• Applied Chemistry for Engineering
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• v.22 no.2
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• pp.155-160
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• 2011

An animal fat is an attractive biodiesel energy source for its high stability against oxidation and low incomplete combustion ratio due to the high heating value and cetane value. However, it requires a refinery process because of the high content of saturated acid and impurity which increas the boiling point. In this study, the optimum biodiesel synthetic process of lard is suggested. Indeed, we demonstrate new biodiesel production processes to alter conventional process of heating and mixing by applying ultrasonic energy. While the optimum reaction temperature and mole ratio of methanol and lard, when using conventional mixing and heating process, were $55^{\circ}C$ and 12, respectively, the reaction time were reduced to 30 minutes by applying ultrasonic irradiation power of 500 W. The new process applying ultrasonic irradiation yielded synthetic biodiesel properties as followings: 3.34 cP of the viscosity, 37.0 MJ/kg of the caloric value and below 0.25 mgKOH/g of the acidic value, which satisfy biodiesel quality criteria.

• Applied Chemistry for Engineering
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• v.21 no.4
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• pp.385-390
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• 2010

Transesterifications of vegetable oils (soybean oil, grapeseed oil, corn oil, canola oil) by ultrasonic energy were examined on various catalysts for biodiesel production. Reaction activities of the transesterifications were evaluated to the ultrasonic energy and thermal energy. The physicochemical properties and product distribution were also investigated to the biodiesels produced from the oils in the reaction using ultrasonic energy. The yields of fatty acid methyl ester (FAME) on the alkali catalysts were higher than those on the acid catalysts. The highest FAME yield was obtained as 83% on potassium hydroxide catalyst in the transesterification. The effective reaction conditions by ultrasonic energy were 1 wt% catalyst loading and 6:1 molar ratio of methanol to vegetable oils. The reaction rate of the transesterification by ultrasonic energy was faster than that by thermal energy. The acid values of the biodiesel products were improved above 30% compared to those of the feedstocks.

• Transactions of the Korean Society of Automotive Engineers
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• v.16 no.4
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• pp.38-46
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• 2008

An object of this study is to understand the correlation between the characteristics of an engine performance and combustion characteristics, applying BD20 fuel reformed by ultrasonic energy irradiation to diesel engines. Before conducting the main experiment, an experiment was performed to determine the optimum injection timimg of reformed BD20 by ultrasonic energy irradiation. To control the duration of the ultrasonic energy irradiation, the capacity of an ultrasonic energy fuel supply system was tested with 550cc and 1100cc chambers. As the result of the analysis of the regular BD20 and reformed BD20 by ultrasonic energy irradiation, the BSFC and the Power of the reformed BD20 was improved 3% and 6%, respectively compared to those of non-irradiated BD20. When the fuel injection timing was delayed by $5^{\circ}$, the engine power was improved by 3%, and the BSFC was improved by 2%. The maximum cylinder pressure of reformed BD20 was improved by a maximum of 6% in comparison to that of regular BD20, and demonstrated a synergistic effect of 3% by delaying the injection timing $5^{\circ}$.

• Journal of Energy Engineering
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• v.13 no.4
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• pp.235-241
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• 2004

This experiment was undertaken to investigate the atomization characteristics of the high viscosity biodiesel blended fuel and ultrasonic energy irradiation one. Test fuels were conventional diesel fuel and biodiesel one. We compared to the characteristics of viscosity and surface tension, SMD between high viscosity biodiesel blended fuel and ultrasonic energy irradiation one. Sauter mean diameter was measured under the variation of the spray distance. Viscosity and surface tension were measured under the variation of the time trace. To measure the droplet size, we used the Malvern system 2600c. Droplet size distribution was analyzed from the result data of Malvern system. Through this experiment, we found that the condition of the ultrasonic energy irradiation situation had smaller Sauter mean diameter of droplet, viscosity and surface tension than those of the conventional situation.

• Korean Chemical Engineering Research
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• v.51 no.4
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• pp.487-492
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• 2013

Transesterifications of waste oils mixed with animal tallows and vegetable oil by ultrasonic energy were examined over various catalysts for biodiesel production. Reaction activities of the transesterification were evaluated to the ultrasonic energy and thermal energy. The physicochemical properties of feedstock and products were also investigated to the biodiesels produced from the oils in the reaction using ultrasonic energy. The highest fatty acid methyl ester (FAME) yield was obtained on the potassium hydroxide catalyst in the transesterification by ultrasonic irradiation. The effective reaction conditions by ultrasonic energy were 0.5 wt% catalyst loading and 6:1 molar ratio of methanol to the mixed oils. The reaction rate of the transesterification by ultrasonic energy was faster than that by thermal energy. The highest yields of FAME were obtained as 80% in 5 min and the reaction equilibrium reached at that time.

• Transactions of the Korean Society of Automotive Engineers
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• v.14 no.1
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• pp.109-114
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• 2006

The reformed bio-diesel fuel irradiated by the ultrasonic wave is applied to the diesel engine of common rail in common use recently. This study has the object to examine the properties of engine performance and discharged materials. The bio-diesel fuel is mixed and used with the diesel fuel in common use at the ratio of $20\%\;or\; 100\%$. The ultrasonic energy is irradiated to the individually mixed fuel in order to reform the fuel. This fuel is applied to the engine in this experiment. And It is compared and analyzed from the experimental results with two cases irradiating the ultrasonic wave and no irradiating.

• Transactions of the Korean Society of Automotive Engineers
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• v.23 no.2
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• pp.214-220
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• 2015

Since resources of fossil fuels are limited, development of alternative energies is emphasized and research on new-regenerative energy is actively in progress worldwide. In present research, physical and chemical characteristics of mixed fuel are analyzed in detail for the different mixture rate of conventional and bio-diesel and ultrasonic irradiation time. Experimental setup consists of ultrasonic generator, vibrator, horn, and reflector. Various physical and chemical characteristics of fuel are investigated for volumetric mixture rate of bio-diesel from 0 to 100%. As results, viscosity and surface tension is increased as mixture rate of bio-diesel is increased. Also, molecular splits and reunions are increased and decreased repeatedly after some period of time as ultrasonic energy irradiation time is increased. As conclusion of experiments, Olefin rate, Branch index, and Aromatic rate are influenced by ultrasonic irradiation time.

• Journal of ILASS-Korea
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• v.12 no.3
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• pp.131-137
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• 2007

This is an experimental study on characteristics of engine performance and discharged materials in common-rail type diesel engine. The bio-diesel fuel is mixed with the diesel fuel in common use at the ratio of 20% or 100%. The diesel fuel and blended fuel is irradiated by ultrasonic wave energy. The diese1 fuel, blended fuel, reformed diesel fuel and reformed blended fuel by ultrasonic wave energy are applied to the experimental engine individually. The results are compared with one of the diesel fuel in common use and analyzed.