• Title/Summary/Keyword: 초임계의

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Monitoring and detecting $CO_2$ injected into water-saturated sandstone with joint seismic and resistivity measurements (탄성파 및 비저항 동시측정에 의한 수포화 암석시료에 주입된 $CO_2$ 모니터링 및 탐지)

  • Kim, Jong-Wook;Matsuoka, Toshifumi;Xue, Ziqiu
    • Geophysics and Geophysical Exploration
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    • v.14 no.1
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    • pp.58-68
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    • 2011
  • As part of basic studies of monitoring carbon dioxide ($CO_2$) storage using electrical and seismic surveys, laboratory experiments have been conducted to measure resistivity and P-wave velocity changes due to the injection of $CO_2$ into water-saturated sandstone. The rock sample used is a cylinder of Berea sandstone. $CO_2$ was injected under supercritical conditions (10 MPa, $40^{\circ}C$). The experimental results show that resistivity increases monotonously throughout the injection period, while P-wave velocity and amplitude decrease drastically due to the supercritical $CO_2$ injection. A reconstructed P-wave velocity tomogram clearly images $CO_2$ migration in the sandstone sample. Both resistivity and seismic velocity are useful for monitoring $CO_2$ behaviour. P-wave velocity, however, is less sensitive than resistivity when the $CO_2$ saturation is greater than ~20%. The result indicates that the saturation estimation from resistivity can effectively complement the difficulty of $CO_2$ saturation estimations from seismic velocity variations. By combining resistivity and seismic velocity we were able to estimate $CO_2$ saturation distribution and the injected $CO_2$ behaviour in our sample.

Antimicrobial Activity of Ginger(Zingiber officinale Roscoe) Oleoresin by Supercritical Fluid Extraction (초임계유체 추출에 의한 생강(Zingiber officinale Roscoe) Oleoresin의 항균활성)

  • Lee, Myung-Hee;Lee, Kyoung-Hae;Kim, Kyung-Tack;Kim, Sung-Soo
    • Journal of Food Hygiene and Safety
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    • v.27 no.2
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    • pp.109-116
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    • 2012
  • The study indicated that antimicrobial activity about gram positive and gram negative bacteria of ginger-oleoresin(GO) extract with the condition of ethanol and supercritical fluid extractions. As the concentration of extraction increases, the clear zone of GO ethanol extract also increased dependently. This led the antimicrobial activity of gram positive bacteria to take bigger place than gram negative bacteria especially in Listeria monocytogenes. There was a high antimicrobial activity in E-III treatment where the ratio of the ginger powder extract to ethanol extraction was 1:6. It was quite effective to treat the antimicrobial activity of GO ethanol extract under $80^{\circ}C$ and there was not big difference in the intervals which were the extraction time - 1 to 7 hours. The antimicrobial activity of supercritical fluid extract seemed to take the biggest place in Listeria monocytogenes. From the supercritical fluid extract, it was shown the strong ability of antimicrobial activity in the condition with 100 bar $35^{\circ}C$, 250 bar $35^{\circ}C$ and 250 bar $65^{\circ}C$. Furthermore, according to the case of solvent extract, there was not any significant difference in the antimicrobial activity with condition of extraction. However, there was significant antimicrobial activity in E-III treatment of 100 bar and 500 bar of extraction pressure, and $35^{\circ}C$ and $65^{\circ}C$ of extraction temperature.

Experimental Study on the Geochemical and Mineralogical Alterations in a Supercritical CO2-Groundwater-Zeolite Sample Reaction System (초임계 이산화탄소-지하수-제올라이트 시료 반응계에서의 지화학적 및 광물학적 변화에 관한 실험적 연구)

  • Park, Eundoo;Wang, Sookyun;Lee, Minhee
    • Economic and Environmental Geology
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    • v.47 no.4
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    • pp.421-430
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    • 2014
  • In this study, a series of autoclave experiments were conducted in order to investigate the geochemical and mineralogical effects of carbon dioxide on deep subsurface environments. High pressure and temperature conditions of $50^{\circ}C$ and 100 bar, which are representative environments for geological $CO_2$ sequestration, were created in stainless-steel autoclaves for simulating the interactions in the $scCO_2$-groundwater-mineral reaction system. Zeolite, a widespread mineral in Pohang Basin where many researches have been focused as a candidate for geological $CO_2$ sequestration, and groundwater sampled from an 800 m depth aquifer were applied in the experiments. Geochemical and mineralogical alterations after 30 days of $scCO_2$-groundwater-zeolite sample reactions were quantitatively examined by XRD, XRF, and ICP-OES investigations. The results suggested that dissolution of zeolite sample was enhanced under the acidic condition induced by dissolution of $scCO_2$. As the cation concentrations released from zeolite sample increase, $H^+$ in groundwater was consumed and pH increases up to 10.35 after 10 days of reaction. While cation concentrations showed increasing trends in groundwater due to dissolution of the zeolite sample, Si concentrations decreased due to precipitation of amorphous silicate, and Ca concentrations decreased due to cation exchange and re-precipitation of calcite. Through the reaction experiments, it was observed that introduction of $CO_2$ could make alterations in dissolution characteristics of minerals, chemical compositions and properties of groundwater, and mineral compositions of aquifer materials. Results also showed that geochemical reactions such as cation exchange or dissolution/precipitation of minerals could play an important role to affect physical and chemical characteristics of geologic formations and groundwater.

Experimental Study on the Secondary Flow Characteristics of a Supercritical Carbon Dioxide Flow in a Gas Cooling Process Within a Square Duct (정사각 덕트 초임계 상태 이산화탄소 가스 냉각과정 중 2차 유동 특성 측정 연구)

  • Han, Seong-Ho;Seo, Jung-Sik;Kim, Young-Chan;Kim, Min-Soo;Choi, Young-Don
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.2
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    • pp.158-165
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    • 2008
  • The carbon dioxide properties change sharply near the critical or pseudo-critical point in the heat transfer processes. The reduction in turbulent, convective heat transfer parameters observed in some supercritical data and in experiments with common gases can be due to property variation, acceleration, buoyancy or combinations of these phenomena, depending on the conditions of the applications. In this study, the measurement for the secondary flow driven by buoyancy was carried out on the supercritical carbon dioxide turbulent flows in the different boundary condition with the constant mass flow rate. The available measuring techniques were used to clarify the behaviour of any supercritical fluid. Laser Doppler Velocimeter (LDV) and a special device was used to measure the secondary velocity and turbulent characteristics of the supercritical flows.

An Experimental Study on Heat Transfer and Pressure Drop Characteristics during Supercritical Process of Carbon Dioxide in a Horizontal Tube (수평관 내에서 이산화탄소 초임계 가스냉각 과정의 열전달 및 압력강하 특성에 관한 실험적 연구)

  • 최이철;강병하;김석현
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.5
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    • pp.414-420
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    • 2004
  • The heat transfer and pressure drop characteristics associated with the gas cooling of the supercritical carbon dioxide in a horizontal tube have been investigated experimentally. This problem is of particular interest in the design of a gas cooler of cooling systems using $CO_2$refrigerant. The test section is consisted of 6 series of 455 mm in length, 4.15 mm ID copper tube, respectively. The effects of the inlet temperature, pressure and mass flow rate on the heat transfer and pressure drop of $CO_2$in a horizontal tube is studied in detail. The heat transfer coefficient of $CO_2$is varied by temperature, inlet pressure, and mass flow rate of $CO_2$. This has maximum value at near the pseudocritical temperature. The pressure drop is changed by inlet pressure and mass flow rate of $CO_2$. The results have been compared with those of previous work. The heat transfer correlation at the supercritical gas cooling process is also suggested.

Effects of Convective Velocity and Ambient Pressure on the Characteristics of Heptane Droplet Vaporization in Supercritical Environments (초임계상태에서 주위 유동 속도와 압력 변화에 따른 헵탄 액적의 기화 특성)

  • Lim, Jong-Hyuk;Lee, Bong-Su;Koo, Ja-Ye
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.33 no.4
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    • pp.71-78
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    • 2005
  • The vaporization characteristics of a liquid heptane droplet in a supercritical nitrogen flow is numerically analyzed. The present model can account for real gas effects, liquid-phase internal circulation, variable thermodynamic properties and high-pressure effects. Time marching method with preconditioning scheme is employed to handle the low Mach number flows in dense heptane droplet region. Computations are made for the wide range of convective velocity and ambient pressure. Numerical results indicate that the droplet deformation becomes stronger by increasing the Reynolds number and it becomes relatively weak by increasing the pressure.

Solubility of Triclosan in Supercritical Carbon Dioxide and its Application to Micronization Process (초임계이산화탄소내 트리클로산의 용해도와 미세입자 제조공정의 응용)

  • Shin, Moon-Sam;Kim, Hwa-Yong
    • Clean Technology
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    • v.14 no.3
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    • pp.153-159
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    • 2008
  • The solubility of triclosan, an anti-acne agent was measured in supercritical carbon dioxide ($scCO_2$) with a variable volume view cell at 313.15, 323.15, and 333.15 K and at pressures between 10 and 40 MPa. We successfully correlated triclosan solubility in $scCO_2$ using the quasi-chemical nonrandom lattice fluid (QLF) equation of state. Triclosan was micronized using the rapid expansion of supercritical solutions (RESS) process. The effects of temperature and pressure on particle size were investigated using phase behavior data and correlated results from the QLF model.

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