• Title/Summary/Keyword: 청자

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The Effect of Micro Constituent Element on the Development of Unique Color of Koryo Celadon (고려 청자 유약 발색에 미량 성분이 미치는 영향)

  • 김형태;이세용;함청순;최의석
    • Journal of the Korean Ceramic Society
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    • v.38 no.6
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    • pp.522-530
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    • 2001
  • 발굴된 과거 고려청자의 화학성분조성과 물리적 특성에 대한 평가를 하고 미량성분의 청자의 발색에 미치는 영향을 고찰한 결과, 고려 청자 태토는 Fe$_2$O$_3$가 2%, TiO$_2$가 0.8% 함유되어 있었으며, 청자유는 석회.장석유로서 Fe$_2$O$_3$가 1.0~1.2%, TiO$_2$가 0.16% 포함되어 있었다. 비색청자의 경우 미량성분인 MnO$_2$가 P$_2$O$_{5}$의 함량이 0.37%와 0.76%, CuO는 300~500ppm 정도 함유하고 있었다. 반사율 측정 결과 일반적인 청자가 540~570nm의 장파장대에서의 반사율이 급격히 떨어지는데 반하여, 13세기 비색 청자의 것은 적색 파장대에서 10%이상 높았다. CoO는 미량 첨가로도 유약의 청색 파장대 반사율이 높고, 적색 파장대의 반사율이 급격히 떨어지며 청자 발색에 부정적인 영향을 미쳤다. CuO는 0.05%를 첨가했을 경우 적색 파장대에서 반사율 곡선이 높게 나타나고 있어 비색 청자발색에 효과적이었다. 또한 명도를 나타내는 L*값도 CuO가 첨가된 유약이 가장 높았고, 비색청자의 색상은 녹청자에 비해 맑고 깊은 색감을 보였다.

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Antioxidant Activity of Ethanol Extract from Different Parts of 5 Types of Imported Citrus (Citrus limon, Citrus paradisi Macfad, Citrus. grandis Osbeck × Citrus. Paradisi Macf., Citrus sinensis, Citrus reticulata Blanco, Citrus x aurantifolia) (수입귤 6종(레몬, 지몽, 청자몽, 오렌지, 만다린, 라임) 부위별 에탄올 추출물의 항산화 활성)

  • Ji-Won Seo;Mi-Kyeong Jang;Won-Seob Song
    • Proceedings of the Plant Resources Society of Korea Conference
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    • 2023.04a
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    • pp.67-67
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    • 2023
  • 수입귤 6종(레몬, 자몽, 청자몽, 오렌지, 만다린, 라임) 부위별 에탄올 추출물의 항산화 활성에 관하여 총 폴리페놀 함량 측정, 총 플라보노이드 함량 측정, DPPH radical 소거 활성 실험을 실시하였다. 수입귤 6종(레몬, 자몽, 청자몽, 오렌지, 만다린, 라임)의 각 부위별 생리활성 실험에서 총 폴리페놀 함량(mg/g)은 청자몽 중피(252.14mg/g)와 청자몽 외피(224.60mg/g), 청자몽 과피(213.13mg/g), 자몽 중피(197.13mg/g) 순으로 모두 150mg/g 이상의 양호한 폴리페놀 함량을 나타내었다. 수입귤 6종(레몬, 자몽, 청자몽, 오렌지, 만다린, 라임)의 각 부위별 총 플라보노이드 함량(mg/g)은 자몽 중피(147.24mg/g)와 청자몽 중피(147.08mg/g), 청자몽 과피(127.74mg/g), 청자몽 외피(122.5mg/g) 순으로 모두 120mg/g 이상의 매우 양호한 플라보노이드 함량을 나타내었다. 수입귤 6종(레몬, 자몽, 청자몽, 오렌지, 만다린, 라임)의 각 부위별 항산화 활성(EDA, %)은 레몬 과피(83.21%)를 시작으로 라임 전체(80.23%), 레몬 과육(77.02%), 레몬 전체(69.85%), 만다린 과피(68.86%), 라임 과육(64.61%) 순으로 EDA 50% 이상 값을 나타내어 양호한 항산화 활성을 보였다.

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A Study on Production Kiln Site Estimation, based on Historical Ceramic Characteristics and Scientific Analysis of the Celadons Excavated From the Beopcheon Temple Site and Son-gok 2-ri 4th Kiln Site (법천사지 청자와 손곡2리 4호 가마터 청자의 도자사적 성격과 과학적 분석을 통한 생산 가마터 추정 연구)

  • Lee, Byeong-hoon;Yun, Seok-in
    • Korean Journal of Heritage: History & Science
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    • v.47 no.3
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    • pp.24-41
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    • 2014
  • Since the celadons excavated from the Son-gok 2-ri 4th kiln site are located in the Beopcheon temple site and at close range, the similarity to the celadons excavated from the Beopcheon temple site is being raised. Thus, this study examined the correlation using a natural-scientific method. In this study, historical ceramic properties of total 19 celadons were examined and they were scientifically analyzed. First of all, according to the scientific analysis, chemical compositions of celadon clay showed a dispersed distribution at RO2 3.79-7.77mole and RO+R2O 0.33-0.49mole. When the microstructure was analyzed, most celadons excavated from the Beopcheon temple site, Wonju, which are estimated to be used in real life, had a favorable state, and some celadons from the Son-gok 2-ri 4th kiln site were found not to be glazed and sintered properly. When analyzing body crystalline phases of the celadons using the XRD method, quartz and mullite were extracted from all of the samples. And corundum was extracted from sg4 sample. Though firing temperature of each sample was different, they were mostly fired to temperatures between 1150 and $1200^{\circ}C$ and some of them experienced a low temperature of $1100^{\circ}C$ or a high temperature above $1200^{\circ}C$. Various chemical compositions and producing techniques were observed in the celadons from the Beopcheon temple site and Son-gok 2-ri 4th kiln site and it is hard to assure that the Son-gok 2-ri 4th kiln site was the production kiln site of the celadons used in the Beopcheon temple site. But according to the analysis of rare earth elements, some of the celadons from the Beopcheon temple site and Son-gok 2-ri 4th kiln site displayed a distribution pattern with certain regularity and this implies there is a possibility that the raw materials used in producing the ceramics might have come from the same origin. From the perspective of ceramic history, the celadons excavated from the Beopcheon temple site and Son-gok 2-ri 4th kiln site were produced using the same molding and sintering technique. Also, it is estimated that they were produced in the 12th or 13th century, judging from the overall shapes and patterns of the celadons.

A Comparative Study on the Decoration of Korean Celadon and Chinese Celadon in the 12th and 13th Centuries (12~13세기 고려청자와 중국청자의 장식디자인 비교 연구)

  • Yue, kun;Ren, chuan;Kim, Hea-jin
    • Journal of Digital Convergence
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    • v.17 no.3
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    • pp.427-432
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    • 2019
  • In the 12th century to the 13th century, was the heyday of celadon, Koryo celadon after experienced celadon firing technology of imitation to the peak period of the development of Chinese celadon, especially on decoration technology pioneered the self unique style, the way of engraving, $xi{\grave{a}}ngqi{\grave{a}}n$. During this period, the southern Song dynasty celadon in China also innovated in the mature celadon firing technology and became more distinctive. The decorative style also promoted the aesthetic interest of the Song dynasty. Celadon decoration is not only a decorative art of ceramic art, but also a representation of national cultural phenomenon with the traditional culture in the development of contemporary art, play a more important role and value.

The Installation of Royal Kilns in Joseon Dynasty and Its Impact on Local Kilns (음각운문청자의 제작현황으로 본 조선시대 관요의 설치와 지방 가마)

  • Oh, Young-In
    • Korean Journal of Heritage: History & Science
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    • v.50 no.4
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    • pp.38-63
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    • 2017
  • This study sets out to investigate the installation of royal kilns and its impact on local kilns, taking note of celadon vase with inlaid cloud pattern in Joseon Dynasty. For that purpose, it determined the kilns and period to produce celadon vases with inlaid cloud pattern, and compared them with the pattern, design, and deformity of the celadon vases produced in the royal kilns in the 15th centuries. The celadon vase with inlaid cloud pattern was superior in quality than the porcelain for tribute ware manufactured together in Jeolla Province before the installation of royal kilns. And then a majority of sagijangs at local kiln had difficult time securing enough supply of manpower and resources, and discontinued manufacturing the celadon vase with inlaid cloud pattern. En revanche, celadon vases with inlaid cloud pattern produced from specially fixed royal kilns reflected the local sagijang's skill. Local kilns were strongly influenced by the installation of royal kilns. Those could not freely use high-quality white clay, limited to the market. Besides, most of the skillful sagijangs were assigned to royal kilns. Celadon vases with inlaid cloud pattern can be used as evidence to show that the manufacturing technique was transferred from local kilns to the royal kilns as well as to show that their production in royal kilns soon became stabilized.

A Study on Goryo Celadons of intaglio '○' pattern and '⊙'pattern (고려 음각 '○'문과 '⊙'문청자의 연구)

  • Han, Seong-Uk
    • KOMUNHWA
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    • no.70
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    • pp.133-161
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    • 2007
  • It is judged that celadons with '○' pattern and '⊙' pattern have the indication of manufacturer by engraving mark at the internal center of the bottom. These celadons were produced at No.8.23.27 kiln sites located at Sadang-ri(사당리), Daegu-myon(대구면), Gangjin-gun(강진군), Jeollanamdo(전라남도), Korea and '⊙’ patterned celadon porcelain was found only at No. 23 and 27 kiln sites, so it is assumed that its production sites were limited. Kinds of celadons included bowl, dish, cup, bottle, case and vessel for emptied wine and there were a lot of dishes with a variety of patterns. These celadons were engraved by molded design technique using the same ceramic design as the pattern of celadons in the period of their prosperity and it was appropriate method to produce celadons of a good quality with production method to keep decorative design like pattern or size uniformly. It was also found that inlay method was not universalized in this period and similar celadons were produced with molded design in large quantities. These celadons had partially fire clay temper, but most of them were burnt by supporting the inner bottom of U-type base with quartzite after whole glazing. It was known through relics excavated at Seokreung(석릉) royal tomb of King Heejong(희종) at Ganghwa(강화) and Hyeeumwon(혜음원) temple site at Paju(파주) and military house at Wakamiyaoji(약궁대로) avenue Kamakura(겸창)-city, Japan(일본) that these celadons were manufactured at two quarters of the 13th century centering around 1230s. Therefore, these celadons will be significant materials to fill the gap of the celadons in the 13th century resulted from the record chronologically that green celadons were manufactured in the 12th century. And this period was invaded by Mongolia(몽고), but central control was achieved and green celadons were continuously produced. It was also considered that these celadons were excavated at Gabgot-ri(갑곶리) and Gwanchung-ri(관청리), Ganghwa(강화), Hyeeumwon temple, Paju which played the role of temporary palace, Bu1guksa(불국사) temple at Gyeongju(경주), Silsangsa(실상사) temple at Namwon(남원) and relics of Jangheung(장흥) adjacent to Daeguso(대구소) and these were produced for high class.

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Variation in the Major Essential Oils Content under Different Leaf-Picking Time of Perilla frutescens spp. (紫蔬의 채엽시기별 주요 정유성분 함량변화)

  • 이상호
    • Korean Journal of Plant Resources
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    • v.10 no.4
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    • pp.314-318
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    • 1997
  • This experiment was carried out to analyze the essential oils from different parts of Perilla frutescens spp. And to know change of the oil content by a diffenent leaf picking time. The analysis of the essential oils was done with gas chromatography(GC),and the results are as follows. Perilla frutescens spp. contained essential oils mostly in their leaves and stems, although their roots also contained the oils. It was suggested that the optimum leaf-picking time of perilla frutescens var. viridis Mak. on the basis of total essential oils was their flowering period around Aug. 24, and that of Perilla frutescens var. for acuta Kudo was Sep. 14. On the basis of perillaldegyde the optium leaf-picking time of Perilla frutescens var. viridis Mak. and Perilla frutescens var. acuta Kudo was Aug. 24. and Aug. 4. respectively.

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An Analysis of Archaeological Chemistry on the Low-grade Celadons Excavated at Noksan dong, Busan in Korea (부산 녹산동 조질청자의 고고화학적 분석)

  • Nam, Kyung Min;Kim, Gyu-Ho
    • Journal of Conservation Science
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    • v.34 no.5
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    • pp.345-358
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    • 2018
  • The purpose of this study is to analyze the characteristics of low-grade 12th-century celadons, which were excavated from a kiln site in Noksan-dong, Busan. The physical and chemical properties of the body and the glaze are evaluated through scientific analyses. All the selected celadon shards have a similar body color, regardless of the kiln from which they originated. The celadon shards from 2 3 kilns are brighter than those from 4 5 kilns, and there are two saturations, namely gray and brown. The brightness of the glaze shows a high contribution of red and yellow. The porosity of the selected shards is 8.8% in the gray saturation and 16.1% in the brown saturation. The major chemical compositions of the body and glaze are in the typical chemical composition of the celadon, but the $TiO_2$ flux contents are different. The visible characteristic difference between the 2 3 kilns and the 4 5 kilns can be attributed to the mixing and the firing process rather than the raw materials used. The difference in the $Fe_2O_3$ and $K_2O$ flux between the 2 3 and 4 5 kilns can be attributed to changes in the ingredient combination during the process. In conclusion, Noksan-dong celadon could not be easier vitrification due to the manufacturing process that primary burning process, It is highly likely that there were process differences in kilns to produce high quality celadon.

Body Composition and Firing Temperature of Ancient Pottery Excavated in Chonnam Province (전남지역에서 출토된 고대 도자기의 태토조성과 소성온도)

  • Kang, Kyeong-In;Jung, Chang-Ju
    • Journal of Conservation Science
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    • v.6 no.1 s.7
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    • pp.15-30
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    • 1997
  • The chamical and physical properties of the fragments of an ancient pottery such as earthenware, gliazed pottery and celadon excavated in Chonnam province has been investigated by X-ray diffraction inductively coupled plasma spectroscopy(ICP), thermal mechanical analysis(TMA). Glazed pottery fragments of Chonnam province are cotaining Fe2O3 $4\~7\%$ by the analyis of ICP, firing temperature range was presumed to $1100-1150^{\circ}C$ by TMA. Celadon fragments of Chonnam province are containing Fe2O3 $2\~3\%$ by the analyis of ICP, firing temperature range was presumed to $1140\~1200^{\circ}C$ by TMA. The charateristics in the trace element composition of an ancient pottery of Chonnam provinceis are similar, it is an reflection of similar geological charateristics. The charateristic elements of Chonnam provincical ancient pottery were Rb, Sr, V, Zr, Y, Nd, Sc, La, Ce, Nb, Sm, Eu, Dy and Yb of the analyzed 21 trace elements. By Fe2O3-Zn ditribution diagram, potteries excavated in Yong-am, celadons excavated in Haenam, Kangjin, Buan and glazed pottery excavated in Hae-nam are grouped into the same class.

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