• Title/Summary/Keyword: 촉매 변환기

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Flow Field Measurement in Catalytic Converter-Comparison with Computational Fluid Dynamics Analyses (촉매 변환기의 내부 유동장 측정-CFD 해석과 비교)

  • Yoo, Seoung-Chool;Jang, Sung-Kuk
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.38 no.3
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    • pp.197-202
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    • 2014
  • The efficiency of a catalytic converter depends on the flow distribution across a system's chemically active substrate. If irregularities or non-uniform flow patterns exist, the system's conversion efficiency decreases, whereas the manufacturing cost increases. Therefore, it is important to analyze the internal flow of a catalytic converter. In this study, flow pattern measurements along the minor axis were recorded at the mid and exit planes of a ceramic honeycomb catalytic converter at flow rates of 37.8 l/s and 94.4 l/s. Flow distributions of the measurement plans were compared with an automotive company's computed velocity profiles. Measurements along the minor axis showed uneven velocity profiles. The ${\upsilon}$-velocity components between the honeycomb bricks were small but somewhat erratic opposite the intake side of the converter, however, they became flatter in measurements recorded near the intake entrance. For almost all velocity values, the computer model suggested velocities greater than the measured values.

Preparation of Porous Ceramic Bead using Mine Tailings and Its Applications to Catalytic Converter (광미(鑛尾)를 활용(活用)한 다공성 세라믹 비드 제조(製造) 및 촉매(觸媒) 변환기(變換機)로의 응용(應用))

  • Seo, Junhyung;Kim, Seongmin;Han, Yosep;Kim, Yodeuk;Lee, Junhan;Park, Jaikoo
    • Resources Recycling
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    • v.22 no.4
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    • pp.38-45
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    • 2013
  • The porous ceramic beads using mine tailing were prepared and applied to catalytic converter for NOx/SOx removal. Catalytic support was used synthesized mesoporous silica (SBA-15) which coated on surface. Internal structure for porous ceramic beads was composed of three-dimensional network structure and porosity was about 80%. In addition, the specific surface area for mesoporous silica(SBA-15) coated on converter was significantly increased 55 $m^2/g$ compared with 0.8 $m^2/g$ before coating. NOx/SOx removal experiment was performed using $V_2O_5$ and $V_2O_5$/CuO converter. NOx conversion ratio for $V_2O_5$/CuO converter was approximately increased 10% compared to $V_2O_5$ converter. In addition, catalytic converter of $V_2O_5$/CuO was shown to remove 95% of NOx and 90% of SOx at reaction temperature of $350^{\circ}C$, space velocity of 10000 $h^{-1}$ and $O_2$ concentrations of 5%, respectively.

Design of the Stand-alone Autothermal Reformer for Natural Gas (자체 기동형 천연가스 자열개질기 설계)

  • Koo, Jeongboon;Kim, Youngae;Kwon, Hyunji;Kwak, Inseob;Sin, Jangsik
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.113.1-113.1
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    • 2010
  • 본 연구에서는 중 소형 SOFC에 적용할 수 있는 연료 변환 시스템으로 자체 기동 및 독립운전이 가능한 천연가스 자열개질(ATR) 반응기를 $10Nm^3/hr$급으로 개발하고자한다. 설계된 천연가스 자열개질기는 자열개질 촉매를 코팅한 금속 모노리스형 촉매체를 반응기 내에 장착함으로써 반응열을 신속하게 제거 또는 공급할 수 있는 시스템으로 구성되었다. 이는 금속 모노리스의 뛰어난 열전도 능력에 의해 반응기 내의 촉매층 전체 온도 분포를 균일하게 유지할 수 있는 저에너지형 자열개질 반응기이다. 또한 빠른 기동 특성을 실현하기 위하여 전기 발열식 촉매체(EHC ; Electically Heated Catalyst)를 장착한 start-up 시스템을 적용하여 천연가스 자열개질 반응기의 신속한 기동과 장치 간편화를 실현하였으며, 합성 syngas의 배열 회수를 위한 최적 열교환 시스템을 설계/적용함으로써 에너지 효율 향상을 도모하였다. 이와 같은 촉매 및 구조 시스템을 가지는 천연가스 자열개질 반응용 소형 연료변환 시스템을 원통형의 이중관 구조로 구성하고, 독립운전 모드로 개발함으로써 소형 SOFC의 연료 변환장치의 적용에 용이하게 하고자 한다.

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Numerical Evaluation of a Radially Variable Cell Density Strategy for Improving Light-off Performance: Focusing on Light-off Catalyst (자동차용 촉매변환기의 활성화 성능 향상을 위한 횡방향 가변 셀 밀도법의 수치적 평가: 활성화 촉매변환기를 중심으로)

  • 정수진;김우승
    • Transactions of the Korean Society of Automotive Engineers
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    • v.10 no.1
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    • pp.115-124
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    • 2002
  • The optimum design of auto-catalyst needs a good compromise between the pressure drop and flow distribution in the monolith. One of the effective methods to achieve this goal is to use the concept of radially variable cell density. However, there has been no study of evaluating the usefulness of this method on light-off catalyst. We have computationally investigated the effectiveness of variable cell density technique applied to the light-off catalyst using a three-dimensional integrated CFD model. in which transient chemical reacting calculations are involved. Computed results show that variable cell density technique can reduce the accumulated emissions of CO and HC during the early 100sec of FTP cycle by 86.78 and 80.87%, respectively, The effect of air-gap between the monoliths has been also examined. It is found that air-gap has a beneficial effect on reducing pressure drop and cold-start emissions.

Development of Program for Predicting GBD to Improve Canning Process Capability for Catalytic Converter (촉매변환기의 캐닝 공정능력 향상을 위한 GBD 예측 프로그램의 개발)

  • Lee, Young Dae;Chu, Seok Jae
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.3
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    • pp.419-427
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    • 2013
  • The catalytic converters for automobile exhaust systems are manufactured by inserting a mat-wrapped substrate into a stainless steel can. A residual pressure that is too high will initiate a fracture in the substrate. In contrast, a residual pressure that is too low will fail to hold the substrate in the acceleration or deceleration phase. Both the process capability and mat pressure on the substrate are predicted while considering the effect of the statistical variation in the dimensions of the parts. The validity of the solutions is then confirmed. A program using EXCEL combines a finite element analysis and process capability analysis in one program.

An Estimation of Thermal fatigue in Three-way catalyst (삼원촉매장치의 열 피로 평가)

  • Cho, Seok-Swoo;Lee, Hyun-Chang;Park, Woo-Chul;Choi, Hyun-Jin
    • Proceedings of the KAIS Fall Conference
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    • 2009.12a
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    • pp.163-166
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    • 2009
  • 현재 자동차 검사 또는 정비 현장에서는 특정 삼원촉매변환기가 요구 내구 수명을 제대로 만족시키지 못하여 파손되는 사례가 발생되고 있다. 이러한 삼원촉매장치의 경우 배기가스 변환 효율이나 압력강하 등은 엔진 효율 측면에서 만족되지만 열적 내구성은 만족되지 못한다. 본 연구에서는 열유동 해석 및 구조 해석을 통하여 국내 승용차용 삼원촉매 변환기의 대한 열적 안전성에 대하여 검토하였다.

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Three-Dimensional Flow Analysis of Catalytic Converter for Reducing Emission (배출물 저감을 위한 촉매변환기 내의 3차원 유동해석)

  • 정수진;김우승
    • Transactions of the Korean Society of Automotive Engineers
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    • v.6 no.5
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    • pp.55-65
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    • 1998
  • A numerical and experimental study of three-dimensional steady incompressible non-reacting flow inside various dual-monolith catalytic converters has been conducted for achievement of performance improvement, reduction of light-off time and longer service life by improving the flow uniformity within the monolith. In this study, the effects of curvature of inlet exhaust pipe and monolith brick length on the flow uniformity and pressure drop within monolith were numerically investigated. The computations are confirmed by measurements of steady flow. The agreement between computations and experiment was relatively good. The result of this study shows that curvature of inlet exhaust pipe and monolith brick length gave a great effect on the flow uniformity and the shorter the brick length, the lower flow uniformity and the less pressure drop.

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A Study of Light-off Performance of Catalytic Converter with the Effect of Flow Characteristics (유동특성을 고려한 촉매변환기의 활성화(Light-off) 성능에 관한 연구)

  • 정수진;김우승
    • Transactions of the Korean Society of Automotive Engineers
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    • v.7 no.5
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    • pp.107-120
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    • 1999
  • Catalytic converters are the most fascinating and complicated chemical reactors. They are most often operated in the transient state with respect to composition, flow rate, temperature, etc. The mathermatical model developed in this work accounts for simultaneous heat and mass transfer, chemical reaction, and multi dimensional flow characteristics to analyze the light-off performance of monolithic catalytic converter with comparable mass flow rate. To validate the mathematical model, comparison between experimental and numerical results has been performed. The numerical results show a good agreement with experimental data. It is forund that inflow rate shows major effect on the characteristics of termal response of catalytic converter.

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Design and Computer Control of a Sliding Mode Fuel-Injection Controller for MPI Gasoline Engines (MPI 가솔린 엔진용 슬라이딩 모드 연료분사 제어기 설계 및 컴퓨터 제어)

  • 김종식;고용서;강건용;황이철
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.15 no.3
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    • pp.1030-1043
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    • 1991
  • 본 연구에서는 모델링오차나 외란 등의 불확실성에도 강인한 슬라이딩 모드 제어방법을 이용하여 새로운 연료분사 제어기를 설계하였다. 그리고 8253 타이머와 A/D 변환기, 인터페이스회로 등으로 MPI가솔린 엔진용 전자 제어장치를 실제 엔진에 적용시킴으로써 새로이 설계된 연료분사 제어시스템의 성능을 파악하였다.엔진의 운전상태를 여러가지 제어 모드로 분류할 수 있으나 엔진회전수가 2000rpm, 부하가 20N의 일정한 부하 조건에서 엔진회전수를 1500rpm에서 2000rpm으로 변화시켰을 때의 과도상태 응답을 파악하였다. 이와 같이 새로운 슬라이딩 모드 연료분사 제어시스템 을 개발하여 3원촉매 변환기의 변환효율을 극대화함으로써 배기가스의 유해물질을 최 소화하는 것을 본 연구의 목적으로 하였다.