• Title/Summary/Keyword: 질화물

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A study on the fabrication and properties of aluminum oxynitride spinel spinel(ALON) prepared by reaction sintering method (반응소결법을 이용한 Aluminum Oxynitride Spinel(ALON) 제조 및 특성연구)

  • 장복기;이종호;백용혁;문종하;신동선;임용무
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.3
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    • pp.320-326
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    • 1999
  • Aluminum oxynitride spinel (ALON) was synthesized by the direct melt nitridation (DMN) process using aluminum metal and aluminium oxide. The amount of ALON increased with increasing the reaction sintering temperature. The specimen containing up to 10 wt% Al showed ALON phase only when heat-treated beyond $1750^{\circ}C$. Whereas the specimen composed of more than 12 wt% Al showed unreacted AlN phase. Bulk density of reaction-sintered specimen was increased with increasing sintering temperature, except the speimen containing unreacted AlN where the density slightly decreased when heat-treated beyond $1750^{\circ}C$, Transgranular fracture mode was observed predominantly in the specimen with higher Al content.

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Study on Rotor and Bushing Material of Gyro-pump (자이로 펌프의 로타 및 붓싱 재료에 관한 연구)

  • 김기선;김정훈;김선화
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.3 no.2
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    • pp.115-119
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    • 2002
  • This study was performed to improve mechanical properties of rotor and bushing materials. SACD and SKD11 steels as rotor and bushing materials were investigated. Gas nitriding and TiN coating were carried out on SACM and SKD11 steels. TiN coating was deposited on SKD11 steel by reactive sputtering process. This coated layer was picked off during the operation because of insufficient adhesion. Gas nitriding was carried out on SACM and SKD11 steels in an ammonia atmosphere at 51$0^{\circ}C$ for 72 hrs. These gas nitrided parts showed good mechanical properties. SKD11 steels were heat-treated to obtain optimum carbide size and distribution. As a results, the hardness increased.

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$B_N$-결함 질화붕소 나노튜브($B_N$-BNNT)를 활용한 $CO_2$ 흡착/전환 반응에 대한 이론 계산 연구

  • Choe, Hui-Cheol;Park, Yeong-Chun;Kim, Yong-Hyeon;Lee, Yun-Seop
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.299.1-299.1
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    • 2013
  • 넓은 표면적을 갖는 탄소나노튜브(CNT)는 기체 분자의 흡착 성능이 기존의 다른 흡착제에 비해 우수한 것으로 알려져 있으나, CNT의 물리/화학적 성질은 튜브의 직경과 기하 구조에 의해 큰 차이를 나타내며 정제가 매우 까다롭다는 단점을 가지고 있다. CNT와 외형적으로 매우 흡사한 질화붕소 나노튜브(BNNT)의 경우, 구조와 직경에 상관없이 열적, 화학적 안정성이 우수하여 $CO_2$를 비롯한 다른 공해 물질들의 제거제나 흡착제로서 응용 가능성이 매우 높다. 본 연구진은, BN-결함을 도입한 BNNT 벽면에서의 $CO_2$ 흡착 반응과 $CO_2$를 에너지 물질인 HCOOH와 $H_2CO_3$로 전환하는 반응에 대한 양자화학 이론 계산 연구를 수행하였다. 그 결과, $CO_2$에 대한 $B_N$-BNNT 흡착 성능이 튜브의 직경에 상관없이 매우 우수하였고, $B_N$-BNNT 벽면상에 흡착된 $CO_2$가 물 분자와 반응할 경우 HCOOH와 $H_2CO_3$로의 전환반응이 효과적으로 진행되었다. 이러한 이론 계산 연구 결과는 BN-BNNT가 $CO_2$ 흡착제 및 에너지 전환 촉매로의 응용 가능성을 훌륭히 제시하고 있다.

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Effects of the Precipitation of Carbides and Nitrides on the Textures in Extra Low Carbon Steel Sheets containing B, Nb and Ti(l) (B,Nb 및 Ti 를 함유한 극저탄소강에서 탄화물 및 질화물의 석출이 집합조직에 미치는 영향(I)-집합조직과 기계적 성질-)

  • Lee, Jong-Mu;Yoon, Kuk-Hoon;Lee, Do-Hyeong
    • Korean Journal of Materials Research
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    • v.3 no.1
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    • pp.43-49
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    • 1993
  • Excellent deep drawability and strain aging rsistance are obtained by the addition of alloying elements such as Ti and Nb which can form carbide and nitride easily into Al killed extra low carbon steel. Recrystallization textures and mechanical properties of the three different extra low carbon steels with B containing Nb only, Ti only, and both Nb and Ti, respectively, along with have been compared. Inverse pole figure shows that (100) and (111) texture intensities of Nb containing steel changed a lot during the annealing treatment and the degree of texture-structural change in the steel containing both Nb and Ti is about the same as that in the Ti-containing 5teel. After annealing the pole figure shows that the {Ill} < 110 > and {112} < 110> textures are the strongest in the cold rolled state and the annealed state, respectively. However, there is little difference in texture structure among the three kinds of steels. There is a tendency that the steel containing both Nb and Ti the grain size of which is the smallest is the highest in hardness. Nb-containing steel is the next and Ti -containing steel is the last in hardness.

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The effect of annealing conditions on ultra shallow $ p^+-n$ junctions formed by low energy ion implantation (저에너지 이온 주입 방법으로 형성된 박막$ p^+-n$ 접합의 열처리 조건에 따른 특성)

  • 김재영;이충근;홍신남
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.41 no.5
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    • pp.37-42
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    • 2004
  • Shallow $p^{+}$-n junctions were formed by preamorphization, low-energy ion implantation and dual-step annealing processes. Germanium ions were implanted into silicon substrates for preamorphization. The dopant implantation was performed into the preamorphized and non-preamorphized substrates using B $F_2$2 ions. Rapid thermal anneal (RTA) and furnace anneal (FA) were employed for dopant activation and damage removal. Samples were annealed by one of the following four methods; RTA(75$0^{\circ}C$/10s)+Ft FA+RTA(75$0^{\circ}C$/10s), RTA(100$0^{\circ}C$/10s)+FA, FA+The Ge Preamorphized sample exhibited a shallower junction depth than the non-preamorphized sample. When the employed RTA temperature was 100$0^{\circ}C$, FA+RTA annealing sequence exhibited better junction characteristics than RTA+FA thermal cycle from the viewpoint of junction depth, sheet resistance, $R_{s}$$.$ $x_{j}$, and leakage current.t.

The Effect of Particle Size of Coating Powder and Coating Temperature on the Thickness of Coating Layer Formed on Metal Surface (Calorizing 처리에서 코팅분말의 입자크기 및 코팅온도가 금속표면에 형성된 코팅층의 두께에 미치는 영향)

  • Ha, Jin-Wook;Park, Hai-Woong
    • Applied Chemistry for Engineering
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    • v.10 no.7
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    • pp.1061-1065
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    • 1999
  • The effect of particle size of coating powder and coating temperature on the thickness of coating layer formed on metal surface was studied by using XRD, SEM and EDXS. Coating powder was separated according to particle size by 3 steps and coating temperatures were varied from $950^{\circ}C$ to $980^{\circ}C$. Calorizing carried out at air and Ar conditions for 5 hrs, respectively. XRD result show that $Al_2O_3$ and AlN were formed during calorizing at air condition. The thickness and Al content of coating layer increased as the particle size of coating powder decreased and coating temperature increased.

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Field Assisted Method of Producing Wide-bandgap Transparent Conductive Electrodes for Deep Ultra-violet Light Emitting Diodes Prepared by Magnetron Sputtering

  • Kim, Seok-Won;Kim, Su-Jin;Kim, Hui-Dong;Kim, Gyeong-Heon;Park, Ju-Hyeon;Lee, Byeong-Ryong;U, Gi-Yeong;Kim, Tae-Geun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.331-331
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    • 2014
  • 3족 질화물에 기반한 발광다이오드는 비소화물이나 인화물에 비해 여러 가지 장점을 가져 각광받아왔다. 특히, (Al)GaN 에 기반한 자외선 영역 발광 다이오드는 자외선 경화, 소독 등의 여러 가지 응용 가능성을 가진다 [1]. 하지만, 심자외선 영역으로 갈수록 높은 접촉 저항과 투명전극에서의 광흡수에 의해 전류주입 효율과 광추출 효율이 감소하여 결국 외부양자 효율이 더욱 열화되는 특성을 보인다. 이는 넓은 밴드갭을 가지는 물질을 이용하여 p-(Al)GaN 층에서 오믹접촉을 이루어야만 해결이 가능하지만 아직까지 이러한 결과가 보고된 바 없다. 본 연구에서는, 우리는 넓은 밴드갭을 가지는 silicon dioxide (SiO2) 에 전기장을 인가하여 p-GaN, and p-AlGaN 층에 전도성 필라멘트를 형성하여 전기전도도를 부여하는 연구를 진행하였다. p-GaN 과 p-AlGaN 위에서 5 nm 두께의 SiO2는 schottky 한 특성과 280 nm의 파장대역에서 약 97%의 투과율을 보였다. 비록 schottky 장벽이 형성되었지만, 전기전도도가 크게 향상되었으며 심자외선 영역에서 매우 낮은 흡수율을 보였다. 이는 기존의 증착후 열처리를 거쳐 제조된 전극에 비하여 우수한 특성을 지니며 향후 심자외선 영역 발광다이오드의 p-(Al)GaN 층 위에 오믹접촉을 이룰수 있는 가능성을 제시한다.

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Topology Optimization of Plane Structures with Multiload Case using a Lower order Finite Element (저차 유한요소를 이용한 다하중 경우를 가지는 평면구조물의 위상최적화)

  • 이상진
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.16 no.1
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    • pp.59-68
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    • 2003
  • An optimization Program is developed to produce new topologies of plane structures under multiload case. A four-node finite element is used in the response analysis to reduce the computation time and to ultimately achieve practical topology optimization. The bilinear finite element is prone to produce chequer-boarding phenomenon and a simple filtering process is therefore adopted. An artificial material model is employed to represent the structural material and the resizing algorithm based on the optimality criteria is adopted to update the material density parameter during optimization process. With newly developed optimization program, the comparison study has been made between single and multiload cases and its results are described in this paper. From numerical results, it appears that multiload case should be considered to achieve the practical topology optimization.

Non-Pt transition metal electrode catalyst for Oxygen Reuction Reaction of Polymer Electrolyte Membrane Fuel Cell (고분자 전해질 연료전지의 산소환원반응을 위한 비백금계 전이금속 전극 촉매)

  • Kim, Jy-Yeon;Lee, Sang-Beom;Park, Kyung-Won
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.383-385
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    • 2009
  • 비백금계 코발트 전이금속 촉매를 탄소지지체에 담지한 뒤, 암모니아 분위기에서 $500^{\circ}C$에서 3시간 동안 열처리하는 과정을 통해 코발트 질화물 촉매를 제조했다. 제조된 촉매들의 구조와 형태를 각각 XRD, HE-TEM등을 통해 분석하였고, 전위 측정기를 이용한 CV, LSV 결과로부터 촉매의 전기화학적 산소 환원특성을 분석하여, 기존의 연료전지 양극 촉매로 사용되는 고가의 백금촉매를 대체하기 위한 비백금계로서의 가능성을 확인하였다.

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