• Title/Summary/Keyword: 천연유기물

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Relationship among Physical & Chemical Properties of Supports and Performance of Methane Fermentation in Anaerobic Fluidized-Bed Reactor (혐기성 유동층 반응기에서 지지체의 물리.화학적 특성과 메탄 발효 성능 사이의 관계)

  • 조무환;남영섭정재학김정목
    • KSBB Journal
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    • v.8 no.5
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    • pp.431-437
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    • 1993
  • Active carbon which has the smallest bulk and wet density was found as the best support media among 4 different kinds of materials(celite, natural zeolite, Pusuk stone, active carbon) to make a proper fluidized-bed with small energy consumption. Its minimum and optimum fluidization velocity were found as 0.03cm/sec and 0.25cm/sec, respectively. As organic loading rate for methane fermentation was increased, CODcr removal efficiencies of all the media were decreased. But, CODcr, removal efficiencies of active carbon was maintained more than 90% in this experimental range of the organic loading rate. Larger amount of microorganism was adsorbed on the active carbon which has very high specific surface area. At the organic loading rate of 16g CODcr,/l day, its adsorbed cell mass was 157mg/g. Comparing natural zeolite with roast celite, adsorbed cell mass did not increase in proportion to specific surface area of the media. Even though roast celite has the same specific surface area as the Pusuk stone, its organic removal ability was superior to that of the Pusuk stone, which explains that the relatively great surface roughness and the positive surface charge are important for cell adsorption. It was concluded that the support media for anaerobic fluidized reactor should have small wet density and small fuidization velocity, if possible, in order to increase cell adsorption by reducing the fluid shear stress.

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Analysis of Forest Resources in Anmyondo for Forest Management Harmonizing with Nature (자연친화적(自然親和的)인 산림경영(山林經營)을 위한 안면도(安眠島) 산림자원(山林資源) 분석(分析))

  • Song, Ho Kyung;Lee, Sun;Heo, Won Mu;Lee, Mi Jeong
    • Journal of Korean Society of Forest Science
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    • v.89 no.2
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    • pp.185-197
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    • 2000
  • This study was carried out to research structure of forest vegetation and site condition, and supply basic data for conservation of pine forest and ecologically sustainable forest management and control in Anmyondo area. The forest of Anmyondo were largely classified as four forest community : Pinus densiflora community, Pinus thunbergii community, Pinus rigida community, and Quercus variabilis community. Organic matter, total nitrogen, and other nutrients in soil of the study area were relatively low, and average soil pH was 4.9. Soil texture was sandy clay or heavy clay and so the aeration and permeability could be poor. In this study site, the methods such as the promotion of germination of pine seeds through removal of forest floor and inducement of natural regeneration through such method as regeneration under shelter wood would be better than the method such as afforestation after clear-cutting for conservation the pine forests. Also, it will be a good method to practice tending for hardwood species in the dominant areas by hardwood species.

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The Effects of Reaction Conditions and NOM on Persulfate Oxidation of RDX (Persulfate에 의한 RDX 산화시 반응조건과 NOM의 영향)

  • Wu, Dabo;Bae, Bum-Han
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.10
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    • pp.723-730
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    • 2011
  • In this experiment, persulfate, a strong oxidant for ISCO (In-Situ Chemical Oxidation) was used to degraded RDX in artificial ground water at ambient temperature. Results of RDX degradation by persulfate in a batch reactor showed that the oxidation reaction was pseudo first order with estimated Ea (activation energy) of $1.14{\times}10^2kJ/mol$ and the rate was increased with the increase of reaction temperature. The oxidation of RDX by persulfate increased slightly with the increase of initial solution pH from 4 to 8. The RDX oxidation rate increased 13 times at pH 10 compared with that at pH 4, however, alkaline hydrolysis was found to be the main reaction of RDX degradation rather than oxidation. The study also showed that the oxidation rate of RDX by persulfate was linearly dependent upon the molar ratios of persulfate to RDX from 5 : 1 up to 100 : 1, with a proportion constant of $4{\times}10^{-4}$ ($min^{-1}$/molar ratio) at $70^{\circ}C$. While NOM (Natural Organic Matter) exerted negative effects on the oxidation rate of RDX by persulfate, with a proportion constant of $1.21{\times}10^{-4}$ ($min^{-1}{\cdot}L/mg-NOM$) at $70^{\circ}C$ and persulfate/NOM molar ratio of 10/1. The decrease in RDX oxidation rate was linearly dependent upon the added NOM concentration. However, the estimated activation energy in the presence of 20 mg-NOM/L was within 3.3% error compared to that without NOM, which implies the addition of NOM does not alter intrinsic oxidation reaction.

Oxidative Coupling Reaction of Purified Aldrich Humic Acid by Horseradish Peroxidase (산화환원효소에 의한 휴믹산의 산화중합반응)

  • Jee, Sang-Hyun;Kim, Do-Gun;Kim, Jeong-Hyun;Ko, Seok-Oh
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.11
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    • pp.1054-1062
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    • 2010
  • Oxidative coupling reactions of humic substances (HS) can be catalyzed by a variety of natural extracellular enzymes and metal oxides. In this study, property changes of HS induced by a natural enzyme, horseradish peroxidase (HRP), and the effect of it to microfiltration (MF) were investigated. PAHA was transformed by oxidative coupling reaction with HRP and hydrogen peroxide ($H_2O_2$), verifying the catalytic effects of the HRP. Size exclusion chromatography (SEC) revealed that weight-average molecular weight (MWw) of PAHA was proportionally increased with the dosages of HRP and $H_2O_2$, indicating the transform action of HS into larger and complex molecules. An increase in the conformational stability of HS was achieved through the promotion of intermolecular covalent bondings between heterogeneous humic molecules. Spectroscopic analysis (fluorescence and infrared spectroscopy) proved that functional groups were transformed by the reaction. Additionally, HS and transformed products were undergone microfiltration (MF) to examine the treatment potential of them in a water treatment facility. Original HS could not be removed by MF but larger molecules of transformed products could be removed. Meanwhile, transformed products caused more fouling on the filtration than original HS. This results proved that natural organic matter (NOM) can be removed by MF after its increase in molecular size by oxidative coupling reaction.

Growth Response of Pinus rigida × P. taeda to Mycorrhizal Inoculation and Efficiency of Pisolithus tinctorius at Different Soil Texture and Fertility with Organic Amendment (리기테다 소나무의 균근(菌根) 접종(接種) 반응(反應)과 토양비옥도(土壤肥沃度)에 따른 모래밭 버섯의 효과(効果) 및 그 생태학적(生態學的) 의미(意味))

  • Lee, Kyung Joon
    • Journal of Korean Society of Forest Science
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    • v.64 no.1
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    • pp.11-19
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    • 1984
  • Potted, germinating Pinus rigida ${\times}$ P. taeda seedlings were inoculated with Pisolithus tinctorius (Pt) ectomycorrhizal fungus to test the effectiveness of Pt in relation to organic amendment and changes in soil fertility and soil texture. Pt was cultured as mycelia in vermiculite-peat moss mixture with nutrients and added to sterilized pot soils with or without organic amendment (fully fermented compost) at three soil texture levels (sand, loamy sand, and sandy loam) in a factorial design. Plants were grown in a greenhouse for 4 months and harvested to compare their growth with non-mycorrhizal plants and plants infected by natural fungi. Regardless of sod texture, soil fertility, or organic amendment, seedlings inoculated with Pt were better in dry weight and height than non-mycorrhizal plants or those infected by natural fungi. An exception was observed in the most fertile soil (0.075% N and 1.32% organic matter content in sandy loam with organic amendment), where non-mycorrhizal plants were slightly bigger (8%) and heavier (18%) than Pt-inoculated plants. In over-all average, Pt-inoculated seedlings were 30% taller and 107% heavier than those infected by natural fungi and 31 % taller and 60% heavier than non-mycorrhizal plants. Growth stimulation of seedlings by Pt was more pronounced in less fertile sand soil when organic was not amended. Mycorrhizal frequency of Pt (% of mycorrhizal root tips) was reduced to about half (from 84 to 33% in sandy loam and from 77 to 40% in loamy sand) by organic amendment, while that of natural fungi was not significantly affected. Severe nitrogen deficiency was observed in the needles of non-mycorrhizal plants (1.38% N), while both Pt-inoculated plants (1.68% N) and those infected by natural fungi (1.89% N) did not develop symptom, suggesting an active role of mycorrhizae in absorption of soil nitrogen. Top to root ratio increased with organic amendment to non-mycorrhizal plants, but was not significantly affected by fungal treatment. It was concluded from this study that relative effectiveness of Pt was determined by soil fertility. Organic amendment to less fertile sand soil increased effectiveness of Pt, while the same amendment to more fertile loamy sand and sandy loam decreased effectiveness of Pt. Benefits of Pt mycorrhizae would be expected most either when organic was not added to the soil, or when soil nutrients were not abundant.

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Synthesis of Alginate-derived Polymeric Surfactants (알지네이트계 고분자 계면활성제의 합성)

  • 강현아
    • KSBB Journal
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    • v.15 no.4
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    • pp.375-379
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    • 2000
  • Alginate derivatives possessing various lengths of alkyl amine (C8, C12, C16) chain were prepared by oxidation followed by reductive amination of alginate and the products were characterized by spectral analysis. The surface tension critical micelle concentration (c. m. c) and solubility of a hydrophobic compound azobenzene were examined. Series of synthesized alginate-derived polymeric surfactants(APSs) reduced the surface tension. The dissolving capacity of APSs toward azobenzene was about half that of SDS. In order to investigate the capacity of metal adsorption Co and Pb were selected as a representative metal. The overall removal efficiency of APSs were high compared with that of alginate at pH 3.5 and 7 respectively. Major mechanism of the heavy metal removal is the complex of metal with carboxyl group.

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Dyeing Properties Evaluation of Functional Sheath-Core Yarn (기능성 Sheath-Core 원사의 염색성 평가)

  • Kim, Jung-Gon;Ryu, Jung-Jae;Lim, Ji-Hye;Kim, Young-Un;Park, Yong-Wan;Ko, Jung-An;Kim, Eui-Hwa
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.11a
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    • pp.45-45
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    • 2011
  • 최근 환경과 건강에 대한 관심이 증대되면서, 복합기능을 갖는 다기능성 섬유에 대한 요구가 증대되고 있는 실정이다. 일반적으로 기능성은 마이크로캡슐이나 후가공제를 이용하여 일반 섬유 제품에 적용하고 있다. 마이크로캡슐이나 후가공제가 적용된 일반 섬유제품은 일상생활 속에서의 마찰 및 세탁 등으로 인해 기능 저하가 발생된다. 이러한 문제점을 개선하기 위해 특수 방사 기술을 이용하여 다기능성을 갖는 섬유 제조 기술이 개발되고 있다. 다기능성 섬유소재 및 응용제품은 그 제조 공정성이 우수하고, 염색 가공 등의 후 공정 조건에 의해 기능성 저하를 초래하지 않고, 지속시간이 오래 유지해야하는 조건을 만족해야한다. 이러한 기능성 저하 문제를 해결하고 내구성 향상 및 기능성의 지속 시간을 오래 유지하기 위하여 복합 방사 기술을 이용하여 이형 단면 원사, Sheath-Core 단면 원사 등이 개발되고 있다. 개발된 기능성 원사의 경우 일반 원사와 다른 형태의 염색성을 보일 수 있으며, 염색 온도 및 염색 시간 등 염색 조건이 달라질 수 있다. 본 연구에서는 식물 등에서 추출한 천연 항균 유기물을 마이크로캡슐화하여 이형단면의 심부에 담지된 형태인 Sheath(Nylon: 50%)-Core(PP MB: 50%) 원사의 염색성 평가 시험을 실시하였다. 시험 방법은 Sheath-Core 원사와 일반 Nylon 원사와 염착 거동 시험을 통해 비교해 나타냈고, 염색 전 후의 물성을 비교해보았다. 또한 염색성 평가 시험을 토대로 기능성 원사의 염색 온도와 시간에 따른 색차 비교 시험을 통해 기능성 원사의 염색 조건을 선정하는 시험을 실시하였다.

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미소조류의 응용연구(개관) (Applied Researches on Microalgae(Overview))

  • YIH Won-Ho
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.25 no.3
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    • pp.205-218
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    • 1992
  • Trends in the applied microalgal researches were described as those in two separate periods. During the first period (earlie. than 1970) . most researches were oriented to using the whole microalgal cells as feed, food, fertilizer, and agent for the treatment of organic waste water. Since early 1970's (the second period) the number of researches on the production of specific cell metabolites has grown so rapidly. Many researchers endeavored after the very expensive 'natural products' form microalge such as vitamins, amino acids, $\beta-carotene$, phycofluor, pharmaceuticals, biologically active compounds, $H_2$ gas, and deutrated chemicals. On the other hand, the applied microalgal researches in Korea are still in the early stage of developments, and urgent activation of the related researchers is quite important to meet the future needs in the microalgal products. Systems for the management of the management of the microalgal clonal cultures from Korean waters should be established soon, which will support many microalgal researchers in Korea.

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A Review on the Chemistry of Soil Organic Matter - Progress in the Study on the Chemical Structure of Humic Substances - (토양(土壤) 유기물(有機物)의 생성(生成)과 성상(性狀) "부식물(腐植物)의 화학구조(化學構造) 연구(硏究)의 진전(進展)에 대하여")

  • Lim, Sun-Uk
    • Korean Journal of Soil Science and Fertilizer
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    • v.11 no.3
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    • pp.127-144
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    • 1979
  • Recent trend in the studies on the forming processes, chemical characteristics and chemical structure of humic substances with some discussions are reviewed and some arguments for the elucidation of the chemical structure of humic substances are summarized.

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Characteristics of Bacterial Community for Biological Activated Carbon(BAC) by Culturable and Unculturable Methods. (배양적 및 비배양적 방법에 의한 생물활성탄 부착세균 군집 특성)

  • Park, Hong-Ki;Jung, Eun-Young;Jung, Mi-Eun;Jung, Jong-Moon;Ji, Ki-Won;Yu, Pyung-Jong
    • Journal of Life Science
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    • v.17 no.9 s.89
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    • pp.1284-1289
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    • 2007
  • The Biological Activated Carbon (BAC) process in the water treatments represents a kind of biofiltration process which capabilities of bacteria to remove organic matters are maximized. It enables to eliminate organic matters and effectively reduce microbial regrowth potentials. As attached bacteria employ natural organic matter as a substrate, they are significantly dependent on indigenous microorganisms. In this study, characteristics of bacterial community by culturable and unculturable Methods have been conducted in a pilot plant using SAC in water treatment process at the downstream of the Nakdong River. Based on the results, HPC and bacterial- production for coal-based activated carbon material were $1.20{\sim}56.2{\times}l0^7$ cfu/g and $1.2{\sim}3.7\;mgC/m^{3}h$, respectively, in the SAC process. The highest level of attached bacteria biomass and organic carbon removal efficiency was found in the coal-based activated carbon. The genera Pseudomonas, Flavobacterium, Alcaligenes, Acilzetobacter, and Spingomonas were identified for each activated carbon material. Pseudomonas vesicularis was the dominant species in the coconut- and coal-based materials, where as Pseudomonas cepacia was the dominant species in the wood-based material. The Scanning Electron Microscope (SEM) observation of the activated carbon surface also found the widespread distribution of rod form and coccus. The community of attached bacteria was investigated by performing Fluorescent in situ hybridization (FISH) analysis. a group was dominant in coal, wood and coccunt-based materials, ${\alpha},\;{\beta}\;and\;{\gamma}$ group ranged from 27.0 ${\sim}$ 43.0%, 7.1 ${\sim}$ 22.0%, 11.3 ${\sim}$ 28.6%, respectively. These results suggest that a group bacterial community appears to be regulated removal efficiency of organic material in water treatment process.