• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2009.11a
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• pp.42-46
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• 2009

For understanding of high performance liquid rocket engine operating at high pressure, dynamic characteristics of liquid oxygen in a swirl injector operating at supercritical conditions has been numerically investigated. Turbulent numerical model is based on large eddy simulation and contains full conservation laws including Soave modification of Redlich-Kwong equation of state and Chung's model. Preconditioning method is applied to get an effective convergence rate. Numerical analysis results are compared with the one that ideal equation of state applied to. Differences of thermodynamic properties and mixing dynamics are investigated at liquid phase area inside injector and combustion chamber.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.38 no.8
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• pp.823-833
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• 2010

For the study of thermophysical properties of kerosene for the liquid rocket and aviation fuels, the surrogate models are investigated. The density distributions based on the real gas equations of state(Soave modification of Redlich-Kwong and Peng-Robinson equation of state) and NIST SUPERTRAPP(extended corresponding state principle) are compared with the previous experimental results at supercritical conditions. The error range of thermophysical properties analyzed for the surrogate models as well. Peng-Robinson equation of state and extended corresponding state principle are especially accurate for the hydrocarbon fuels but the appropriate surrogate models need to be chosen to the operation conditions such as pressure and temperature.

• Journal of the Korean Society of Propulsion Engineers
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• v.17 no.6
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• pp.48-58
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• 2013

Characteristics of thermophysical properties and flow structures in a swirl injector at supercritical pressure have been investigated using the kerosene surrogate consisting of four species and various ideal and real gas equations of state. The quantitative comparisons of thermophysical properties for equations of state have been performed. Also, a large eddy simulation and preconditioning technique for getting an effective convergence rate are applied to analyze turbulent flow in a swirl injector. The flow characteristics in the injector has significantly different behaviors depending on the equations of state due to the different thermophysical properties in the injector. The Redlich-Kwong-Peng-Robinson equation of state provides the most suitable results in the wide range of temperature.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2003.11a
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• pp.121-126
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• 2003

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.16 no.6
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• pp.538-545
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• 2004

This paper presents the experimental data for the heat transfer and pressure drop characteristics obtained during the gas cooling process of carbon dioxide in a horizontal tube. The tube in which carbon dioxide flows is made of copper with an inner diameter of 7.73 mm. Experiments were conducted for various mass fluxes and inlet pressures of carbon dioxide. Mass fluxes are controlled at 225, 337 and 450 kg/$m^2$s and inlet pressures are adjust-ed from 7.5 to 8.8 ㎫. The experimental results in this study are compared with the existing correlations for the supercritical heat transfer coefficient, which generally under-predict the measured data. Pressure drop data agree very well with those calculated by the Blasius' equation. Based on the experimental data, a new empirical correlation to estimate the near-critical heat transfer coefficients has been developed.

• Journal of ILASS-Korea
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• v.4 no.3
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• pp.8-14
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• 1999

The characteristics of the breakup process in supercritical spray is investigated during the injection of supercritical sulfur hexafluoride into dissimilar gases at supercritical pressures and subcritical temperature of the injected fluid. The visualization techniques used are backlighting and shadowgraph methods. The spray angles are measured and the breakup and mixing process are observed at near and supercritical conditions. The results show that spray angles are decreased with the in..ease of the ratio of density $(\frac{\rho_f}{\rho_g})$. At the supercritical temperature, the spray angles in atomization region are kept nearly constant such as the typical spray angle in gas injection. The mixing process is changed radically at the temperature where $\frac{d\rho}{dT}=\frac{1}{2}[\frac{d\rho}{dT}]_{max}$ at given pressure.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.28 no.3
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• pp.289-295
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• 2004

The heat transfer coefficient and pressure drop during gas cooling process of carbon dioxide in a horizontal tube were investigated. The experiments were conducted without oil in the refrigerant loop. The main components of the refrigerant loop are a receiver, a variable-speed pump, a mass flowmeter, an evaporator, and a gas cooler(test section). The main components of the water loop consist of a variable-speed pump, an isothermal tank, and a flowmeter. The gas cooler is a counterflow heat exchanger with refrigerant flowing in the inner tube and water flowing in the annulus. The test section consists of smooth, horizontal stainless steel tube of the outer diameter of 9.53mm and of the inner diameter of 7.75mm. The length of the test section is 6m. The refrigerant mass fluxes were 200∼300kg/(m2$.$s) and the inlet pressure of the gas cooler varied from 7.5㎫ to 8.5㎫. The main results were summarized as follows : Pressure drop of CO2 increases with increasing gas cooler pressure. The friction factors of CO2 in a horizontal tube show a relatively good agreement with the correlation by Blasius. The heat transfer coefficient of CO2 in transcritical region increases with decreasing gas cooler pressure and decreasing mass flux of CO2. Most of correlations proposed in a transcritical region showed significant deviations with experimental data except for those predicted by Gnielinski.

• Clean Technology
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• v.16 no.3
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• pp.191-197
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• 2010

Repair reaction of plasma damaged porous methyl doped SiOCH films was carried out with silylation agents dissolved in supercritical carbon dioxide ($scCO_2$) at various reaction time, pressure, and temperature. While a decrease in the characteristic bands at $3150{\sim}3560cm^{-1}$ was detectable, the difference of methyl peaks was not identified apparently in the FT-IR spectra. The surface hydrophobicity was rapidly recovered by the silylation. In order to induce effective repair in bulk phase, the wafer was heat treated before reaction under vacuum or ambient condition. The contact angle was slightly increased after the treatment and completely recovered after the subsequent silylation. Methyl groups were decreased after the plasma damage, but their recovery was not identified apparently from the FT-IR, spectroscopic ellipsometry, and secondary ion mass spectroscopy analyses. Furthermore, Ti evaporator was performed in a vacuum chamber to evaluate the pore sealing effect. The GDS analysis revealed that the open pores in the plasma damaged films were efficiently sealed with the silylation in $scCO_2$.

• Journal of the Korean Institute of Gas
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• v.11 no.3
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• pp.44-48
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• 2007

The cooling heat transfer characteristics of supercritical $CO_2$ in a helical coil gas cooler on the change of coil diameters are experimentally investigated. The main components of the refrigerant loop are a receiver, a variable speed pump, a mass flow-meter, a pre-heater and a helical coil gas cooler (test section). The test sections are made of a copper tube which the inner diameter is 4.55 mm and the helical coil diameters are done of 26.75 mm and 41.35 mm. The mass fluxes of refrigerant are varied from 200 to 800 [$kg/m^2s$] and the inlet pressures of gas cooler are 7.5 to 10.0 (MPa). A gas cooler with helical coil diameter of 26.75 mm has larger heat transfer coefficient than that of 41.35 mm. Also, when compared with experimental data and published correlations avaliable, most of correlations are under-predicted, but Pitla published correlations avaliable, most of correlations are under-predicted, but Pitla et al.'s correlation shows a relatively good coincidence with the experimental data except the region of pseudo critical temperature.

• Applied Chemistry for Engineering
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• v.9 no.1
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• pp.76-81
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• 1998

Physical adsorption on a silica gel(pore size of 80 nm, particle size of $10{\mu}m$)has been studied for binary mixture of acetone diluted in $CO_2$ by use of a FTIR transmission technique and we have compared the result of FTIR transmission technique with that of a chromatographic technique. Measurements were made at 313.2 K and under pressures up to 15MPa. As the pressure increases from 0.1MPa, the IA(Integral Absorbance) of the hydrogen-bonded OH groups interacting with acetone and adsorbed amount by use of a chromatographic technique increases at first, and reaches a maximum at a pressure below the critical pressure of $CO_2$, and then the intensities decrease gradually with increasing pressure. It is found that the pressure dependency of the chromatographic isotherm is a little larger than that of spectroscopic isotherm in the supercritical fluid region. This difference might be attributable to the weaker van der Waals force and relatively stronger hydrogen-bonding force influencing the adsorption of acetone on the sllica gel. The unique spectroscopic characteristics of amine group which vibrational frequencies of hydroxyl groups on the silica gel surface shift downward to about $1300cm^{-1}$ were measured from experimental result of triethylamine diluted in $CO_2$ or $N_2$.