been conducted. Three different mean particle diameters(4, 14 and $35{\mu}m$) and four different substitution ratios(3, 5, 10, 15wt%) have been tested while the dosage of two superplasticizers - naphtalenic(NSF) and polycarboxylic(NT-2) - has been varied from 0 to 2.0wt%. To investigate the effects of those parameters, the variation in fluidity and apparent viscosity of the cement paste has been observed as a function of the elapsed time. The initial fluidity of the cement paste is more affected by the increase in substitution ratio than by the mean particle size of the II-anhydrite. When the substitution ratio of the II-anhydrite is fixed at 10wt%, addition of 1.0wt% NT-2 improves the fluidity of paste cement more than that for NSF. This case has showed the best improvement of the fluidity in the range of parameters investigated. At the addition of 1.0wt% NT-2, apparent viscosity of the cement paste has been noticeably decreased as substitutional ratio of II-anhydrite increases. It was found that it would be more effective to substitute II-anhydrite at a certain ratio to improve the fluidity of the cement paste, in addition to adding NT-2.

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Phase transition and crystal structure analysis of PTCR $BaTiO_3$ ceramics with dopants (Y, Nb) (첨가제(Y, Nb)에 따른 PTCR $BaTiO_3$계 세라믹스의 결정구조 해석과 상전이 특성)

  • 차용원;원승신;백종후;이희수;엄우식;송준광;이인식;정훈택
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.2
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    • pp.253-258
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    • 1997
  • The characteristics of crystal structure and phase transition with dopants ($Nb_2O_5$= 0.1~0.4 mol% and $Y_2O_3$ : 0.2~0.4 mol%) on the PTCR $BaTiO_3$ system were investigated. In the case of $Nb_2O_5$ additive, the lattice parameter of PTCR $BaTiO_3$ was changed linearly with the increasement of $Nb_2O_5$ which substituted B-site of BaTiO$_3$ and the lattice parameter of c-axis decreased abruptly at 0.3 mol%. These phenonmena were assumed to originate from the distortion of octahedron and we could confirm that the change of lattice parameter accorded with the characteristics of the phase transition temperature. $Y^{3+}$ ions substituted both of A- and B-site until the 0.3 mol% addition, but $Y^{3+}$ substitution preferred A- to B-site above 0.3 mol%. This was affirmed by the variation ,of lattice parameter and the characteristics of phase transition. It also was found that $Y^{3+}$ions in the A-site substituted both of $Ba^{2+}$ and $Ca^{2+}$ ions with equal ratio by Rietveld method.

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Tensile Behavior of Highly Ductile Cementitious Composites Using Normal Sand as Fine Aggregate (일반모래를 잔골재로 사용한 고연성 시멘트 복합체의 인장거동)

  • Lee, Bang Yeon;Kang, Su-Tae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.6
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    • pp.178-184
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    • 2017
  • This study was aimed to investigate the tensile behaviors of PE(Polyethylene) fiber-reinforced highly ductile cementitious composites with different combinations of micro silica sand and normal sand(river sand) with maximum particle size of 4.75 mm. Flow test result indicated the increase of flowability with higher replacement ratio of river sand. There was no noticeable difference in the mean compressive strength with different replacement ratio of river sand, but the variation in the compressive strength increased as higher amount of river sand was adopted for the replacement. The difference in the uniaxial tensile strength was negligible, but the tensile strain capacity was significantly influenced by the replacement ratio of river sand. It is thought that increased density of multiple cracks induced improved tensile strain capacity when higher percentage of river sand was adopted for fine aggregate. The deviation in the strain capacity increased as the replacement ratio of river sand was higher, as in the compressive strength. This study presented the feasibility of using normal sand instead of micro silica sand for highly ductile cementitious composites with equivalent or better uniaxial tensile performance, even though it might increase the deviation in the performance.

Study on the Development of Accelerator for Early Strength of Concrete using Industrial by-product (산업부산물을 활용한 조기강도 촉진제 기술 개발을 위한 연구)

  • Lee, Ji-Hwan;Lee, Jin-Woo;Lee, Jae-Sam;Lee, Kang-Jin
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.1
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    • pp.1-10
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    • 2013
  • In this study utilize industry product for OPC(ordinary portland cement) and BFS(blast furnace slag) mixing concrete early age compressive strength elevation and executed study for high strength binder. Association ratio of industry product for high strength binder manufacture is Titanogypsum (4) : Limestone (3) : Waterworks Sludge by ratio of (3) as it is proper move. high strength binder mixing rate appeared that (7~9) % are proper via preliminary test. Could confirm that display high compressive strength incidence rate in early age than plain harmony according as mix high strength binder mixing concrete compressive strength high strength binder. Also, high strength binder generality that give function than high strength binder used in existing displayed more excellent intensity, and compressive strength displayed result that multiply single breadth according as high strength binder substitute that give function increases.

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Magnetic properties of $(Nd_{1-x}R_x)_2Fe_{14}B$ (R=Y, Pr) ($(Nd_{1-x}R_x)_2Fe_{14}B$ (R=Y, Pr)의 자기특성)

  • 김만중;김윤배;김희태;김택기
    • Journal of the Korean Magnetics Society
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    • v.8 no.5
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    • pp.271-274
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    • 1998
  • Spin reorientation and magnetocrystalline anisotropy of magnetically aligned $(Nd_{1-x}R_x)_2Fe_{14}B$ (R=Y, Pr) power were studied. The spin reorientation temperature $(T_{SR})$ of $(Nd_{1-x}R_x)_2Fe_{14}B$ decreases linearly by increasing Pr-substitution with the ratio of ${\Delta}T_{SR}=-1.35$ K/Pr at.% in composition range of 0$\leq$x$\leq$0.75. The spin reorientation temperature of $(Nd_{1-x}R_x)_2Fe_{14}B$ decreases by increasing Pr-substitution to 118 K (x=0.5) then increases to 122 K (x=0.75). The spin reorientation angle at 4.2 K decreases by increasing rare earth substitution with the ratio of $\Delta$SRA=-0.073$^{\circ}$/Y at.% and $\Delta$SRA=-0.258$^{\circ}$/Pr at.% in composition range of 0$\leq$x$\leq$0.5. The spin reorientation is expected to disappear at x$\geq$0.9 in case of $(Nd_{1-x}R_x)_2Fe_{14}B$ and at x$\geq$0.8 in case of $(Nd_{1-x}R_x)_2Fe_{14}B$.

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The Effect of Different Stocking Rate on Growth, Cast production and Conversion Efficiency of Organic Matter to Tissues of Earthworm (Eisenia fetida L.) (사육밀도의 차이가 지렁이의 생육, 체조직으로의 유기물 전환효율 및 분립생산에 미치는 영향)

  • Lee, Ji-Young;Lee, Ju-Sam
    • Journal of Animal Environmental Science
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    • v.18 no.2
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    • pp.63-74
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    • 2012
  • This experiment was carried out to investigate the effect of different stocking rate on growth, cast production and conversion efficiency of organic matter to tissues of earthworm. The carbon and nitrogen ratio (C/N) of tested Korean cow manure was 25.1, it was estimated an adequate ratio as feed for earthworms. The different stocking rates were 1:8(S-1), 1:16(S-2), 1:32(S-3) 1:64(S-4) 1:128(S-5) and 1:256 (S-6) as the ratios of earthworm fresh weight to biomass of Korean cow manure, respectively. A stocking rate of 1:32(S-3) was obtained a significantly highest values of increasing rate and conversion efficiency of organic matter to earthworm tissues. The mean values of increasin g rate of fresh weight and conversion efficiency of organic matter to earthworm tissues were 10.63 mg/day and 6.65% at the ratio of 1:32(S-3) with a rearing volume was $56.6cm^3$. A stocking rate of 1:8(S-1) was obtained a highest ratio of vermicasts, but showed a negative values of increasing rate and conversion efficiency of organic matter to earthworm tissues, it may due to severely food competition between individuals during the rearing periods. The pH, total nitrogen, available phosphorus, cation exchange capacity and exchangeable cations of vermicasts tended to increase with stocking rate. Especially, available phosphorus, cation exchange capacity and exchangeable cations of vermicasts tended to increase with rearing progressed. Vermicasts have the potential for improving plant growth when amended to container medium and soil according to increased availability of nutrients and improved physicochemical properties.

Reactions of Iron Alkynyl(Ethoxy)Carbene Complexes with Amines (철 알킨일(에톡시)카르벤 착물 유도체와 아민의 반응)

  • Park, Jaiwook;Kim, Jinkyung;Jung, Hyunmin
    • Journal of the Korean Chemical Society
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    • v.40 no.8
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    • pp.571-578
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    • 1996
  • Iron alkynyl(amino)carbene complexes, (${\beta}$-aminovinyl)carbene complexes, ${\eta}^3$-(2-(alkylcarbonyl)vinyl)carbene complexes, and a 3-aminoallenylidene complex were formed in the reactions of iron alkynyl(ethoxy)carbene complexes with amines. The ratio of the products, which were formed by substitution reaction, the Michael addition of amines, rearrangements after the addition reaction, and the addition followed by the elimination of the ethoxy group, respectively, was dependent on reaction temperature, the substituent of the alkynyl moiety, and employed amines.

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Phylogenetic Study of the Genus Pungitius (Gasterosteidae: Pisces) from Korea by the Sequence Analysis of 18s Ribosomal DNA (18s 리보좀 DNA 서열 분석에 의한 한국산 가시고기속 (genus Pungitius, Gasterosteidae: Pisces) 어류의 계통학적 연구)

  • Seo, Bo-Keun;Chae, Byung-Soo
    • Korean Journal of Ichthyology
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    • v.12 no.1
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    • pp.14-19
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    • 2000
  • The sequences of two fragments of 18s ribosomal DNA were determined to elucidate relationship between Pungitius sinensis and P. kaibarae. The proportion of G+C pair is 54.85% to 55.15% in P. kaibarae populations and 52.76% in P. sinensis. Number of substitutions ranges from 10~18 among the populations of P. kaibarae and up to 165 between P. sinensis and P. kaibarae. The value of sequence divergence were 0.0118~0.0195 among the populations of P. kaibarae and 0.2136~0.2306 between P. sinensis and P. kaibarae. The result of pairwise comparison of the sequences indicate that phylogenetic relationship between P. sinensis and P. kaibarae was differentiated to specific level.

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Characteristics of geopolymer based on recycling resources (재활용 폐자원에 따른 지오폴리머의 특성변화 연구)

  • Kim, Yoo-Teak;Kim, Hyun-Jung;Jang, Chang-Sub
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.22 no.3
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    • pp.152-157
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    • 2012
  • In this study, geopolymer was prepared with reject ash and blast furnace slag using NaOH as an alkali activator and water glass. The aim of this study was to investigate the compressive strength variation according to the contents of NaOH and water glass and replacement ratio of reject ash (RA) and blast furnace slag (BS). The compressive strength measured after 28 days was 38.91 MPa for the geopolymer which consist of 100 % of BS with 1 wt% NaOH and 3 wt% water glass. The major factor for improving compressive strength was the alkali activator proportion and the replacement ratio of RA and BS.

Isomer Formation in the Chlorination of Highmolecular Paraffinic Hydrocarbons by Various Halogenating Agents (여러 종류의 할로겐 화합물과 고분자량 파라핀계 탄화수소의 염소화에서 생기는 이성질화에 관한 연구)

  • Li-Hoan Kung
    • Journal of the Korean Chemical Society
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    • v.32 no.4
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    • pp.390-405
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    • 1988
  • The chlorination of $C_7H_16,\;C_8H_18,\;C_10H_22,\;and\;(Me_2CH)_2$ with N-Chlorosuccinimide, tert-BuOCl, $CCl_3SO_2Cl,\;CCl_4,\;CCl_3SCl,\; PCl_5,\;and\;Cl_2\;in\;C_6H_6\;or\;CS_2$ which both form loose complexes with $Cl_2$ atoms yielded mixtures of isomeric monochloroalkanes which were analyzed quantitatively. An isomer ratio differing from that known for the substitution of paraffinic hydrocarbons was observed. The isomer distribution observed is the result of the combined effects of the differing C-H dissociation energies of the different types of H atoms of the alkane and of the free energy of the attacking radical with polar effects of the attacking radical as well as of the hydrocarbon.

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