• Journal of the Korean Recycled Construction Resources Institute
• /
• v.4 no.2
• /
• pp.143-148
• /
• 2016

The aim of research is inducing the optimum proportion of fly ash(FA) and blast furnace slag(BS) for ternary cement. In this research, hence, the fundamental properties of mortar mixtures were evaluated depending on various proportion of FA and BS. The results of the experiment, within the scope of the study, obtained the following conclusions. Flow of the mixtures was increased with addition of binary supplementary cementitious material(SCM), and especially, portion of FA. The air content of the mixtures was increased with addition of binary SCMs, while it was decreased with increased FA content. In the case of unit mass, increased value was obtained due to the increased air content within 25 to 45% of binary SCM content, while it was increased within 65 to 100% of binary SCM up to only 20% of FA content and decreased more than 20% of FA because of the low density of FA. The setting time of the mixtures was delayed with addition of binary SCM and FA. In the case of compressive strength, at 91-day age, the highest value was obtained with 25 and 45% of binary SCM with the proportion of FA to BS of 40 to 60. Therefore, based on the compressive strength, it is considered that the binary SCM content of 25 and 45% with the proportion of FA to BS of 2 : 3 is the most favorable conditions in this research scope.

• Korean Journal of Soil Science and Fertilizer
• /
• v.27 no.3
• /
• pp.179-188
• /
• 1994

This study was conducted to investigate the distribution of potassium fractions and to establish the soil chemical indices for assessing potassium availability in upland soil. Soil samples were collected from 66 vegetable crop fields of Chungbuk Jungweon, Jeonbuk Imsil and Kyengbuk Euiseong and these samples were analyzed water soluble(W. S. -K), exchangeable(Exch. -K) and nonexchangeable potassium(Nonex. -K). The distribution of potassium fractions was examined for soils having different physico-chemical properties and compared with the soil parameters related to the potassium availability. 1. The distribution ranges of W.S.-K, Exch.-K and Nonex.-K were 0.07~1.42, 0.27~2.30, and 0.84~4.74me/100g, and average contents of relevent fractions were 0.40, 1.03 and 2.37me/100g respectively. 2. Contents of W.S.-K and Exch.-K were decreased with increasing soil pH, CEC, Exch. Ca and Exch. Mg contents but Nonex. -K showed a low correlationship with these factors. 3. Exch.-K content slightly inereased with increasing clay content, while W.S.-K and Nonex. -K contents were grandually decreased with clay contents. 4. The relationship between W.S.-K and Exch.-K was significant and W.S.-K was released from soil at 0.23me/100g content of Exch.-K 5. Contents of W.S-K and Exch.-K showed high correlationship with soil chemical parameters such as ratio of exchangeable cations(K/Ca+Mg), ratio of exchangeable cation equivalent[$K/{\sqrt{Ca+Mg}}:(me/100g)^{1/2}$], potassium exchangeable free energy(${\Delta}F=RT$ 1n $K/{\sqrt{Ca+Mg}}$ : calories/mole) and saturation percentage of potassium($Exch.K/CEC{\times}100$), and these factors were considered to be good parameters for assessing soil potassium availability.

• Proceedings of the Korean Society of Organic Agriculture Conference
• /
• 2005.12a
• /
• pp.55-64
• /
• 2005

1. 지렁이 분립량이 증가할수록 용적비중(bulk density), 유효수분함량(available water content), pH, 전기전도도(electrolytic conductivity), 무기물(ash), 전질소(total nitrogen), 양이온치환능력(cation exchange capcaity), 유효인산(available $P_{2}O_{5}$), 치환성양이온(exchangeable cation)이 증가하였다. 2. 근대는 분립 40${\sim}$100%의 혼합비율에서 초장(PL), 엽면적(LA), 엽수(NL), 엽면적(LA), 지상부 건물중(SHW), 근중(RW), 줄기두께(SD), 근중(RW) 및 생물학적수량(BY)이 다른 처리구보다 유의하게 높았다. 3. 열무는 분립 40${\sim}$60%의 혼합비율에서 초장(PL), 지상부 건물중(SHW), 근중(RW), 생물학적수량(BY)이 다른 처리구보다 유의하게 높았다. 3. 시금치와 상추는 40%의 혼합비율에서 지상부중(SHW), 근중(RW), 생물학적수량(BY)이 다른 처리구에 비해 유의하게 높았다(p${\leq}$0.05).

• The Korean Journal of Zoology
• /
• v.36 no.1
• /
• pp.14-20
• /
• 1993

한국산 도룡농, Hvnobius leechii의 7개 집단에서 mitochondrial DNA(mtDNA)의 변이가 조사되었다. MtDNA의 크기에서의 차이는 관찰되지 않았으나 제한효소 인식 부위에서의 차이가 조사되었다. MtDNA의 절편 양상은 각 집단에서 동일하게 나타났다. 제한 효소로 처리하여 얻어진 절편의 비교에서 종내 변이는 염기 치환에 의하여 발생한 것임이 분석되어졌다. 특히 하동과 제주 집단은 몇개의 제한 효소 인식 위치에서 나머지 5개 집단과 뚜렷한 차이를 보였다. 염기치환율(p값)은 공통 절편 비율(p값)을 토대로 하여 얻어졌으며 그 값은 0.004에서 0.064의 범위 내의 값으로 측정되었다. 하동과 제주 집단을 제외한 5개 집단의 비교에서는 비교적 낮은 침의 염기 치환율을 보였으나 제주와 나머지 집단들과의 비교에서는 염기치환율이 높게 측정되었다. 염기 치환율과 관련지어 염기 분화 연대를 측정한 결과 도룡뇽 7개 집단은 3개의 group으로 나뉘어 졌으며 이들은 약 188만년전에 분화된 것으로 사료되어 진다.

• Journal of the Korea Institute of Building Construction
• /
• v.20 no.1
• /
• pp.27-34
• /
• 2020

In the industry, due to the carbon dioxide gas produced during cement production is increasing, research on recycling by-products has been actively conducted. In the industrial by-products, the high calcium fly ash(HCFA) produced by the blast-furnace in the circulating fluidized bed combustion method has a high ratio of CaO and CaSO4. In view of this, the purpose of this is to use high calcium fly ash(HCFA) as a stimulant in blast furnace slag powder and use it as a cement substitute. As a result, it is judged that the substitution ratio of HCFA should be 15% or less. In addition, although durability and strength are relatively lower than of OPC, it is considered that it can be utilized as an environmentally building material.

• Journal of the Korea Concrete Institute
• /
• v.15 no.1
• /
• pp.35-42
• /
• 2003

To use ferro copper slag as aggregate in the construction, an evaluation upon the two kinds of ferro copper slag being produced was conducted to determine the basic physical, and mechanical properties, chemical component and environmental noxiousness. As a result of experiment, it was found that two kinds of ferro copper slag satisfies the physical and mechanical properties of aggregate, prescribed in KS F 2526, and that in the result of noxious heavy metal eruption test by single bach extraction, no eruption of noxious heavy metal was detected or the eruption was far below the reference value. And mortar test was conducted by replacing sand of 25, 50, 75, 100% and the performance level was presented upon reviewing the fluidity property and variable aspects of unit weight. The increase of strength in accordance with replacement rate of sand was found to be the below than the equivalent level compared to the testing specimens that did not use ferro copper slag, but those of 25% replacement rate was above than 0%. Thus, two kinds of ferro copper slag, produced in the domestic, were found to be possessing the enough physical properties to use as concrete aggregate assuming that used with sand and in particular, it was reviewed to be advantageous in manufacturing concrete or mortar that requires weight.

• Journal of the Korean Chemical Society
• /
• v.45 no.6
• /
• pp.538-545
• /
• 2001

The ratio of regioisomers in nitration of biphenyl derivatives containing electron-with-drawing group was examined. The ratio of isomers was determined efficiently by quantitative analysis of $^1$H NMR spectrum of product mixture based on $^1$H NMR spectrum of each isomer. Some isomers were isolated after chemical transformation, nitro to amine or carboxylic acid to its ethyl ester, because direct separation was very difficult. To improve the regiselectivity, representative several reaction conditions were tried and the NMR method was applied to determine regioselectivity in nitration of biphenyl derivatives. It was observed that the regioselectivity depend on not only reaction conditions but also position and kind of substituents.

• 한국방재학회:학술대회논문집
• /
• 2011.02a
• /
• pp.160-160
• /
• 2011

현대의 건설기술은 자원절약과 환경보전이라는 시대적 흐름 속에, 자원순환과 지속 가능한 친환경 건설기술 개발은 차세대 연구분야로써, 연구가 시급한 분야가 되었다. 최근에는 골재 수급불균형 문제를 해결하고 동시에 자원순환을 위한 방안으로서 건설폐기물로부터 생산된 순환골재를 콘크리트용 천연골재의 대체재로 활용하기 위한 연구개발이 이루어지고 있다. 지속가능형 건설기술을 국내 독자 기술로 확립하고 건설현장에서 발생하는 폐기물의 순환시스템을 확고하게 구축하여 순환자원에 의한 국가경쟁력 강화를 기대할 수 있다. 본 연구의 목적은 순환골재 콘크리트의 역학적 특성을 개선하기 위해 순환골재 콘크리트 공시체를 제작하여 강도 및 강성을 검증하는 것이다. 실험방법으로 순환굵은골재의 치환 비율을 0%에서 100%까지 변화시킨 공시체를 제작하고 각 공시체의 정적 극한강도 거동을 비교 분석하였다. 하중은 공시체가 파괴가 발생 할 때까지 변위제어 방식으로 재하 하였으며 이 때 공시체의 파괴거동은 설치된 계측센서들을 이용하여 계측 및 분석하였다. 실험결과 공시체의 압축강도는 순환굵은골재 치환률이 25% 미만일 경우 일반 콘크리트 압축강도의 95% 이상의 구조성능을 갖지만, 순환굵은골재 치환률이 100%인 경우, 일반콘크리트 압축강도의 85% 수준의 구조성능을 나타냈다. 강성은 FRP 부재의 순환골재 치환률에 따라 최대 14%의 강성차이를 보였다. 이를 통해 순환골재 치환률이 높을수록 순환골재 표면의 폐모르타르와 이물질의 영향으로 재료간의 부착강도가 감소되어 강도와 강성이 저하되었음을 확인하였다.

• Journal of the Korea institute for structural maintenance and inspection
• /
• v.24 no.4
• /
• pp.1-9
• /
• 2020

This study conducted to understand effects of CA (CaAl₂O₄) and CA₂ (CaAl₄O₇) ratio on chloride binding ability and compressive strength and pore structure of cement mortar incorporating mixture of CA and CA₂. The Portland cement based specimens were mixed with the clinkers CA and CA₂, and these calcium aluminate clinker mixture were replaced 0, 5, 10% by weight of cement. After all the test specimens were cured for 28 days under water curing, they were immersed in the distilled water and NaCl solution. As a result, 28 days compressive strength of all specimens was similar, and As the replacement ratio of calcium aluminate clinker in the specimen increased, Friedel's salt production tended to increase. However, it was dependent on the amount of Al₂O₃ in the level of 5% replacement and CA ratio in the level of 10% replacement. Through equilibrium isotherm result, it was also indicated that as replacement ratio of calcium aluminate clinker in cement matrix increased, chloride binding capacity was improved, and chloride penetration was suppressed. In this study, the specimen replaced with 10% of the calcium aluminate clinker mixture (CA 39%, CA₂ 60%) was remarkable to control chloride attack. We figured out necessity to understand optimal CA/CA₂ ratio to effectively apply CA₂ as a sustainable building material by improving the chloride binding ability in Portland cement based system.

• Journal of the Korean Chemical Society
• /
• v.37 no.2
• /
• pp.249-254
• /
• 1993

N-p-nitrophenyl poly(m-phenylene isophthalamide) was obtained from treatment of poly(m-phenylene isophthalamide) with sodium hydride in dimethyl sulfoxide followed by the addition of 1-fluoro-4-nitrobenzene in 43 wt% yield. Its inherent viscosity was 0.606 g/cm${\cdot}$sec determined from a solution of 0.125 g of the above polymer dissolved in 25 ml of 98% sulfuric acid at $30^{\circ}C.$ In order to synthesize poly(m-phenylene isophthalamide), 1,3-phenylenediamine is allowed to react with isophthaloyl chloride in chloroform in the presence of triethylamine and added triethylamine hydrochloride. The value of inherent viscosity is 0.560 g/cm${\cdot}$sec measured at the same condition. The substitution ratio of N-p-nitrophenyl poly(m-phenylene isophthalamide) was to be 16.7∼47.0% by using the $^1H-NMR$ integration. When the higher inherent viscosity of poly(m-phenylene isophthalamide) was used, lower substitution ratio would be calculated.