• Korean Journal of Soil Science and Fertilizer
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• v.1 no.1
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• pp.61-71
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• 1968

1. In pot exreriments, the leaf blades of rice plants grown on Akiochi soil were weakened and the leaves dropped noticeably. This phenomenon could be prevented with application of silicate materials such as potassium silicate, Wallastonite and silicate slag (normally used silicate fertilizer in Korea). 2. Grain yield was increased by application of all the silicate materials. The effect of wollastonite was not lower than the effect of silicate slag. 3. Basal application of wollastonite gives a higher effect on the grain yield than top dressing. With higher wollastonite application, the nitrogen effect on the grain yield increases. This increase in nitrogen effect becomes more pronounced when the nitrogen level is higher. 4. Silica content in the plant waas increased by application of silicate materials to the soil. The increase in silica content in the plant was most noticeable with wollastonite. Basal application of wollastonite proved to be more effective than top dressing. Iron and nitrogen content in the plant decreased by application of the silicate materials. 5. The application of the silicate materials to Akiochi soil increases the resistance of rice to leaf blast, neck blast and Helminthosporium leaf spot. Among the silicate materials, wollastonite was most effective. 6. Damage by leaf blast increased proportionally with the nitrogen level, but decreased clearly with increase in wollastonite level. This phenomon was most pronounced for late transplanting time. 7. Damage by Helminthosporium leaf spot was also proportionally reduced by wollastonite application.

• Korean Journal of Soil Science and Fertilizer
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• v.20 no.2
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• pp.123-129
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• 1987

In order to find out more effective countermeasures against growth damage of paddy rice due to the irrigation of livestock waste water, pot experiments were carried out in 1985 and 1986. Experiment I conducted in 1985 was to find out the effects of irrigation control and application of ameliorators to paddy soil with irrigation of animal waste water. Experiment II conducted in 1986 was to find out the amounts of wollastonite to be applied. The results obtained were as follows. Experiment I ; Rice yields were higher in the treatment of continuously submersion until harvest than in that of intermittent irrigation. The yield was also increased with the application of soil ameliorators and it showed higher increase in the treatment of zeolite and wollastonite. Nitrogen contents in plant were increased with the nitrogen application and more amounts of irrigation of waste water, but they were considerably decreased with the application of soil ameliorators. Experiment II ; Rice yields were increased with the application of wollastonite and the optimum level of wollastonite for maximum yield in condition of 3.0 g/pot of nitrogen application was belived to be 60g/pot. The increment of yield by the application of wollastinte was though to be due to increase of No. of grains per panicle and ripening ratio. Steriled neck occurred by rice disease such as rice blast was increased with increasing the amounts of nitrogen application and nitrogen contained in irrigated waste water but that was remarkably decreased with the application of wollastonite.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2001.11a
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• pp.51-56
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• 2001

정유공장으로부터 발생으로 중잔사유를 이용하는 가스화 복합발전 플랜트에 대한 공정모사를 수행하였고, 공기분리장치의 연계공정 최적화를 통해 IGCC 플랜트이 효율을 극대화하였다. 가스화 복합사이클의 발전계통을 모델링하기 위해, 본 연구는 MS7001FA 가스터빈이 공기분리장치와 연계되어 있고, 공기분리장치를 위한 공기 추출과 공기분리장치로 부터의 질소회석이 이루어진다고 가정하였다. 가스터빈의 폐열은 삼중압력의 폐열회수 증기발생장치로부터 회수하였다. 정유공장 중잔사유는 Shell 가스화 및 Sulfinol-SCOT-Claus 공정을 거쳐, 합성가스 연료를 발생시키는 것으로 가정하였다. 공기분리 장치의 연계 공정 최적 결과는 가스화 복합사이클의 효율이, 질소 회석이 없는 경우와 있는 경우에 대해, 공기추출비 20% 또는 40-60%에서 가장 우수함을 보여주었다.

• Korean Journal of Soil Science and Fertilizer
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• v.19 no.4
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• pp.327-332
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• 1986

Laboratory experiments were conducted to estimate extractable nitrogen by buffer phosphate solution of pH 7. A series of experiment soils were a) Sandy soil applied with compost, lime, and Wallastonite every years for 32 years. b) Sandy soils with and without waterlogging for 70 days before transplanting. c) Normal soils produced high and common yields. The results were summarized as follows: 1. Extractable organic nitrogen by pH 7 phosphate buffer solution was increased in order of NPK + compost > NPK > NPK + compost + lime + Wollast-onite > NPK + compost + lime > NPK + wollastonite > no fertilizer plot. 2. Extractable organic nitrogens at plots of NPK and NPK + compost were decreased as the growth stage processed regardless of tretments. 3. In case of normal soils having high and common yields the content of total N, organic matter and $NH_4-N$ were increased in high productive soil, while, only $NO_3-N$ content was increased in common productive soil. Especially, there was a highly positive correlation between extractable total nitrogen and $NH_4-N$ content submerged for 4 weeks under incubated condition. 4. Organic nitrogen content of soil was increased on the condition of non-waterlogging, however, nitrogen uptake by rice plant was increased in waterlogged paddy. 5. The content of extractable total nitrogen increased in the order of normal soil, sandy soil, unmatured soil, saline soil, and estimation of optimum nitrogen rates by extracted organic nitrogen was in order of saline soil, unmatured soil, sandy soil, normal soil.

• Journal of the Korean Society of Marine Environment & Safety
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• v.22 no.7
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• pp.829-835
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• 2016

An excess in the nutrients such as nitrogen and phosphate leads to a phenomenon called eutrophication. In order to avoid this, numerous methods have been used to remove excess nutrients in the water. In this study, the use of a chemical method was assessed through the formation of magnesium ammonium phosphate. The difference in the removal efficiency of seawater and sea salt solution as primary sources of $Mg^{2+}$ ions and $Ca^{2+}$ ions for the formation of magnesium ammonium phosphate (MAP) and hydroxyapatite (HAP) respectively, were observed, taking into account the changes in pH and concentration. The results showed that seawater removed about 90 % phosphate and less than 50 % ammonia in sewage water condition, whereas the sea salt solution removed almost 90 % phosphate and 70 % ammonia in solution at pH 9 and 10 mM concentration of sea salt which further increases as the optimum ${Mg/PO_4}^{3-}$, ${NH_4}^+$ ratio reaches 2. The difference in the removal efficiency of seawater and sea salt was due to the fact that the set-ups were prepared in different conditions. This study suggests that both seawater and sea salt can be used to remove nutrients from the water. The relatively higher removal of phosphate can be explained by the formation of HAP from free $Ca^{2+}$ ions initially present in seawater and sea salt solution.

• Korean Journal of Environmental Agriculture
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• v.1 no.2
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• pp.116-122
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• 1982

Investigation on the water quality of Hwangguji River and experiment on the effects of nitrogen and soil improvements were carried out in the paddy field irrigated with polluted water of the river. The obtained results are as follows: 1) Amount of COD and $NH_4-N$ in water of the river were 54 ppm, 65 ppm, during the seeding time, and were 52 ppm, 512 ppm during the transplanting time respectively. Their concentrations were over the standard levels. It seemed that the water pollution was mainly caused by organic waste matters. 2) It seemed that the effective nitrogen level was $7{\sim}8$kg/10a in the paddy field irrigated with polluted water of the river. 3) The rice yields of potassium twice quantity application plot with N.P.K. fertilizer, the calcium application plot with N.P.K. fertilizer and the combined plot with potassium, wallarstonite, calcium and fresh straw, were increased 4, 5 and 8%, respectively, than that of the N.P.K. fertilizer standard level plot.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.26 no.4
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• pp.279-286
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• 1981

This study was conducted to find out the effect of wollastonite application in degraded saline soil condition on the growth of japonica rice variety. The variety, Palgweng was tested with 4 levels of wollastonite (200, 400, 600 and 400/200 kg/l0a) and two nitrogen levels (12 and 16 kg/l0a). The effect of wollastonite was higher in 16 than 12 kg of nitrogen application. The wollastonite application reduced rice leaf blast and dead left at lower nodal position, and increased percentage of effective tillers, percentage of ripened grains and 1, 000 grain weight. The SiO$_2$ content of upper leaf was higher than lower leaf in 200 kg of wollastonite application, but there was no difference under high wollastonite application (400 kg/l0a). Highly significant positive correlationships were obtained between SiO_2 content of plant at heading and percentage of ripened grains, (r=0.613) and SiO_2 content of flag leaf and percentage of ripened grains (r=0.407). Wollastonite application did not affect the development and degeneration of primary and secondary rachis branches of panicles, but it increased the number of spikelets. The highest grain yield was obtained with 16 kg of nitrogen and 600 kg of wollastonite.

• Korean Journal of Soil Science and Fertilizer
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• v.8 no.2
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• pp.61-68
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• 1975

A laboratory study was conducted to determine the effect of nitrogen mineralization in accordance with addition of calcium silicate and wollastonite on the fresh soil condition. Results are summarized as follows. 1. Nitrogen mineralization due to application of silica materials was rapidly occured in Saweon sand soil than in Honam clay soil. Also wollastonite application more stimulated the nitrogen mineralization than calcium silicate. 2. Silica material application enhanced loss of applied nitrogen by denitrification due to accelerate the nitrification in Suweon sand soil. This tendency was more severe in calcium silicate applicated treatment than in wallasnonite applicated. 3. From these results, nitrogen should be applicated with organic matter to improve the supply of nitrogen nutrient to plant when silica materials were applied.

• Korean Journal of Soil Science and Fertilizer
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• v.3 no.1
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• pp.1-10
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• 1970

A pot experiment of paddy rice was carried out primarily to find out the effect of potash in relation to the application of wollastonite on paddy rice. The result which showed increased paddy rice yield has been evaluated from the factors of yield, yield components, soil and plant analysis data at different stages of plant growth and the summary of review is described as follows : 1. Effect of potash is likely to be greater in the presence of wollastonite and a larger quantity of wollastonite application would require correspondingly larger quantities of potash. 2. Application of potash and wollastonite resulted increased paddy rice yield may be largely due to increased contents of potassium, calcium and silica in the soil and increased concentration of $K_2O$, CaO and $SiO_2$, $SiO_2/N$ ratio and $K_2O/N$ ratio in rice straw. 3. The maximum paddy rice yield, at less than 300kg/10a application of wollastonite was obtained by applying 8kg of $K_2O$ per 10 are while 600kg/10a application of wollastonite gave the maximum yield by applying 16kg of $K_2O$ application per 10 are. 4. Application of wollastonite decreased the number of ears per hill and number of grains per ear. While ripening percentage and 1,000 grain weight tended to increase with wollastonite. The increased contents of CaO and $SiO_2$ in straw due to wollastonite application showed a negative correlation with the number of ears per hill and the number of grains per ear but a positive correlation was shown with ripening percentage and 1,000 grains weight. 5. Potash application appeared to be increasing the number of ears per hill and the number of grains per ear. There was a positive correlation exist between the higher content of $K_2O$ in rice straw and the number of grains per ear 6. Amount of nitrogen absorbed tended to decrease with increase in quantities of potash and wollastonite but the ratio of $SiO_2/N$ was increased by further application of potash and wollastonite. 7. $K_2O/N$ ratio was increased with incrementing in quantities of potash application but in the absence of potash, $K_2O/N$ ratio was decreased as to increasing wollastonite application.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 1997.10a
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• pp.52-53
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• 1997

수역의 유기오염 개선을 위하여 생활하수, 산업폐수 등의 저하시키는데 주안점을 두어왔으나 공공수역에서의 제거되지 않은 질소와 인의 유입으로 부영양화가 진행되어 하천에는 남조류가 대량발생하고 해역에는 적조가 광역에서 발생하여 큰 사회문제가 되고 있고, 질소와 인의 유입으로 인한 자생 COD가 전체COD의 약 절반을 차지하고 있는 실정이다. 따라서 앞으로의 수질을 개선하기 위해서는 조류증식의 제한인자인 질소와 인의 규제가 필요할 뿐만아니라 하수처리장에 고차처리를 적용하거나, 해양의 회석자용을 이용한 Ocean을 적용하여 연안해역 수질을 관리해야 할 것이다. 따라서 본 연구는 수영만을 대상으로 Ocean Outfall과 폐수처리시절을 적절하게 조합하기 위해서 3차원 생태계모델을 적용하여 유기물질 뿐만 아니라 영양염류인 질소와 인의 농도를 예측하여 환경기준을 만족시키고 비용을 최소화 할 수 있는 폐수처리공법과 해중방류관의 위치를 선정하고자 하였다. 본 연구결과 수영만의 1994년 COD는 II등급, DIN과 DIP는 III등급이었다. 현재의 활성슬러지공법으로 질소와 인을 제거하지 않고 방류할 경우 2001년에 는 하수처리량의 증가로 인해 COD의 경우 1994년 보다 조금 감소하지만 DIN 과 DIP는 1994년과 같은 III등급을 유지하였다. 고도처리공법을 도입할 경우 COD의 농도는 광안리와 해운대해수욕장에서 I등급을 보이고, DIP의 농도도 수영만 전체에서 강등급을 보이지만, DM의 농도는 광안리해수욕장에서 II등급, 해운대해수욕장에서 IH등급을 보였다 하수처리장 유출수를 Ocean Outfall을 이용하여 하수처리장으로부터 4km에 서 방류할 경우의 COD농도는 I등급을 보이고, DE 농도도 광안리와 해운대해 수욕장에서는 I등급을 보이고, DU의 농도는 ll등급을 보여 수질이 개선된 것 을 볼 수 있다. 이상에서와 같이 광안리와 해운대해수욕장의 해역환경기준 ll등급을 만족 하는 하수처리방법은 Ocean Outfall이었다. 수영하수처리장에 인을 처리하기 위한 화학적 침전법의 경우 956억원이 소요되고, 질소를 제거하기 위한 질소제거공정을 추가 건설 할 경우는 2181억원이 전요된다. 그리고 두공정을 같이 건설할 경우에는 3137억원의 비용이 소요된다 수영하수처리장에서 4km 거리와 관경을 2m의 Ocean Outfall 건설비용은 325 억원 정도가 소요되는 것으로 산출되었다. 고차처리시 증가되는 비용으로 건설할 수 있는 Ocean Outfall의 길이는 인 제거공정을 첨가하는 경우에는 18km을 건설할 수 있고, 질소제거공정을 첨가 하는 경우에는 46km를 건설할 수 있는 것으로 산출되었다.