• Applied Chemistry for Engineering
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• v.31 no.6
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• pp.668-673
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• 2020

In this work, ultrathin and two-dimensional (2D) cobalt hydroxide [Co(OH)2] nanosheets were synthesized by a sonication assisted liquid-phase exfoliation of bulk Co(OH)2. The resulting exfoliated Co(OH)2 is a hexagonal mono-layered nanosheet with a high specific surface area of 27.5 ㎡ g-1. The depolymerization of polyethylene terephthalate (PET) based on glycolysis reaction was also performed using an exfoliated Co(OH)2 catalyst. Excellent catalytic reaction performances were demonstrated; a high PET conversion and bis(2-hydroxyethyl) terephthalate (BHET) yield of both 100% using the nanosheet catalyst were achieved within a reaction time and temperature of 30 min and 200 ℃, respectively. The long-term stability of exfoliated Co(OH)2 catalysts was also demonstrated by recyclability tests of the catalyzed glycolysis reaction of PET over four cycles, showing both 100% of high PET conversion and BHET yield.

• Journal of the Korean Chemical Society
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• v.54 no.1
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• pp.59-64
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• 2010

The synthesis of a series of fluorinated thiadiazoles 3, triazoles 4 and oxadiazoles 5 are synthesized from thiosemicarbazides 2 containing (2-(6-methyl-2-p-tolyl-lH-imidazo[1,2-a]pyridin-3-yl nucleus. These reactions were carried out by conventional method as well as ultra sound irradiation method. All products have been characterized by IR, 1H NMR, MS study and screened for their antimicrobial activity.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.27 no.12
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• pp.2085-2091
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• 2003

An ultrasonic machining process has been known as efficient and economical means fer precision machining of glass or ceramic materials. However, because of its complexity, the mechanism of the machining process is still not well understood. Therefore, it is hard to optimize the process parameters effectively. The conventional ultrasonic machining which uses the abrasive slurry only, furthermore, is time-consuming and gives the relatively rough surface. In order to increase the material removal rate and improve the integrity of the machined surface, we have introduced the novel ultrasonic machining technique, Chemical-assisted UltraSonic Machining(CUSM). The desktop-style micro ultrasonic machine has been developed and the z-axis feed is controlled by the constant load control algorithm. To obtain the chemical effects, the low concentration HF(hydrofluoric acid) solution, which erodes glass, added to alumina slurry. Through various experiments and comparison with conventional results, the superiority of CUSM is verified. MRR increases over 200%, the surface roughness is improved and the machining load decreases dramatically.

• Analytical Science and Technology
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• v.24 no.2
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• pp.61-68
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• 2011

Ni-coated alumina was prepared by sonochemical method. To increase an efficiency of Ni coating on alumina, amorphous alumina was prepared by sol-gel method and Ni was coated to fine particles of alumina. Ni-coated alumina was prepared from various calcination temperatures ($500^{\circ}C$, $1,000^{\circ}C$), concentrations of Ni solution (0.01 M~0.2 M) and sonochemical reaction times (30 min, 2h). The prepared fine particles were characterized by X-Ray Diffractometer (XRD), Scanning Electron Microscope (SEM), Inductively Coupled Plasma Atomic Emission Spectroscopy (ICP-AES), and Particle Size Analyzer (PSA). The coating amount of Ni increased, as Ni concentration and ultrasonication time increased. The maximum amount of Ni was coated to fine particles of alumina, when Ni-coated alumina was prepared with 0.1 M concentration of Ni solution for 2 h of sonication time at $1000^{\circ}C$ of calcination temperature. The average particle size was in the range of 835.9 to 986.7 nm.

• Korean Chemical Engineering Research
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• v.47 no.2
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• pp.258-261
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• 2009

In this work, we the ettect on extraction amounts and general composition content of phytoestrogen genistein and formononetin extracted from Sophoraflavescens Aiton by various ultrasonic waves(35, 72, and 170 KHz) and extraction time(30, and 60 min) were compared using extraction solvent water 100%. The pretreatment step was composed of ultrasonic waves extraction, filtration, concentration, and membrane filtration. The extracted sample was analyzed by reversed-phase high performance liquid chromatography(RP-HPLC). And the mobile phase applied was linearly changed with A/B of 80/20~65/35 vol% for 60 min(A water/acetic acid, 99.9/0.1 vol%, B acetonitrile/acetic acid, 99.9/0.1 vol%). The experimental results, general composition carbohydrate(0.255 to 0.413%) excepts, other ingredients was confirmed almost similarly. Also, The highest yield of extraction amount 3.17g was obtained by ultrasonic waves with a frequency of 170 KHz and an extraction time of 60 min. This work offers would be useful for chemical and biological studies of natural plants and its products.

• Clean Technology
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• v.15 no.3
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• pp.147-153
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• 2009

Waste three-way catalysts were remanufactured by ultrasonic wave treatment followed by active component re-impregnation and the catalytic activities and surface properties of remanufactured catalysts were measured at various remanufacturing conditions. In case of the catalyst prepared by ultrasonic wave cleaning, the optimal period for elimination of surface contaminants from the waste catalyst was found to be about 5 minutes. The proper re-impregnation amounts of the active components for the best catalytic performance were investigated and the catalytic performance tests were also carried out with various temperature for the total hydrocarbon (THC), carbon monoxide (CO) and nitrogen oxides (NOx) conversions. The experimental results showed that the catalytic performances of the remanufactured catalysts were recovered almost the same level as those of the fresh catalyst except those of the NOx conversion.

• Journal of the Korean Society for Nondestructive Testing
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• v.18 no.4
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• pp.304-312
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• 1998

In order to assure the reliability and integrity of structures such as bridges, Power and petrochemical plants, nondestructive evaluation techniques are recently playing more important roles. Among the various kinds of nondestructive evaluation techniques, ultrasonic technique is one of the most widely used methods for nondestructive inspection of internal defects in structures. For the reliable quantitative evaluation of internal defects from the experimental ultrasonic signals, a numerical analysis of ultrasonic scattering field due to a defect distribution is absolutely required. In this paper, the SH-wave scattering by multi-cavity defects using elastodynamic boundary element method is studied. The effects of shape of defects on transmitted and reflected fields are considered. The interaction of multi-cavity defects in 50-wave scattering is also investigated. Numerical calculation by the boundary element method has been carried out to predict near field solution of scattered fields of ultrasonic SH-wave. The presented results would be useful to improve the sensitivity of flaw defection for inverse analysis and pursue quantitative nondestructive evaluation for inverse problem.

• Proceedings of the Korea Water Resources Association Conference
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• 2017.05a
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• pp.75-75
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• 2017

하천의 합류부는 서로 다른 지형학적 특성과 수리학적 특성을 가지는 두 개의 하천이 하나로 합쳐지는 구간으로 급격한 흐름의 변화 및 퇴적물의 유입과 수리학적 지형변화가 발생하는 구간이다. 이러한 합류부에서는 흐름구조와 물의 물리 화학적인 특성이 지속적으로 변화할 수 있고, 침식과 퇴적으로 인한 하상변동과 같은 하도 변화가 발생할 수 있다. 또한, 하천의 합류부는 두 지류가 만나 형성되는 지역으로 하천생태계에서 매우 중요한 역할을 하는 구간이다. 이러한 합류부 구간의 혼합 매커니즘을 이해하기 위해서는 지류의 다양한 유입조건에 따른 본류와의 수체혼합의 공간적인 패턴을 분석하는 것이 중요하다. 그러나, 대부분의 합류부 연구들은 실측에 기반한 공간적인 수체혼합의 패턴 분석의 어려움으로 인해 수리 및 수질 수치모형에 의존하여, 실측자료에 기반하여 지류의 유입에 따른 수체혼합을 공간적으로 분석하는 연구는 매우 제한적이었다. 따라서, 본 연구에서는 ADCP를 활용하여 합류부의 혼합 현상을 규명하는 인자로 유속과 수심 등 기본적인 수리학적 인자들뿐만 아니라 최근 활발하게 연구되고 있는 ADCP의 초음파반사율을 활용하여 상이한 농도의 유사가 혼합되는 양상을 측정하여 합류부의 혼합 특성을 공간적으로 분석하고자 하였다. 초음파반사율은 부유사와 관련되는 인자로 SonTek ADCP 이동식으로 측정된 SNR자료를 확산, 물에 의한 흡수를 고려하여 보정한 후 3차원 혼합거동의 공간적인 분포를 도출하였다. 그리고 초음파반사율을 활용한 방식을 검증하고 지류와 본류의 유입 전후 입도분포를 확인하기 위해 LISST 측정을 수행하였고, 드론 영상을 활용하여 유입 유사의 2차원 공간적인 분포를 확보하여 초음파반사율을 활용한 방법과 비교하였다. ADCP, LISST, 드론의 계측자료는 낙동강과 남강 합류부에서 측정되었고, ADCP로부터 제공되는 유속, 수심자료의 공간적인 분포를 분석하여 합류부의 수리특성을 분석할 수 있었고, 초음파반사율을 유사 혼합의 공간적 특성을 규명하는 인자로 활용하여 본류와 지류의 유입량에 따른 다양한 유사 혼합의 3차원 공간적인 패턴을 분석할 수 있었다.

• Applied Chemistry for Engineering
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• v.22 no.2
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• pp.155-160
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• 2011

An animal fat is an attractive biodiesel energy source for its high stability against oxidation and low incomplete combustion ratio due to the high heating value and cetane value. However, it requires a refinery process because of the high content of saturated acid and impurity which increas the boiling point. In this study, the optimum biodiesel synthetic process of lard is suggested. Indeed, we demonstrate new biodiesel production processes to alter conventional process of heating and mixing by applying ultrasonic energy. While the optimum reaction temperature and mole ratio of methanol and lard, when using conventional mixing and heating process, were $55^{\circ}C$ and 12, respectively, the reaction time were reduced to 30 minutes by applying ultrasonic irradiation power of 500 W. The new process applying ultrasonic irradiation yielded synthetic biodiesel properties as followings: 3.34 cP of the viscosity, 37.0 MJ/kg of the caloric value and below 0.25 mgKOH/g of the acidic value, which satisfy biodiesel quality criteria.

• Food Science and Industry
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• v.53 no.3
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• pp.277-283
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• 2020

Microbial disinfection is essential to increase the preservation and safety of food. In general, thermal sterilization technology is most frequently used, but it often causes nutrient denaturation, and deterioration of food quality. Accordingly, non-thermal sterilization using a novel technology is emerging as an alternative technology. Among them, ultrasonic technology produces a disinfection effect by promoting the destruction of microorganisms by cavitation. Ultrasound technology alone has a low effect, so research is being actively conducted to develop an effective technology by applying as a hurdle technology with various other technologies. Ultrasound can be treated with various processes including traditional sterilization methods such as heating, high pressure, and chemical treatment, as well as novel technologies such as ultraviolet irradiation. Ultrasound assisted sterilization technology still remains at the laboratory level, requiring additional research such as the development of equipment for industrial application and establishment of an optimal process.