• Title/Summary/Keyword: 최적 평균법

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Synthesis of ITO Nano-Particles by SAS Method and Preparation for Conductive PET Film with Multi-Layers (SAS법을 이용한 ITO 나노입자의 합성과 적층 도포된 PET 도전필름의 제조)

  • Yun, Sang-Ho;Kim, Moon-Sun;Lee, Hee-Dai;Kim, Chul Kyung
    • Applied Chemistry for Engineering
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    • v.19 no.1
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    • pp.37-44
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    • 2008
  • The multi-layer PET film of ITO/ATO was prepared by a wet coating method to obtain the transparent film with a high conductance at low cost. ITO nano-particles were synthesized by a SAS method at 15 MPa and $50^{\circ}C$, where optimized rate of In/Sn was 65. Average diameter and resistivity of ITO obtained from SAS are $15{\pm}2nm$ and $4{\times}10^4{\Omega}{\cdot}cm$. Coating solution was prepared at pH 10. Roughness (Ra), resistivity, and transmissivity of ATO film on PET are 9 nm, $5.5{\times}10^6{\Omega}{\cdot}cm$, and 91%. The multi-layered film of ITO/ATO was obtained by solution including 0.1, 0.5, 1.0, and 2.0 ITO wt% on ATO layer. Roughness (Ra) of multi-layered film with 0.1, 0.5, 1.0, and 2.0 ITO wt% is 4, 10, 12, and 16 nm, respectively. Corresponding resistivity with an increasing ITO concentration is $3.7{\times}10^6$, $2.4{\times}10^6$, $8{\times}10^5$, and $2{\times}10^5{\Omega}{\cdot}cm$. Transmissivity of ITO/ATO film decreases as 89, 88, 86, and 82% with an increasing ITO concentration as 0.1, 0.5, 1.0, and 2.0 wt%.

Enhanced Catalytic Activity of Cu/ZnO/Al2O3 Catalyst by Mg Addition for Water Gas Shift Reaction (Mg 첨가에 따른 수성가스전이반응용 Cu/ZnO/Al2O3 촉매의 활성 연구)

  • Park, Ji Hye;Baek, Jeong Hun;Hwang, Ra Hyun;Yi, Kwang Bok
    • Clean Technology
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    • v.23 no.4
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    • pp.429-434
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    • 2017
  • To investigate the effect of magnesium oxide addition, $Cu/ZnO/MgO/Al_2O_3$ (CZMA) catalysts were prepared using co-precipitation method with fixed molar ratio of Cu/Zn/Mg/Al as 45/45/5/5 mol% for low-temperature water gas shift reaction. Synthesized catalysts were characterized by using BET, $N_2O$ chemisorption, XRD, $H_2-TPR$ and $NH_3-TPD$ analysis. The catalytic activity tests were carried out at a GHSV of $28,000h^{-1}$ and a temperature range of $200{\sim}320^{\circ}C$. At the same condition, magnesium oxide added catalyst (CZMA 400) showed that the lowest reduction temperature and stable presence of $Cu^+$, that is active species and abundant weak acid site. Also magnesium oxide added catalysts (CZMA) showed higher catalytic activity at temperature range above $240^{\circ}C$ than the catalyst without magnesium oxide (CZA). Consequently, CZMA 400 catalyst is considered to be excellent catalyst showing CO conversion of 77.59% without deactivation for about 75 hours at $240^{\circ}C$, GHSV $28,000h^{-1}$.

Experimental Study on Source Locating Technique for Transversely Isotropic Media (횡등방성 매질의 음원추적기법에 대한 실험적 연구)

  • Choi, Seung-Beum;Jeon, Seokwon
    • Tunnel and Underground Space
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    • v.25 no.1
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    • pp.56-67
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    • 2015
  • In this study, a source locating technique applicable to transversely isotropic media was developed. Wave velocity anisotropy was considered based on the partition approximation method, which simply enabled AE source locating. Sets of P wave arrival time were decided by the two-step AIC algorithm and they were later used to locate the AE sources when having the least error compared with the partitioned elements. In order to validate the technique, pencil lead break test on artificial transversely isotropic mortar specimen was carried out. Defining the absolute error as the distance between the pencil lead break point and the located point, 1.60 mm ~ 14.46 mm of range and 8.57 mm of average were estimated therefore it was regarded as thought to be 'acceptable' considering the size of the specimen and the AE sensors. Comparing each absolute error under different threshold levels, results showed small discrepancies therefore this technique was hardly affected by background noise. Absolute error could be decomposed into each coordinate axis error and through it, effect of AE sensor position could be understood so if optimum sensor position was able to be decided, one could get more precise outcome.

Fundamental Study for Feasibility on Soil Flushing for TPHs-Contaminated Soil Treatment (유류오염토양 정화를 위한 토양세정기술의 적용성 기초연구)

  • Kang, Hui-Cheon;Kim, Joung-Dae;Han, Byeong-Gi;Seo, Seung-Won;Shin, Chul-Ho;Park, Joon-Seok
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.4
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    • pp.740-747
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    • 2015
  • This research was performed to evaluate the feasibility of in situ soil flushing for TPH-contaminated soil remediation. It was conducted in batch test as fundamental research for in situ soil flushing. The 30% of initial TPH concentration was removed by shaking only in batch test. The removal efficiency of TPH in case of groundwater as surfactant dilution solution was approximate 2~6% lower than that of distilled water. Mixing ratio of soil to surfactant solution did not practically effect on the TPH removal efficiency. In the experiment of using single or mixed surfactant solution with 0.1~4.0 wt%, Tween-80, SWA-1503, SWA-1503+SDS showed averagely over 80%. It was determined that the optimum surfactant concentration was 0.1 wt% because there was no significant difference between concentrations of 0.1~4.0 wt%.

Analysis of large-scale flood inundation area using optimal topographic factors (지형학적 인자를 이용한 광역 홍수범람 위험지역 분석)

  • Lee, Kyoungsang;Lee, Daeeop;Jung, Sungho;Lee, Giha
    • Journal of Korea Water Resources Association
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    • v.51 no.6
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    • pp.481-490
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    • 2018
  • Recently, the spatiotemporal patterns of flood disasters have become more complex and unpredictable due to climate change. Flood hazard map including information on flood risk level has been widely used as an unstructured measure against flooding damages. In order to product a high-precision flood hazard map by combination of hydrologic and hydraulic modeling, huge digital information such as topography, geology, climate, landuse and various database related to social economic are required. However, in some areas, especially in developing countries, flood hazard mapping is difficult or impossible and its accuracy is insufficient because such data is lacking or inaccessible. Therefore, this study suggests a method to delineate large scale flood-prone area based on topographic factors produced by linear binary classifier and ROC (Receiver Operation Characteristics) using globally-available geographic data such as ASTER or SRTM. We applied the proposed methodology to five different countries: North Korea Bangladesh, Indonesia, Thailand and Myanmar. The results show that model performances on flood area detection ranges from 38% (Bangladesh) to 78% (Thailand). The flood-prone area detection based on the topographical factors has a great advantage in order to easily distinguish the large-scale inundation-potent area using only digital elevation model (DEM) for ungauged watersheds.

Synthesis of ITO Nano-Particles by a SAS Method and Preparation of Conductive Film by Coating Them (SAS법을 이용한 ITO 나노입자의 합성과 ITO 도포에 의한 도전필름의 제조)

  • Kim, Moon-Sun;Yun, Sang-Ho;Kim, Byung-Woo
    • Clean Technology
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    • v.13 no.3
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    • pp.180-187
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    • 2007
  • The indium tin oxide(ITO) film on PET was prepared by a wet coating method to obtain the transparent film with a high conductance. ITO nano-particles was synthesized by a SAS method at 15 MPa and $50^{\circ}C$, where optimized rate of In/Sn was 65. Average diameter and resistivity of ITO obtained from SAS are $15{\pm}2\;nm$ and $4{\times}10^4\;{\Omega}{\cdot}cm$. Coating solution was prepared at pH 10. The ITO film was obtained by solution including 0.1 0.5, 1, and 2 ITO wt% on PET. Roughness(Ra) of ITO film with 0.1, 0.5, 1. and 2 ITO wt% is 4, 10, 12, and 16 nm. Resistivity with an increasing ITO concentration is $3.7{\times}10^6,\;2.4{\times}10^6,\;8{\times}10^5,\;and\;2{\times}10^5\;{\Omega}{\cdot}cm$. Transmissivity of ITO film decreased as 89, 88, 86, and 82% with an increasing ITO concentration as 0.1, 0.5, 1, and 2 wt%.

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Determination of Hydraulic Parameters in Unconfined Sandy Aquifer in a Laboratory Scale (실내 자유면 사질 대수층의 수리상수 결정)

  • 김정석;김동주
    • Journal of the Korean Society of Groundwater Environment
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    • v.6 no.3
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    • pp.152-157
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    • 1999
  • Oil leaked from underwound storage tanks and leachate from sanitary landfills have been known as contaminant sources of the high-quality groundwater resources. The mobility of contaminants in the aquifer largely depends on the groundwater flow and the determination of associated hydraulic parameters is essential for a proper remediation of contaminated grnundwater. This study aimed at determining an optimum set of hydraulic parameters for an unconfined sandy aquifer of a laboratory scale through comparison of various methods. Results showed that the specific yield obtained from gravity drainage experiment was an average of 0.20 with minor variations in aquifer depths. and the permeabilities obtained from Dupuit approximation and slug test gave similar values of 5.33 cm/min and 5.85 cm/min but the constant head method gave 0.17 cm/min, which is much ion than the other methods. This experimental evidence reveals that the permeability of the unconfined sandy aquifer could be accurately determined by Dupuit assumption or slug tut rather than by constant head method conducted for a disturbed separate soil column.

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Microwave Mediated Production of FAME from Waste Cooking Oil : Optimization of Process Parameters by RSM (마이크로웨이브를 이용한 폐식용유로부터 FAME의 제조 : RSM에 의한 공정변수 최적화)

  • Hong, In Kwon
    • Applied Chemistry for Engineering
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    • v.31 no.2
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    • pp.172-178
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    • 2020
  • In this study, the optimization of the biodiesel production process from waste oil using microwave with response surface methodology (RSM) was conducted. The microwave irradiation time and power in addition to the alcohol/oil mole ratio were chosen as process parameters. Also the fatty acid methyl ester (FAME) content (over 96.5%) and kinematic viscosity (1.9~5.5 cSt) were selected as response values. From basic experiments, the range of quantitative factors were set as following; 4~6 min, 400~600 W, and 7~9 for the microwave irradiation time and power, and alcohol/oil molar ratio, respectively. The optimum conditions for the methanolysis were 5.0~5.1 min, 481.3~525.5 W, 7.9~8.4, and 2.0 or 3.0 mg KOH/g for the microwave irradiation time and power, methanol/oil molar ratio, and each acid value, respectively. The FAME content and kinematic viscosity were predicted as 97.49~96.34% and 4.01~4.12 cSt, respectively, under the condition above. Under the optimum experimental conditions, the results showed that the FAME content and kinematic viscosity of 97.82~96.42% and 4.07~4.16 cSt, respectively were measured and the mean error rates were 0.22% and 0.98%, respectively.

A Development of Optimum Operation Models for Express-Rail Systems (급행열차 도입을 통한 최적운행방안 수립에 관한 연구 - 수도권 광역 도시철도를 중심으로 -)

  • Park, Jeong-Soo;Lee, Hoon-Hee;Won, Jai-Mu
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.4D
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    • pp.679-686
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    • 2006
  • Recently, the city railway in the Seoul Metropolitan Area (SMA) has offered a low quality of service as a passage time, because it was operated slowly. So, the people who live in modern society are not satisfied about passage time, therefore, this study tried to make that the subway in the SMA becomes a more functional and effective wide-area-transportation-network through an express train introduction's method which examined cases from abroad and current system. and then presented how express train could be applied to current system. In a case study, We used the An-San Line and Su-In Line as a examples and developed a schedule which can minimize the delaying time of subway by using Branch & Bound Algorithm. The train operational plan was loaded to consider a railroad siding, Obtained site, and the dispatch interval(three to ten minutes) for the express and local lines and finally, We presented an alternative operational plan which made by those factors.

Development of Measuring Technique for Milk Composition by Using Visible-Near Infrared Spectroscopy (가시광선-근적외선 분광법을 이용한 유성분 측정 기술 개발)

  • Choi, Chang-Hyun;Yun, Hyun-Woong;Kim, Yong-Joo
    • Food Science and Preservation
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    • v.19 no.1
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    • pp.95-103
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    • 2012
  • The objective of this study was to develop models for the predict of the milk properties (fat, protein, SNF, lactose, MUN) of unhomogenized milk using the visible and near-infrared (NIR) spectroscopic technique. A total of 180 milk samples were collected from dairy farms. To determine optimal measurement temperature, the temperatures of the milk samples were kept at three levels ($5^{\circ}C$, $20^{\circ}C$, and $40^{\circ}C$). A spectrophotometer was used to measure the reflectance spectra of the milk samples. Multilinear-regression (MLR) models with stepwise method were developed for the selection of the optimal wavelength. The preprocessing methods were used to minimize the spectroscopic noise, and the partial-least-square (PLS) models were developed to prediction of the milk properties of the unhomogenized milk. The PLS results showed that there was a good correlation between the predicted and measured milk properties of the samples at $40^{\circ}C$ and at 400~2,500 nm. The optimal-wavelength range of fat and protein were 1,600~1,800 nm, and normalization improved the prediction performance. The SNF and lactose were optimized at 1,600~1,900 nm, and the MUN at 600~800 nm. The best preprocessing method for SNF, lactose, and MUN turned out to be smoothing, MSC, and second derivative. The Correlation coefficients between the predicted and measured fat, protein, SNF, lactose, and MUN were 0.98, 0.90, 0.82, 0.75, and 0.61, respectively. The study results indicate that the models can be used to assess milk quality.