• Title/Summary/Keyword: 질소 거동

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Characteristics of Autoignited Laminar Lifted Flames in Heated Coflow Jets of Carbon Monoxide/Hydrogen Mixtures (일산화탄소/수소 혼합기의 가열된 동축류 제트에서 자발화된 층류 부상화염의 특성)

  • Choi, Byung-Chul;Chung, Suk-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.6
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    • pp.639-646
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    • 2012
  • The characteristics of autoignited lifted flames in laminar jets of carbon monoxide/hydrogen fuels have been investigated experimentally in heated coflow air. In result, as the jet velocity increased, the blowoff was directly occurred from the nozzle-attached flame without experiencing a stabilized lifted flame, in the non-autoignited regime. In the autoignited regime, the autoignited lifted flame of carbon monoxide diluted by nitrogen was affected by the water vapor content in the compressed air oxidizer, as evidenced by the variation of the ignition delay time estimated by numerical calculation. In particular, in the autoignition regime at low temperatures with added hydrogen, the liftoff height of the autoignited lifted flames decreased and then increased as the jet velocity increased. Based on the mechanism in which the autoignited laminar lifted flame is stabilized by ignition delay time, the liftoff height can be influenced not only by the heat loss, but also by the preferential diffusion between momentum and mass diffusion in fuel jets during the autoignition process.

A study on the thermal oxidation process of bulk AlN single crystal grown by PVT (PVT 법으로 성장 된 bulk AlN 단결정의 열 산화 공정에 관한 연구)

  • Kang, Hyo Sang;Kang, Seung Min
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.5
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    • pp.168-173
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    • 2020
  • To analyze and describe the behavior and mechanisms occurring in the thermal oxidation process of AlN, bulk AlN single crystals were thermally treated with different temperatures. As a result, it was confirmed that full-scale oxidation of bulk AlN and growth of Al-oxide occurred from the temperature of 800℃, which confirmed that the weight% of O elements tended to increase while the N elements decreased with increasing the temperature. In the case of thermal treatment at 900℃, the grown Al-oxides were merged with neighboring Al-oxides and began to form α-Al2O3 poly-crystals. During thermal treatment at the temperature of 1000℃, hexagonal pyramidal shaped poly-crystalline α-Al2O3 was clearly observed. Through the X-ray diffraction pattern analysis, the changes of surface crystal structure according to the temperature of bulk AlN were investigated in detail.

Edge-flame Instability in A Low Strain-rate Counterflow Diffusion Flame (저신장율 대향류확산화염에서 에지화염 진동불안정성)

  • Park, June-Sung;Kim, Hyun-Pyo;Park, Jeong;Kim, Song-Cho;Kim, Jeong-Soo
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.11a
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    • pp.295-298
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    • 2006
  • Experiments in methane-air low strain rate counterflow diffusion flames diluted with nitrogen have been conducted to study the behavior of flame extinction and edge flame oscillation in which lateral conduction heat loss in addition to radiative heat loss could be remarkable at low global strain rates. Onset conditions of edge flame oscillation and flame oscillation modes are also provided with global strain rate. It is seen that flame length is closely relevant to lateral heat loss, and this affects flame extinction and edge flame oscillation. Edge flame oscillations in low strain rate flames are categorized into three: a growing oscillation mode, a decaying oscillation mode, and a harmonic oscillation mode. The regime of flame oscillation is also provided at low strain rate flames.

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A Study on the Behaviour of Organics and Nitrogen Using Upflow Anaerobic Reactor When Acid Fermenter is Added (상향류식 혐기성반응조와 산발효조의 병합처리시 유기물질과 질소거동에 관한 연구)

  • Oh, Dae-Min;Lee, Young-Shin
    • Journal of Environmental Science International
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    • v.18 no.3
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    • pp.325-331
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    • 2009
  • This study was aimed to behaviour of organics and nitrogen on the upflow anaerobic reactor when a acid fermenter is added. Up flow anaerobic reactor (UAR) reaction will result which operates, COD removal efficiencies of reactor with nitrate loading rate 0.11, 0.66g/L/d were over 77%, but one with 1.0g/L/d was 73.5%. Especially, on NLR 0.11g/L/d, COD removal was 77% and nitrate removal efficiency was 93% simultaneously. The other side upflow anaerobic reactor and acid fermenter (UAR+AF) reaction will result witch operates, COD removal efficiencies of reactor with nitrate loading rate 0.11, 0.66g/L/d were over 85%, but one with 1.0g/L/d was 80%. Especially, on NLR 0.11g/L/d, COD removal was 85% and nitrate removal efficiency was 98% simultaneously. Also, without in reaction condition increase of influent nitrate concentration resulted in the linear decrease of nitrate removal efficiency and nitrate removal efficiency at influent nitrate-nitrogen 800mg/L was 50%. Alkalinity was increased theoretically by denitrification at low nitrate-N concentration, however, it was not increased theoretically at high nitrate-No 40% nitrate-N of UAR was denitrified until 70% height of reactor and 90% nitrate-N of UAR+AF was denitrified until 30% height of reactor Upflow anaerobic reactor was to occur accumulate acid, which TVA/Alkalinity is 0.3$\sim$0.47. Increase of NLR resulted increase of effluent alkalinity and TVA production

Creep Behavior Analysis of 25Cr-20Ni Stainless Steels With Omega Methods (오스테나이트계 25Cr-20Ni 스테인리스강의 $\Omega$ 법을 이용한 고온 크리프 거동 해석)

  • Park, In-Duck;Nam, Ki- Woo
    • Proceedings of the KSME Conference
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    • 2001.11a
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    • pp.117-122
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    • 2001
  • For two kinds of 25Cr-20Ni stainless steels, SUS310J1TB TB and SUS310S with and without a small amount of Nb and N, creep behavior has been studied in a stress and temperature range from 147 to 392MPa and from 923 to 973K with a special reference to tertiary creep. The average creep life of SUS310J1TB was about 100 times longer than that of the SUS310S. The apparent activation energy for the initial creep rate was 330 kJ/mol in SUS310J1TB, while that of the SUS310S was 274 kJ/mol in a power law creep region and 478 kJ/mol in a region of power law breakdown (PLB). The activation energy for SUS310S below PLB is close to the that for self-diffusion. When compensating for the temperature dependence of the Young's modulus and the omega value, it was found that the apparent activation energy for SUS310J1TB was reduced to the activation energy for diffusion of chromium atom in a gamma steel. The stress exponent of SUS310S was about 12 above PLB and 5.1 in a power law creep region. Notwithstanding that the creep condition for SUS310J1TB was in a power law creep region, its stress exponent was 8.3 larger than that of SUS310S corresponding to the same creep conditions. This was ascribed to the presence of fine precipitates in SUS310J1TB.

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Cure Shrinkage Behavior of Polymer Matrix Composite according to Degree of Cure (경화도에 따른 고분자 기지 복합재의 경화 수축률 거동)

  • Kwon, Hyuk;Hwang, Seong-Soon;Choi, Won-Jong;Lee, Jae-Hwan;Kim, Jae-Hak
    • Composites Research
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    • v.27 no.3
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    • pp.90-95
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    • 2014
  • Cure shrinkage during cure process of polymer matrix composites develope residual stress that cause some structural deformation, such as spring-in, spring-out and warpage. The carbon/epoxy prepreg used in this study is Hexply M21EV/34%/UD268NFS/IMA-12K supplied by Hexcel corp. Cure shrinkage and degree of cure measured by TMA(thermomechanical analyzer) and DSC(differential scanning calorimetry). Cure shrinkages are measured by TMA within a temperature range of $140{\sim}240^{\circ}C$ in a nitrogen atmosphere, and degree of cure determined by the heat of reaction using dynamic and isothermal DSC runs in argon atmosphere. As a result, the cure shrinkage is increased dramatically in a degree of cure range between 27~80%. the higher the cure temperature, the lower the degree of cure occurring to begin cure shrinkage.

Investigation of Bubble Behavior in Rectangular Microchannels for Different Aspect Ratios (다른 세장비의 사각 마이크로채널 내의 기포 거동에 관한 연구)

  • Choi, Chi-Woong;Yu, Dong-In;Kim, Moo-Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.5
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    • pp.471-479
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    • 2010
  • The adiabatic two-phase flow in single rectangular microchannels was studied for different aspect ratios. The working fluids were liquid water and nitrogen gas. The hydraulic diameters of the rectangular microchannels were 490, 322, and $143\;{\mu}m$, and the widths of the microchannels were around $500\;{\mu}m$. The two-phase flow pattern was visualized using a high-speed camera and a long-distance microscope. This study was focused on bubble flow regimes. From the visualized images, the bubble velocity, bubble length, number of bubbles, and void fraction were evaluated. Further, the pressure drop in a single bubble was evaluated by using a unit cell model. The bubble velocity is proportional to the superficial velocity. Further, the relationship between the void fraction and the volumetric quality is linear. The pressure drop in a single elongated bubble is strongly related to the aspect ratio. Finally, the new correlation about the pressure drop of a single elongated bubble in the rectangular microchannel was proposed.

Characterization of Algal-Bacterial Ecological Interaction and Nutrients Removal Under Municipal Wastewater Condition (실제 하수조건에서 조류-세균 복합군집의 생태적 상호작용 및 영양염류 제거 특성 규명)

  • Lee, Jang-Ho;Park, Joon-Hong
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.5
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    • pp.314-324
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    • 2011
  • Algal biomass cultivated by wastewater is potentially useful resource for biodiesel production. However, little is known about algal nutrient metabolism and microbial interaction with bacteria under real municipal wastewater condition. In this work, we characterized nitrogen and phosphorus removals of municipal wastewater by a representative wastewater-growing algal population. Ankistrodesmus gracilis SAG 278-2, and analyzed its ecological interaction with wastewater bacterial communities. Compared to wastewater sludge itself, algal-bacterial co-culture improved nutrient removal. According to bacterial community analysis with 16S rRNA genes, a selective and dominant growth of a Unclassified Alcaligenaceae population resulted from algal growth in the algal-bacterial co-culture. The selectively stimulated bacterial population is phylogenetically close to Alcaligenes faecalis subsp. 5659-H, which is known to be co-present interact with algae in aquatic environment. These findings suggest that algal growth/metabolism may have effects on selection of a specific bacterial population in algal-bacterial co-cultures that can efficiently remove nutrients from municipal wastewater.

The Nitrogen Behavior and Budget in Lake Paldang (팔당호의 질소거동과 수지)

  • Lee, Jangho;Park, Hae-Kyung;Lee, Kyoo;Kim, Eunmi
    • Journal of Korean Society on Water Environment
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    • v.26 no.1
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    • pp.71-80
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    • 2010
  • We studied the nitrogen behavior and budget of Lake Paldang from March to December 2008. The particulate nitrogen (PN) concentrations ranged from 7 to 13% of the total nitrogen concentration (TN) in the stream inflows, the downstream outflow, and the lake water. The nitrate nitrogen ($NO_3-N$) concentration ranged from 67 to 78% of the TN. In the three rivers of Lake Paldang, Gyeongan River (In3 site) had the highest average of the TN, 5.037 mgN/L, but North Han River (In2 site) had the lowest average TN, 1.683 mgN/L. South Han River (In1 site) had the average TN of 2.399 mgN/L. In the dam discharge, TN showed the average 2.063 mgN/L. In the lake water, L4 site (Gyeongan River area) had the highest average TN, 3.781 mgN/L, but L3 site (North Han River) had the lowest average TN, 1.587 mgN/L. Total input of nitrogen loads to Lake Paldang was about 30,875 ton/year in 2008. Inflow rivers contributed 30,643 ton/year (South Han River: 18,111 ton/year (59%), North Han River: 11,333 ton/year (37%), and Gyeongan River: 1,199 ton/year (4%)). The atmospheric deposition had 135 ton/year, the nitrogen release from the bottom sediments had 88 ton/year, and macrophytes had 9 ton/year. Total output of nitrogen loads from Lake Paldang was about 31,256 ton/year. The downstream from dam contributed 29,877 ton/year, and the sediment deposition was 1,379 ton/year.

Formation behaviour of Bromate in Processes of Advanced Water Treatment System using Nakdong river water (고도정수처리 공정에서 브로메이트의 거동 평가)

  • Kim, Young-Jin;Hyun, Kil-Soo
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.4
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    • pp.605-610
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    • 2011
  • The objectives of this study are to investigate a bromate behaviour in the processes of advanced water treatment system (AWTS: preozonation, coagulator-settler, rapid sand filter, postozonation, biological activated carbon (BAC) beds) and to investigate the effects of ozonation, pH and ammonia nitrogen on bromate (${BrO^-}_3$) formation. As a result, $BrO_3$ was not detected in the processes of the AWTS without ozonation, while it was detected in a preozonated and postozonated water. For $BrO_3$ formation during June to November, the $BrO_3$ concentration of <9.4${\mu}g/L$ was observed in postozonated water, while it was reduced to about 46% by BAC beds. When applied ozone dosage and ozone contact time for influent with $Br^-$ of <0.3mg/L were 0.5-2.0mg/L.min and 10 min., $BrO_3$ concentration increased with increasing ozone dosage. Longer contact time and lower ozone level also was needed to inhibit the formation of $BrO_3$. At ozone dosage of 1.4 mg/L.min, the formation rate of $BrO_3$ increased with increase of pH value. When $NH_4-N$ concentration increased from 0.1mg/L to 0.4mg/L, $BrO_3$ concentration decreased to about 38%. These results revealed that $BrO_3$ concentration increased with increasing Br level, ozone dosage, and pH value, while it decreased with increase of $NH_4-N$ concentration.