• Title/Summary/Keyword: 질소와 인의 농도

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Ocean Outfall과 폐수처리 공정의 비용분석을 이용한 수영만의 수질관리

  • Park, Hae-Sik;Park, Cheong-Gil;Lee, Seok-Mo
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 1997.10a
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    • pp.52-53
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    • 1997
  • 수역의 유기오염 개선을 위하여 생활하수, 산업폐수 등의 저하시키는데 주안점을 두어왔으나 공공수역에서의 제거되지 않은 질소와 인의 유입으로 부영양화가 진행되어 하천에는 남조류가 대량발생하고 해역에는 적조가 광역에서 발생하여 큰 사회문제가 되고 있고, 질소와 인의 유입으로 인한 자생 COD가 전체COD의 약 절반을 차지하고 있는 실정이다. 따라서 앞으로의 수질을 개선하기 위해서는 조류증식의 제한인자인 질소와 인의 규제가 필요할 뿐만아니라 하수처리장에 고차처리를 적용하거나, 해양의 회석자용을 이용한 Ocean을 적용하여 연안해역 수질을 관리해야 할 것이다. 따라서 본 연구는 수영만을 대상으로 Ocean Outfall과 폐수처리시절을 적절하게 조합하기 위해서 3차원 생태계모델을 적용하여 유기물질 뿐만 아니라 영양염류인 질소와 인의 농도를 예측하여 환경기준을 만족시키고 비용을 최소화 할 수 있는 폐수처리공법과 해중방류관의 위치를 선정하고자 하였다. 본 연구결과 수영만의 1994년 COD는 II등급, DIN과 DIP는 III등급이었다. 현재의 활성슬러지공법으로 질소와 인을 제거하지 않고 방류할 경우 2001년에 는 하수처리량의 증가로 인해 COD의 경우 1994년 보다 조금 감소하지만 DIN 과 DIP는 1994년과 같은 III등급을 유지하였다. 고도처리공법을 도입할 경우 COD의 농도는 광안리와 해운대해수욕장에서 I등급을 보이고, DIP의 농도도 수영만 전체에서 강등급을 보이지만, DM의 농도는 광안리해수욕장에서 II등급, 해운대해수욕장에서 IH등급을 보였다 하수처리장 유출수를 Ocean Outfall을 이용하여 하수처리장으로부터 4km에 서 방류할 경우의 COD농도는 I등급을 보이고, DE 농도도 광안리와 해운대해 수욕장에서는 I등급을 보이고, DU의 농도는 ll등급을 보여 수질이 개선된 것 을 볼 수 있다. 이상에서와 같이 광안리와 해운대해수욕장의 해역환경기준 ll등급을 만족 하는 하수처리방법은 Ocean Outfall이었다. 수영하수처리장에 인을 처리하기 위한 화학적 침전법의 경우 956억원이 소요되고, 질소를 제거하기 위한 질소제거공정을 추가 건설 할 경우는 2181억원이 전요된다. 그리고 두공정을 같이 건설할 경우에는 3137억원의 비용이 소요된다 수영하수처리장에서 4km 거리와 관경을 2m의 Ocean Outfall 건설비용은 325 억원 정도가 소요되는 것으로 산출되었다. 고차처리시 증가되는 비용으로 건설할 수 있는 Ocean Outfall의 길이는 인 제거공정을 첨가하는 경우에는 18km을 건설할 수 있고, 질소제거공정을 첨가 하는 경우에는 46km를 건설할 수 있는 것으로 산출되었다.

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Fertilization Effects on Growth, Foliar Nutrients and Extract Concentrations in Ginkgo Seedlings (은행나무 묘목(苗木)에 대(對)한 시비(施肥)가 생장(生長) 및 엽내(葉內) 양분(養分)과 유용(有用) 추출물(抽出物) 농도(濃度)에 미치는 영향(影響))

  • Son, Yowhan;Kim, Zin-Suh;Hwang, Jae Hong;Park, Jung Soo
    • Journal of Korean Society of Forest Science
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    • v.87 no.1
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    • pp.98-105
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    • 1998
  • We measured seedling growth, foliar nutrient and extract concentrations of 3-year-old Ginkgo biloba seedlings growing in a nursery following a single fertilization with nitrogen (N), phosphorus (P) and nitrogen plus phosphorus (N+P) fertilizers. Fertilization did not change foliage, stem and root biomass of the seedlings except for the high N+P treatment, Foliar N and P concentrations following fertilization varied according to the amount of fertilizers. In general, foliar N and P concentrations increased with fertilization, but fertilization with 400kg N/ha and 100kg P/ha decreased foliar N and P concentrations, respectively. Seedling growth and foliar nutrient concentrations showed that N and P were the growth-limiting nutrients in our study site. It was found that fertilization reduced the concentrations of secondary metabolites (Ginkgo flavon glycosides and terpene lactones) in foliages. It seemed there was a relationship between foliage biomass production and secondary chemicals in G. biloba seedlings.

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Removal Effect of Nitrogen and Phosphorus of Acorus cazamus var. angustatus oil Its Growth Stage and Water-storage Time (생장단계와 체류시간에 따른 창포의 질소와 인 제거효과)

  • Seo Byung-Soo;Park Chong-Min
    • Korean Journal of Environment and Ecology
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    • v.19 no.1
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    • pp.1-8
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    • 2005
  • The removal affect of nitrogen and phosphorus were analyzed using a Acorus calamus var. angustatus. The nutrient concentration, growth stage of plants and the storage time of polluted water were considered. The results of this study were as follows: after an hour the content of nitrogen and phosphorus were considerably reduced in the Acorus calamus var. angustatus, while after two-four hours the rate of reduction was extremely low. This situation was the same in the early growth stage, growing stage and highest growth stage of the plant. The removal rate of nitrogen and phosphorus with the Acorus calamus var. angustatus was higher, when these two minerals remained in high levels of water. The Acorus calamus var. angustatus was more effective to remove nitrogen than that of phosphorus. The plant removed the most nitrogen and phosphorus when in the highest growth stage, but this was not clear in the growth stages. The removal rate was higher, in the case of moving polluted water to other plants after two days, than in the case of four days of growth in the same plants.

Inhibition Effects of $Ca^{2+}$ and $F^-$ Ion on Struvite Crystallization ($Ca^{2+}$$F^-$ 이온이 Struvite 결정화 반응에 미치는 영향)

  • Kim, Seung-Ha;Kim, Keum-Yong;Ryu, Hong-Duck;Lee, Sang-Ill
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.7
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    • pp.730-737
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    • 2010
  • It is very important to remove fluoride ion before treating semiconductor wastewater containing high concentration of ammonia, phosphates, and fluoride ions by struvite formation. Calcium ion was generally added for the removal of fluoride ion. However, calcium ions remained after removal of fluoride ion can deteriorate the performance of struvite crystalization. It should be removed completely before struvite formation. In this study, the effect of fluoride and calcium ion concentration on the struvite crystalization was investigated. Removal efficiencies of ortho-phosphate with struvite formation were more abruptly decreased than those of ammonium nitrogen, as increase of fluoride ion concentration in synthetic wastewater. The structures of struvite formed in synthetic wastewater containing calcium ion of up to 500 mg/L were identical. Purity of struvite was deteriorated as increase of calcium ion over 500 mg/L. Removal efficiencies of ammonium nitrogen were more decreased than those of phosphate ions as increase of cacium ion in synthetic wastewater.

Process Development of Algae Culture for Livestock Wastewater Treatment Using Fiber-Optic Photobioreactor (축산폐수 처리를 위한 광섬유 생물반응기를 이용한 조류 배양 공정 개발)

  • 최정우;김영기;류재홍;이우창;이원홍;한징택
    • KSBB Journal
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    • v.15 no.1
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    • pp.14-21
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    • 2000
  • In this study, algae cultivation using the photobioreactor has been applied to remove the nitrogen and phosphorus compounds in the wastewater of the livestock industry. The optimal ratio of nitrate and ortho-phosphate concentration was found for the enhancement of removal efficiency. To achieve the high density culture of algae, the photobioreactor consisted of optical fibers wes developed to get the sufficient light intensity. The light could be illuminated uniformly from light source to the entire reactor by the optical fibers. The structured kinetic model was proposed to describe the growth rate, consumption rate of nitrates and ortho-phosphates in algae culture. The self-organizing fuzzy logic controller incorporated with genetic algorithm was constructed to control the semi-continuous wastewater treatment system. The proposed fuzzy logic controller was applied to maintain the nitrated concentration at the given set-point with the control of wastewater feeding rate. The experimental results showed that the self-organizing fuzzy logic controller could keep the nitrate concentration and enhance algae growth.

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A Comparative Study on the Use of Seawater and Sea Salt in Nutrient Elimination (영양염제거에서 해수 및 해수염에 관한 비교연구)

  • Cainglet, Annaliza Pabrua;Kim, Woo-Hang
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.22 no.7
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    • pp.829-835
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    • 2016
  • An excess in the nutrients such as nitrogen and phosphate leads to a phenomenon called eutrophication. In order to avoid this, numerous methods have been used to remove excess nutrients in the water. In this study, the use of a chemical method was assessed through the formation of magnesium ammonium phosphate. The difference in the removal efficiency of seawater and sea salt solution as primary sources of $Mg^{2+}$ ions and $Ca^{2+}$ ions for the formation of magnesium ammonium phosphate (MAP) and hydroxyapatite (HAP) respectively, were observed, taking into account the changes in pH and concentration. The results showed that seawater removed about 90 % phosphate and less than 50 % ammonia in sewage water condition, whereas the sea salt solution removed almost 90 % phosphate and 70 % ammonia in solution at pH 9 and 10 mM concentration of sea salt which further increases as the optimum ${Mg/PO_4}^{3-}$, ${NH_4}^+$ ratio reaches 2. The difference in the removal efficiency of seawater and sea salt was due to the fact that the set-ups were prepared in different conditions. This study suggests that both seawater and sea salt can be used to remove nutrients from the water. The relatively higher removal of phosphate can be explained by the formation of HAP from free $Ca^{2+}$ ions initially present in seawater and sea salt solution.

Nutrient Removal Potential of water Hyacinth Cultured in Nutrient-enriched Water and Swinery Wastewater (부레옥잠의 수중영양염 제거 잠재력에 관한 고찰)

  • 전만식;김범철
    • Korean Journal of Environmental Biology
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    • v.17 no.1
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    • pp.117-124
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    • 1999
  • Nutrients removal by water hyacinth, Eichhornia crassipes (Mart.) Solms from nutrient enriched waters and swinery wastewater were evaluated. The contents of nitrogen and phosphorus of dried water hyacinth increased from 1.4 to 3.3% and 0.21 to 0.80% when water hyacinth available N and P in the culture medium were increased from 0.7 to 5.0 mgN/1 and 0.06 o 1.5 mgP/l. respectively. Maximum N and P contents were found to be 4.1 and 0.90%, respectively. The significant relationship was observed between the standing crop of water hyacinth and the biomass yield per unit area and time. Biomass yield increased gradually until standing crop reached 15 kg wet wt./m$^2$, and then rapidly decreased. The high biomass yield of up to 0.5 kg/m$^2$/day was obtained in the range of 7 to 20 kg/m$^2$of standing crop. The potential removal rates of N and P by the water hyacinth during summer were found to be 2,250 to 2,710 mgN/m$^2$/day and 570 to 595 mgP/m$^2$/day, respectively, when 15 kg/m$^2$in standing crop and nutrient concentrations of culture medium were ranged from 1.24 to 6.2 mgP/1 and 3.2 to 32.5 mgN/1, respectively, Inorganic N and P concentrations of swinery wastewater were in the range of 82 to 121 mgN/1 and 22 to 79 mgP/1, respectively. Nitrogen and P removal rates of water hyacinth cultured in swinery wastewater were found to be in the ranges of 2,000 to 2,600 mgN/m$^2$/day and 157 to 254 mgP/m$^2$/day, respectively, at 10 times diluted water of swinery wastewater.

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Effects of Nitrogen and Phosphorus Fertilization on Seasonal Changes and Retranslocation of Nutrition in Foliage and Twig of Pinus rigida and Larix kaempferi (질소와 인 시비가 리기다소나무와 낙엽송 침엽 및 소지에서의 부위별 양분의 계절적 변화 및 재분배에 미치는 영향)

  • 이임균;손요환
    • The Korean Journal of Ecology
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    • v.27 no.4
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    • pp.199-210
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    • 2004
  • Effects of nitrogen and phosphorus fertilization on seasonal changes of nutrient content in tree components, and retranslocation N and P in foliage and twig were determined in adjacent 41-year-old plantations of Pinus rigida Miller and Larix kaempferi Gordon on a similar soil in Yangpyeong, Gyeonggi Province. In general, foliage N and P concentrations of L kaempferi were significantly higher than current and 1-year-old foliages of P. rigida. N and P concentrations were higher in foliage than in twigs for both tree species. However, there were no significant differences in foliage and twig N and P concentrations with ages. Significant seasonal differences in foliage and twig N and P concentrations were observed for both tree species because of nutrient retranslocation. Foliage nutrient concentrations were highest in the mid-growing season and lowest in autumn, whereas twig nutrient concnetrations have gradually increased since July. These seasonal trends indicated nutrient retranslocation from foliage into twigs before foliage senescence. However, there were no significant changes in foliage and twig nutrient retranslocation, and no consistent patterns in foliage and twig nutrient retranslocation following N and P fertilizer additions. No significant changes in nutrient retranslocation between different foliage and twig ages were observed following fertilization.

Effect of N and P Fertilization on Nutrient Use Efficiency of Pinus densiflora, Larix leptolepis, and Betula platyphylla var. japonica Seedlings (질소와 인 시비가 소나무, 일본잎갈나무, 자작나무 묘목의 양분이용효율에 미치는 영향)

  • Shin, Jung-A;Son, Yo-Whan;Hong, Sung-Gak;Kim, Young-Kul
    • Korean Journal of Environmental Agriculture
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    • v.18 no.4
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    • pp.304-309
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    • 1999
  • Biomass, tissue (foliage, stem. and root) nutrient concentration, and nutrient use efficiency (NUE) were determined for 1-year-old Pinus densiflora, Larix leptolepis and Betula platyphvlla var. japonica seedlings in a greenhouse under nitrogen (N) and phosphorus (P) fertilization treatments. There were no consistent patterns in the effect of fertilization on seedling growth, however, in most cases the addition of N and P had no stimulating effect on biomass. In general, seedling tissue N and P concentrations increased after fertilization. It appeared that fertilization induced luxury nutrient consumption because uptake was increased without altering biomass. The NUE. calculated as the ratio between total above and belowground production and nutrient content in seedlings, decreased with increasing N and P supply for P. densiflora and B. platyphylla var. japonica while that for L. leptolepisthe did not change. B. platyphylla var. japonica had the highest NUE, L. leptolepis the lowest, with P. densiflora having the intermediate NUE.

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