• Title/Summary/Keyword: 축소 노즐

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Improvement of Sensing Properties in Nanowires/Nanofibers by Forming Shells Using Atomic Layer Deposition (원자층증착법으로 형성된 셀형성을 이용한 나노선/나노섬유 화학센서의 감응성 향상)

  • Kim, Jae-Hun;Park, Yu-Jeong;Kim, Jin-Yeong;Kim, Sang-Seop
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.96-96
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    • 2016
  • 나노섬유(nanofiber), 나노선(nanowire), 그리고 나노튜브(nanotube)와 같은 1차원 구조의(one-dimensional structure) 나노재료는 벌크(bulk) 및 박막(film) 재료와는 다르게 물리적, 화학적으로 특이한 성질을 가지고 있으며, 이러한 성질은 나노재료의 구조, 형상, 크기 등에 큰 영향을 받는다. 첫 째, 전기방사(electrospinning) 공정을 이용한 나노섬유의 합성; 용액의 특성, 전기장 세기, 방사시간 등의 변수를 조절하게 되면 방출되는 재료의 형상을 입자 혹은 섬유상의 형태로 얻을 수 있으며, 전기방사를 통해 합성된 나노재료의 소결 온도 및 시간을 달리함으로써 나노입자의 크기를 조절할 수 있다. 또한, 템플레이트 합성법(template synthesis) 및 이중노즐(coaxial nozzle)을 이용해 속이 빈 형태인 중공(hollow) 구조의 나노섬유를 얻을 수 있으며, 전기방사에 사용되는 전구물질에 원하는 금속 및 산화물을 첨가함으로써 복합체(composite) 나노섬유를 얻을 수 있다. 둘 째, VLS(Vapor-Liquid-Solid) 공정을 이용한 나노선의 성장; 온도, 압력, 전구물질의 양, 그리고 시간 등의 변수를 조절하게 되면 원하는 직경 및 길이를 갖는 나노선을 성장시킬 수 있다. 그리고 ALD(Atomic Layer Deposition)를 이용해 나노선에 추가적인 층을 형성함으로써 코어-셀 구조를 형성할 수 있으며, 감마선, UV와 같은 공정을 이용해 귀금속 촉매를 나노선에 기능화 시킬 수도 있다. 코어-셀 구조를 갖는 나노선/나노섬유는 코어 혹은 셀 층의 전자나 홀의 이동을 유발하여 전자공핍층(electron depletion layer) 또는 정공축적층(hole accumulation layer)을 확대 및 축소시켜 센서의 초기저항을 증가시키거나 감소시키는 역할로써 이용되고 있으며, 특히, 셀 층의 두께가 셀 층 재료의 Debye length와 유사한 크기를 갖게 되면, 셀 층은 완전공핍층(fully depleted layer)을 형성해 최대의 감도를 나타낼 수 있다. 본 연구에서는 다양한 제조 공정을 통해 제작될 수 있는 1차원 나노-구조물을 가스센서에 적용하는 사례들을 소개하고, 이러한 가스센서의 감응성능을 향상시키기 위한 방법의 한 가지로 원자층증착법으로 나노선/나노섬유의 표면에 셀층을 형성하여 감응성 향상 메커니즘 및 관련 주요 변수들을 조사하고자 한다.

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Effects of Change in Heat Release Rate on Unsteady Fire Characteristics in a Semi-Closed Compartment (반밀폐된 구획에서 발열량 변화에 따른 비정상 화재특성)

  • Hwang, Cheol-Hong
    • Fire Science and Engineering
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    • v.26 no.2
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    • pp.75-83
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    • 2012
  • An experimental study was conducted to investigate the effects of change in heat release rate on unsteady fire characteristics of under-ventilated fire in a semi-closed compartment. A standard doorway width of the full-scale ISO 9705 room was modified to 0.1 m and the flow rate of heptane fuel was increased linearly with time using a spray nozzle located at the center of enclosure. Temperature, heat flux, species concentrations and heat release rate were continuously measured and then global equivalence ratio (GER) concept was adopted to represent the unsteady thermal and chemical characteristics inside the compartment. It was observed that there was a significant difference in unsteady behavior between global and local combustion efficiency, and the GERs predicted by ideal and measured heat release rate were also shown different results in time. The unsteady behaviors of temperature, heat flux and species concentrations were represented well using the GER concept. It was important to note that CO concentration was gradually decreased with the increase in GER after reaching its maximum value in the range of 2.0~3.0 of global equivalence ratio. In addition, the experimental data on unsteady thermal and chemical behaviors obtained in a semi-closed compartment will be usefully used to validate a realistic fire simulation.

Performance Evaluation of FDS for Predicting the Unsteady Fire Characteristics in a Semi-Closed ISO 9705 Room (반밀폐된 ISO 9705 화재실에서 비정상 화재특성 예측을 위한 FDS의 성능평가)

  • Mun, Sun-Yeo;Hwang, Cheol-Hong
    • Fire Science and Engineering
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    • v.26 no.3
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    • pp.21-28
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    • 2012
  • The objective of this study is to evaluate the prediction accuracy of FDS(Fire Dynamic Simulator) for the thermal and chemical characteristics of under-ventilated fire with unsteady fire growth in a semi-closed compartment. To this end, a standard doorway width of the full-scale ISO 9705 room was modified to 0.1 m and the flow rate of heptane fuel was increased linearly with time (until maximum 2.0 MW based on ideal heat release rate) using a spray nozzle located at the center of enclosure. To verify the capability of FDS, the predicted results were compared with a previous experimental data under the identical fire conditions. It was observed that with an appropriate grid system, the numerically predicted temperature and heat flux inside the compartment showed reasonable agreement with the experimental data. On the other hand, there were considerable limitations to predict accurately the unsteady behaviors of CO and $CO_2$ concentration under the condition of continuous fire growth. These results leaded to a discrepancy between the present evaluation of FDS and the previous evaluation conducted for steady-state under-ventilated fires. It was important to note that the prediction of transient CO production characteristics using FDS was approached carefully for the under-ventilated fire in a semi-closed compartment.