• Journal of Energy Engineering
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• v.4 no.1
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• pp.115-125
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• 1995

본“천연가스 다단연소기술 연구”는, 공업적으로 널리 쓰이는 선회확산 방식으로 천연가스를 연소시킬 때 그 연소 특성과 발생되는 환경오염물질인 일산화탄소(CO)와 질소산화물(NOX)의 저감에 대한 연구로서, 천연가스의 난류확산화염과 선회확산화염의 유동장, 온도장, 농도장을 실험과 수치해석을 통하여 분석하여 각각 연소방식의 화염구조와 특성을 규명하고 해석하였다. 그리고 그 결과를 토대로하여 다단확산 연소실험 장치를 제작 다단확산연소의 중요한 인자인 1차당량비, 2차공기주입위치, 유속, 선회도 등을 변화시켜 질소산화물 저감과 높은 연소효율을 얻을 수 있는 최적의 연소조건을 찾아 내었다. 본고에서는 실험부분만을 간추려 발표하고 수치해석 부분은 다음 기회로 미루고자 한다.

• 한국연소학회:학술대회논문집
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• 2012.04a
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• pp.69-74
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• 2012

Looming global environmental pollution problems around the world movement to minimize the environmental pollution is actively taking place. International Maritime Organization (IMO) a significant portion of the marine pollution by exhaust gases emitted from vessel considered, and accordingly developed around the ship and ship-related environmental regulations, emission standards are going to strengthen gradually, the development of environmentally friendly vessels and equipment is proceeding actively.

• Proceedings of the KAIS Fall Conference
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• 2009.05a
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• pp.543-545
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• 2009

유럽을 포함한 많은 선진국들은 자동차 배기가스에 대한 환경규제를 만족하기 위해서 노력을 하고 있다. 가솔린 엔진에 비해서 문제가 되는 디젤엔진에서 배출되는 배기가스 즉 질소 산화물과 입자상 물질을 저감하려는 노력은 꾸준히 진행되고 있다. 본 논문은 11,000cc 대형 터보 디젤엔진에 배기가스 순환장치를 설치하여 질소산화물을 효과적으로 저감하는 기술을 개발하고자한다.

• Journal of the Korean Society of Marine Environment & Safety
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• v.28 no.7
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• pp.1209-1215
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• 2022

The selective catalytic reduction (SCR) is known as a very efficient method to reduce nitrogen oxides (NOx) and the catalyst performs reduction from nitrogen oxides (NOx) to nitrogen (N₂) and water vapor (H2O). The catalyst, which is one of the factors determining the performance of the nitrogen oxide (NOx) ruduction method, is known to increase catalyst efficiency as cell density increases. In this study, the reduction characteristics of nitrogen oxides (NOx) under various engine loads investigated. A 100CPSI(60Cell) catalysts was studied through a laboratory-sized simulating device that can simulate the exhaust gas conditions from the power generation engine installed in the training ship SEGERO. The effect of 100CPSI(60Cell) cell density was compared with that of 25.8CPSI(30Cell) cell density that already had NOx reduction data from the SCR manufacturing. The experimental catalysts were honeycomb type and its compositions and materials of V₂O₅-WO₃-TiO₂ were retained, with only change on cell density. As a result, the NOx concentration reduction rate from 100CPSI(60Cell) catalyst was 88.5%, and IMO specific NOx emission was 0.99g/kwh satisfying the IMO Tier III NOx emission requirement. The NOx concentration reduction rate from 25.8CPSI(30Cell) was 78%, and IMO specific NOx emission was 2.00g/kwh. Comparing the NOx concentration reduction rate and emission of 100CPSI(60Cell) and 25.8CPSI(30Cell) catalysts, notably, the NOx concentration reduction rate of 100CPSI(60Cell) catalyst was 10.5% higher and its IMO specific NOx emission was about twice less than that of the 25.8CPSI(30Cell) catalysts. Therefore, an efficient NOx reduction effect can be expected by increasing the cell density of catalysts. In other words, effects to production cost reduction, efficient arrangement of engine room and cargo space can be estimated from the reduced catalyst volume.

• Journal of Biosystems Engineering
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• v.24 no.6
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• pp.465-472
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• 1999

To remove nitrogen oxides(NOx) in exhaust gas of diesel engine, three-way catalytic process with plasma discharger has great possibilities. Characteristics of NOx removal depends on NO conversion to NO$_2$and/or HNO$_3$due to high activation energies for NO oxidation and reduction. NOx removal efficiency by using three-way catalytic with plasma discharger indicated about 50% at 40watt power consumption condition.

• Transactions of the Korean Society of Automotive Engineers
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• v.7 no.8
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• pp.83-90
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• 1999

To remove nitrogen oxides(NOx) in exhaust gas of diesel engine, three-way catalytic process with plasma discharger has great possbilities. Characteristics of NOx removal depends on NO conversion to $NO_2$ and/or $HNO_3$ due to high activation energies for NO oxidationand reduction. NOx removal efficiency by using three-way catalytic with plasma dischager indicated about 50% at 40 watt power consumption condition.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.11 no.9
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• pp.3578-3582
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• 2010

The nitrogen oxidized substance(NOx) from cars in city is one of serious air-polution problems. In advanced country, the powder or the liquid photocatalystic for asphalt pavement and noise barrier have been used to reduce the air-polution. In this paper, the effect of photocatalystic on asphalt pavement has been evaluated, especially for UV optical science reactions analyzed NOx purification efficiencies of the automobile waste gas. Judging from the limited lab-scale test, the use of the powder or the liquid photocatalystic is one of alternatives to reduce the NOx from automobile.

• Prospectives of Industrial Chemistry
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• v.22 no.5
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• pp.25-40
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• 2019

전 세계적으로 환경문제를 해결하기 위한 방안으로 환경규제를 강화시키며 특히 다양한 대기오염 물질 중 최근 큰 이슈인 초미세먼지 저감을 위해 전구물질로 알려진 질소산화물을 제어하기 위한 다양한 기술개발이 가속화되고 있다. 특히, 다양한 처리기술 중에 기술적·경제적인 이점을 갖춘 선택적 촉매환원법(selective catalytic reduction, SCR) 기술을 통하여 질소산화물 제거를 위해 암모니아를 환원제로 반응에 참여시켜 인체에 무해한 H₂O, N₂로 전환하는 기술이 대표적이다. 최근 전 세계적으로 다양한 산업군에서 질소산화물이 배출되고 있으며, 점오염원뿐만이 아니라 비점오염원(mobile sources)에 대한 규제가 강화되고 있다. 디젤엔진이 장착된 선박 배가스 처리장치 내 SCR 기술이 주목을 받고 있으며, NH₃-SCR에 사용되는 촉매는 주로 VO_x/TiO₂, VO_x/W/TiO₂ 촉매가 대표적이다. 한편 선박 디젤엔진에 사용되는 연료에 따라 연소배가스 특성이 다르다. 이러한 연료가 연소됨에 따라 SO₂, SO₃가 발생되고 환원제인 NH₃와 결합하여 황산암모늄염((NH₄)₂SO₄), ABS (ammonium bisulfate, NH₄HSO₄)과 같은 염을 형성시켜 탈질촉매의 비활성화 문제가 발생된다. 이러한 비활성화 물질이 침적된 탈질촉매를 재활성화 시키기 위하여 열 산화를 통해 재생시키고 있다. 이처럼 선박용 SCR 촉매는 강화되는 배출규제 및 엔진기술의 발달로 저감되는 운전 온도에 대비하여 저온 활성 재생이 가능한 고활성, 고내구성 촉매기술 개발이 필요하다.

• Journal of Advanced Marine Engineering and Technology
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• v.38 no.1
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• pp.15-22
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• 2014

Multiple devices have been installed to reduce exhaust emissions and to increase thermal efficiency. Those devices reduce the exhaust pipe opening area and increase the exhaust gas pressure. The pressure increase disturbs a gas flow and has a bad effect on the engine performance. However there is some study that NOx can be reduced with exhaust gas pressure increase. In this study an engine performance is tested with various opening ratios. The result shows that the fuel consumption rate is reduced in case of little amount of the pressure increase, and NOx is reduced with the pressure increase, while the concentration of the toxic exhaust gases are increased in the case of high back-pressure.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.10 no.5
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• pp.79-84
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• 2011

Air pollutants from a small marine diesel engine are increasing and the IMO(International Marine Organization) regulation asked for its reduction. In this study, NOx reduction technologies such as improvement of various cooling systems are applied to the small marine diesel engine. The various cooling systems are a intercooler, a heat exchanger for engine coolant, and an exhaust manifold by water cooling. These systems are tested on an engine dynamometer and a exhaust gas analyzer by a marine diesel engine test regulation. Test results are shows that the small marine engine are satisfied the IMO NOx regulations; Tire II.