• Title/Summary/Keyword: 층상 구조

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The structure of intercalation compound between a layered double hydroxide and an ethyl orange (층상이중수산화물과 에틸오렌지의 삽입화합물의 구조)

  • Jung, Woo-Chan;Huh, Young-Duk
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.1
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    • pp.137-142
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    • 1997
  • We synthesized the intercalation compound between a layered double hydroxide and an ethyl orange. The orientation of the intercalated ethyl orange into the layered double hydroxide was investigated. The molecular plane of the ethyl orange and its N=N axis lie nearly perpendicular to the hydroxide layers with an antiparallel pattern.

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Preparation of Porous Layered Carbon Using Magadiite Template (Magadiite 주형을 이용한 층상 카본의 합성)

  • Choe, Seok-Hyon;Jeong, Soon-Yong;Oh, Seong-Geun;Kwon, Oh-Yun
    • Applied Chemistry for Engineering
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    • v.16 no.3
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    • pp.408-412
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    • 2005
  • Porous layered carbon was prepared by interlayer pyrolysis of pyrolysis fuel oil (PFO) using magadiite template and successive dissolution of template. Particle morphology was plate type with d-spacing of approximately 0.7 nm and it had constant interlayer space. Specific surface area was $147{\sim}385m^2/g$ depending upon template type, mixing ratios and pyrolysis time.

Nonlinear Dynamic Analysis of Reinforced Concrete Shells Using Layered Elements with Drilling DOF (회전자유도를 갖는 층상화 요소를 이용한 철근콘크리트 쉘구조의 비선형 동적해석)

  • 김태훈;이상국;신현목
    • Journal of the Earthquake Engineering Society of Korea
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    • v.5 no.6
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    • pp.21-27
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    • 2001
  • In this paper, a nonlinear finite element procedure is presented for the dynamic analysis of reinforced concrete shells. A computer program, named RCAHEST(reinforced concrete analysis in higher evaluation system technology), for the analysis of reinforced concrete structures was used. A 4-node flat shell element will drilling rotational stiffness is used for spatial discretization. The layered approach is used to discretize behavior of concrete and reinforcement through the thickness. Material nonlinearity is taken into account by comprising tensile, compressive and shear models of cracked concrete and a model of reinforcing steel. The smeared crack approach is incorporated. Solution of the equations of motion is obtained by numerical integration using Hilber-Hughes-Taylor(HHT) algorithm. The proposed numerical method for the nonlinear dynamic analysis of reinforced concrete shells is verified by comparison with reliable analytical results.

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Formation of Chalcophanite and Todorokite from the Hydrothermal Reaction of Zn-doped δ-MnO2 (Zn 도핑 된 δ-MnO2의 수열반응을 통한 chalcophanite 및 todorokite 결정 생성 및 성장)

  • Haesung Jung
    • Korean Chemical Engineering Research
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    • v.61 no.1
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    • pp.162-167
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    • 2023
  • Diverse structures of Mn oxides in natural and engineered systems occur from the transformation of δ-MnO2, the most common crystalline phase of nucleated Mn oxides, to other structures via redox reactions, adsorption of metals, etc. Recently, together with emerging interests of Zn-based rechargeable battery systems, which use Mn oxides as a cathode, the transformation and recrystallization of Mn oxides have garnered interests. Here, using hydrothermal reaction of Zn-doped δ-MnO2, the formation of todorokite and chalcophanite is observed. When the concentration of doped Zn increases, the formation of chalcophanite is dominant, but occurs slower than that of the lower concentration of doped Zn. This study will provide a new understanding of the effect of Zn on the recrystallization process of Mn oxides during redox cycles in energy storage systems and environmental systems.

Analysis of Stratified Rock under Vertical Load in Pile Foundation of Wind Turbine Using Circular Foundation Analysis Method with Equivalent Effective Width (등가유효폭을 가진 원형기초해석법을 이용한 풍력발전기 말뚝기초의 연직하중에 대한 층상암반 해석)

  • Kim, Dohan;Park, Sangyeol;Moon, Kyoungtae
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.33 no.6
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    • pp.2411-2425
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    • 2013
  • In the design of pile foundation on the rock layer in the stratified structure with sedimentary and rock layers, the structural analysis of the stratified rock layer is required to determine the failure modes (flexural failure, punching shear failure or end bearing failure) and the bearing capacity of the rock layer. However, the existing usable Elastic Plate Analysis Method (EPAM) suggested by ACI committee 436 and Korean Code Requirements for Structural Foundation Design is very complex, and engineers have many difficulties in using it. Therefore, in this research, we proposed the relatively simple Circular Foundation Analysis Method (CFAM) with the concept and the equation of the equivalent effective width (radius) instead of the complex EPM, and the related equations of bending moment and shear force to be equal to the analysis results of EPAM. As a result, the proposed CFAM using the equivalent effective width (radius) is simple and convenient to use, and the analysis results of it are very good in their accuracies comparing those of EPAM and Finite Element Method.

Synthesis and characterization of layered basic zine p-toluenesulfonates (층상구조의 염기성 zinc p-toluenesulfonate의 합성 및 성질에 관한 연구)

  • 김형동;조영식;허영덕
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.4
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    • pp.651-654
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    • 1998
  • The layered basic zinc p-toluenesulfonates has been directly synthesized by the surface modification. The chemical formula of layered basic zinc p-toluenesulfonate is determined by CHNS and TG-DTA. From the X-ray diffraction data and the guest size, the orientation of the p-toluenesulfonate onto the zinc hydroxide layer is determined. The molecular plane of the p-toluenesulfonate lies perpendicular to the zinc hydroxide layers.

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Numerical Studies for the Application of the SASW Method in an Inclined Soil Layer (경사지반에서 SASW기법 적용시 수치해석을 이용한 영향요소 연구)

  • 김동수;윤종구;이병식;박형춘
    • Journal of the Korean Geotechnical Society
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    • v.17 no.1
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    • pp.77-84
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    • 2001
  • SASW 기법은 실험에서 얻은 실험분산곡선이 현장 지반 강성의 주상을 합리적으로 반영하므로 실험결과로부터 전단파 속도 주상도를 신속하게 결정할 수 있는 장점을 가지고 있다. 그러나, 실험결과를 해석하는 과정에서 현재까지는 지반의 층상구조를 수평으로 가정하는 근본적인 한계점을 지니고 있었다. 이는 지반이 수평층상구조가 아닐 경우 해석적인 해를 구하기 힘들기 때문이다. 본 논문에서는 유한요소 수치해석을 통하여 경사진 지반에서 SASW 기법을 수행했을 경우 지반경사를 고려한 지반 조건이 실험분산곡선에 미치는 영향을 규명하였다. 이를 위하여 지반의 기울기와 표면파 전파 방향이 실험분산곡선에 미치는 영향과 파의 전파형상에 미치는 영향을 규명하기 위한 해석을 수행하였다. 해석결과 경사지반에서 지반 조건이 변함에 따라 실험 분산곡선에 많은 변화가 나타났고, 경사진 지반에서 파의 전파현상은 수평 층에서의 파의 전파형상과는 전혀 다른 특성으로 나타남을 알 수 있었다.

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A Study on Vibration Control of Multi-layer Structure(I) (다층 층상 구조물의 진동제어에 관한 연구 (I))

  • Jeong, Hae-Jong;Byeon, Jeong-Hwan;Yang, Ju-Ho
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.33 no.2
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    • pp.141-148
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    • 1997
  • This paper is concerned with the vibration control of multi-layer structure for ultra-tall buildings and main tower of large bridge etc. We have modeled the multi-layer structure with the distributed mass system as the lumped mass system of two-degree-of-freedom structure and made experimental equipment. The LQ optimal control theory is applied to the design of the control system. The designed control system is simulated by computer. As a result, the LQ regulator showed good vibration control performance with impact excitation.

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