• Title/Summary/Keyword: 착화수

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Tris(2-phenylpyridine)iridium(III)를 사용하여 제작한 인광 유기발광소자의 삼중항 엑시톤 충돌을 억제하여 발광 효율을 증가시킨 유기발광소자

  • Kim, Jeong-Hwa;Kim, Dae-Hun;Chu, Dong-Cheol;Lee, Dae-Uk;Kim, Tae-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.320-320
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    • 2011
  • 차세대 디스플레이로 각광 받고 있는 유기발광소자는 빠른 응답속도, 넓은 시야각 및 얇은 두께로 제작이 가능한 장점들을 가지고 있으나, 고효율 유기발광소자를 제작하기 위하여 엑시톤 형성 효율을 증가시키고 형성된 엑시톤의 소멸을 감소시켜 발광 효율을 증진하는 연구가 활발히 진행되고 있다. 유기발광소자의 발광 효율을 증진하기 위하여 소자의 구조에 대한 구조적 연구와 발광 물질에 대한 재료적 연구 등이 진행되고 있으며, 그 중에서 발광층에 사용하는 인광 물질은 삼중항 상태의 엑시톤을 광자로 천이할 수 있는 특성이 있어서 높은 발광 효율의 유기발광소자 제작이 가능하기 때문에 많은 연구가 진행되고 있다. 그러나 인광 물질을 사용한 유기발광소자의 엑시톤 수명이 형광 물질을 사용한 유기발광소자의 엑시톤 수명보다 길기 때문에, 인광 물질을 사용한 유기발광소자에서 형성된 삼중항 엑시톤끼리 서로 충돌하여 소멸될 확률이 높아지는 문제점이 있다. 또한, 인광물질을 사용한 유기발광소자 동작시에 높은 전류 영역에서 삼중항 엑시톤 형성 양이 많아서 삼중항 엑시톤 소멸 확률이 증가하는 문제점이 있다. 본 연구에서는 고효율 유기발광소자를 제작하기 위하여 유기발광소자의 발광층으로 인광 호스트 물질에 iridium을 포함한 중금속 착화합물 계열의 녹색 인광 도펀트 물질인 tris(2-phenylpyridine) iridium(III) ($Ir(ppy)_3$)를 도핑하였다. 제작된 유기발광소자는 전류 증가에 따른 삼중항 엑시톤 충돌로 인한 발광 효율 감소를 억제하기 위하여 인광 도펀트인 $Ir(ppy)_3$와 같은 lowest unoccupied molecular orbital 준위를 가지는 4,7-diphenyl-1,10-phenanthroline 전자 수송층을 사용하였다. 전기적 및 광학적 특성 분석 결과 제작된 유기발광소자에서 삼중항 엑시톤 소멸을 최소화하여 발광 효율이 증가한 것을 확인하였다. 본 실험의 결과는 $Ir(ppy)_3$을 도핑한 녹색 인광 유기발광소자의 삼중항 엑시톤 충돌을 억제하여 유기발광소자의 발광 효율을 증진하는 메커니즘을 이해하는데 중요하다.

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Facilitated Transport Membrane for Ethylene/Ethane and Propylene/Propane Separation (SPEEK-Ag 촉진 수송 분리막을 이용한 $C_2,\;C_3$ 계 올레핀/파라핀 분리)

  • Kim, Ji-Yeon;Lee, Hyun-Joo;Kim, Hoon-Sik;Jung, Hyun-Wook;Choi, Dae-Ki
    • Clean Technology
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    • v.13 no.1 s.36
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    • pp.79-84
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    • 2007
  • Separation of ethylene from ethane and propylene from propane have been conducted using facilitated olefin transport membrane with SPEEK-Ag (Ag substituted sulfonated poly(ether ether ketone)). SPEEK was prepared by the sulfonation of PEEK using cone. $H_2SO_4$ and the reaction time affected the degree of sulfonation (DS) of the resulting SPEEK. SPEEK-Ag composite membrane was formed by soaking SPEEK in the polyester support into the Ag salt solution. With increasing the concentration of SPEEK in MeOH, the thickness of SPEEK on the polyester increased. The selectivity and the flux of SPEEK-Ag membrane for the separation of ethylene/ethane and propylene/propane were changed by the thickness of SPEEK layer on the top of polyester support. The anion of silver salt also affects the membrane performance.

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A Experimental Study on Characteristics of the Ignition by Cigarette Light (담뱃불 발화특성에 관한 실험적 연구)

  • Yun, lnsu;Kim, Byungseon;Cho, Won Cheol;Lee, Tae Shik
    • Journal of Korean Society of societal Security
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    • v.1 no.1
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    • pp.81-87
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    • 2008
  • The cigarette holds more than 10 percents of the entire fire accidents despite the number of smokers rapidly decreases every year. The purpose of this study is to examine the ignition characteristics of cigarette by experimentation. This study analyzed the cases of fires inferred that they were caused by cigarette in Incheon during 2006. As the representative ignition materials, corrugated board, gasoline, lacquer thinner, tarpaulin, flexible PVC sheet, and poly ethylene were tested. In this experimentation, the corrugated board was ignited by cigarette. However gasoline, lacquer thinner, tarpaulin, flexible PVC sheet, and poly ethylene were seldom ignited. Meanwhile most fire investigators have argued that oils and tents were ignited by cigarette, but this study experimentally proved that such an argument might be ungrounded.

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Separation and Distribution Coefficients of Some Transition Metal Ions in Some Mixed Solvents (혼합용매에서의 양이온교환수지에 의한 전이원소의 분리와 분배계수)

  • Kee Won Cha;Si-Joong Kim;Kee Chae Park
    • Journal of the Korean Chemical Society
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    • v.17 no.6
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    • pp.434-438
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    • 1973
  • Distribution coefficients (C) of some transition metal ions such as Ni(II), Cu(II), Cd(II), Zn(II), and Hg(II) have been determined in methanol-, ethanol-, isopropanol-, acetone-, and dimethylsulfoxide-water mixtures by using Rexyn 101 (Na-form) resin and 0.2 M sodium chloride solution. The log C values of the metallic ions decrease almost straightly with the increase in reciprocal values of the dielectric constants of the mixed solvents. In the solvents having the same dielectric constants, the distribution coefficients of the metallic ions decrease with the increase in the basicity of the aprotic organic molecule and with the decrease in the molecular size of the protic organic molecule. The separation of the metallic ions has been accomplished with the eluting agent suggested by the C values.

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Basic Experimental Study on the Application of Biofuel to a Diesel Engine (바이오연료의 엔진 적용을 위한 실험적 기초연구)

  • Yeom, Jeong-Kuk
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.11
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    • pp.1163-1168
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    • 2011
  • Compared with the spark-ignition gasoline engine, the compression-ignition diesel engine has reduced fuel consumption due to its higher thermal efficiency. In addition, this reduction in the fuel consumption also leads to a reduction in $CO_2$ emission. Diesel engines do not require spark-ignition systems, which makes them less technically complex. Thus, diesel engines are very suitable target engines for using biofuels with high cetane numbers. In this study, the spray characteristics of biofuels such as vegetable jatropha oil and soybean oil were analyzed and compared with those of diesel oil. The injection pressures and blend ratios of jatropha oil and diesel oil (BD3, BD5, and BD20) were used as the main parameters. The injection pressures were set to 500, 1000, 1500, and 1600 bar. The injection duration was set to $500{\mu}s$. Consequently, it was found that there is no significant difference in the characteristics of the spray behavior (spray angle) in response to changes in the blend ratio of the biodiesel or changes in the injection pressure. However, at higher injection pressures, the spray angle decreased slightly.

A New Spray Chrysanthemum Cultivar, 'Noble Wine' with Good Color, Single Type and Bi-color Petals for Cut Flower (화색이 우수한 복색 홑꽃 스프레이국화 'Noble Wine' 육성)

  • Hwang, Ju Chean;Chin, Young Don;Chung, Yong Mo;Kim, Su Gyeong;Jeong, Byoung Ryong
    • FLOWER RESEARCH JOURNAL
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    • v.17 no.2
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    • pp.137-140
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    • 2009
  • A new spary chrysanthemum(Dendranthema grandiflorum) cultivar 'Noble Wine' was developed from a cross between 'SL03-01' and 'Artist Pink' by selection of seedlings and lines at the Flower Research Institute, Gyeongnam Agricultural Research and Extention Services(ARES) from 2003 to 2007. Its characteristics were investigated three times from 2005 to 2007 under condition of forcing culture in spring and retarding culture in autumn. The natural flowering time of 'Noble Wine' was October 26th, and yearround production was possible by day length treatment. Its capitulum was 5.4 cm in diameter, and had 21.6 ray florets and 28.5 head per stem in autumn. Its ray floret was red-purple with green central zone. 'Noble Wine' was about 45 days in spring, and 'Noble Wine' showed the vase life of 21.3 days in autumn. This cultivar was registered for a commercialization in 2007.

A New Spray Chrysanthemum Cultivar, 'Serapina' with Good Shape, Single Type and Yellow Petals for Cut Flower (화형, 화색이 우수한 황색 홑꽃 스프레이국화 '세라피나' 육성)

  • Hwang, Ju Chean;Chin, Young Don;Chung, Yong Mo;Park, Young Bae;Kim, Su Gyeong;Jeong, Byoung Ryong
    • FLOWER RESEARCH JOURNAL
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    • v.16 no.3
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    • pp.200-204
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    • 2008
  • A new spary chrysanthemum(Dendranthema grandiflorum) cultivar 'Serapina' was developed from a cross between 'Relanse' and 'Yen' by selection of seedlings and lines at the Flower Research Institute, Gyeongnam Agricultural Research and Extention Services(ARES) from 2002 to 2006. Its characteristics were investigated three times from 2004 to 2006 under condition of forcing culture in spring and retarding culture in autumn. The natural flowering time of 'Serapina' was October 23th, and year-round production was possible by day length treatment. Its capitulum was 2.8cm in diameter, and had 43.4 ray florets and 28.9 head per stem in autumn. Its ray floret was yellow with green central zone. To flower in the short day condition, for 'Serapina' was about 46 days in spring, and 'Serapina' showed the vase life of 21.7 days in autumn. This cultivar was registered for a commercialization in 2007.

Influence of degree of maturity and duration of cold treatment on the growth and flowering of L. elegans 'Connecticut King' bulb (Lilium elegans 'Connecticut King'의 촉성재배(促成栽培)에 있어서 구근(球根)의 숙도(熟度) 및 저온처리기간(低溫處理期間)이 생육(生育) 및 개화(開花)에 미치는 영향(影響))

  • Lee, Jeng;Shin, Hak Ki;Choi, Sang Tai
    • Current Research on Agriculture and Life Sciences
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    • v.9
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    • pp.147-155
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    • 1991
  • Effects of harvest date, number of the leaves remained on stump after flower cutting, duration of cold treatment on the growth and flowering of L. elegans 'Connecticut King' bulb were tested. Shoot emerging rate increased over 90% by delayed cold treatment, late harvesting time and more leaves remained. Flowering rate increased over 90% when conducted cold treatment of 90 days to the premature bulb at flowering date, the bulb matured for 50 days with 10 leaves and the bulb matured for over 30 days with 20 leaves, and when conducted cold treatment of 50 days to the bulb matured for over 30 days with all leaves. Delayed cold treatment duration shortened days needed to shoot emergence and flowering. Especially days to flower of the premature bulb at flowering date were the shortest of all treatments, and can be flowered within 100 days after planting. In generally, plant height, number of flowers per plant and stem diameter generally increased by longer bulb maturing period after flower cuting, and the premature bulb harvested at flowering date showed poor growing and flowering responses. But, if used the larger size bulb, it is believed that the prematured bulb can be forced to flower normally in current year without bulb maturing period.

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Extension of Low Temperature Combustion Regime by Turbocharging Using Diesel and Biodiesel Fuels (과급에 의한 디젤 및 바이오디젤의 저온연소 운전영역 확장에 관한 연구)

  • Jang, Jae-Hoon;Oh, Seung-Mook;Lee, Yong-Gyu;Lee, Sun-Youp
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.11
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    • pp.1065-1072
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    • 2012
  • Due to its oxygen (O) content, biodiesel (BD) is advantageous in that it lowers PM emissions in CI engines. Therefore, BD is considered one of the best candidates for low temperature combustion (LTC) operation because its use can extend the regime for simultaneous reduction of PM and $NO_x$. Thus, in this study, LTC operation was realized using BD and diesel with a 5~7% $O_2$ fraction. Engine test results show that the use of BD increased the efficiency and reduced emissions such as PM, THC, and CO; furthermore, IMEP reduced by 10~12% owing to the lower LHV of the fuel. In particular, smoke was suppressed by up to 90% because O atoms in the BD enhanced the soot oxidation reaction. To compensate the IMEP loss, turbocharging (TC) was then tested, and the results showed that the power output increased and PM was reduced further. Moreover, TC in BD engine operation allowed a similar level of reduction in both $NO_x$ and PM at 11~12% $O_2$ fraction, suggesting that there is a potential to widen the operating range by the combination of TC and BD.

A Study on Flame Retardant Performance of Vertical Blind and Roll Screen (버티칼 브라인드와 롤 스크린의 방염성능 유지에 관한 연구)

  • Jeong, Hyun Gyu;Cho, Woncheol;Lee, Tae Sik
    • Journal of Korean Society of societal Security
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    • v.3 no.2
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    • pp.41-46
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    • 2010
  • This study focuses on two points. First, I have examined the difference on combustion between flame-retardant and non flame-retardant products including vertical blinds and roll screens that are widely used as a substitute for fabric curtains. The second point is to see how long flame-retardant goods can be durable, that is, flame retardant durability after washing in liquid. the experiment on the flame-retardant ability before and after washing of vertical blinds and roll screens that have been used for a long time in fire protection construct. Comparing and analyzing domestic and foreign laws on flame-retardant after the experiment on durability of these products. I aim to draw necessity for increased application of internal laws and regulations on flame-retardant and show how to improve the point at issue. According to the result, clear differences in performance and safety were observed between flame-retardant and non flame-retardant products. flame-retardant materials can prevent things from fire spread without igniting but melting when they've met flame and burnt, In contrast, non flame-retardant material for experiment which size is 120cm long takes less than 3 minutes only to be completely destroyed by fire. However, it was expected for flame-retardant durability of flame-retardant blinds which are not washable to decrease flame-retardant durability after being washed with water, there was no sharp difference. so it is demonstrated that flame-retardant blinds can keep flame-retardant durability. accordingly through the strict course of product we are concerned about keeping durability.

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