• Journal of Energy Engineering
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• v.10 no.3
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• pp.188-194
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• 2001

The process simulations are made on the IGCC power plant using heavy residue oil from refinery process. In order to model combined power block of IGCC, the present study employs the gas turbine of MS7001FA model integrated with ASU (Air Separation Unit), and considers the air extraction from gas turbine and the combustor dilution by returned nitrogen from ASU. The exhaust gas energy of gas turbine is recovered through the bottoming cycle with triple pressure HRSG (Heat Recovery Steam Generator). Clean syngas fuel of the gas turbine is assumed to be produced through Shell gasification of Visbreaker residue oil and Sulfinol-SCOT-Claus gas cleanup processes. The process optimization results show that the best efficiency of IGCC plant is achieved at 20% air extraction condition in the case without nitrogen dilution of gas turbine combustor find at the 40% with nitrogen dilution. Nitrogen dilution of combustor has very favorable and remarkable effect in reducing NOx emission level, while shifting the operation point of gas turbine to near surge point.

• Journal of Korean Society of Environmental Engineers
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• v.36 no.4
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• pp.277-285
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• 2014

The usage of efficient microorganism (EM) is increasing in concern for server purposes including odor removal during carcasses degradation. In this study, we have studied the type of soil and its effect on efficient microorganisms for the removal of odorous gases during buried carcasses degradation in lab-scale reactor. The carcasses are buried in the reactor with various soil types such as normal soil, 20% sandy and 20% clay soil with the efficient microorganism KEM. The efficient microorganisms KEM have the ability to stabilize the degradation of carcasses of the burial site. We have focused on the analysis of odorous gases such tri-methylamine (TMA), hydrogen sulfide ($H_2S$), methyl mercaptan (MM), dimethyl sulfide (DMS), dimethyl disulfide (DMDS), carbon dioxide ($CO_2$), and methane ($CH_4$) along with the changes of microbial community changed during complete degradation of buried carcasses for a year. The results suggested that the 20% sandy soil contain lesser level of $H_2S$ and MM (0.09 and 0.35 mg) but 20% clay has higher nitrogen compound removing effect and leave only less amount of ammonia and TMA (0.31 and 2.06 mg). The 20% sandy soil also has the ability to breakdown the carcasses more quality compared with other types of soil. Based on the data obtained in this study suggesting that, the use of 20% sandy soil can effectively control sulfur compounds whereas 20% clay soil controls nitrogen compounds in the buried soil. Depending on the type of the soil, the dominant of microbial communities and the distribution was change.

• Journal of Advanced Marine Engineering and Technology
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• v.37 no.8
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• pp.855-861
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• 2013

Small-pore Cu-chabazite SCR catalysts with high NOx conversion at low temperatures are of interest for marine diesel engines with exhaust temperatures in the range of 150 to $300^{\circ}C$. Unfortunately, fuels for marine diesel engines can contain a high level of sulfur of up to 1.5% by volume, which corresponds to a $SO_2$ level of 500 ppm in the exhaust gases for an engine operating with an A/F ratio of 50:1. This high level of $SO_2$ in the exhaust may have detrimental effects on the NOx performance of the Cu-chabazite SCR catalysts. In the present study, a bench-flow reactor is used to investigate the effects of sulfur poisoning on the NOx performance of Cu-chabazite SCR catalysts. The SCR catalysts were exposed to simulated diesel exhaust gas stream consisted of 500 ppm $SO_2$, 5% $CO_2$, 14% $O_2$, 5% $H_2O$ with $N_2$ as the balance gas at 150, 200, 250 and $300^{\circ}C$ for 2 hours at a GHSV of 30,000 $h^{-1}$. After sulfur poisoning the low-temperature NOx performance of the SCR catalyst is evaluated over a temperature range of 150-$300^{\circ}C$ to determine the extent of the catalyst deactivation. Desulfation is also carried out at 600 and $700^{\circ}C$ for 30 minutes to determine whether it is possible to recover the NOx performance of the sulfur-poisoned SCR Catalysts.

• Journal of Wetlands Research
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• v.19 no.1
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• pp.80-89
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• 2017

Researches about NPS(Non-point Pollution Source) reduction have been widely carried out in recent years. A pilot channel-type constructed wetland (wet swale) was constructed in Rongyin area to treat stormwater generated from a green house agro-land of 22.7 ha. From 2006 to 2008, monitoring was conducted to evaluate its performance on the removal effect for organic pollutants as well as nutrients. Totally, sampling trips of 17 rainfall events were made and they covered most types of storm events in Korea. The channel-type constructed wetland have average removal efficiencies of 78.3~92.0%, 56.4~66.1%, 28.2~45.5% and 50.6~66.4% for SS, COD, TN and TP, respectively. According to four methods for estimating the removal efficiency, the average efficiencies of TSS, COD, TN and TP are 86.0%, 60.1%, 30.1% and 53.5%, respectively. From 2006 to 2008, annual efficiency improved due to infiltration potential increase. It was found that most of the pollutants removed in this channel type of wetland was particulate solids bound pollutants, which is assumed fact that it lacks of physico-chemical treatment conditions which are commonly observed in the retention type of constructed wetlands.

• Journal of the Korean Society of Marine Environment & Safety
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• v.27 no.7
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• pp.1074-1081
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• 2021

Nitrous oxide (N₂O) is one of the six major greenhouse gases and is known to produce a greenhouse ef ect by absorbing infrared radiation in the atmosphere. In particular, its global warming potential (GWP) is 310 times higher than that of CO₂, making N₂O a global concern. Accordingly, strong environmental regulations are being proposed. N₂O reduction technology can be classified into concentration recovery, catalytic decomposition, and pyrolysis according to physical methods. This study intends to provide information on temperature conditions and reaction time required to reduce nitrogen oxides with cost. The high-temperature ranges selected for pyrolysis conditions were calculated at intervals of 100 K from 1073 K to 1373 K. Under temperatures of 1073 K and 1173 K, the N₂O reduction rate and nitrogen monoxide concentration were observed to be proportional to the residence time, and for 1273 K, the N₂O reduction rate decreased due to generation of the reverse reaction as the residence time increased. Particularly for 1373 K, the positive and reverse reactions for all residence times reached chemical equilibrium, resulting in a rather reduced reaction progression to N₂O reduction.

• Korean Journal of Soil Science and Fertilizer
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• v.41 no.6
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• pp.393-398
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• 2008

Several researchers have proposed models or equations to predict soil $CO_2$ flux from more readily available biotic and abiotic measurement. Tree commonly used abiotic variables were N mineral and soil temperature and soil water content. This study was conducted to determine $CO_2$ emission to mineral N, soil water content and soil temperature with clay loam and sandy loam in pepper cultivation in 2004~2005. $CO_2$ flux in the upland with different levels of soil water potential was measured at least once in two weeks during the cropping period in the pepper cultivation plots. Soil water potential in the clay loam and sandy loam soils was established at -30kPa and -50kPa by measuring the soil gravimetric water content with two replications. $CO_2$ emission rate from the differently managed plots was highly correlation coefficient to between the mineral N ($R=0.830^{**}$, $0.876^{**}$) and soil temperature ($r^2=0.793^{**}$, $0.804^{**}$) in the clay loam and sandy loam, respectively. However, the relationships between $CO_2$ emission and soil water content were non-significant. $CO_2$ emissions at sandy loam soils was lower to 21~37% than at clay loam soils for both soil water conditions without differences in yield. At difference levels of soil water conditions, $CO_2$ emission at -50kPa decreased to 37.5% in comparison with that at -30kPa. From the path analysis as to contribution factors of GHGs, it appeared that contribution rate was in the order of soil temperature (54.9%), mineral N (32.7%), and soil moisture content (12.4%).

• Transactions of the Korean Society of Mechanical Engineers B
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• v.35 no.5
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• pp.539-545
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• 2011

Combustion characteristics of industrial radiant tube (RT) burners with forced oscillating combustion technology are investigated using a real-scale (125,000 kcal/h) industrial RT burner facility in both laboratory and field tests. Three different types of industrial RT burners using a by-product gas from the iron-and-steelmaking process are examined in a laboratory facility equipped with a W-type RT. During the field tests, an industrial RT burner is characterized in a large facility equipped with multiple RTs. Their performance and emission controls are investigated under diverse operating conditions. The feasibility of the forced oscillating combustion technology is evaluated by the extent of $NO_x$ reduction and the efficiency improvement. These improvements are able to save energy, extend the RT lifetime, and enhance productivity. The operating conditions that achieve the best performance and emission control for each RT burner are determined.

• Journal of Wetlands Research
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• v.12 no.3
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• pp.165-175
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• 2010

Recently, various development projects have occurred due to rapid industrialization and urbanization. Both industry and population grew rapidly which causes a corresponding rise in pollution. The accumulated pollutants are washed-off during rainy days, highly degrading the water quality of the receiving water body. This is because a lot of non point source (NPS) pollutants were accumulated on the surface during dry periods. This research focuses on the development of Eco-Bio Filter (EBF) system that treats NPS pollutants. It is constructed at Kongju National University campus. The EBF is a type of a structured infiltration system that falls under the category of Low Impact Development (LID) hydrologic design practices. The monitoring of rain events was performed. It includes the development of design, the lessons learned from the post-construction testing and the improvements in the renovation made. After a series of monitoring, the MOE will use the results to apply the design to other areas in the country.

• Proceedings of the Korea Water Resources Association Conference
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• 2012.05a
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• pp.186-186
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• 2012

새만금에서 농업용수의 안정적인 확보를 위해서는 새만금호의 수질관리가 절대적으로 필요하며 농업비점오염 부하량이 총인기준으로 52~72%를 차지하는 것을 고려할 때 농업비점오염 관리는 중요하다. 이에 "새만금유역농업비점오염 저감기법 개발 연구"를 통해 논과 밭 등의 농업비점 오염원별 최적관리기법 개발을 목적으로 모니터링 연구가 수행되었다. 유역규모 물수지 및 물질수지 분석에 있어서 논은 전체 농업용수의 60%를 차지하고 있다. 특히 농업비점오염 중에서 논은 물고 및 담수심의 관리에 따라서 기타 토지이용과 상이한 유출특성을 보인다. 따라서 유역규모에서 논으로부터 발생되는 비점오염의 시공간적인 부하량의 변화를 예측하기 위해서는 반드시 논에서의 물관리와 시비관리에 따른 수량과 수질의 유출특성에 대한 분석이 선행되어야 한다. 물관리 및 시비관리 방법에 따라 논으로부터 발생되는 오염부하량이 수질에 미치는 영향을 분석하기 위해서는 논에서의 물수지 및 물질수지 모니터링 기법이 활용될 수 있다. 하지만 모니터링 접근 방식은 오랜 시간과 많은 비용을 필요로 하는 단점을 가지고 있다. 따라서 고려되어 지고 있는 여러 저감기법들 중에서 농업비점오염물질의 유출에 미치는 영향을 파악하여 가장 적합한 저감기법 (Best Managment Practices, BMPs)을 선정하기 위해서 다양한 수학적인 모형들이 사용되어 왔다. 비점오염 관리는 오염물질이 오염원에서 발생되는 양 자체를 줄이거나 또는 오염원으로부터 수체에 이르기까지의 과정에서 운송을 차단시키는 방법들을 활용하고 있다. 따라서 논에서의 비점오염 모델링 또한 논에서의 유출 특성 및 질소와 인과 같은 영양물질과 관련된 기작을 고려한 모형들이 선택 및 적용되어야 한다. 논에서의 물관리 및 시비관리를 고려할 수 있는 모형들로는 CREAMS-PADDY, GLEAMS-PADDY, PADDYMOD, APEX와 같은 모형들이 개발되어 사용되어 왔다. 따라서 본 연구에서 논으로부터의 비점오염 부하량 예측을 위해 사용되어 온 모형들의 장단점을 비교 분석하고 적합한 모형들을 동일한 시험포장에 적용하여 논 비점오염관련 모형들의 국내 적용성을 제시하였다.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.44 no.7
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• pp.603-610
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• 2016

This paper describes experimental results about emission and NOx reduction of dilution effect (Nitrogen and carbon dioxide) about various fuel compositions of synthetic natural gas (SNG). Combustion experiment was performed to investigate the combustion characteristics for SNG with various hydrogen ratio in SNG, heat input and equivalence ratio in a partially premixed model gas turbine combustor. NOx emission was similar to each hydrogen ratio and flame characteristics was investigated from OH chemiluminescence images. There was a singularity of CO emission in stoichiometric condition and it can be identified using OH chemiluminescence intensity. In addition, dilution effect was studied in using nitrogen and carbon dioxide as diluent to reduce the NOx emission. Carbon dioxide diluent was more effective to NOx reduction than nitrogen diluent because of its high diluent specific heat and its heat capacity.