• Title/Summary/Keyword: 초음파화학

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Improvement of Fouling in Membrane Separation Process for Leachate Treatment using Ultrasound(II) : Analysis of Membrane Materials, Solutes and Multi-ultrasonic Effect (초음파를 이용한 침출수 처리를 위한 막분리 공정의 막힘현상 개선(II) : 막의 재질, 용질과 복합초음파의 효과 분석)

  • Kim, Seok-Wan;Lim, Jae-Lim;Lee, Jun-Geol
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.2
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    • pp.207-215
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    • 2006
  • This study evaluated the effect of ultrasonic irradiation on reducing membrane fouling for the treatment of chemically treated leachate and biologically treated leachate. The experiments on improvement of membrane flux according to the membrane types(MF and UF) and membrane materials were performed with changing frequency(40 kHz and 120 kHz) and intensity(200 W and 400 W) of ultrasound in ultrasonic membrane separation apparatus which ultrasound can be periodically irradiated. Additionally, the effect of dual frequency ultrasound which 40 kHz md 120 kHz are irradiated simultaneously was evaluated. The improvement of membrane flux by periodical ultrasound irradiation was higher in microfiltration(MF) membrane than in ultrafiltration(UF) membrane. It was sustained more in the MF membrane of polyvinylidene fluoride(PVDF) than in that of polysulfon(PS). Ultrasonic improvement of membrane flux was different depending on the characteristics of target wastewater. It was sustainably maintained without reclogging using dual frequency ultrasound although the improvement of membrane flux was lower.

Enhanced Transdermal Permeation Effects of Lidocaine Gel by Low Frequency Ultrasound (저주파수 초음파를 이용한 Lidocaine Gel의 피부투과 촉진 효과)

  • Jung, Dae-In;Lee, Jung-Woo;Ahn, Hyo-Cho;Yang, Jae-Heon;Kim, Tae-Youl;Cho, Seong-Wan;Kim, Young-Il
    • Korean Chemical Engineering Research
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    • v.46 no.2
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    • pp.217-221
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    • 2008
  • To investigate the enhancing effects in transdermal permeation of drug using newly designed ultrasound apparatus of 500 kHz, the transdermal permeation studies through the hairless mouse skin were conducted with lidocaine. The ultrasound apparatus of 500 kHz frequency and transducer were newly developed. The drug permeation studies were performed according to the ultrasound frequencies such as 1 MHz and 500 kHz at $1W/cm^2$ in intensity in continuous mode or pulsed mode, respectively. The results on transdermal permeation of lidocaine according to ultrasound intensity showed that the drug permeation increased as the intensity was higher.

Investigation for Optimization of Ultrasonic Soil-Washing Process for Remediation of Diesel Contaminated Soil (유류오염토양의 복원을 위한 초음파 토양세척 공정의 최적화에 대한 연구)

  • Park, Beom-Guk;Son, Young-Gyu;Hwang, An-Na;Khim, Jee-Hyeong
    • Journal of the Korean Society of Hazard Mitigation
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    • v.11 no.1
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    • pp.101-105
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    • 2011
  • Determination of ultrasonic frequency and experimental design approach to optimization of ultrasonic soil-washing process for remediation of diesel contaminated soil were investigated. Ultrasonic frequencies of 35, 72, and 100 kHz were used for determination of optimal frequency. $MINITAB^{(R)}$ program was used for experimental design of optimal washing condition. The optimal ultrasonic frequency was 35 kHz. Even though the number of cavitation bubble is little, however cavitation bubbles involving larger energy compared with high frequency was generated. Therefore, the removal efficiency at low frequency was higher than at high frequency. However the input energy has to be considered when the process is applied. The statistical tests from a factorial experiment shows that the application of ultrasound and mechanical mixing are the most important factor for design of an ultrasonic soil washing process. The lab-scale experiments are required to get the optimal condition of ultrasound and mechanical mixing for application of ultrasonic soil washing process.

Feasibility Study on Remediation for Railroad-contaminated Soil with Waste-lubricant (윤활유 유래 철도 오염토양의 정화방법 연구)

  • Park, Sung-Woo;Shin, Min-Chul;Jeon, Chil-Sung;Baek, Ki-Tae;Lee, Jae-Young
    • Journal of Soil and Groundwater Environment
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    • v.13 no.2
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    • pp.30-35
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    • 2008
  • In this study, the feasibility of soil washing, chemical oxidation and sonication was investigated to treat lubricantcontaminated railroad soil. Tergitol, a non-ionic surfactant, was used as a washing agent with or without iso-propyl acohol as a cosolvent. However, it was not effective to remove lubricant from soil even though tergitol was the most effective washing agent for diesel-contaminated soil. The cosolvent reduced the overall washing efficiency. Chemical oxidation removed 30% of lubricant from contaminated soil. Soil washing after chemical oxidation extracted additionally 16-17% of lubricant. Sonication enhanced-soil washing showed enhanced overall efficiency of soil washing. Lubricant-contaminated soil should be remediated by the other technology used for diesel-contaminated soil.

Development of An Improved Acetone-Water Fractional Precipitation Process for Purification of Paclitaxel from Taxus chinensis and Its Kinetic and Thermodynamic Analysis (Taxus chinensis로부터 파클리탁셀 정제를 위한 개선된 아세톤-물 분별침전 공정 개발 및 그 동역학 및 열역학적 해석)

  • Kang, Hoe-Jong;Kim, Jin-Hyun
    • Korean Chemical Engineering Research
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    • v.59 no.3
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    • pp.379-392
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    • 2021
  • In this study, an improved acetone-water fractional precipitation process for paclitaxel using ultrasonic cavitation bubbles and gas bubbles was developed. Compared to the conventional method, the time required for precipitation has been reduced by 20~25 times. In addition, the particle size of paclitaxel decreased by 3.5~5.5 times and the diffusion coefficient of paclitaxel increased by 3.5~6.7 times. In the case of precipitation using ultrasonic cavitation bubbles, as the ultrasonic power increased and the temperature decreased, the precipitation rate constant increased. In the case of precipitation using gas bubbles, as the gas flow rate increased and the temperature decreased, the precipitation rate constant increased. Thermodynamic parameters revealed the exothermic, irreversible, and nonspontaneous nature of the improved fractional precipitation.

A Study on Micro-Hole Drilling by EDM (미세구멍의 방전가공에 관한 연구)

  • 윤재웅;양민양
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.14 no.5
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    • pp.1147-1154
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    • 1990
  • Micro-hole drilling by EDM and production of fine rods for the tool electrode or other purpose have become very important in industry. This paper suggests a new method for production of very fine rods by ultrasonic-assisted chemical machining and describes the machining characteristics of micro-hole drilling by EDM. For fine rods, copper wires of initial diameter of 250.mum are used and successfully machined into a diameter of less than 30.mum with good repeatability. The ultrasonic agitation not only accelerated the material removal rate uniformly, but also produced smooth surfaces of fine rods. To drill the micro-hole, kerosene and pure water is used as a dielectric. From the experiment, water is superior to kerosene with respect to surface roughness of inlet and outlet of hole and machined surface as well as electrode wear. However, due to the electrochemical reaction of water, small pits are remained on the workpiece surface.

A Case of Concurrent Gallbladder Mucocele and Hypothyroidism in a Dog; Dermatologic, Serum Chemical and Ultrasonographic Changes (담낭점액종과 갑상선기능저하증이 병발한 개에서 피부, 혈청화학치 및 초음파상의 변화)

  • Cho, Sun-Hyung;An, Daegi;Kim, Ha-Jung;Kang, Ji-Houn;Chang, Dong-Woo;Jung, Dong-In;Lim, Ha-Young;Yang, Mhan-Pyo;Kang, Byeong-Teck
    • Journal of Veterinary Clinics
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    • v.30 no.6
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    • pp.464-467
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    • 2013
  • A 6-year-old, spayed female Cocker Spaniel was presented with generalized seborrhea sicca. Initially gallbladder mucocele (GM) was suggested by high liver enzyme activities and a stellate pattern in ultrasonography. There were no responses during 16 months of medical treatments for GM. Hormonal assay and histopathological findings were consistent with a diagnosis of hypothyroidism. Levothyroxine therapy led to rapid resolution of dermatologic, serum chemical and ultrasonographic abnormalities. This report describes serial changes of skin lesions, serum chemistry and ultrasonography in a dog with concurrent GM and hypothyroidism following treatment of hypothyroidism.

Ultrasonic, Chemical Stability and Preparation of Self-Assembled Fullerene$[C_{70}]$-Gold Nanoparticle Films (자기조립 풀러렌$[C_{70}]$-금 나노입자 필름 제조와 초음파적, 화학적 안정성)

  • Ko, Weon-Bae;Shon, Young-Seok
    • Elastomers and Composites
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    • v.40 no.4
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    • pp.272-276
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    • 2005
  • [ $C_{70}$ ]-gold nanoparticle multilayer films were self-assembled using a 'dirt-ball' method on the reactive surface of glass slides functionalized with 3-aminopropyltrimethoxysilane. The functionalized glass slides were soaked in the solution containing both unmodified $C_{70}$ and ${\omega}$-amino-functionalized gold nanoparticles. Organic reaction (amination) facilitated the assembly of multilayer $C_{70}$-gold nanoparticle films, which have grown up to several layers. Chemical stability of $C_{70}$-gold nanoparticle films was studied by monitoring the changes in absorbance after the immersion of the films in acidic solution. In addition, ultrasonic stability of these nanoparticle films was studied by exposing them to ultrasonic irradiated surrounding, which resulted in partial desorption and a little aggregation of nanoparticles on solid surfaces.