• Title/Summary/Keyword: 질산화반응

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Change of Sludge Denitrification and Nitrification Rate according to the Operating Conditions in Advanced Wastewater Treatment Processes (하수고도처리공법의 유입하수량 변화에 따른 슬러지 질산화/탈질속도 변화)

  • Lee, Myoung-Eun;Oh, Jeongik;Park, No-Suk;Ko, Dae-Gon;Jang, Haenam;Ahn, Yongtae
    • Membrane Journal
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    • v.28 no.1
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    • pp.31-36
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    • 2018
  • The purpose of this study is to investigate the changes of sludge characteristics according to the changes of influent sewage flowrate in the advanced wastewater treatment processes including MBR, SBR, and $A_2O$. The ratio of the actual sewage flowrate to the design flowrate is decreased from 100% to 70, 40%, and 10%, and the specific denitrification rate and ammonia oxidation (nitrification) rate was measured. The specific nitrification rate of the sludge collected from the aeration tank of each process was measured at a similar value ($0.10gNH_4/gMLVSS/day$) in all three process under the condition of 100% of sewage flowrate. It has tended to decrease significantly as the sewage flowrate decreased from 70% to 40%. The specific denitrification rate was also decreased by ~50% as the sewage flowrate decreased. However, considering the total nitrogen concentration in the influent and the microbial concentration in the reactor, the changes in kinetic parameter did not affect overall nitrogen removal. Therefore, it can be concluded that stable nitrogen removal will be possible under low influent flowrate condition if the MLVSS concentration is kept high.

Improvement of Nitrification Efficiency by Activated Nitrifying Bacteria Injection at Low Temperature (활성화된 질산화균 주입에 의한 저온 질산화효율 향상)

  • Lim, Dongil;Kim, Younghee
    • Journal of the Korean Society of Urban Environment
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    • v.18 no.4
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    • pp.473-483
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    • 2018
  • In this study, we have developed a lab scale bioreactor to identify the characteristics of nitrification reaction according to operation condition (temperature, inhibitor (as Cl), activated nitrifying bacteria (ANB). etc) to improve nitrification efficiency at low temperature. Recovery rate of nitrification took about 4 days to reach the normal level by injected ANB after inhibition shock of CI injection at $20^{\circ}C$, when measured the concentration of $NO_2{^-}-N+NO_3{^-}-N$ in the effluent. In the case of $10^{\circ}C$, recovery of nitrification rate took about 4 days to reach the level of half to the normal level and 7 days for complete recovery which took 3 days more than those at $20^{\circ}C$. At $10^{\circ}C$ considering the winter season, the specific nitrification rate(SNR) of the from 1 day to 6 days after injected ANB according to its operation condition increased from 0.029 to 0.767 mgN/gSS/hr. The simulated SNR for the 8th day after the injected ANB at $10^{\circ}C$ was 0.840, 3.625 mgN/gSS/hr, respectively as linear function and exponential function, expecting to exceed level of 2.592 mgN/gSS/hr at normal condition. It was confirmed that injection of ANB during low temperature operation has many effects for improving nitrification efficiency through this study. In future studies, if further studies are carried out the determination of ANB injection and the design of efficient ANB reactor considering the changes of operating characteristics by site, it will contribute to the improvement of nitrification efficiency in winter season.

Applicability of Theoretical Adsorption Models for Studies on Adsorption Properties of Adsorbents(II) (흡착제의 흡착특성 규명을 위한 흡착모델의 적용성 평가(II)-흡착속도론을 중심으로)

  • Na, Choon-Ki;Park, Hyun-Ju
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.11
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    • pp.804-811
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    • 2011
  • The aim of this study is to evaluate the applicability of adsorption models for understanding adsorption properties of adsorbents. For this study, the adsorption charateristics of $NO_3^-$ by commercial anion exchange resin, PA-308, were investigated in bach process. The adsorption kinetic data for $NO_3^-$ by anion exchange resin showed two stage process comprising a fast initial adsorption process and a slower second adsorption process. Both the pseudo-first-order kinetic model and the pseudo-second-order kinetic model could not be used to predict the adsorption kinetics of $NO_3^-$ onto anion exchange resin for the entire sorption period. Only the fast initial portion ($t{\leq}20min$) of adsorption kinetics was found to follow pseudo-first-order kinetic model and controlled mainly by external diffusion that is very fast and high, whereas, the slower second portion (t > 20 min) of adsorption kinetics seems to be controlled by a second-order chemical reaction and by intraparticle diffusion.

Culture of Nile Tilapia (Oreochromis niloticus) in Recirculating Aquaculture System (순환여과식 양식 시스템에서 나일 틸라피아(Oreochromis niloticus)의 사육)

  • Seo Kuen Hack;Kim Byong Jin;Jo Jae Yoon
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.35 no.1
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    • pp.27-34
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    • 2002
  • The performances of fish culture were evaluated in the integrated recirculating aquaculture system consisting of a double drain type rearing tank ($2.5 m^3$), a sedimentation tank, a floating bead filter, a foam separator and a rotating biological contactor. A system was stocked with nile tilapia at an initial rearing densities of $5\%$ (A), $5\%$ (B) and $7\%$ (C) oyer 30 days. Feed coefficient was 1.62, 1,79 and 1.80 and average daily growth rate was $0.452\%$, 0.u5% and $0.423\%$, respectively. The level of TAN was maintained below $1 g/m^3$ for $5\%$ of initial rearing density and $2-4 g/m^3$ for $7\%$. The dissolved oxygen level ($2-4 g/m^3$) was not optimum but should not be inhibitory to fish growth. The total suspended solid was completely removed during overall experimental period.

Influence of Ammonia and Dissolved Oxygen Concentrations on Nitrite Accumulation in a MBR (MBR 반응조에서 아질산염 축적에 미치는 암모니아와 용존산소 농도의 영향 연구)

  • Choi, In-Su;Wiesmann, Udo
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.8
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    • pp.922-929
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    • 2007
  • The complete oxidation of ammonia to nitrate is a distinctive two-step process divided into the oxidation of ammonia to nitrite(nitritation) by Nitrosomonas and the oxidation of nitrite to nitrate(nitratation) by Nitrobacter. The nitrogen removal via nitrite accumulation offers several advantages such as saving costs for aeration, saving carbon source and finally reduction of sludge discharge. In this work a suspended bioreactor coupled with membrane filtration(MBR) was used to find the process conditions of nitrite build-up. The MBR enables to reach sufficient nitrifying bacteria in the bioreactor, although the autotrophic bacteria can be easily washed out due to their lower growth rate. The dissolved oxygen concentration $c'_{O2}$ and ammonia concentration $c_{NH3}$ in the reactor were varied and investigated as parameters for nitrite accumulation. As a result the higher ammonia concentration in the reactor is very effective for starting nitrite build-up and the effect was strengthened in combination with lower dissolved oxygen concentration. With lower $c'_{O2}<0.3$ $mgL^{-1}$ $O_2$ and high $c_{NH3}=6.3\sim14.9$ $mgL^{-1}$ $NH_3N$ the 74% of the nitrite accumulation was achieved. Specially, it was found that the nitrite accumulation could occur not only in biofilm reactor as many references showed but also in the membrane bioreactor carried out in this study.

부유상의 Batch식 배양에서의 암모니아 및 아질산염의 제거특성

  • Jo, Sun-Ja;Jeong, Yong-Ju;Lee, Na-Eun;Son, Hyeong-Sik;Cha, Mi-Seon;Lee, Sang-Jun
    • 한국생물공학회:학술대회논문집
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    • 2003.04a
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    • pp.348-350
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    • 2003
  • Using acclimated sludges with inorganic nitrogen medium for three months and raw sludges, we investigated characteristics of biological nitrogen removal. As results, the acclimated sludges accomplished nitrification efficiently. But raw sludges have hardly done ammonium-nitrification and there was a increasing of ammonium concentration in flask with raw sludges for established experimental period of 72 hrs.

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무산소-호기공정을 이용한 순환식 생물여과반응기에서 동시 질산화 및 탈질화의 특성 연구

  • Lee, Su-Cheol;Kim, Dong-Jin
    • 한국생물공학회:학술대회논문집
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    • 2000.04a
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    • pp.343-346
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    • 2000
  • This study was carried out to investigate the effects of influent $NH_4^{\;+}-N$ load, C/N ratio and superficial air velocity on the nitrogen removal efficiencies. Laboratory scale upflow biological aerated filter(BAF) was consisted of an anoxic-aerobic filter packed with porous ceramic media and operated with synthetic wastewater. BAFs requires less energy and space for the system when compared to conventional activated sludge process. The influent C/N ratios were varied from 0 to 1 by adjusting acetate. Various superficial air velocity had been applied to investigate aeration effect on nitrogen removal. The BAF reactor showed more than 90% average $NH_4^{\;+}-N$ removal efficiencies at $NH_4^{\;+}-N$ loading in the range of $0.26{\sim}1.33$ kg $NH_4^{\;+}-N/m^3{\cdot}d$ and 62% average T-N removal efficiencies at the C/N ratio of 1. Moreover, average T-N removal efficiencies increased as the superficial air velocity increased, because of the increase $NH_4^{\;+}-N$ removal efficiencies.

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Removal Characteristics of COD and Nitrogen by Aerated Submerged Bio-film(ASBF) Reactor (ASBF 생물반응기를 이용한 COD 및 질소 제거특성)

  • Choi, Young-Ik;Jung, Byung-Gil;Son, Hee-Jong;Sung, Nak-Chang
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.9
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    • pp.997-1002
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    • 2007
  • The objectives of this research are to remove dissolved organic matter and nitrogen compounds by using aerated submerged bio-film(ASBF) reactors in batch systems and improve understanding of dissolved organic matter and nitrogen compounds removal rates with dynamic relationships between heterotrophic and autotrophic bacteria in the fixed-film reactor. This research explores the possibility of enhancing the performance of shallow wastewater treatment lagoons through the addition of specially designed structures. These structures are designed to encourage the growth of a nitrifying bacterial bio-film on a submerged surface. Specially, the effects of cold temperatures on the dissolved organic matter and ammonia nitrogen performance of the ASBF pilot plant was investigated for the batch system. It is anticipated thai the ASBF would be used for a design of biological treatment for removing of dissolved organic matter and nitrogen compounds in new wastewater treatment plants as well as existing wastewater treatment plants.