• Nuclear Engineering and Technology
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• v.27 no.1
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• pp.121-132
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• 1995

중수로형 원자력 발전소에서는 가동년수가 증가함에 따라 중수는 삼중수소로 오염된다. 오염된 중수의 정화에 적합한 공정으로 평가되는 기액촉매교환-화학평형 -증류공정으로 이루어진 촉매복합공정의 주요 설계변수를 설정하여, 이 변수들이 촉매탑 및 증류탑의 용적과 초저온 냉동부하에 미치는 영향을 분석하였다. 촉매탑은 조작선 기울기가 약 0.634, 그리고 제 1, 제 2 증류탑의 농축율 및 삼중수소 제거율을 변화시킬 때 최적 환류비 값이 각각 약 7과 4.7일 때 최적조건임을 밝혔다. 그리고 저온증류공정해석을 위하여 Fenske, Underwood, and Gilliland Equation과 Smoker Equation을 사용하여 이 두모델식의 계산값을 비교 검토한 결과 거의 유사한 설계값을 얻을 수 있음을 확인하였다.

• Korean Chemical Engineering Research
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• v.53 no.3
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• pp.372-381
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• 2015

The effect of preparation method on the catalytic activities of the $Ni/Al_2O_3$ catalysts on steam reforming of ethylene glycol was investigated. The catalysts were prepared with various preparation methods such as an incipient wetness impregnation, wet impregnation, and coprecipitation method. In the case of coprecipitation method, various precipitants such as KOH, $K_2CO_3$, and $NH_4OH$ were compared. The prepared catalysts were characterized by using $N_2$ physisorption, inductively coupled plasma-atomic emission spectroscopy, X-ray diffraction, temperatureprogrammed reduction, pulsed $H_2$ chemisorption, temperature-programmed oxidation, scanning electron microscopy, and thermogravimetric analysis. Among the catalysts reduced at 773 K, the $Ni/Al_2O_3$ catalyst prepared by a coprecipitation with KOH or $K_2CO_3$ as precipitants showed the best catalytic performance. The preparation method affected the particle size of Ni, reducibility of nickel oxides, catalytic performance (activity and stability), and types of coke formed during the reaction. The $Ni/Al_2O_3$ catalyst prepared by a coprecipitation with KOH showed the increasing catalytic activity with an increase in the reduction temperature from 773 to 1173 K because of an increase in the reduction degree of Ni oxide species even though the particle size of Ni increased with increasing reduction temperature.

• Journal of Korean Society of Environmental Engineers
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• v.37 no.10
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• pp.558-562
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• 2015

This study was tested to evaluate the effect of the six different combinations of microbubble, catalyst, and air as oxidant on the sludge and organic matter reduction. When all of microbubbles and catalyst, and an oxidizing agent (under Conditions 1) such as air were used, the sludge was removed more than 99%, and TCOD and SCOD removal was 58% and 13%, respectively. This result was the highest value of six conditions. In the following order, the sludge reduction of the microbubbles with air (Condition 2) and catalyst with air (condition 4) was 95% and 93.1%, respectively. TCOD removal was found to be each 53% and 47%. When the microbubbles were used with oxidant like air, the removal of sludge and organic matter was high. All of these values were higher than that of using only microbubbles and catalyst without air. In the microbubbles and catalyst react under air supply condition, OH-radicals were generated in the reaction process. These OH-radicals in the reaction process decomposed the pollutants by the strong oxidizing power. In all conditions with air, the sludge reduction was high removal rate more than 93% and TCOD removal was over 47%.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2006.11a
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• pp.407-412
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• 2006

Most of the monopropellant thrusters use catalyst for decomposing hydrazine. The thruster lifetime is determined mainly by catalyst lifetime, which can be investigated by firing tests. For the development of hydrazine decomposition catalyst, Hot-fire test to verify long-life performance of catalyst is required. This study describes the development of test equipment for long duration hot-firing and test/evaluation plan.

• Polymer(Korea)
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• v.29 no.1
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• pp.14-18
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• 2005

Nylons were synthesized by anionic polymerization of ${\varepsilon}$--caprolactam while varying the content of catalyst. Polymerization rates, molecular weights, mechanical properities and frictional properties of the nylons were investigated. As the ratio of catalyst to initiator was increased up to 1.0%, the polymerization rate, conversion and molecular weight were found to increase, and mechanical properties except impact strength were improved. Frictional properties were affected mainly by tensile strength and hardness. According to the study on the friction coefficient, product of stress (P) and velocity (V), PV limit, and abrasive wear rate, nylon synthesized at 1.0% of the ratio of catalyst to initiator showed the best performance for sliding machine elements.

• The tire
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• s.7
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• pp.25-29
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• 1967

이미 Srereo Rubber 에 관해서 많은 연구보문이 발표된 바 있으나 대부분이 중합법, 성질 및 가공법등을 품목별 또는 부분적으로 해설한 것이기 때문에 본장에서는 미국제를 중심으로 각종 Stereo Rubber 의 중합촉매, 구조특성 및 가공특성등을 함께 묶어서 논술한 것을 소개코자 미국 Ohio주 Akron시 수강한 "Stereo Rubber"란 제목을 간추린 것이다.

• Korean Journal of Crystallography
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• v.4 no.1
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• pp.36-41
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• 1993

Small angle X-ray scattering was used to study on the oxopolymers of sols derived from BaTiethoxide. The growths of the oxopolymers in tools obtained with NH40H as catalyst and catalystfree sol are similar. Their radii of gyration are 1.66-2.08nm. They exhibit a mass fractal behavior with a dimension of 1.6, which is almost inde pendent with amount of NH40H addition. Sols catalyzed with CHSCOOH have greater radii of gyration of 3.24-4.OOnm. Their scattering curves are similar in the intermediate Q region, showing a mass fractal dimension of 1.8. The oxopolymers of the tools from the base and the neutral hydrolysis conditions may have a short chain structure.

• 발명특허
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• v.29 no.10 s.340
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• pp.38-43
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• 2004

• Proceedings of the KAIS Fall Conference
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• 2000.10a
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• pp.237-240
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• 2000

본 연구에서는 비스페놀 A, 에피크로로히트린을 반응시킨 에폭시 기본주제를 중심으로 경화제, 희석제, 충진제, 촉매 등을 배합하여 토목, 건축용 반고체형 에폭시 접착제를 개발하였다. 여기서 특히 에폭시 주제와 희석제의 종류 및 배합비율에 따른 기본 물성, 접착성능 등을 측정하였다. 상온 경화 특성을 측정하기 위하여 경화시 간을 측정한 결과 희석제의 종류와 관계없이 희석제의 양이 증가할수록 경화시간이 증가하고 경화온도도 증가하는 경향을 알 수 있었으며 촉매의 양이 적을 경우가 경화시간이 빠른 것을 알 수 있었다. 또한 경화 시간은 30분 내지 40분 정도로 상온에서 사용할 수 있을 것으로 기대한다. 접착력 시험 결과는 촉매의 양이 적당한 때 가장 좋은 접착력을 나타내고 희석제 중에서 HDGE의 경우가 가장 좋은 접착력을 나타내었고 희식제의 양이 증가할수록 접착력은 증가하였다. 실리카와 철분을 섞어 반고체형 에폭시 접착제를 제조한 경우 기존의 제품보다 우수한 접착력을 나타내었다. 따라서 본 연구에서 개발한 반고체형 접착제는 제조공정 코스트 등에 대한 검토와 함께 제품화하여 토목, 건축 분야의 콘크리트 균열 접착, 볼트와 콘크리트의 접합, 목재의 접합 등에 간편하게 사용될 수 있으며, 배합물질과 비율에 따라 전기전자. 토목건축, 자동차산업 등의 산업용 접착제로서 응용될 수 있을 것으로 기대된다.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2002.11a
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• pp.263-264
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• 2002

연소시설에서 배연가스중의 NOx 배출을 저감하기 위하여 선택적 촉매 환원법(SCR)과 선택적 무촉매 환원법(SNCR)이 널리 이용되고 있다. 이러한 촉매처리는 Pt와 같은 귀금속이 포함된 촉매 하에서 암모니아를 환원제로 사용하였으나, R와 같은 귀금속의 경우 배연가스내에 함유된 중금속이나 비소(Arsenic), SOx, 비산재(fly ash)등에 의해 쉽게 비활성화(deactivation)되는 단점이 있다(Sumitra R et al., 1995). (중략)