• Title/Summary/Keyword: 질소분석

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Dry Nitrogen Venting System for Ultra-high Vacuum (초고진공용 건조질소 통풍장치)

  • 이성수;유선일;정진욱;정석민
    • Journal of the Korean Vacuum Society
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    • v.1 no.3
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    • pp.332-335
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    • 1992
  • 초고진공 시스템에 있어서 시스템을 대기압으로 바람을 넣은 후 정상상태로의 신 속한 원상회복을 위하여 건조질소 통풍(venting) 장치를 고안 제작하였다. 이 장치는 액체 질소 저장통, 증발기 및 여과기로 구성되어 있다. 이 장치에 의한 통풍효과와 다른 방법에 의한 통풍효과를 가스 방출률 측정을 통하여 정성적으로 비교 분석하였을 때, 본 장치가 가 장 낮은 가스 방출률과 가장 빠른 진공회복을 보여주었다.

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Real Time Monitoring of Mal-ordor Nitrogen Substances in the Air at Siwha Industrial Complex (시화공단 대기중 악취유발 질소화합물의 실시간 모니터링)

  • 이동수;김영훈;김영화;한진석;이석조;김덕현
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2003.11a
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    • pp.353-355
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    • 2003
  • 시화공단에서 악취물질의 원인규명을 위한 공동연구가 실시된바 있다. 이 연구에서 본 연구팀은 주요 악취유발물질인 질소화합물과 카르보닐화합물의 실시간 모니터링 기술을 소개한 바 있다. 이 연구의 후속사업으로 금년 6월부터 3개월에 걸친 장기모니터링을 실시하여 이 기술의 현장 적용성과 악취모니터링의 유용성을 평가한바 있다. 이번 연구에서는 질소화합물, 카르보닐화합물, 유황화합물에 대한 세 분석시스템을 평가하였다. (중략)

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A study on the physical and corrosion properties of CrN films with nitrogen concentration (질소 인입량 조절에 따른 박막의 물성 및 부식특성에 대한 연구)

  • Kim, Eun-Yeong;Myeong, Hyeon-Sik;Park, Jong-In;Jeon, Yu-Taek;Na, Sang-Muk
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2007.11a
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    • pp.149-150
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    • 2007
  • 플라즈마 코팅공정시 질소 인입량 조절에 따라 비대칭 마그네트론 스퍼터링법으로 CrN 박막을 합성하였으며 증착된 CrN 박막을 XRD, SEM, EDX, ESCA, 양극분극시험 등을 통하여 분석을 실시하였다. 플라즈마 공정시 챔버에 인입하는 질소량이 증가함에 따라 박막의 부식특성이 우수해짐을 확인하였다.

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Effects of organic matter sources on nitrogen supply potential in arable land (농경지에서 유기물 시용에 의한 질소 공급 효과)

  • Lee, Ye-Jin;Yun, Hong-Bae;Song, Yo-Sung;Lee, Chang-Hoon;Sung, Jwa-Kyung;Ha, Sang-Keun
    • Korean Journal of Agricultural Science
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    • v.42 no.4
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    • pp.431-437
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    • 2015
  • Recently, assessment of nitrogen balance has been required for environmental agriculture. Nutrient management using organic matters in farmlands has been strongly required as a means of extending resource-cycling agriculture and reduction of nitrogen balance. Organic matters-derived nutrients and soil-available nitrogen should be necessarily considered to manage nutrient balance in soil-plant system. In this study, we reviewed the amount of N supply according to types of organic matter such as livestock compost and green manure in arable land. In case of applied livestock compost in soil, nitrogen mineralization was influenced by nitrogen amount of livestock manure and mixed materials. And nitrogen mineralization of green manure in arable land was influenced by types of crop and return period of green manure because of change of C/N ratio. Also, nitrogen supply by organic matter in arable land can be changed by environmental factors such as temperature, moisture in soil. Therefore, nitrogen supply according to C/N ratio of organic matter and analysis method for estimation of soil nitrogen supply availability should be evaluated to set up the nutrient management model.

Estimation of surface nitrogen dioxide mixing ratio in Seoul using the OMI satellite data (OMI 위성자료를 활용한 서울 지표 이산화질소 혼합비 추정 연구)

  • Kim, Daewon;Hong, Hyunkee;Choi, Wonei;Park, Junsung;Yang, Jiwon;Ryu, Jaeyong;Lee, Hanlim
    • Korean Journal of Remote Sensing
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    • v.33 no.2
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    • pp.135-147
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    • 2017
  • We, for the first time, estimated daily and monthly surface nitrogen dioxide ($NO_2$) volume mixing ratio (VMR) using three regression models with $NO_2$ tropospheric vertical column density (OMIT-rop $NO_2$ VCD) data obtained from Ozone Monitoring Instrument (OMI) in Seoul in South Korea at OMI overpass time (13:45 local time). First linear regression model (M1) is a linear regression equation between OMI-Trop $NO_2$ VCD and in situ $NO_2$ VMR, whereas second linear regression model (M2) incorporates boundary layer height (BLH), temperature, and pressure obtained from Atmospheric Infrared Sounder (AIRS) and OMI-Trop $NO_2$ VCD. Last models (M3M & M3D) are a multiple linear regression equations which include OMI-Trop $NO_2$ VCD, BLH and various meteorological data. In this study, we determined three types of regression models for the training period between 2009 and 2011, and the performance of those regression models was evaluated via comparison with the surface $NO_2$ VMR data obtained from in situ measurements (in situ $NO_2$ VMR) in 2012. The monthly mean surface $NO_2$ VMRs estimated by M3M showed good agreements with those of in situ measurements(avg. R = 0.77). In terms of the daily (13:45LT) $NO_2$ estimation, the highest correlations were found between the daily surface $NO_2$ VMRs estimated by M3D and in-situ $NO_2$ VMRs (avg. R = 0.55). The estimated surface $NO_2$ VMRs by three modelstend to be underestimated. We also discussed the performance of these empirical modelsfor surface $NO_2$ VMR estimation with respect to otherstatistical data such asroot mean square error (RMSE), mean bias, mean absolute error (MAE), and percent difference. This present study shows a possibility of estimating surface $NO_2$ VMR using the satellite measurement.

Studies on Biological Nitrogen Fixation -III. Influences of organic matter sources, kinds and amount of fertilizer nitrogen on the changes of biological N2-fixation and kjeldahl nitrogen under dark and light condition in submerged paddy soil (생물학적(生物學的) 질소고정(窒素固定)에 관(關)한 연구(硏究) -III. 담수토양(湛水土壤)에서 유기물종류(有機物種類), 질소비종(窒素肥種)과 시비량(施肥量)을 달리했을때 광합성(光合成) 및 타양성질소고정력(他養性窒素固定力)에 미치는 영향(影響))

  • Lee, Sang-Kyu;Lee, Myeong-Gu
    • Korean Journal of Soil Science and Fertilizer
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    • v.20 no.3
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    • pp.261-268
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    • 1987
  • A green house experiment was conducted to find out the differences in the amount of biologically fixed nitrogen and kjeldahl nitrogen on the different soil texture, kinds and amounts of fertilizer nitrogen under light (photosynthetic $N_2$-fixation) and dark (heterotrophic $N_2$-fixation) condition in submerged paddy soil. The reults obtained were summarized as follows; 1. The amount of biologically fixed nitrogen per mg carbon from different organic matter was obtained as 0.13 mg in glucose, 0.09 mg in rice straw, and 0.07 mg in refused mushroom compost and barley straw under 60 days of incubation. 2. Nitrogen fixing activities were decreased with increase of fertilizer nitrogen and those tendency was pronounced more in sandy soil with application of urea than that of ammonium sulfate. 3. The application of ammonium sulfate in sandy soil under light condition was increased the photosynthetic $N_2$-fixation and the applied urea was remarkably reduced the heterotrophic $N_2$-fixation in sandy soil. The proportion of biologically fixed total nitrogen after experiment in sandy soil was obtained as 25% for dark(heterotrophic $N_2$-fixation) and 75% for light (photosynthetic $N_2$-fixation) condition. On the other hand, very similar biological $N_2$-fixing tendency was obtained between kinds of nitrogen fertilizer and two light condition in clayey soil. 4. The kjeldahl nitrogen was remarkably decreased after experiment under dark condition with application of urea than that of light condition with ammonium sulfate, and no remarkable decreasing tendency was obtained in clayey soil between two kinds of fertilizer nitrogen. 5. The high significant positive correlationship was obtained between calculated biological nitrogen fixation by acetylene reducing activity and kjeldahl nitrogen after experiment under light (y=0.8488X-5.9632, $r=0.9928^{**}$, n=21) and dark (y=0.8795X-7.1056, $r=0.9782^{**}$, n=21) condition. In this experiment condition, conversion factors of 6:1 was obtained from biological nitrogen fixation to soil nitrogen.

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Cooking condition for shelling process of raw oyster and contents of nitrogenous compounds in the cooked-released fluid of oyster (굴 가공 부산물의 이용에 관한 연구 (II) -통조림 원료 굴의 탈각 자숙조건과 자즙중의 질소화합물의 함량분포-)

  • KIM Jeung-Keun
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.8 no.2
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    • pp.101-106
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    • 1975
  • Following the previous report(Kang et al, 1974), the conditions of cooking for shelling process of oyster were discussed, and the content of nitrogenous compounds in the cooked-released fluid of oyster by different cooking conditions has been investigated. The heating condition of $110^{\circ}C$ and 15 minutes was adequate for effective shelling and the condition of meat content in cooking of oyster. The contents of total nitrogen, protein nitrogen, nonprotein nitrogen and amino-nitrogen were seemed to be increased with heating time, and the tendency was to be more exact in the cooking condition of $110^{\circ}C$. The content of nitrogenous compounds at the cooking condition of $110^{\circ}C$ and 15 minutes was determined: total nitrogen, $225.6\;mg\%$ protein nitrogen, $54.4\;mg\%$; amino-nitrogen, $89.2mg\%$. The content of free amino acid was also analysed: arginine, $26mg\%$; histidine, $12.1mg\%$; tyrosine, $2.7mg\%$; leucine, $2.2mg\%$; lysine, $1.9mg\%$ Trace amounts of glutamic acid, isoleucine, serine, threonine, and glycine were detected.

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Multivariate Analysis and Gas Chromatographic Determination of the Smelly Nitro Compounds in Dried-Fishes (GC에 의한 건어물 냄새성분중 질소화합물 분석과 다변량해석)

  • Bae, Sun Young;Lee, Dong Sun
    • Journal of the Korean Chemical Society
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    • v.41 no.2
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    • pp.105-112
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    • 1997
  • The smelly nitro compounds were extracted from dried fishes by simultanous distillation and extraction, then were analyzed by GC-MS. Carbon number and order of an amine could be predicted by using retention time and equivalent chain length. Anchovy, codfish, imitation crab meat, cuttle fish, file fish, pollack, shrimp, octopus, harvest fish, and hard-shelled mussel were used for this investigation. Various smelly nitro compounds such as methylamine, acetamide, thiazole, 2-hydroxy isopropylamine, N-methyl pyrroline, piperidine, cyclohexylamine were identified, however, dimethylamine, trimethylamine, diethylamine were not detected. Principal components analysis was applied to GC-MS profiles for pattern recognition of smelly nitro compounds in dried fishes. Multivariate aspects using principal components analysis were very useful for pattern recognition of smelly components, category similarity.

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Visualization of Cryogenic Nitrogen Spray from a Pintle Injector (초저온 질소 분사 핀틀 인젝터 분무의 가시화)

  • Lee, Keonwoong;Son, Min;Shin, Dongsoo;Yoon, Youngbin;Kim, Jeong Soo;Koo, Jaye
    • Journal of the Korean Society of Propulsion Engineers
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    • v.21 no.2
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    • pp.41-47
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    • 2017
  • By using liquid and gaseous nitrogen as simulants, effects of pintle opening distance and simulant supplying condition on spray from pintle injector were investigated qualitatively. The experiment was performed by fixing the liquid supply pressure and varying the opening of the pintle and the supply pressure of gaseous nitrogen. Shadowgraph method with CCD camera was used for image visualization, and the differences of liquid-gas spray were compared by image post processing. In case of liquid nitrogen single injection, as the opening distance was increased, the injection speed was decreased. Therefore, the end of liquid sheet were converged to the center of spray. In the case of liquid nitrogen/Gaseous nitrogen spray, although shadowgraph images look similar to each other, It is shown that it can be analysed by image post processing.

A study on the mechanism of NO-induced apoptosis in human gingival fibroblast (사람 치은 섬유아세포에서 산화질소 유도 세포고사에 대한 연구)

  • Kim, Kang-Moon;Chung, Hyun-Ju;Kim, Won-Jae
    • Journal of Periodontal and Implant Science
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    • v.34 no.4
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    • pp.807-818
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    • 2004
  • 산화질소는 생리적 농도에서 세포내 신호전달자로 작용하지만 높은 농도에서는 세포독성을 일으킨다. 최근 치은 섬유아세포와 치주인대 섬유아세포는 산화질소 합성효소를 가지고 있고 세균의 lipopolysaccharide나 cytokine에 의해 대량의 높은 농도의 산화질소가 합성된다는 보고가 있음에도 지금까지 치은 조직에서 산화질소의 세포독성에 대한 연구는 아직 이루어 지지않고 있다. 본 연구는 사람의 치은 섬유아세포에서, 산화질소유도세포 고사기전을 밝히는데 목적이 있다. 세포 생장력은 MTT 방법으로 측정하였고, 세포의 형태적 변화는 Diff-Quick 염색법으로 조사하였다. Bcl-2 famly와 Fas 발현 정도는 RT-PCR 방법에 의해 확인하였으며, caspase-3, -8 와 -9의 활성은 spectrophotometer로 reactive oxygen species (ROS)는 형광분광계에 의해 측정되었다. 미토콘드리아에서 세포질로 분비된 cytochrome c는 western blot으로 조사하였다. 산화질소 유리제인 sodium nitroprusside (SNP) 처리는 사람 섬유아세포의 생존률을 시간과 농도 의존적으로 감소시켰고, 세포용적축소, 염색사 용축, DNA 절편화를 일으켰다. 또한, SNP 처리로 미토콘드리아에서 세포질로 유리되는 cytochrome c 양이 증가되었고, caspase-9 과 caspase-3 의 활성이 증가되었다. 한편, SNP 처리에 의해 death receptor 구성요소인 Fas 발현이 증가되었고, caspase-8의 활성이 증가되었다. Bcl-2 family 에 대한 RT-PCR 분석결과, 세포고사를 억제하는 Bcl-2 발현은 감소되었으나 세포고사를 자극하는 Bax와 Bid의 발현은 증가되었다. Soluble guanylate cyclase 억제제인 ODQ는 SNP에 의한 세포 생존율 감소를 차단하지 못했다. 따라서, 본 실험의 결과들은 사람 섬유아세포에서 산화질소유도 세포고사에 Bcl-2 family나 ROS가 매개하는 미토콘드리아 의존 및 death receptor 의존 세포고사기전이 관여함을 시사하였다.