• Title/Summary/Keyword: 질소처리

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Comparison of efficiency in Mainstream ANAMMOX process for ratio of ammonium to nitrite (암모니아성 질소 대비 아질산성 질소 비율에 따른 Mainstream A NAMMOX 공정 효율 비교)

  • Gil, Kyung Ik;Lee, Da Won;Lee, Ji Won
    • Proceedings of the Korea Water Resources Association Conference
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    • 2021.06a
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    • pp.421-421
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    • 2021
  • 도시화, 산업화로 인해 하수처리장 유입하수 내 질소 농도가 증가하면서 그에 따른 부영양화 발생, 수생태계에 독성을 미치는 등의 악영향 또한 증가하게 되었다. 하수 내 고농도 질소를 처리하기 위해 1990년 초 연구가 시작되어 현재 보편적으로 사용되고 있는 생물학적 질소 제거 공정은 산소공급과 외부탄소원 보충 과정에서 상당한 비용이 소요된다. 이와 같은 문제점이 대두됨에 따라 고도의 질소 제거 공정이 요구되면서, 경제적으로 개선이 이루어져 기존의 질산화·탈질 공정보다 효율적인 혐기성 암모늄 산화 공정(ANaerobic AMMonium OXidation, ANAMMOX)이 제안되었다. ANAMMOX 공정은 혐기성 조건 아래 전자공여체와 전자수용체로써 암모니아성 질소와 아질산성 질소를 이용해 질소가스 형태로 질소를 제거하는 공정이다. 질산화·탈질 공정과 비교했을 때, 폭기과정에서의 산소요구량 감소, 외부탄소원 불필요, 질소 제거 과정 단축 등의 장점을 가진다. 본 연구는 수처리공정에서의 ANAMMOX 공정의 적용 가능성을 확인하고, 암모니아성 질소대비 아질산성 질소 비율에 따른 Mainstream ANAMMOX 공정의 효율 비교를 통해 공정의 안정성과 높은 제거효율을 확보할 수 있는 NH4+ 대비 NO2- 비율을 도출하는데 목적이 있다. 실험실 규모의 Mainstream ANAMMOX 반응조에 적용한 비율은 선행연구를 비롯한 화학양론식에서 제시된 비율을 바탕으로 산정하였다. 1.00부터 1.30의 전체적인 비율을 Initial과 Advanced 2개의 구간으로 나누어 운전한 결과, 각 구간의 NH4+ 제거효율은 각각 58~86%, 94~99%였다. NH4+ 대비 NO2- 비율이 증가함에 따라 공정의 안정성이 확보되고, NH4+ 및 총질소(TN) 제거효율이 증가하는 경향이 나타났다. 본 연구의 결과는 수처리공정에서의 안정적인 ANAMMOX 공정 적용을 유도하고, ANAMMOX 공정의 성능개선을 도모하는 연구의 기초로 활용될 수 있다.

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Effect of Mixed Liquid Fertilization on Growth Responses of Cherry Tomatoes and Soil Chemical Properties (생초미생물혼합액비의 시용이 방울토마토의 생육반응과 토양화학성에 미치는 영향)

  • Park, Ji-Suk;Lee, Min-Jin;Lee, Seo-Youn;Kim, Jong-Sung;Lee, Tae-Kyu;Ro, Hee-Myong;Kim, Sang-Jun;Jeon, Seung-Woo;Seo, Sang-Gug;Kim, Kil-Yong;Lee, Geon-Hyoung;Jeong, Byung-Gon
    • Horticultural Science & Technology
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    • v.33 no.2
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    • pp.268-275
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    • 2015
  • We evaluated the effect of mixed liquid fertilizer (MLF) on growth responses of plants and soil chemical properties. To do so, a pot experiment with cherry tomatoes (Lycopersicon esculentum var. cerasiforme) using loam soil was conducted for 81 days in a temperature-controlled glasshouse, and four N fertilization treatments were laid out in a completely randomized design with three replicates: control (C), chemical fertilizer treatment (CF), and two rates (MLF-0.5 and MLF-1.0) of MLF treatment. Soils were periodically sampled and analyzed for pH, EC, total N, inorganic N and total C, and growth characteristics of cherry tomatoes were measured. During the experimental periods, the pH of MLF soils was higher than that of CF soils. Soil total-N content increased right after CF-application and ultimately decreased to the level of the control (C) soil, while MLF-application slightly increased the level of soil total-N and this level remained unchanged throughout the experiment. The levels of soil inorganic N content increased after application of CF or MLF, but the initial increase disappeared in 56 days after transplanting (DAT). The dry weight of shoots and roots increased in CF or MLF plants, while the number of fruit increased only in MLF plants. Whereas soluble solid contents were higher in MLF plants than in the other (C and CF) plants, the titratable acidity was not different among treatments. However, no consistent effect of N treatments on major elements of the organs of cherry tomatoes was found. The amounts of N taken up by plants were 0.91 g for CF, 0.61 g for MLF-1.0, 0.43 g for MLF-0.5, and 0.25 g for control treatments, resulting in greater N efficiency for CF than for MLF.

Effect of Calcium Cyanamide on Control of Clubroot of Chinese Cabbage Caused by Plasmodiophora brassicae (석회질소에 의한 배추뿌리혹병 방제효과)

  • Kim, Jeom-Soon;Lee, Jeong-Tae;Lee, Gye-Jun
    • Research in Plant Disease
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    • v.12 no.3
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    • pp.278-283
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    • 2006
  • The effect of calcium cyanamide($CaCN_2$) on suppression of clubroot of Chinese cabbage was evaluated in the fields infested with Plasmodiophora brassicae at National Institute of Highland Agriculture, Pyeongchang, Korea, from 2002 to 2003. Calcium cyanamide was found to be more effective in reducing disease severity than flusulfamide dust powder. The optimal dosage of calcium cyanamide for control of clubroot of Chinese cabbage was 61 kg/10a. When calcium cyanamide was incorporated into soil at 5, 10, 15 and 20 days before planting(DBP), maximum disease suppression was obtained in the plot with calcium cyanamide, applied 5DBP. The fertilizer property of calcium cyanamide as a nitrogen fertilizer was also investigated by comparing with urea on cv. CR Gangta, a resistant variety of Chinese cabbage. The nitrogen uptake in calcium cyanamide treatment(17.6 kg/10a), was not significantly different from that of urea(17.8 kg/10a). These results indicated that calcium cyanamide could be used as a soil disinfectant as well as a nitrogen fertilizer.

수학적 모델로 이용한 질소$\cdot$인 처리 공정 설계

  • 안세영
    • Environmental engineer
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    • v.18 s.193
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    • pp.28-32
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    • 2002
  • $\cdot$폐수처리시설의 설계에서 컴퓨터 모델링을 사용하는 목적은 처리공정을 최적화 하기 위함이다. 기존의 하$\cdot$폐수처리장을 생물학적 질소$\cdot$인 제거 (이하 BNR) 시설로 개조하거나 신설 BNR 공정을 설계하려면 계획 시설에 대한 타당성 조사를 수행해야 하는데, 여러가지 처리공법을 분석하여 처리공정을 선정하고 선정된 공정의 성능과 운영방법, 그리고 시설비용 및 운영비용을

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Growth Responses of Various Ornamental Foliage Plants According to the Amount of Nitrogen Application (질소처리에 따른 여러 관엽식물의 생육반응)

  • Shim, Myung Syun;Kil, Mi Jung
    • Journal of Bio-Environment Control
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    • v.21 no.4
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    • pp.485-490
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    • 2012
  • This study was carried out to investigate the plant growth of various foliage plants affected by the amount of nitrogen application. There was not an accurate criterion for fertilization to each foliage plant. Moreover, the foliage plants grow slowly during the early stage and this period must be shortened for commercial production. Ficus benjamina, Hedera helix, Philodendron tatei, Rhapis excelsa, and Spathiphyllum spp. were used in this experiment. Nutrient nitrogen concentrations were 120, 150, 180, and $210mg{\cdot}L^{-1}$ (N1, N2, N3, N4) and they were based on the Sonneveld solution. Plant height and width, leaf number, leaf area, fresh and dry weights of shoots were measured for 8 weeks to compare the responses to the different treatments. The nitrogen contents of various plant parts were also analyzed. The growth of Ficus and Hedera was improved at the N1 treatment and that of Philodendron, Rhapis and Spathiphyllum at N4 treatment. The required amounts for nitrogen nutrients were different among the various foliage plants. The nitrogen treatments had no effects on SPAD values and there were no correlations between nitrogen treatments and nitrogen contents of plant parts. Therefore, the various foliage plants should supply with each proper nitrogen treatments to grow faster with better quality. In this case, the plant growth played a more important role than nitrogen levels of plant parts in deciding the proper nitrogen levels for each foliage plant.

A Study on the Optimum Operating Conditions and Effects of Wastewater Characteristics in Electrochemical Nitrogen Removal Process (질소 제거를 위한 전기화학적 처리 공정의 최적 운전조건 및 폐수 성상에 따른 영향에 관한 연구)

  • Sim, Joo-Hyun;Kang, Se-Han;Seo, Hyung-Joon;Song, Su-Sung
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.1
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    • pp.29-34
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    • 2009
  • This study was performed under four operational conditions for nitrogen removal in metal finishing wastewater. The conditions include electrode gap, reducing agent, the recycling of treated wastewater in 1st step and the simultaneous treatment of nitrate and other materials. Result showed that the removal efficiency of $NO_3{^-}-N$ was highest at the electrode gap of 10 mm. As the electrode gap was shorter than 10 mm, the removal efficiency of $NO_3{^-}-N$ decreased due to increasing in concentration polarization on electrode. And, in case that the electrode gap was longer than 10 mm, the removal efficiency of $NO_3{^-}-N$ increased with an increase in energy consumption. Because hydrogen ions are consumed when nitrate is reduced, reducing reaction of nitrate was effected more in acid solution. As 1.2 excess amount of zinc was injected, the removal efficiency of $NO_3{^-}-N$ increased due to increasing in amount of reaction with nitrate. As the effluent from 1st step in the reactor was recycled into the 1st step, the removal efficiency of $NO_3{^-}-N$ increased. Because the zinc were detached from the cathode and concentration-polarization was decreased due to formation of turbulence in the reactor. The presence of $NH_4{^+}-N$ did not affect the removal efficiency of $NO_3{^-}-N$ but the addition of heavy metal decreased the removal efficiency of $NO_3{^-}-N$. As chlorine is enough in wastewater, the simultaneous treatment of nitrate and ammonia nitrogen may be possible. The problem that heavy metal decrease the removal efficiency of $NO_3{^-}-N$ may be solved by increasing current density or using front step of electrochemical process for heavy metal removal.

Effects of Nitrogen Application on the Patterns of Amino Acids, Nitrogen Contents and Growth Response of Four Legume Plants under Saline Conditions (염분 환경하에서 4종 콩과식물의 생장, 아미노산 및 질소함량에 미치는 질소원의 영향)

  • 배정진;추연식;김진아;노광수;송종석;송승달
    • The Korean Journal of Ecology
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    • v.26 no.3
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    • pp.135-142
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    • 2003
  • Four legume plants showed better growth by the external nitrogen supply rather than the symbiotic nitrogen fixation only under salt additions. In case of Glycine max and Phaseolus angularis, total nitrogen contents decreased by high salinity level but their amino acid levels significantly increased with the increase of salt treatments and indicated high soluble-/insoluble-N ratios. Cassia tora and Albizzia julibrissin contained less amino acids than G. max and P. angularis but total N (esp. insoluble N fraction) increased with higher salt levels. Asparagine occurred as a main amino acid especially in G. max and P. angularis and can be seen as potential N-storage form in these plants. It might be play an important role for the osmoregulation mechanism under the saline condition. Meanwhile, to investigate what kinds of nitrogen sources are effective for overcoming salt stress on soybean plants, various N forms and concentrations (NH₄NO₃-N, NO₃-N, NH₄NO₃-N; 2.5 and 5 mM) were additionally supplied to the salt gradient medium. Soybean plants treated with NH₄NO₃-N showed the best growth up to 40 mM NaCl and NO₃- fed plants indicated good growth even at 80 mM NaCl treatments. Contrary to NH₄NO₃- and NO₃- fed plants, NH₄/sup +/- fed plants showed remarkable growth reduction and died by 40 and 80 mM NaCl treatments after the first harvest (15th day). Consequently, these results suggest that salt excluding and resistant capacities of soybean plants under NaCl treatments are increased in order of NH₄ - N, control, NO₃- N and NH₄NO₃- N depending on N concentration except NH₄- N treatments.

The Effect of Nitrogen Rates on The Growth and Yield of Maize in Agricultural Fields with the Stream (하천변 농경지에서 질소 시비량 차이가 옥수수 생육 및 수량에 미치는 영향)

  • Lim, Jung Taek;Chang, Jae-Hyuk;Rho, Ye-Jin;Ryu, Jin-Hee;Chung, Dong Young;Cho, Jin-Woong
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.59 no.1
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    • pp.101-108
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    • 2014
  • This study was conducted to investigate the effect of nitrogen rates on the growth characteristics and yield of maize in agricultural fields with the stream. This indicates the necessity and optimal level of nitrous fertilization to examine the possibilities of quantity enhancement. Plant height and ear height of maize were not significantly different among the nitrogen rates. Stem diameter and leaf area index increased in the nitrogen treatment compared to untreated control. Changes of photosynthetic rate in maize leaves depending on nitrogen treatments increased as much as nitrogen rates were increased up to the highest level, 36 kg per 10a. NDF and ADF content levels of maize were investigated with different nitrogen rates regardless of treatments. In the case of NDF, it showed a tendency to decrease after 8 days of tasseling date. ADF had also decreased after 15 days of tasseling date. Nitrogen uptake of maize leaves with different nitrogen rates showed the highest level, $4.9g\;kg^{-1}$ with 36 kg per 10a on the tasseling date. Ear length and 100-kernel weight, there were no significant differences according to yield and the components with different nitrogen rates. Ear diameter and kernel number, nitrogen rates of 18 kg and 36 kg were increased compared to nitrogen rate of 9 kg per 10a and untreated control. The pericarps in 9 kg nitrogen rate and control were thicker than those of 18 kg and 36 kg treatment. The yield, 18 kg, 36 kg, and 9 kg treatments were increased by 10.96%, 9.27%, and 3.31%, compared to control. The component analysis on maize kernel with different nitrogen rates, starch showed no significant differences among treatments. Total sugar in 18 kg nitrogen treatment represented the highest content level, 6.37%. In addition, Amylopectin in 18 kg treatment showed the highest content level of 90.38%. However, amylose in 18 kg treatment showed the lowest level, 9.62% which drew a conclusion that waxy of 18 kg treatment is considered to be the strongest one. From the results described above, nitrous fertilization is essential to grow maize in agricultural fields with the stream. The optimum level of nitrous fertilization is considered 18 kg per 10a.

Cool Tolerance at Booting Stage and Respiration of Anther as Affected by Nitrogen in Rice Plant (질소시용량에 따른 수도의 수잉기 내랭성과 약의 호흡활성 변화)

  • 최장수;이선용
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.35 no.1
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    • pp.23-27
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    • 1990
  • To elucidate the influence of nitrogen application rate on cool tolerance at the booting stage and respiratory activity of anther at the heading stage in the rice plants, the relationships among nitrogen content in the leaf blade and leaf sheath+culm at young microspore stage, cool tolerance at the booting stage and respiratory activity of anther at the heading stage were investigated for 3 rice cultivars-Yeomyungbyeo, Unbongbyeo and Milyang 23. Nitrogen content in the leaf blade at the young microspore stage was negatively correlated with respiratory rate of anther at the heading stage and fertility index, respectively. Respiratory activity of anther at the heading stage with 10ppm nitrogen application was higher than that of anther with 100ppm nitrogen application. On the Arrhenius plot of respiratory activity of anther at the heading stage, Yeomyungbyeo and Unbongbyeo showed a break at 18$^{\circ}C$ and 18.5$^{\circ}C$, respectively, with 100ppm nitrogen application, but did not show a break in respiratory activity of anther with 10ppm nitrogen application, while Milyang 23 showed a break at 20.5$^{\circ}C$ and 21$^{\circ}C$ with 10ppm and 100ppm nitrogen application, respectively. The highest correlation coefficient between fertility and respiratory rate of anther at the heading stage was shown at 20$^{\circ}C$ in the temperature range of 15$^{\circ}C$-30$^{\circ}C$.

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Influence of Fertilization Treatment using Organic Amendment based on Soil Testing on Plant Growth and Nutrient use Efficiency in Cabbage (토양검정에 의한 유기자원 시비처방이 양배추의 생육 및 양분이용효율에 미치는 영향)

  • Lim, Jin-Soo;Lee, Bang-Hyun;Kang, Seung-Hee;Lee, Tae-Guen
    • Korean Journal of Environmental Agriculture
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    • v.39 no.2
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    • pp.95-105
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    • 2020
  • BACKGROUND: In this study, in order to verify the effects of supplemented organic amendment fertilizers recommended by the soil testing on cabbages, we used various amounts of organic amendment fertilizers. The amount of organic amendment fertilizers was decided by calculating each ratio of inorganic nitrogen, phosphorus, and potassium based on the recommended fertilizer composition. METHODS AND RESULTS: The cabbages subjected to treatments 1 and 2 showed similar or greater leaf colors (SPAD values), head heights, head widths, head weight, soil organic matter content, nitrate-nitrogen level, and conductivity after harvest, when compared with cabbages treated with chemical fertilizers. The phosphorus and potassium fixation in the soil were higher in the plot where cabbages were treated with chemical fertilizers, and the nutrient use efficiency was greater in the plots with organic amendments and mineral addition. CONCLUSION: The treatments 1 and 2 that were supplemented with 180-200% of nitrogen, 100-130% of phosphorus, and 185-250% of potassium in comparison to chemical fertilizers, applied by the inorganic ratios of nitrogen, phosphorus, and potassium can be used as organic amendment fertilizers for cabbages.