• Title/Summary/Keyword: 철(III)

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A Study on the Classification of Road Type by Mixture Model (혼합모형을 이용한 도로유형분류에 관한 연구)

  • Lim, Sung Han;Heo, Tae Young;Kim, Hyun Suk
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.6D
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    • pp.759-766
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    • 2008
  • Road classification system is the first step for determining the road function and design standards. Currently, roads are classified by various indices such as road location and function. In this study, we classify road using various traffic indices as well as to identify traffic characteristics for each type of road. To accomplish the objectives, mixture model was applied for classifying road and analyzing traffic characteristics using traffic data that observed at permanent traffic count stations. A total of 8 variables were applied: annual average daily traffic(AADT), $K_{30}$ coefficient, heavy vehicle proportion, day volume proportion, peak hour volume proportion, sunday coefficient, vacation coefficient, and coefficient of variation(COV). A total of 350 permanent traffic count points were categorized into three groups : Group I (Urban road), Group II (Rural road), and Group III (Recreational road). AADT were 30,000 for urban, 16,000 for rural, and 5,000 for recreational road. Group III was typical recreational road showing higher average daily traffic volume during Sunday and vacational periods. Group I showed AM peak and PM peak, while group II and group III did not show AM peak and PM peak.

Arsenic Removal using the Surface Modified Granular Activated Carbon treated with Ferric Chloride (염화철(III)로 표면개질 활성탄을 이용한 비소제거)

  • Park, Y.R.;Hong, S.H.;Kim, J.H.;Park, J.Y.
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.1
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    • pp.77-85
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    • 2012
  • The present study investigates treatment methods for removal of arsenic from wastewater. The granular activated carbon (GAC) with the coating of iron chloride ($FeCl_3$) was used for the treatment of a low concentration of arsenic from wastewater. Batch experiments were performed to investigate the synthesis of Fe-GAC (Iron coated granular activated carbon), effects of pH, adsorption kinetics and the Langmuir model. The synthesized Fe-GAC with 0.1 M $FeCl_3$ shows best removal efficiency. Adsorption studies were carried out in the optimum pH range of 4-6 for arsenic removal. The Fe-GAC showed promising results by removing 99.4% of arsenic. In the adsorption isotherm studies, the observed data fitted well with the Langmuir models. In continuous column study showed that As(V) could be removed to below 0.25 mg/L within 1,020 pore volume. Our results suggest that the surface modified granular activated carbon treated with $FeCl_3$ for effective removal of arsenic from wastewater.

Application of Electron Energy Loss Spectroscopy - Spectrum Imaging (EELS-SI) for Microbe-mineral Interaction (생지구화학적 광물변이작용 연구에서 전자에너지 손실 분광 분석 - 스펙트럼 영상법의 활용)

  • Yang, Kiho;Park, Hanbeom;Kim, Jinwook
    • Journal of the Mineralogical Society of Korea
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    • v.32 no.1
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    • pp.63-69
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    • 2019
  • The oxidation states of structural Fe in minerals reflect the paleo-depositional redox conditions for the biologically or abiotically induced mineral formation. Particularly, nano-scale analysis using high-resolution transmission electron microscopy (HRTEM) and electron energy loss spectroscopy (EELS) is necessary to identify evidence for the microbial role in the biomineralization. HRTEM-EELS analysis of oxidation states of structural Fe and carbon bonding structure differentiate biological factors in mineralization by mapping the distribution of Fe(II)/Fe(III) and source of organic C. HRTEM-EELS technique provides geomicrobiologists with the direct nano-scale evidence of microbe-mineral interaction.

Mineralogical and Geochemical Characteristics of Soils of Barton Peninsula, King George Island, South Shetland Islands, West Antarctica (서남극 사우스셰틀랜드 킹조지섬 바톤반도 육상 토양의 광물학적, 지화학적 특성)

  • Jung, Jaewoo;Koo, Taehee;Yang, Kiho;Kim, Jinwook
    • Journal of the Mineralogical Society of Korea
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    • v.30 no.1
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    • pp.21-29
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    • 2017
  • Surface soils on Barton Peninsula, King George Island, West Antarctica were investigated to acquire the mineralogical and geochemical data of soil in Antarctica. Multiline of techniques for example, X-ray diffraction (XRD), transmission electron microscopy (TEM)-electron energy loss spectroscopy (EELS), and wet chemistry analysis were performed to measure the composition of clay minerals, Fe-oxidation states, cation exchange capacity, and total cation concentration. Various minerals in sediments such as smectite, illite, chlorite, kaolinite, quartz and plagioclase were identified by XRD. Fe-oxidation states of bulk soils showed 20-40% of Fe(II) which would be ascribed to the reduction of Fe in clays as well as Fe-bearing minerals. Moreover, redox states of Fe in smectite structure was a ~57% of Fe(III) consistent to the values for the bulk soils. The cation exchange capacity of bulk soils ranged from 100 to 300 meq/kg and differences were not significantly measured for the sampling locations. Total cations (Mg, K, Na, Al, Fe) of bulk soils varies, contrast to the heavy metals (Co, Ni, Cu, Zn, Mn). These results suggested that composition of bed rocks influenced the distribution of elements in soil environments and soils containing clay compositions may went through the bio/geochemical alteration.

No Association of DRD4 Exon III Polymorphism with Attention-Deficit Hyperactivity Disorder in Korean Children Population (도파민 소용체 제4형 Exon III 다형성과 주의력결핍 과잉운동장애의 연합연구)

  • Cho, Soo-Churl;Park, Tae-Won;Kim, Jae-Won;Yoo, Hee-Jeong;Kim, Boong-Nyun;Shin, Min-Sup;Hwang, Jun-Won
    • Journal of the Korean Academy of Child and Adolescent Psychiatry
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    • v.18 no.2
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    • pp.154-161
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    • 2007
  • Objectives: The aim of the current study is to test for the association of DRD4 exon III VNTR polymorphism with attention-deficit hyperactivity disorder(ADHD) in Korean children population. Methods: 113 Korean children with ADHD, 102 parents, and 133 control subjects participated with the current study. The distribution of genotypes and alleles of DRD4 exon III VNTR in children with ADHD was compared with that in control subjects. In addition, 69 children with ADHD and their parents were analyzed using the transmission disequilibrium test(TDT). Results: We could not find any significant differences in the distribution of genotypes and alleles at DRD4 exon III VNTR polymorphism between children with ADHD and control subjects. In addition, there was no preferential transmission of long allele of DRD4 exon III VNTR polymorphism. Conclusion: These results suggest that DRD4 is not associated with ADHD in Korean children population.

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Experimental Study on Effect of Water-based Iron(III) Oxide Nanofluid on Minimum Film Boiling Point During Quenching of Highly Heated Test Specimen (고온 시편의 급랭 시 산화철 나노유체가 최소막비등점에 미치는 영향에 대한 실험적 연구)

  • Jeong, Chan Seok;Hwang, Gyeong Seop;Lee, Chi Young
    • Journal of the Korean Society of Safety
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    • v.35 no.5
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    • pp.128-136
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    • 2020
  • In the present experimental study, the effect of water-based iron(III) oxide nanofluid on the MFB(Minimum Film Boiling) point during quenching was investigated. As the highly heated test specimen, the cylindrical stainless steel rod was used, and as the test fluids, the water-based iron(III) oxide nanofluids of 0.001 and 0.01 vol% concentrations were prepared with the pure water. To examine the effect of location in the test specimen, the thermocouples were installed at the bottom and middle of wall, and center in the test specimen. Through a series of experiments, the experimental data about the influences of nanofluid concentrations, the number of repeated experiments, and locations in the test specimen on the reaching time to MFB point, MFBT(Minimum Film Boiling Temperature), and MHF(Minimum Heat Flux) were obtained. As a result, with increasing the concentration of nanofluid and the number of repeated experiments, the reaching time to MFB point was reduced, but the MFBT and MHF were increased. In addition, it was found that the effect of water-based iron(III) oxide nanofluid on the MFB point at the bottom of wall in the test specimen was observed to be greater than that at the middle of wall and center. In the present experimental ranges, as compared with the pure water, the water-based iron(III) oxide nanofluid showed that the maximum reduction of reaching time to MFB point was about 53.6%, and the maximum enhancements of MFBT and MHF were about 31.1% and 73.4%, respectively.

Characteristics of the TCE removal in FeO/Fe(II) System (FeO/Fe(II) 시스템에서 TCE의 제거 특성)

  • Sung, Dong Jun;Lee, Yun Mo;Choi, Won Ho;Park, Joo yang
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.1B
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    • pp.149-152
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    • 2008
  • The reaction between iron oxide and ferrous iron is known to be the adsorption of ferrous iron onto the oxide surfaces that produces Fe(II)-Fe(III) (hydr)oxides and ferrous oxide oxidized to ferric ion which is the reducing agent of the target compounds. In our investigations on DS/S using ferrous modified steel slag, the results did not follow the trends. FeO and Fe(II), the major component of steel slag, were used to investigate the degradation of TCE. Degradation did not take place for the first and suddenly degraded after awhile. Degradation of TCE in this system was unexpected because Fe(II)-Fe(III) (hydr)oxides could not be produced in absence of ferric oxide. In this study, the characteristics of FeO/Fe(II) system as a reducing agent were observed through the degradation of TCE, measuring byproducts of TCE and the concentration of Fe(II) and Fe(III). Adsorption of ferrous ion on FeO was observed and the generation of byproducts of TCE showed the degradation of TCE by reduction in the system is obvious. However it did not correspond with the typical reducing mechanisms. Future research on this system needs to be continued to find out whether new species are generated or any unknown mineral oxides are produced in the system that acted in the degradation of TCE.

Study on residual stress characteristics according to the substrate type and V/III ratio during GaN growth by HVPE (HVPE 법을 통한 GaN 성장 시 기판 종류 및 V/III 비에 따른 잔류 stress 특성 연구)

  • Lee, Joo Hyung;Lee, Seung Hoon;Lee, Hee Ae;Kang, Hyo Sang;Oh, Nuri;Yi, Sung Chul;Lee, Seong Kuk;Park, Jae Hwa
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.2
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    • pp.41-46
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    • 2020
  • The characteristics of the residual stress on the types of the substrate was investigated with adjusting the V/III ratio during GaN growth via the HVPE method. GaN single crystal layers were grown on a sapphire substrate and a GaN template under the conditions of V/III ratio 5, 10, and 15, respectively. During GaN growth, multiple hexagonal pits in GaN single crystal were differently revealed in accordance with growth condition and substrate type, and their distribution and depth were measured via optical microscopy(OM) and white light interferometry(WLI). As a result, it was confirmed that the distribution area and depth of hexagonal pit tended to increase as the V/III ratio increased. Moreover, it was found that the residual stress in GaN single crystal decreased as the distribution area and depth of the pit increased through measuring micro Raman spectrophotometer. In the case of GaN growth according to substrate type, the GaN on GaN template showed lower residual stress than the GaN grown on sapphire substrate.

Effect of Swimming Exercise and Achyranthes Radix Extracts on Inflammatory and Pain Responses in Rheumatoid Arthritis Rats (류마티스 관절염 흰쥐에서 수중운동과 우슬추출물이 염증 및 통증 반응에 미치는 영향)

  • Choi, Ki-Bok;Nam, Ki-Won;Kim, Gye-Yeop;Sim, Ki-Cheol;Kim, Eun-Jung
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.23 no.1
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    • pp.113-120
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    • 2009
  • This study was performed to investigate the effects in inflammatory and pain status on rheumatoid arthritis(RA) induced rats by swimming exercise and Achyranthes Radix(AR) extracts ointment according to the application methods with the change of motor-behavioral and histochemistry study through the change of safranin o-fast green stain in the knee joint and prostaglandin $E_2(PGE_2)$ concentration production in serum for 28 days. They were randomly divided into four groups; Group I: RA induction, Group II: application of only swimming exercise after RA induction, Group III: application of only AR extracts ointment after RA induction, Group IV: application of both AR extracts ointment and swimming exercise after RA induction. The following results were obtained. Volume change of hind paw edema and arthritis indices test and arthritic dorsal flexion & plantar flexion pain test, group II, III, IV were showed that significantly decrease to each scores compared with group I (p<.01). Safranin o-fast green stain were showed histological indices, group II, III, IV were showed that significantly decrease the scores of cellular infiltration and synovial hyperplasia(p<.05), pannus formation and cartilage destruction(p<.01) compared with group I. Group IV were the most decreased compared with group II, III. The $PGE_2$ concentration of the group II, III, IV were decreased compared to the group I (p<.01) In conclusion, swimming exercise and AR extracts ointment acts were the most therapeutic intervention in inflammatory and pain control of RA induced rats.

Catalytic Activity of Metal-phthalocyanine Bonded on Polymer for Decomposition of Hydrogen Peroxide (고분자에 결합된 금속-프탈로시아닌의 과산화수소수 분해반응에 대한 촉매활성)

  • KimKong Soo 김공수;Yong Chul Chun;Young Woo Lee;Sang Ho Lee
    • Journal of the Korean Chemical Society
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    • v.33 no.6
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    • pp.662-668
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    • 1989
  • The decomposition reaction of hydrogen peroxide was carried out by using metal-4,4',4",4"'-tetraaminophthalocyanine [Mt-$PcNH_2$, Mt = Fe(III), Co(II)] supported on poly (styrene-co-methacrylic acid), in heterogeneous aqueous system. These catalysts showed a catalse-like activity and Fe(III)-$PcNH_2$ supported on the copolymer was particularly effective for the decomposition of hydrogen peroxide. It was found that the rate of decomposition increased smoothly in the higher pH region and catalytic reaction was interfered by adding $CN^-,\;CNS^-,\;{C_2O_4}^{-2},\;I^-$ ions. The kinetics of the catalytic reaction was also investigated and the reaction proceeds according to the Michaelis-Menten type mechanism.

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