• 제목/요약/키워드: 초기경화

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질소첨가 316L 스테인레스 강에서 고온 저주기피로시 발생하는 경화거동

  • 김대환;류우석;김영철;홍준화;최시경
    • Proceedings of the Korean Nuclear Society Conference
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    • 1996.11b
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    • pp.463-468
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    • 1996
  • 질소의 함량을 0.04%~0.15% 까지 변화시킨 316L 스테인레스 강으로 공기 중에서 저주기 피로시험을 수행하였다. 전체변형범위 1%, 변형속도 2$\times$$10^3$/sec, 삼각파로 상온 ~$600^{\circ}C$ 온도범위에서 시험을 수행하였다. 상온에서는 사이클이 진행됨에 따라서 연화가 계속해서 발생하지만 온도가 증가하면 초기에 경화가 발생한다. 피로시험 초기에 경화되는 정도와 saturation 응력은 온도가 증가하면 증가한다. 이러한 경화현상은 동적변형시효에 의해서 발생되는 것으로 판명되었다. 질소를 첨가하면 강도는 증가하지만 경화는 감소되었다. 질소에 의한 경화의 감소는 질소가 동적변형시효를 억제하기 때문이다.

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A Study on the Determination of Setting Time of Concrete in the Determination of Slip-up Speed for Slip-Form System (슬립폼 시스템 상승속도 결정에 요구되는 콘크리트에서의 초기경화시간 결정을 위한 연구)

  • Kim, Heeseok;Kim, Young-Jin;Chin, Won-Jong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.4A
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    • pp.295-302
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    • 2011
  • The setting time which is the important element for the determination of slip-up speed of Slip-Form system is the hardening time of early-age concrete when the in place concrete has minimum compressive strength before the concrete appears out of Slip-Form system. But it is very difficult to predict the setting time because it depends on not only the composition ratio of concrete but also various conditions of construction fields. Thus, the technique to estimate accurately and continuously the hardening time of early-age in place concrete during operating Slip-Form system is necessary to guarantee the safety of Slip-Form system and the maintenance of the shape of concrete. Ultrasonic wave-based nondestructive testing methods have the advantages which are accurate and continuous in estimating concrete compressive strength. Of such methods, the method using surface wave which propagates along the surface of material is effective for thick member such as a pylon. Thus, in this paper a study on the determination of slip-up speed for Slip-Form system using surface wave velocity is performed. The relation between the slip-up speed of Slip-Form system and the setting time is formulated, and the surface wave velocity is estimated from continuous wavelet transform of the numerical results for surface wave propagation. Finally, the accuracy of this method according to the distance between the wave source and receivers and the relation between the estimated surface wave velocity and the elastic modulus are investigated.

An Experimental Study on Hardening Performance at Early Age of Polymer Concrete (폴리머 콘크리트의 초기경화특성에 관한 실험적 연구)

  • 오병환;이형준;차수원;장제욱
    • Proceedings of the Korea Concrete Institute Conference
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    • 1993.10a
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    • pp.162-166
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    • 1993
  • 폴리머 콘크리트에 대한 연구는 세계 각국에서 오래전부터 수행하여 구조물에 적용한다든가 보수재로 사용하고 있는데 비해 국내에서의 연구는 최근에 시작되었으며, 폴리머 콘크리트에 대한 재료의 기초적 특성 연구가 활발히 진행되고 있으나 체계적인 연구 결과나 실용화 실적이 적다. 따라서 본연구에서는 폴리머 콘크리트의 초기경화 특성을 고찰하여 콘크리트 포장의 보수재료로서의 폴리머 콘크리트의 활용 토대를 구축하고자 한다.

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A Study on the resistance of acrylic rubber pressure sensitive adhesives with curing agents and tackifiers (경화제와 점착부여제가 아크릴 고무점착제의 내열성에 미치는 영향)

  • Nam, Kyong min;Kim, Chul Yong;Kim, Eun Seon;Kim, Kwang-Je;Choi, Woo Jin;Kim, Ki-Tae;Park, Myung-Chul
    • Journal of Adhesion and Interface
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    • v.18 no.4
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    • pp.166-170
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    • 2017
  • In this study, acrylic rubber pressure sensitive adhesives was polymerized with 2-ethylhexyl acrylate, styrene, butadiene, 2-hydroxyethyl acrylate, and acrylic acid by controlling the initiator content. The initial tackiness, peel strength, holding power, and heat resistance of the PSAs were investigated by changing the content of tackifier and curing agent. The results showed that the initial tackiness and peel strength increased as the content of tackifier increased, whereas the holding power decreased. Also, the results exhibited that that the initial tackiness, peel strength, and heat resistance decreased as the content of curing agent increased, whereas the holding power and decreased.

A Study on the Determination of Slip-up Time for Slip-Form System using Surface Wave Velocity (표면파 속도를 이용한 슬립폼 시스템 상승 시기 결정에 관한 연구)

  • Kim, Heeseok;Kim, Young Jin;Chin, Won Jong;Yoon, Hyejin
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.5D
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    • pp.483-492
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    • 2012
  • The early setting time of concrete is an important factor determining the slip up velocity of the slip-form system. Accordingly, need is for a technique evaluating the early setting time in order to secure the safety of the slip-form system and the construction quality of concrete. This paper intends to estimate the early setting time by evaluating the setting degree of concrete using surface wave velocity so as to determine the slip up time of the slip-form system. Penetration resistance test and compressive strength test are performed first to clarify the relationship between the early setting time of concrete and the compressive strength. Then, compressive strength test and ultrasonic wave test are conducted to examine the relation between the compressive strength and the surface wave velocity. Continuous wavelet transform is adopted to measure the surface wave velocity. Numerical analysis is carried out to demonstrate the appropriateness of the application of continuous wavelet transform. Based on these results, the propagation velocity of the surface wave required for the slip up of slip-form system is suggested. Finally, a reduced model test of the slip-form system is conducted to verify the feasibility of the proposed surface wave velocity for the determination of th slip up velocity.

Investigation of Early-Age Concrete Strength Development Using Hardening Accelerator (경화촉진제를 사용한 콘크리트의 초기강도 발현 특성 검토)

  • Kim, Gyu-Yong;Kim, Yong-Ro;Park, Jong-Ho
    • Journal of the Korea Concrete Institute
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    • v.28 no.3
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    • pp.309-316
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    • 2016
  • In this study, performance of hardening accelerator types which promote setting and hardening of cement has been reviewed in order to develop early age strength of concrete with compressive strength of 21~27 MPa after examination of strength development of the concrete at early age according to curing temperature and unit cement(binder) content. As results, soluble mineral salt showed better hardening acceleration effect than organic salt in the scope of this study. Also, hydration reaction accelerating effect of $C_3S$ by Soluble mineral salt is effective on development of early age compressive strength and it was shown that the Pt's hydration reaction accelerating effect was the best. Construction duration reduction can be expected by securing compressive strength for prevention of early aged freezing damage in 25hour-curing time under curing temperature at $15^{\circ}C$. Also, it was shown that compressive strength of specimen cured at $5^{\circ}C$ was similar with plain specimen cured at $10^{\circ}C$. Therefore, it is expected that fuel costs and carbon dioxide can be reduced when the same construction duration is considered.

Analysis of Early-age Property of JPCP Slab of Incheon International Airport (인천국제공항 줄눈콘크리트 슬래브의 초기재령 특성분석)

  • Sun, Ren Juan;Jeong, Jin-Hoon;Cheon, Sung-Han;Lim, Jin-Sun
    • 한국방재학회:학술대회논문집
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    • 2007.02a
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    • pp.335-339
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    • 2007
  • A jointed plain concrete pavement(JPCP) slab was tested in Incheon International Airport construction work to study the early-age property of JPCP slab. The temperature and moisture data of the concrete slab had been collected and analyzed. The setting time of the concrete was decided by using the maturity method. The initial setting time is 2 hours 40 minutes after the placement of the slab. The investigation and analysis of the slab began from the initial setting time. The strains of different locations and different depths of the slab show different variation character.

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Cure Behavior of a DGEBF Epoxy using Asymmetric Cycloaliphatic Amine Curing Agent (비대칭 고리형 지방족 아민 경화제를 이용한 DGEBF 계열 에폭시의 경화 거동)

  • Kim, Hongkyeong
    • Korean Chemical Engineering Research
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    • v.46 no.1
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    • pp.200-204
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    • 2008
  • The curing kinetics of diglycidyl ether of bisphenol F (DGEBF) with an asymmetric cycloaliphatic amine curing agent were examined by thermal analysis in both isothermal and dynamic curing conditions. From the residual curing of the samples partially cured in isothermal condition and from the dynamic curing with various heating rates, it was found that there exist two kinds of reactions such as at low temperature and at high temperature regions. It was thus also found that the cure parameters obtained from the isothermal curing kinetic model hardly estimate experimental results for a degree of cure larger than 0.6. The activation energies and frequency factors of these two kinds of reactions were obtained from the dynamic curing experiments with various heating rates. From the curing analysis, it was verified that the total cure kinetics for low degrees of cure is dominated by the cure reaction in the low temperature region.

Experimental Study on the Early Strength Development Mechanism of Cement Paste Using Hardening Accelerator and High-Early-Strength Cement (경화촉진제와 조강시멘트를 사용한 시멘트 페이스트의 조기강도 발현 메커니즘에 관한 실험적 연구)

  • Min, Tae-Beom;Cho, In-Sung;Lee, Han-Seung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.18 no.1
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    • pp.84-92
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    • 2014
  • The purpose of study is to analyze mechanism with early high portland cement and hardening accelerator. As the result, it was concluded that hardening accelerator makes accelerates appearance of $Ca(OH)_2$ through experiment using TG-DTA when it hydrates with cement. On the result of compressive strength, as increasing the amount of hardening accelerator used, early compressive strength was improved. Also, as a result of hydration heat, hardening accelerator accelerates hydration of $C_3S$ that is cement's component. On the result of XRD's analyzation, hydration product for each age could be check and it was shown that as increasing the amount of hardening accelerator used, peak point of hydration product was recorded high. As the result of SEM, appearance of C-S-H was shown as the amount of $Ca(OH)_2$'s appearance and each age according to additive contents of hardening accelerator. Therefore hardening accelerator used on this study is effective on getting early compressive strength.

Characteristics of the Hardening Shrinkage and Creed of Eporxy Resin Concerte (에폭시 수지 콘크리트의 경화수축 및 크리이프 특성)

  • 허남철;연규석
    • Magazine of the Korea Concrete Institute
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    • v.2 no.1
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    • pp.109-119
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    • 1990
  • This study was accomplished to investigate the characteristics of hardening shrinkage and initial creep of epoxy resin concrete depending on the presence of filler. According to the test results, the hardening shrinkage was increased with increment of sLOrage temperature, and the ef¬feel of tempemture on the hardening shrinkage of epoxy resin concrete with 6% filler was more Significant than that of epoxy resin concrete without filler. Also, the initial creep strain was increased with loading times, stress--strength ratio and elastic strain, and the values for opoxy resin concrete with 6 % filler are higher than that for eposy resin concrete without filler.