• Title/Summary/Keyword: 질소산화물 저감방법

Search Result 52, Processing Time 0.025 seconds

The Effects of Advanced Reburning with SNCR on NOx and CO Reduction (무촉매 환원법이 적용된 응용 재연소 방법에 의한 NOx와 CO의 저감 효과)

  • Lee Chang-Yeop;Kim Dong-Min;Baek Seung-Wook
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.30 no.8 s.251
    • /
    • pp.788-795
    • /
    • 2006
  • From the view of the environmental protection against the use of fossil fuels, the great of efforts have been exerted to find an effective method which is not only pollutant reduction but also high thermal efficiency. Reburning is a useful technology in reducing nitric oxide through injection of a secondary hydrocarbon fuel. In this paper, an experimental study has been conducted to evaluate the hybrid effects of reburning and selective non-catalytic reaction (SNCR) on $NO_x/CO$ reduction from oxygen-enriched LPG flame. Experiments were performed in flames stabilized by a co-flow swirl burner, which was mounted at the bottom of the furnace. Tests were conducted using LPG gas as main fuel and also as reburn fuel. The paper reported data on flue gas emissions, temperature distribution in furnace and various heat fluxes at the wall for a wide range of experimental conditions. Overall temperature in the furnace, heat fluxes to the wall and $NO_x$ generation were observed to increase by oxygen-enriched combustion, but due to its hybrid effects of reburning and SNCR, $NOx/CO$ concentration in the downstream has considerably decreased.

The Methods Calculating the Reduction Efficiency of Nitrogen Oxide for the Facilities Including the Low NOx Burners (저녹스 버너 설치 시설의 질소산화물 저감 효율 산정 방법)

  • Lee, Ki Yong;Talukder, Niladri
    • 한국연소학회:학술대회논문집
    • /
    • 2015.12a
    • /
    • pp.295-296
    • /
    • 2015
  • We presented the methods calculating the reduction efficiency of nitrogen oxide for the low $NO_x$ burner as the pollution prevention facilities. The standard $NO_x$ concentration was used on the emission factor of LNG, $3.7g/m^3$. The $NO_x$ reduction efficiency based on the $NO_x$ concentration was presented and the relationships between the $NO_x$ concentration and the emission factor or the specific heat emission factor were derived. These results could be accurately reflected on calculating the amount of the nitrogen oxide emissions. In addition, according to the arrangement of the low $NO_x$ burners the methods of applying their $NO_x$ reduction efficiency were proposed. The $NO_x$ reduction efficiency for the facilities consisting of the low $NO_x$ burners and the non-low $NO_x$ burners could be estimated with information about the reduction efficiency of each low $NO_x$ burners, the fuel consumption rate, and the heating value of fuel.

  • PDF

A Study on Performance and Simultaneous Reduction of Smoke and NOx Emission by an DMM Addition and Application of EGR Method in a Diesel Engine (디젤기관에세 DMM 첨가와 EGR 방법 적용에 의한 기관성능 및 매연과 NOx의 동시저감 연구)

  • Oh Young-Taig;Choi Seung-Hun
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.30 no.3 s.246
    • /
    • pp.208-214
    • /
    • 2006
  • Dimethoxy methane$(CH_3-O-CH_2-O-CH_3)$, also known as methylal or DMM, is an oxygenated additive that contains 42.5% oxygen by weight and is soluble in diesel fuel. It is a colorless liquid and a gas-to-liquid chemical 방tat has been evaluated for use as a diesel fuel component. Experiments were conducted by using the five blends with different volumetric percentage of DMM(2.5, 5, 7.5, 10, and 12.5%) in baseline diesel fuel. The test engine was single cylinder, four stroke, DI diesel engine unmodified. Also, data was collected for steady state operation at 24 engine speed-load conditions. The focus of this study was to investigate the effects of the addition of oxygenated fuel to diesel fuel on the engine-out emissions and the performance. Smoke emissions of all DMM blends were reduced substantially in comparison with conventional diesel fuel. These results indicate that DMM may be an effective blendstock for diesel fuel as an environment-friendly alternative fuel. Besides, this study showed that simultaneous reduction of smoke and NOx emissions could be achieved by oxygenated fuel and EGR method that was applied to decrease NOx emissions increasing with smoke emissions reduction.

Experimental Study on Thermal NOx and CO Emission in a Laboratory-Scale Incinerator with Reversed Secondary Air Jet Injection (역방향 2차 공기 주입 방식을 적용한 소각 연소로의 Thermal NOx 및 CO 배출특성에 대한 축소모형실험 연구)

  • Choi, Chonggun;Choi, Woosung;Shin, Donghoon
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.40 no.8
    • /
    • pp.503-510
    • /
    • 2016
  • Incinerators generally emit pollutants such as NOx and CO during the combustion process. In this paper, pollutant emissions and temperature distributions were studied in a simulated incinerator with a reversed (relative to the flue gas flow) secondary air injection system. The experiments were performed by using a lab-scale furnace in order to evaluate the effects of the injection location, direction and flow rate of secondary air jets. The emission of NOx was lower in the case of reversed secondary air injection than in the case of cross injection, due to the recirculation and mixing of the exhaust gas. In the reversed air injection cases, thermal NOx emissions decreased as secondary air ratio increased from 30 to 60 and slightly increased at secondary air ratios higher than 60. In most cases, CO emissions were not detected except for a few reversed secondary air injection cases, in which cases CO concentrations below 2ppm were observed.

Modeling of $NH_3$-SCR Diesel $NO_x$ Reduction and Effects of $NO_2/NO_x,\;NH_3$/NO Ratios on the De-$NO_x$ Efficiency ($NH_3$-SCR 방법에 의한 디젤기관의 $NO_x$ 저감과정의 모델링 및 $NO_2/NO_x,\;NH_3$/NO비에 따른 저감효율 변화 해석)

  • Jung, Seung-Chai;Yoon, Woong-Sup
    • Transactions of the Korean Society of Automotive Engineers
    • /
    • v.16 no.3
    • /
    • pp.179-187
    • /
    • 2008
  • A mathematical modeling of $NO_x$ reduction in $NH_3$-SCR process is conducted. The present deterministic model solves one-dimensional conservation equations of mass and species concentrations for channel flows and the catalytic reaction. NO and NO_2$ reactions by the vanadium catalyst in the presence of $NH_3$ are calculated with the rate expressions of Langmuir-Hinshelwood scheme. The modeling was validated with extensive empirical data regarding $NO_x$ reduction efficiency. Analysis of De-$NO_x$ sensitivity conducted with regard to oxygen and water yielded highly accurate prediction over a wide range of $NO_2/NO_x$ ratios from 0 to 1 in a temperature range of $200^{\circ}C{\sim}550^{\circ}C$. The $NO_x$ reduction largely depends on $NO_2/NO_x$ ratio at temperatures lower than $300^{\circ}C$. NO reduction efficiency is significantly augmented with increasing in $NH_3$/NO ratio at higher temperatures, whereas rather insensitive to the $NH_3$/NO ratio at lower temperatures.

Investigation of Plume Opacity Induced by the Combustion of Orimulsion (오리멀젼 연소로 인한 가시백연의 원인 규명)

  • Kim, Young-Hun;Kim, Jong-Ho;Joo, Ji-Bong;Lee, Jeong-Jin;Kim, Jin-Soo;Kwak, Byung-Kyu;Jeong, Jin-Heun;Park, Soong-Keun;Yi, Jong-Heop
    • Journal of Korean Society of Environmental Engineers
    • /
    • v.29 no.3
    • /
    • pp.297-303
    • /
    • 2007
  • Orimulsion, a bitumen-in-water emulsified fuel, has been used throughout the world as a substitute fuel for heavy oil and coal. Orimulsion has relatively high levels of sulfur, nickel, and vanadium, compared to other fuel oils and coals, and has been the subject of much debate regarding the environmental impacts. In Korea, Y power plant has operated boilers with Orimulsion as a fuel, and they has some drawbacks during the plant operation, such as plume opacity. In this study, we investigated the cause of formation mechanism and factors for the plume opacity by investigating the operation data, and measuring the particle size distribution at EP(Electrostatic Precipitator), FGD(Fuel Gas Desulfurization) and TMS(Telecommunications Management System) units. Resulting data showed the primary particles below 1 ${\mu}m$ formed were regrown by the recombination of $SO_3$ in wet-limestone FGD process, and thus the secondary particles are induced to cause the plume opacity.

A Study on Synthetic Method and Material Characteristics of Magnesium Ammine Chloride as Ammonia Transport Materials for Solid SCR (Solid SCR용 암모니아 저장물질인 Magnesium Ammine Chloride의 합성방법 및 물질특성 연구)

  • Shin, Jong Kook;Yoon, Cheon Seog;Kim, Hongsuk
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.39 no.11
    • /
    • pp.843-851
    • /
    • 2015
  • Among various ammonium salts and metal ammine chlorides used as solid materials for the sources of ammonia with solid SCR for lean NOx reduction, magnesium ammine chloride was taken up for study in this paper because of its ease of handling and safety. Lab-scale synthetic method of magnesium ammine chloride were studied for different durations, temperatures, and pressures with proper ammonia gas charged, as a respect of ammonia gas adsorption rate(%). To understand material characteristics for lab-made magnesium ammine chloride, DA, IC, FT-IR, XRD and SDT analyses were performed using the published data available in literature. From the analytical results, the water content in the lab-made magnesium ammine chloride can be determined. A new test procedure for water removal was proposed, by which the adsorption rate of lab-made sample was found to be approximately 100%.

A Study on the Cold Flow Characteristics of a Flue Gas Recirculation Burner with Both Outlets Opening (양쪽 출구가 트인 배기가스 재순환 버너의 냉간 유동 특성에 관한 연구)

  • Ha, Ji Soo
    • Journal of the Korean Institute of Gas
    • /
    • v.22 no.3
    • /
    • pp.7-12
    • /
    • 2018
  • Thermal NOx is generated in a high temperature environment in a combustion facilities. Exhaust gas recirculation method is widely used among various methods for reducing nitrogen oxides in combustion devices. In the present study, the computational fluid dynamic analysis was accomplished to elucidate the cold flow characteristics in the flue gas recirculation burner with both outlets opening. Because the reciculation pipes is installed toward the tangential direction, the swirling flow is formulated in the burner and the phenomenon of the reverse flow creation is detected at the center area of circular burner. We are confirmed that this is the similar trend with the burner with one side outlet closed. From the present study, it was seen that the recirculated inflow from both recirculated burner outlets increased by about 5% compared to the burner with one side outlet opening. At the outlet located at the exhaust gas recirculation pipe inlet(gas exit 1), the inlet flow was formed in the entire region. At the opposite outlet(gas exit 2), the total flow was discharged, but the center part of the burner was observed to have a reverse flow. The flow rate at the gas exit 2 was 3 ~ 5 times larger than the flow rate at the gas exit 1.

A Study of the Combustion Flow Characteristics of a Exhaust Gas Recirculation Burner with Both Outlets Opening (양쪽 출구가 트인 배기가스 재순환 버너의 연소 유동 특성에 관한 연구)

  • Ha, Ji-Soo
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.19 no.6
    • /
    • pp.696-701
    • /
    • 2018
  • The nitrogen oxides generated during combustion reactions have a great influence on the generation of acid rain and fine dust. As an NOx reduction method, exhaust gas recirculation combustion using Coanda nozzles capable of recirculating a large amount of exhaust gas with a small amount of air has recently been utilized. In this study, for the burner outlet with dual end opening, the use of a recirculation burner was investigated for the distribution of the pressure, streamline, temperature, combustion reaction rate and nitrogen oxides using computational fluid analysis. The gas mixed with the combustion air and the recirculated exhaust gas flow in the tangential direction of the circular cylinder burner, so that there is a region with low pressure in the vicinity of the fuel nozzle exit. As a result, a reverse flow is formed in the central portion of the burner near the center of the circular cylinder burner and the exhaust gas is discharged to the outside region of the circular cylinder burner. The combustion reaction occurs on the right side of the burner and the temperature and NOx distribution are relatively higher than those on the left side of the burner. It was found that the average NOx production decreased from an air flow ratio of 1.0 to 1.5. When the air flow ratio is 1.8, the NOx production increases abruptly. It is considered that the NOx production reaction increases exponentially with temperature when the air ratio is more than 1.5 and the NOx production reaction rate increases rapidly on the right-hand side of the burner.

A review on the Plan for the Further Reinforcement of the NOx Emission Limit for Marine Diesel Engine (선박에서 배출되는 NOx의 배출량 규제에 대한 대응 방안 고찰)

  • Jang M.S.;Kim S. H.;Kang K.S.
    • Journal of the Korean Society for Marine Environment & Energy
    • /
    • v.7 no.4
    • /
    • pp.174-179
    • /
    • 2004
  • Domestic marine diesel engine makers reduce the NOx emission mostly by applying low NOx fuel nozzle and injection timing retard. However, it is necessary to develop high efficient technology (EGR, DWI and SCR, etc.) to reduce NOx emission in order to prepare for the further reinforcement of the NOx emission limit. Also, in the near future, IMO will restrict additively THC, PM and CO with NOx. Therefore, domestic engine makers have to prepare for it and the relevant government ministries should give a sufficient support to these technology research and establish or amend the relevant law, which should include the excursion riverboat.

  • PDF