• Title/Summary/Keyword: 질소분석

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Characteristics of reoxidation of nitried oxide for gate dielectric of charge trapping NVSM (전하트랩형 NVSM의 게이트 유전막을 위한 질화산화막의 재산화특성에 관한 연구)

  • 이상은;한태현;서광열
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.11 no.5
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    • pp.224-230
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    • 2001
  • The characteristics of $NO/N_2O$ annealed reoxidized nitrided oxide being studied as super thin gate oxide and gate dielectric layers of Non-Volatile Semiconductor Memory (NVSM) were investigated by Dynamic Secondary Ion Mass Spectrometry (D-SIMS), Time-of-Flight Secondary Ion Mass Spectrometry (ToF-SIMS), and Auger Electron Spectroscopy (AES). The specimen was annealed by $NO/N_2O$ after initial oxide process and then rcoxidized for nitrogen redistribution in nitrided oxide. Out-diffusion of incorporated nitrogen during the wet oxidation in reoxidation process took place more strongly than that of the dry oxidation. It seems to indicate that hydrogen plays a role in breaking the Si N bonds. As reoxidation proceeds, incorporated nitrogen of $NO/N_2O$ annealed nitrided oxide is obsen-ed to diffuse toward the surface and substrate at the same time. ToF-SIMS results show that SiON species are detected at the initialoxide interface, and Si,NO species near the new $Si_2NO$ interface that formed after reoxidation. These SiON and $Si_2NO$ species most likely to relate to the origin of the state of memory charge traps in reoxidized nitrided oxide, because nitrogen dangling bonds of SiON and silicon dangling bonds of $Si_2NO$ are contained defects associated with memory effect.

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Seasonal Change in Inorganic Nitrogen Content in the Soil Profile of Urea-Fertilized Grassland (요소(尿素)(Urea)를 시용(施用)한 초지(草地)의 토양단면(土壤斷面)에서 무기태질소(無機態窒素) 함량(含量)의 계절적(季節的) 변화)

  • Yun, Sun-Gang;Yoo, Sun-Ho
    • Korean Journal of Soil Science and Fertilizer
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    • v.24 no.3
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    • pp.171-176
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    • 1991
  • Field experiment was conducted to investigate the seasonal change in inorganic nitrogen content in grassland soil profile after urea application. Urea was applied at the levels of 0 (0N), 14 (14N), and 28 (28N) Kg N per 10a. Soil samples were taken at every 20 cm interval upto 100 cm soil depth in spring (May 26), summer (July 27), and autumn (October 18) and analysed for total and inorganic nitrogen ($NH_4-N$ and $NO_3-N$). The results obtained are as follows ; 1. In spring, the $NH_4-N$ content of ON treatment was higher than $NO_3-N$ content both in surface and subsoil. The urea application increasing both $NH_4-N$ and $NO_3-N$ contents in the surface soils and these contents decreased with soil depth. 2. In summer, increase in urea application rate elevated the $NO_3-N$ content in soil profile of 0 to 100cm and the content reached upto 42 ppm in the 28N treatment. 3. The seasonal difference in $NH_4-N$ content between summer and autumn was insignificant throughout soil profile. Soil $NO_3-N$ content in autumn were 7 and 14 ppm for 14N and 28N respectively, showing very low values compared with that of summer. 4. The ratio of inorganic nitrogen to total nitrogen increased with soil depth and with urea application rates.

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Effects of Rice Straw on the Microflora in Submerged Soil -III. Microflora in Relation to Nitrogen Fixation and Acetylene Reducing Activity (볏짚시용(施用)이 논토양(土壤)의 미생물상(微生物相)에 미치는 영향(影響) -III. 질소고정(窒素固定)에 관여(關與)하는 미생물상(微生物相)과 질소고정능(窒素固定能))

  • Kim, Yong-Woong;Kim, Kwang-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.17 no.4
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    • pp.399-405
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    • 1984
  • The results of these experiments which were carried out to investigate the effects of rice straw for nitrogen metabolism and acetylene reducing activity, during rice plants were cultured under the percolated condition, are as follows. Azotobacter had tendency to increase with the passage of time, but decreased when rice straw was added. Population change of Clostridia was little as rice grew. Blue green algae increased until heading stage but decreased after the stage. And the application of rice straw increased the number of microorganisms. Thiorhodaceae were never detected, but yeast tended to increase slightly with passing time. Acetylene reducing activity was increased with increasing the number of nitrogen fixing microorganisms, and nitrogen fixing activity was between 0.2kg N/10 a and 0.4kg N/10 a during the growing season of rice plants. Though acetylene reducing activity was promoted by the use of rice plants on non-plant area, but the activity was not clearly affected by percolation.

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Various Nitrogen Efficiencies and their Interrelation Among Rice Varieties (수도품종간(水稻品種間) 여러 질소효율(窒素効率)의 상호관계(相互關係))

  • Park, Hoon;Mok, Sung Kyun
    • Korean Journal of Soil Science and Fertilizer
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    • v.9 no.2
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    • pp.83-92
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    • 1976
  • The relationships between various nitrogen efficiencies among 57 rice cultivars grouped into three developmental categories were investigated by simple correlation with (12kg/10a) and without nitrogen fertilizer under the field condition. The relationship showed similar in a group or among all varieties of three groups. Yield among varieties showed highly significant correlation with Fe (fertilization efficiency: yield increment/nitrogen applied), E (nitrogen efficiency for yield), Ef(efficiency of nitrogen derived from fertilizer) and Eu (fertilizer use efficiency: nitrogen derived from fertilizer divided by total nitrogen applied). The E was correlated significantly and positively with harvest index (HI), percent translocation (T) of nitrogen to ear and negatively with nitrogen uptake amount (N), nitrogen concentration in grain (GN%) and in straw (SN%). The E depends almost on Ef and only inTongil group partly on Es (efficiency of nitrogen derived from soil). The Ef contributes to Fe more than Eu does (Fe = $Ef{\cdot}Eu$). It appears that Ef and Eu increased from the old group to the recommended local varieties, but only EF and Es increased markedly when rice was developed from recommended local group to Tongil line ($indica{\times}japonica$ hybrid selction). The fact that E and Fe depend more on Ef among rice varieties is very good contrast to the result that E and Fe depend more on Es and Eu respectively among soils in the previous investigatigation. The Ef appears as the most important parameter for rice varietal selection under fertilizer application system.

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Relationship between Cucumber Yield and Nitrate Concentration in Plastic Film House with Ryegrass Application (호밀이 투입된 오이 시설재배지에서 수량과 토양용액의 질산태질소과의 관계)

  • Lee, Chang Hoon;Lim, Tae Jun;Kang, Seong Soo;Kim, Myung Sook;Kim, Yoo Hak
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.6
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    • pp.943-948
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    • 2012
  • This study was conducted to estimate the effect of nitrogen reduction by applying ryegrass and to determine the relationship between yield and nitrate concentration of soil solution for cucumber cultivation in plastic film house. Nitrogen levels with recovery of ryegrass ($42.3Mg\;ha^{-1}$) was 0, 50, 75, 100 % of 199 kg N $ha^{-1}$ as N recommendation by determining soil EC value. Yield and nitrate concentration in soil solution was investigated during cucumber cultivation. Yields of N treatments applied ryegrass showed 64.3, 70.9, 70.3, and $76.5Mg\;ha^{-1}$, respectively, it could reduce about 25-50% of nitrogen application compared to yield ($68Mg\;ha^{-1}$) of NPK plot applied 199 kg N $ha^{-1}$. Nitrate concentration in soil solution was average 26.0, 30.1, 41.4, $58.5mg\;L^{-1}$ during cucumber cultivation and was related between yield and average nitrate concentration of soil solution following as; $Y=49.3+0.63X+0.0034X^2$ ($R^2=0.778^{**}$). However, it needs to conduct extra-experiment due to high variation of nitrate concentration during cultivation periods.

Growth, Deficiency Symptom and Tissue Nutrient Contents of Leaf Perilla (Perilla frutesens) as Influenced by Nitrogen Concentrations in the Fertigation Solution (질소 시비농도가 잎들깨의 생육, 생리장해 발현 및 무기원소 함량에 미치는 영향)

  • Choi, Jong-Myung;Park, Jong-Yoon
    • Journal of Bio-Environment Control
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    • v.16 no.4
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    • pp.365-371
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    • 2007
  • Objective of this research was to investigate the effect of nitrogen concentrations in the fertilizer solution on growth and development of nutrient deficiency in leaf perilla (Perilla frutesens). The nutrient concentrations in above-ground plant tissue, petiole sap and soil solution of root media were also determined. Nitrogen deficiency resulted in dwarfed growth, small leaves, and bright yellow color of older leaves. The leaves of deficient plants became uniform yellowing in color and finally necrosis occurred on the deficient leaves. Elevation of N concentrations in the fertigation solution from 0 to 20 mM increased the crop growth in leaf length and width as well as fresh and dry weights of above ground plant tissue. That also resulted in the increase of chlorophyll contents. However, light toxicity symptoms such as abnormal leaf surface appeared on crops grown in 20 mM N fertilization. The plant growth was commercially acceptable in the treatments of 10 and 15 mM N. The plants with acceptable growth had 0.9 to 1.25% in N contents of above-ground plant tissue, 800 to $3,300mg{\cdot}kg^{-1}$ in the $NO_3-N$ concentrations of petiole sap, and 28.7 to $47.3mg{\cdot}kg^{-1}$ in the $NO_3-N$ concentrations of soil solution (1:2 extract) at 75 days after transplanting.

Field Application of a Continuously Aerated Bio-Reactor (CABR) for the Treatment of Swine Wastewater (양돈분뇨처리에 있어서 연속폭기배양조(CABR)의 현장적용연구)

  • Lee, Myung-Gyu
    • Journal of Animal Environmental Science
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    • v.1 no.1
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    • pp.55-64
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    • 1995
  • A wastewater purifying system using phototrophic bacterium, Rhodopseudomonas capsulata, is currently in operation in several countries, One of them, is a continuously aerated bioreactor(CABR) system, which treats concentrated swin wasterwater using small amounts of phototrophic bacteria as additive bacterial seeding. Using this plant, total biochemical oxygen demand was decreased to 13%, and most of volatile fatty acids were removed. About 40% of the wastewater(Influx) was evaporated during aerobic digestion for 24h, and 60% of that erupted in a decodorized foam(Efflux). The efflux had enough nutrients, N, P and K kor growing plant, as well as organic matters. When the efflux was applied to Italian ryegrass with high dose, fresh shoot and root weights were significantly greater, and $NO_3-N$ contents of the dried shoot were lower than those of control plant (CDU). These results indicate that the CABR plant is useful for reduction and deodorization of swine wastewater and the efflux from CABR can be used for crop production as an organic fertilizer.

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Factors Regulating the Nitrogen Fixation Activity and Growth of Anabaena variabilis ATCC 29413 (Anabaena variabilis ATCC 29413 의 생장과 질소고정활성의 조절요인)

  • 송승달;한동훈
    • Korean Journal of Microbiology
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    • v.30 no.5
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    • pp.391-396
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    • 1992
  • Anabaena variabilis A TCC 29413. a photoautotrophic and nitrogen fixing cyanobacteria. was investigated on the environmental factors regulating the growth and nitrogen lixation activity. A good growth of cyanobacteria] cells was observed due to nitrogen t1xation by the heterocyst differentiation in nitrogen free Allen and Arnon (]/8) medium. The nitrogenase activity was appeared to be in proportion to the cell growth lor 6 days then drastically decreased in the later growth period when the nitraTe was accumulated to high level in the culture to cause the inhibition. The optima] conditions lilr the cell growth and nitrogenase activity of A. varillbili.l were anaerobic. IO.OO0 lux. $30^{\circ}C$ and pH 8 with the nitrogen Cree minimal medium. The activity was significantly inhihited by the low concentrations of ammonium and nitrate. but was stimulated b) the ]ow Ieve] of phosphate and carbonate sources. The treatments of several toxic heavy metals showed strong inhibition of the cell growth and nitrogenase activity by O.3~10 ppm in the order of $Hg^{2+}$ > $Cd^{2+}$ > $Co^{2+}$ > $Zn^{2+}$ > $Ph^{2+}$, and the concentrations for 50% inhibition of the maximum activity were 0.41. 0.47. 0.5 L 0.66 and 8.1 ppm. respectively. The addition of carbohydrates (0.5~ 1.0%) in the dark condition stimulated the growth and activity in the order of sucrose > fructose > glucose.

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Relationship Between Soil Properties and Tip Burn of Chinese Chive Cultivated in Plastic Film House (시설재배 부추 잎끝마름증 발생에 영향을 미치는 토양특성)

  • Seo, Young-Jin;Choi, Young-Seub;Park, Jun-Hong;Kweon, Tae-Young;Choi, Seong-Yong;Kim, Chan-Yong;Kim, Jong-Su;Park, So-Deuk;Park, Man;Jeon, Sang-Ho;Jang, Yong-Sun;Ha, Sang-Keun
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.3
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    • pp.380-386
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    • 2011
  • Tip burn has been reported as one of the most serious physiological disorder in Chinese chives (Allium tuberosum Rottl.) cultivated in plastic film house. In this study, a physiography and chemical properties of 132 plastic film house soils were investigated to elucidate factors affecting tip burn symptom. Also influence of soil properties on tip burn was statistically determined by path analysis and association analysis including a chi-square test or logistics analysis. Probability distribution of inorganic aqueous species, such as ammonia (g) was calculated using MINTEQ program. Soil order and chemical properties, especially pH, exchangeable calcium and inorganic nitrogen, showed a significant relationship with tip burn of Chinese chives. Tip burn symptoms occur mainly in an alkaline soil classified as Alfisols. Result of linear regression and path analysis exhibited that formation of ammonia (g) from soil solution depend upon soil pH and were associated with ammonium resulting from soil organic matter or nitrate. These results indicate that tip burn symptom of Chinese chives is directly affected by ammonia gas originated from alkaline soil condition.

Nitrogen Leaching and Balance of Soils Grown with Cabbage in Weighing Lysimeter (중량식 라이시미터에서 배추 재배에 따른 질소 용탈과 수지)

  • Lee, Ye Jin;Ok, Jung Hun;Lee, Seul Bi;Sung, Jwa Kyung;Song, Yo Sung;Lee, Deog Bae
    • Korean Journal of Environmental Agriculture
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    • v.37 no.3
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    • pp.166-171
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    • 2018
  • BACKGROUND: Nitrogen leaching depends on the drainage pattern and nitrate content, and those are influenced by soil hydraulic properties and fertility. The purpose of this study was to confirm how soil texture contributed to leaching and balance of nitrogen, as well as to drainage. METHODS AND RESULTS: This study was performed using undisturbed weighing lysimeters which were piled up with clay loam (Songjung series) and sandy loam (Sanju series) soils in National Institute of Agricultural Science experimental field. Chinese cabbage was cultivated from August 30 to October 31, 2017. The application rates of N, $P_2O_5$, and $K_2O$ were 21.5, 7.8, and $15.0kg\;10a^{-1}$, respectively, and irrigation was supplied at -33 kPa in 30 cm soil depth. Drainage in clay loam was not noticeable, although it was increased by rainfall in early September. By contrast, the trend of drainage in sandy loam was strongly dependent upon rainfall pattern. Owing to different drainage patterns between both soil textures, nitrogen leaching was 5-fold higher in sandy loam than in clay loam. Nitrogen use efficiencies in clay loam and sandy loam were represented as 43% and 52%, respectively. CONCLUSION: The pattern of drainage and nitrogen leaching were greatly depended on clay content in soil. From this study, we carefully suggest that soil texture should be considered as an incidental factor to estimate nitrogen balance.