• 제목/요약/키워드: 천연 가스

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Dimethyl Ether(DME) 합성을 위한 파일럿 규모의 고정층 반응기의 모델링과 모사를 통한 향류 냉각방식과 포화액체 풀비등 방식의 비교 (Comparison of Counter-Current Cooling and Pool Boiling System Through Modeling and Simulation of a Pilot-Scale Fixed bed Reactor for Dimethyl Ether(DME) Synthesis)

  • 송대성;고재욱;윤인섭
    • Korean Chemical Engineering Research
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    • 제47권4호
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    • pp.446-452
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    • 2009
  • 최근 청정대체에너지로 각광을 받고 있는 dimethyl ether(DME)를 천연가스를 이용하여 직접 생산하는 1단계법의 고정층 촉매 반응기를 모사하였다. 1단계법의 고정층 반응기의 경우, 발열 반응인 메탄올 합성반응과 메탄올 탈수 반응이 동시에 일어나기 때문에 촉매의 비활성화를 일으킬 수 있는 hot spot의 발생을 막는 것이 가장 중요하다. 따라서 향후 상용공정에 적용 가능한 향류 냉각방식(count-current cooling system)과 포화액체 풀비등 방식(pool boiling system)을 적용하여 반응기 거동을 모사하고 이를 비교하였다. CO 전환율과 DME 생산성 면에서 향류 냉각방식이 더 효과적이었다. 하지만 포화비등액체 풀비등 방식이 더 작은 온도 범위에서 운전되어 hot spot(국소 고온점)의 가능성을 낮추고 더 안정적인 반응기 운전범위를 확보할 수 있었다.

비금속광물 분체의 기능성 건축소재화 특성 (A Preparation and Characteristics of Functional rchitecture Materials Made frm Non-metallic Minerals)

  • 김병곤;최상근;박종력;전호석
    • 한국세라믹학회지
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    • 제40권8호
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    • pp.811-817
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    • 2003
  • 최근 들어 비금속광물의 구조적 특성을 이용한 활용분야가 매우 다양해지고 있다. 특히 판상광물은 차폐(은폐)력이 매우 우수하고, 층간특성을 이용한 흡착 및 저장특성이 매우 우수하다. 본 연구에서는 이와 같은 판상광물의 기본의 특성에 또 다른 기능성 물질을 흡착시킴으로써 부가적인 새로운 기능성을 갖는 친환경성 건축소재를 개발하고자 천연산 인상흑연 및 견운모를 기능성 모소재로 사용하고 미립화 및 ABDM(Alkyl Benzyle Demethyle Ammonium Chloride)으로 흑연입자 표면을 항균처리를 하였다. 항균처리를 위한 흡착은 전위차를 이용한 1차 흡착과 ABDM 상호간의 steric 작용에 의한 2차 흡착으로 완전 이중층이 형성되어 충분한 항균효과를 나타낼 수 있었다. 제조된 기능성 재료를 모르타르로 제조하여 다양한 기능성을 측정한 결과 세균감소율 99.7% 이상과 80% 이상의 암모니아 가스 흡착(탈취) 효과 및 95% 이상의 전자파 차폐율과 5% 정도의 열저장(축열, 잠열) 효과를 갖는 것으로 나타났다.

5kW 급 주택용 고분자 연료전지 시스템 (Development of the 5kW Class Polymer Electrolyte Fuel Cell System for Residential Power Generation)

  • 양태현;박구곤;윤영기;이원용;윤왕래;김창수
    • 한국수소및신에너지학회논문집
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    • 제14권1호
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    • pp.35-45
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    • 2003
  • Polymer electrolyte fuel cells(PEFC) have been considered to be a suitable candidate for residential, portable and mobile applications, due to their high efficiency and power density, even at low operating temperature. KIER developed a 5kW class PEFC system for residential application and operated the system for over 1,000 hours. To develop a 5kW PEFC system, performance of a cell was improved through successive tests of single cell of small and large area. Fabrication of three 2,5 kW class stacks, design and fabrication of natural gas reformer, design of auxiliary equipments such as DC/DC converter, DC/AC inverter and humidifying units were carried out along with integration of components, operation and evaluation of total system. During the development period from 1999 to 2001, MEA(membrane electrode assembly) fabrication technologies, design and fabrication technologies for separators, stacking technologies and so on were developed, thereby providing basis for developing stacks of higher efficiency and power density in the future. Experience of development of natural gas reformer opened possibilities to use various kinds of fuels. Main results obtained from the development of a 5kW class PEFC system for residential application are summarized.

고압 천연 가스 인젝터의 분무 특성에 관한 연구 (An Investigation on the Spray Characteristics of a Compressed Natural Gas Injector)

  • 삭다 통차이;강유진;임옥택
    • 한국수소및신에너지학회논문집
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    • 제29권2호
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    • pp.219-225
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    • 2018
  • This study was carried out to investigate the injection characteristics of 800 kPa compressed natural gas compressed natural gas (CNG) injector developed in Korea. The CNG injector with multi-holes, employed in this experiment, was designed to inject CNG in the manifold at high pressure of 800 kPa. The spray macroscopic visualization test was carried out via Schlieren photography to study fuel-air mixing process. The fundamental spray characteristics, such as spray penetration, spray cone angle and spray velocity, were evaluated in the constant volume combustion chamber (CVCC) with varying the constant back pressure in CVCC from 0 to 1.8 bar. For the safety reason, nitrogen ($N_2$) and an acetone tracer were utilized as a surrogate gas fuel instead of CNG. The surrogate gas fuel pressures were controlled at 3, 5.5, and 8 bar, respectively. Injection durations were set at 5 ms throughout the experiment. The simulating events of the low engine speed were arranged at 1,000 rpm. The spray images were recorded by using a high-speed camera with a frame rate of 10,000 f/s at $512{\times}256pixels$. The spray characteristics were analyzed by using the image processing (Matlab). The results showed the significant difference that higher injection pressure had more effect on the spray shape than the lower injection pressure. When the injection pressure was increased, the longer spray penetration occurred. Moreover, the linear relation between speed and time are dependent on the injection pressure as well.

냉동능력 2 kW 급 역브레이튼 극저온 냉각시스템 성능시험 (Performance Test of 2 kW Class Reverse Brayton Refrigeration System)

  • 고준석;이근태;박성제;김종우;추상윤;홍용주;인세환;박지호;김효봉;염한길
    • 한국수소및신에너지학회논문집
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    • 제31권5호
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    • pp.429-435
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    • 2020
  • This paper describes the experimental study of reverse-Brayton refrigeration system for application to high temperature superconductivity electric devices and LNG re-liquefaction. The reverse-Brayton refrigeration cycle is designed with operating pressure of 0.5 and 1.0 MPa, cooling capacity of 2 kW at 77 K, and neon as a working fluid. The refrigeration system is developed with multi scroll compressor, turbo expander and plate heat exchanger. From experiments, the performance characteristics of used components is measured and discussed for 77-120 K of operating temperature. The developed refrigeration system shows the cooling capacity of 1.23 kW at 77 K and 1.64 kW at 110 K.

오리피스 유량계와 터빈 유량계의 직관부길이와 유동안정기에 관한 연구 (A Study of Straight Pipe Length and Straightener in Orifice Meter Turbine Meter)

  • 허재영;안승희;이강진;이승준
    • 유체기계공업학회:학술대회논문집
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    • 유체기계공업학회 2000년도 유체기계 연구개발 발표회 논문집
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    • pp.265-271
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    • 2000
  • Orifice meters and turbine meters are frequently used for measuring gas flow in gas industry. However, to insure the accuracy of the measurement, a certain length of the meter run at the upstream of the flow meter is required. The objective of this study is to analyze flow measurement errors of the orifice meter quantitatively for shorter lengths of the meter runs than those suggested in the standard manuals with variation of diameter ratio( $\beta$ ratio) and flow rate and also to analyze flow measurement errors of the turbine meter with and without straightener. The test results showed that the flow measurement errors of the orifice meter were inversely proportional to the diameter ratio. In other words, when the diameter ratio is 0.3 and 0.7, the measurement error is $-7.3\%$ and $-3.5\%$, respectively. the main reason of the measurement error is due to the swirl effect from the configuration of the meter run at the upstream of the flow meter. In case the length of the meter run is shorter than that suggested In the standard, the swirl effect is not removed completely and it affects the flow meter's performance. As mentioned above, the less the pipe diameter ratio, the mon the flow measurement error. It means that the swirl effect on the orifice meter increases as the $\beta$ ratio decreases.

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RI-CNG 엔진에서 연료 분사시기에 따른 연소특성에 관한 연구 (Study on Combustion Characteristics with Fuel Injection Timing in a RI-CNG Engine)

  • 박종상;하동흔;염정국;하종률;정성식
    • 동력기계공학회지
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    • 제12권4호
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    • pp.5-11
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    • 2008
  • The RI gasoline engine haying a sub-chamber had a high cycle variation due to the difficulty of the residual gas scavenge in the sub-chamber. To solve this problem and improve the combustion performance of RI engine, we devised a method to inject directly CNG fuel into the sub-chamber. A DI diesel engine of single cylinder was converted into a RI-CNG engine and an electronic control unit for the engine was manufactured. In this study, the combustion characteristics of the RI-CNG engine were investigated with the injection timings and air excess ratios at the load conditions of 50% throttle open rate and 1700rpm. As the results from this study, the RI-CNG engine worked reliably under the condition of the ignitable lean limit of $\lambda=1.7$ by showing the $COV_{imep}$ below about 5%. And the highest thermal efficiency could be obtained in the injection timing that produced the high imep and the low $COV_{imep}$ at the same time. The CO emission concentration indicated very low values and the THC and $NO_x$ showed an opposite pattern. With a view to improving the thermal efficiency and reducing the harmful emissions, the proper control region of the ignition timing and the mixture ratio were nearly ATDC $20^{\circ}\sim50^{\circ}$ and $\lambda=1.4$ respectively.

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원격장 와전류 배관 탐상 시스템 개발 (Development of Remote Field Eddy Current Pipeline Inspection System)

  • 정진오;이재경;김형진
    • 비파괴검사학회지
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    • 제21권5호
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    • pp.556-560
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    • 2001
  • 배관의 관벽투과 특성을 지닌 원격장 와전류 비파괴 검사법은 열교환기 세관 검사에서부터 천연가스 수송관에 이르기까지 다양한 형태의 배관과 결함을 대상으로 적용 연구가 진행되고 있다. 공칭 외경 100mm의 주철관은 주로 상수도 관로의 배수관으로 활용되고 있는데, 차량 진동과 부식에 의한 결함의 생성으로 정수의 누수 문제를 일으킨다. 그러나, 탐상 경제성 및 효용성 문제로 관내 검사장치 투입과 같은 직접적인 검사 방법의 수행이 제한되어 왔다. 원격장 와전류 방법은 시스템 구성이 용이하고 내 외부 부식 결함에 대한 정량적인 평가가 가능하기 때문에 경제성 있는 장치 개발이 가능하다. 본 연구에서는 원격장 와전류 기술을 이용하여 상수도 관망의 특성을 고려한 매설 배관 검사시스템 개발을 수행하였다. 세부적으로는 관내 투입 원격장 와전류 검사의 기구부 설계 및 제작, 원격장 와전류 신호의 획득 및 처리 프로그램 개발, 그리고 개발 장치의 운용 방법 및 절차 검토 등으로 되어 있다.

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LNG FPSO 액화공정에 적용되는 플레이트 핀 열교환기의 열전달 특성 (Heat Transfer Characteristics of Plate-fin Heat Exchanger Using LNG FPSO Liquefaction Process)

  • 유선일;김현우;정영권;윤정인;박승하;김창수
    • Journal of Advanced Marine Engineering and Technology
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    • 제34권6호
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    • pp.798-805
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    • 2010
  • LNG FPSO 액화 플랜트와 같은 초저온 분야에서 플레이트 핀 열교환기의 국내 연구 실적은 전무한 상태이다. 본 연구에서는 플레이트 핀 열교환기의 독자적 기술을 확보하기 위해 응축 열전달 특성을 이론 및 실험적으로 검증하였다. 시뮬레이션 결과 Plain fin을 제외한 Serrated, Wavy fin은 압력 69bar, 온도 $-140^{\circ}C$에서 응축되었고, 국소열전달계수는 Serrated, Wavy, Plain fin 순으로 높게 나타났다. 실험결과는 정상상태에서 10분간 데이터를 획득하였고 시뮬레이션 데이터값과 12% 미만의 오차범위를 만족하였다.

천연가스 선회 예혼합 화염의 NOx 생성 및 배출 특성 (NOx Formation and Emission Characteristics of Premixed Swirl Flame of Natural Gas)

  • 유현석;이중성;한정옥
    • 대한기계학회논문집B
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    • 제23권6호
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    • pp.788-794
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    • 1999
  • The swirl flame is mostly used to stabilize the flame on the burner nozzle in the industrial combustor. In the case of the weak swirl flame(S<0.4), the recirculation zone could not be formed, but in the strong swirl(S>0.6) flame, it could be formed in the center of the swirl flame. In this study, the measurement and analysis of emission species, temperature, radicals of premixed swirl flame in the combustor were performed to understand the NO formation and emission characteristics of the swirl flame of natural gas. The result of NO emission in the swirl flame is that the amount of NO emission in the strong swirl flame decreased about 60% compared with that of the weak swirl flame. The main region of NO formation of the weak swirl flame is positioned in the down stream(z=100~200mm) of the flame, but that of the strong swirl flame is positioned in the up stream(z=40mm) where the recirculation zone seems to be formed. It is supposed that the increase of flame surface and the formation of inversed flame cause the reduction of the high temperature region on the production of NO in the strong swirl flame. The result of NO-temperature relation revealed that the factor of NO formation is not only temperature but also another parameters in the weak swirl flame, but in the strong swirl flame, NO is proportional to the temperature of higher than 1200K.