• Title/Summary/Keyword: 철부식

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Corrosion characterization of Fe-aluminide alloys with various sulphuric acid solution ($H_2SO_4$ 수용액 변화에 따른 철 알루미나이드 합금의 부식특성)

  • Lee, B.W.;Choi, H.L.
    • Journal of Power System Engineering
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    • v.10 no.2
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    • pp.83-88
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    • 2006
  • Corrosion characterization of Fe-XAl-0.3Y(X=5, 10, 14 wt%) alloys in $0.1{\sim}1N$ sulphuric acid at room temperature was studied using potentiodynamic techniques. The morphology and components of corrosion products on surface of Fe-aluminide alloys were investigated using SEM/EDX, XRD. The potentiodynamic polarization curve of alloys exhibited typical active, passive, transpassive behaviour. Corrosion potential($E_{corr}$) and corrosion current density($I_{corr}$) values of Fe-XAl-0.3Y alloys followed linear rate law. $E_{corr}$ of 10Al alloy and 14Al alloy was ten times lower than 5Al alloy. Icorr of 14Al alloy was five times lower than 5Al alloy. The passive film on the surface of Fe-5Al-0.3Y alloy was formed iron oxide. Fe-10Al-0.3Y and Fe-14Al-0.3Y alloys passive films were aluminium oxide. especially, Fe-14Al-0.3Y alloy showed good corrosion resistance in $0.1{\sim}1N$ sulphuric acid. This is attributed to the forming of protective $Al_2O_3$ oxide on the surface of Fe-14Al-0.3Y alloy.

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A Study on the Cavitation Corrosion of Gray Cast Iron Liner by Antifreeze (부동액에 따른 회주철 라이너의 캐비테이션 부식에 대한 연구)

  • Kim, Byeong-Ho;Kim, Byung-Hyun;Koo, Young-Ho;Seo, Jae-Hyun
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.16 no.4
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    • pp.76-82
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    • 2017
  • The cylinder liner of a diesel engine is commonly made of gray cast iron. However, this cylinder liner can be damaged by the cavitation phenomenon in wet conditions. This cavitation has remained an unsolved problem until now. In this study, the cause of cavitation corrosion due to antifreeze solution was examined using a scanning electron microscope (SEM) and a 3D microscope. The necessary data to prevent the damage caused by cavitation erosion and the corrosion of gray cast iron cylinder liner was obtained. Analysis determined that the gray iron structure consists of an ${\alpha}-matrix$, flake graphite, and steadite. Cavitation erosion was initiated in the coarse flake graphite and propagated into the steadite with pitting. Under repetitive reaction conditions, the ${\alpha}-matrix$ was partially separated from the gray cast iron. This study is expected to be used as the basic data for the prevention of gray cast iron cavitation erosion and corrosion by controlling the graphite and steadite phases.

Aluminum Toxicity on Corn Seedlings (옥수수 유묘(幼苗)에 대(對)한 알미늄 독성(毒性))

  • Lee, Yong-Seok
    • Korean Journal of Soil Science and Fertilizer
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    • v.10 no.2
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    • pp.75-78
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    • 1977
  • Corn (Zea may, L.) was grown alternatively in nutrient solution and hydroxy Al or Al-citrate solution to identify the form of Al which induces Al toxicity on Corn seedlings. Corn seedlings exposed to hydroxy Al solution was very toxic but Al-citrate solution did not show any toxic symptoms. At pH 7 with Al-citrate solution, severe Fe, deficiency was induced probably by the decrease of stability constant of Al-and Fe-oganic complexes and subsequent precipitation of Al-and Fe-as a hydroxide form. Addition of humic acid ameliorated the Al toxicity somewhat at pH 4.7 with hydroxy-Al solution but at pH 7 it induced more severe Fe deficiency.

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Strength Characteristics on Sulfuric Acid Corrosion of Recycled PET Polymer Concrete with Different Fillers (충전재 종류에 따른 PET재활용 폴리머콘크리트의 황산부식에 대한 강도 특성)

  • Jo Byung-Wan;Shin Kyung-Chul;Park Seung-Kook
    • Journal of the Korea Concrete Institute
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    • v.17 no.4 s.88
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    • pp.499-504
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    • 2005
  • Polymer concrete shows excellent mechanical properties and chemical resistance compared with conventional normal cement concrete. The polymer concrete Is drawing a strong interest as high-performance materials in the construction industry Resins using recycled PET offer the possibility of a lower source cost of materials for making useful polymer concrete products. Also the recycling of PET in polymer concrete would help solve some of the solid waste problems Posed by plastics and save energy. An objective of this paper is to estimate the damage of sulfuric acid, through investigating recycled PET polymer concrete, immersed at sulfuric acid solution for 84 days. As a result of testing, recycled PET PC, used $CaCO_3$ as filler, makes a problem of appearance and strength if they are exposed for long term at corrosion environment. On the other hand, recycled PET PC, used fly-ash as filler, had less effect on decrease in weight and strength. Recycled PET PC is excellent chemical resistance, resulting in the role of unsaturated polyester resin which consists of polymer chain structure accomplishes bond of aggregates and filler strongly. Also, recycled PET PC, used fly-ash as filler, is stronger resistance of sulfuric acid corrosion than $CaCO_3$, because it is composed of $SiO_2$ and very strong glassy crystal structure. Therefore, recycled PET PC, used fly-ash as filler, is available under corrosion circumstances like sewer pipe or waste disposal plant.

Seismic Fragility Evaluation of Bridges Considering Rebar Corrosion (철근 부식을 고려한 교량의 지진취약도 평가)

  • Shin, Soobong;Kong, Sina;Moon, Jiho;Song, Jong-Keol
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.34 no.4
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    • pp.231-241
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    • 2021
  • Although the deterioration of bridges may occur due to various causes, one of the representative causes is that the chloride used for deicing in the winter penetrates bridge members and results in corrosion. This study aims to quantify the ageing degree resulting from the corrosion of a bridge, apply it to the inelastic dynamic analysis model of the bridge, perform a seismic fragility analysis, and evaluate the relationship between the ageing degree and the seismic fragility curve. It is important to appropriately define the threshold values for each damage state in seismic fragility analyses considering the ageing degree. The damage state was defined using the results of existing experimental studies on the characteristics of the deterioration in the displacement ductility capacity of the pier, according to the ageing degree. Based on the seismic fragility analyses of six types of bridges divided by three types of bearing devices and two pier heights, it was found that the seismic vulnerability tends to increase with the ageing degree. The difference in seismic vulnerability with respect to the ageing degree exhibits a tendency to increase as the damage state progresses from slight to moderate, severe, and collapse.

A Study on Anti-Corrosion Effect of Powder Self Water Proof Admixture Mixed Corrosion Inhibitor for Reinforcing Steel (철근부식억제형 구체방수재의 방청효과에 관한 연구)

  • 신도철;손형호;김원화
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.10a
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    • pp.409-414
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    • 2002
  • This study is intended to develop the self water proof admixture for durability concrete by anti-corrosion inhibitor. Chloride induced corrosion of reinforcement is one of the main factor which cause the deterioration of concrete structure. When the substitute anti-corrosion agents for a part of self waterproofing agent, the corrosion-proof increases for the increased water proofing capacity. And proper self waterproofing agent by cement weight in concrete was generally positive effect to concrete compressive strength, slump, freezing and thawing resistance. Also, permeability and absorption show a straight decrease when self waterproofing agent is added.

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PFA 라이닝 밸브의 헬륨누설 측정 및 비산배출 평가

  • Lee, Won-Ho;Lee, Won-Seop;Lee, Jong-Cheol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.121.2-121.2
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    • 2016
  • PFA 라이닝 밸브 (PFA Lined Valve)는 고온 (~120oC) 고압 (~10 bar)에서 강한 부식성을 갖은 화학물질 (염산, 황산, 질산 등)을 이송시킬 수 있도록 내식성, 비점착성, 내열성 향상을 위한 불소계 수지 PFA (Perfluoroalkoxy)가 밸브 내면부에 가공되어 있으며, 고순도 화학약품 및 반도체 LCD 석유화학 제철 제약 분야 등의 제조공정에서 사용되고 있다. 미국 EPA (Environmental Protection Agency)에서는 석유화학 플랜트에서 발생되는 비산배출 (fugitive emission)의 대부분인 60% 정도가 밸브에서 발생된다고 보고하고 있으며, 근래 빈번한 불산 노출사고 내용을 매스컴에서 접할 수 있는 것처럼 PFA 라이닝 밸브가 설치되는 산업현장에서는 미소 누설에도 치명적인 인명피해 사고가 발생하기 때문에 국제규격에 따른 PFA 라이닝 밸브의 기밀누설에 관한 규제 및 관리가 중요하다. 본 논문에서는 가압진공법을 이용하여 PFA 라이닝 볼밸브의 비산배출 측정하였으며, 작동횟수/온도변화에 따른 PFA 라이닝 볼밸브의 비산배출 특성을 고찰하였다.

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Fatigue Vulnerability Evaluation of Steel Bridge Members Affected by Corrosion (부식의 영향을 받는 강교 부재의 피로 취약도 평가)

  • Kim, Dong-Jo;Kim, Hyo-Jin;Lee, Hyeong-Cheol;Lee, Sang-Ho
    • 한국방재학회:학술대회논문집
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    • 2007.02a
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    • pp.67-70
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    • 2007
  • A methodology to evaluate fatigue vulnerability of steel bridge members affected by corrosion and truck traffic variation is proposed. A fatigue limit state function including corrosion and traffic variation effects is established to make the criterion whether the steel bridge member is damaged by fatigue. Corrosion effects are expressed as increase of the average corrosion depth, and the traffic variation effects are modeled as the accumulated number of stress cycles. Reliability analysis is carried out by Monte-Carlo simulation method for the fatigue limit state function. The methodology Proposed is verified by comparing reference study and applying for the steel bridge in service.

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Problem Analysis and Repair Techniques of Underground Concrete Box Structures (지하 박스 콘크리트 구조물(지하철)의 결함 원인 및 대책)

  • 변근주;오병환;신용석;송하원;원대연;남진원
    • Magazine of the Korea Concrete Institute
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    • v.14 no.2
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    • pp.70-76
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    • 2002
  • 지하철, 고속철도, 신공항, 공동구, 지하보도, 지하차도, 하수도, 도로 및 철도 등 의 지하구조에는 일반적으로 박스형태의 콘크리트 구조물이 건설되고 있다. 1990년 대 중반 이후 시공 및 사용중인 지하 박스 콘크리트 구조물의 균열 및 누수 등의 문제점이 사회적인 문제로 부각되기 시작하였다. 이러한 지하 박스 콘크리트 구조물에 발생할 수 있는 문제점은 크게 결함(defect), 손상(damage), 열화(deterioration)의 3가지로 구분될 수 있으며, 이들 원인은 구조물에 균열(cracking), 누수(leakage), 처짐(deflection), 부동침하(settlement) 재료분리(segregation) , 박리(delamination), 부식(corrosion), 박락(spalling)등의 현상으로 나타난다.(중략)

A Study on the Investigation of Remaining Life for the Domestic Reinforced-Concrete Apartment by the Corrosion Probability of Reinforcing-steel (철근부식확률에 의한 국내 철근콘크리트조 아파트구조물의 잔여수명 검토에 관한 연구)

  • 강석표;김규용;권영진;정성철;이덕찬;송병창;김무한
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.10c
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    • pp.223-228
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    • 1998
  • This study is to investigate on the remaining life of reinforced concrete apartment by using the probability of a reinforcing-steel corrosion and the carbonation tendency of domestic reinforced concrete apartments by using the statistic method. The results are as follow. ·To compare with the carbonation velocity of Kishitani's formula (x=3.727{{{{ SQRT { t} }}) when water-cement ratio is w=0.6, R=1, it is founded out that the carbonation velocity is slow a little in all area investigated and inland area, and fast a bit in coastal area. ·In the influencing factors in regard to the probability of reinforcing-steel corrosion, It seems that the influence of elapsed time is more effective than that of region. Therefore, it is necessary that it makes sure of the cover depth under apartment construction in recent so far as the durability is considered.

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