• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.105.1-105.1
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• 2010

바이오디젤 보급 활성화에 따른 식물성 원료유의 가격 상승 및 수급 불안정성 문제를 해결하고자 폐유지를 원료로 바이오디젤을 생산하고자 하는 시도가 이루어지고 있다. 폐유지의 사용은 폐자원 활용 측면에서 의미가 있으며 바이오디젤 생산 단가를 낮출 수 있다. 다양한 폐유지가 산업체로부터 배출되며 이 중에서 dark oil은 식용유 공장에서 식물성 원료유의 정제 과정에서 생기는 부산물로 바이오디젤로 전환 가능한 성분을 포함하고 있다. 본 연구에 사용된 dark oil은 54.9%의 유리지방산과 28.0%의 triglyceride, 4.4%의 diglyceride, 그리고 1% 이하의 monoglyceride를 함유하고 있다. Dark oil의 초기 산가는 109.8 mg KOH/g이었다. 본 연구에서는 dark oil의 유지 부분(triglyceride, diglyceride, monoglyceride)을 유리지방산으로 전환시켜 HAAO(high acid acid oil)을 생산한 후, 고체 산 촉매에 의한 에스테르화 반응을 통하여 바이오디젤을 생산하고자 하였다. 유지 부분의 유리지방산 전환 반응을 위하여 음이온성 계면활성제인 SDBS(sodium dodecyl benzene sulfonate)가 사용되었다. Dark oil:황산:물의 질량비가 10:2:10이고 SDBS가 오일 대비 3%인 조건에서 dark oil의 산가는 190.8 mg KOH/g까지 증가하였고, dark oil:황산:물의 질량비가 10:4:10이고 SDBS가 2%인 조건에서는 산가가 194.2 mg KOH/g까지 증가하였다. 생산된 HAAO을 이용하여 오일 대비 30%의 Amberlyst-15 촉매 하에서 HAAO:메탄올 몰비 1:9인 조건에서 에스테르화 반응을 수행하였을 경우 FAME(fatty acid methyl ester) 함량은 81.3%까지 증가하였다. 고체 산 촉매로써 Amberlyst-15와 가격 면에서 저렴한 PC101을 비교하였을 경우 FAME 함량은 각각 80.7%, 77.9%로 비슷한 효율을 나타내었다. 생산된 바이오디젤의 FAME 함량을 높이기 위해 증류 공정을 필요로 하였다.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.34 no.6
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• pp.629-634
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• 2010

Natural gas is a promising alternative fuel that can be used to satisfy the strict engine emission regulations in many countries. To develop natural-gas engines, low emission, efficient fuel consumption, and increased power ratings have to be realized. In this study, a cylindrical constant-volume combustion chamber (CVCC) was used to investigate natural-gas combustion characteristics for different prechamber design parameters and equivalence ratios. In particular, the maximum combustion pressure and mass fraction of the burned gas were evaluated by considering orifice diameter, volume ratio of prechamber and equivalence ratio. Using this result and by analyzing the changes in combustion characteristics with variations in design parameters, the optimum prechamber parameters were determined.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.11 no.4
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• pp.45-54
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• 1991

The closed forms of mass matrix with rotational inertia matrix are developed for free vibration analysis in space structures containing linearing tapered members with cross section of thin-walled tube. The exact displacement functions are used for formulating mass matrix. The very small slopes of the tapered member are used in usual practice, such that the series expansion forms of these are also developed to avoid numerical failure in vibration analysis. Significant improvements of accuracy and efficiency of free vibration analysis are achieved by using the mass matrices developed in this study. Frequencies of free vibration of tapered members are compared with solutions based upon stepped representation of beam element.

• Transactions of the Korean Society of Mechanical Engineers
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• v.15 no.6
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• pp.2015-2025
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• 1991

A long and light-weight forearm of the vertical 2 DOF robot manipulator with a heavy payload driven by parallel drive mechanism is modelled as a Euler-Bernoulli beam with a tip mass subjected to a high speed rotation. Governing equation is obtained by Hamilton's principle and represented as state variable form using the perturbed variables which describe the perturbed errors at the manipulator's final configuration. Digitial optimal control and observer theory are used to suppress the forearm vibration and control the positions of the joint angles with measured/estimated state feedback. Computer simulations and experimental results are obtained and compared each other.

• Journal of the Korea Convergence Society
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• v.11 no.10
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• pp.225-229
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• 2020

In this study, the deformation and stress on each model was analyzed and the strength was compared with each other when the impacts on a total of four smart phone models was given. Models B and D with cases can be seen to have less deformation and stress than models A and C without cases. The models including the case have higher masses than the models without the case. So, the deformation and stress can be reduced by absorbing the impact force. In addition, the masses of models C and D are smaller than models A and B, but the stresses and deformations are seen to be smaller. If a case specialized for edge protection is chosen and designed when manufacturing a smart-phone in order to absorb the shock while weighing less, it is thought to improve the strength of the smart-phone and increase the durability. And it is seen that this study is adequate at the efficient design with durability of smart phone case practically and the aesthetic convergence of smart phone.

• Analytical Science and Technology
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• v.13 no.3
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• pp.297-303
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• 2000

Isotope-dilution inductively coupled plasma mass spectrometry was used to determine trace amounts of Cd, Cu, Pb, Ni and Zn in sediment. Sediment samples were dissolved by microwave digestion with addition of mixed acid ($HNO_3$, HF and $HClO_4$). Lead was determined after separation of alkaline and alkaline earth metals by an ammonium pyrrolidenedithiocarbarmate (APDC) solvent extraction. The other elements were determined after separation of iron, tin and titanium by hydroxide precipitation. Recovery efficiency of the analyte elements was not satisfactory, but most of matrix elements causing the isobaric interference could be effectively eliminated by the separation. Good agreement was achieved with the certified values in the analysis of the two sediment reference materials.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.1
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• pp.238-244
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• 2017

A spindle with a built-in motor can be used to simplify the structure of a machine tool system, but the rotor inevitably has unbalanced mass. This paper presents an analysis of the dynamic behavior. The spindle was used in a CNC lathe and investigated using the finite element method and transfer matrices. The high-speed spindle can be very sensitive to the rotation of an unbalanced mass, which has a harmful effect on many machine tools. Thus, a balancing procedure was performed with a spindle-bearing system for the CNC lathe by numerical analysis. The balancing was performed through the influence coefficient method, and the whirl orbit radii before and after balancing were compared to evaluate the effects. The results show that the rotational speed of the spindle seriously affects the whirl responses of the spindle. The whirl responses were also affected by other factors, such as the unbalanced mass and bearing stiffness. The balancing of the assembled spindle model significantly reduced the whirl orbit magnitude.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.21 no.12
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• pp.2318-2324
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• 2017

Quantum cryptography, which is emerging as a next generation password, is being studied by quantum cryptographic transfer protocols and quantum secret communication. Quantum key transfer protocol can be used in combination with the modern password because of the inefficiency of the use of the password, or the use of OTP(one time password). In this paper an algorithm for direct communication by means of direct cryptographic communications rather than quantum keys. The method of implementing quantum secure direct community was adopted using 2-channel methods using Einstein gravity field. Two channels were designed to adopt a quantum secret communication protocol that applies time delay between 2-channels of channel to apply time difference between 2-channels. The proposed time delay effect reflects the time delay by reflecting the gravitational lensing phenomenon. Gravity generator with centrifugal acceleration is incorporated in the viscometer, and the time delay using this implies the correlation between the variance of the metametry.

• Geophysics and Geophysical Exploration
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• v.5 no.3
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• pp.169-177
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• 2002

We develop the weighted-averaging finite-element method which uses four kinds of element sets. By constructing global stiffness and mass matrices for four kinds of element sets and then averaging them with weighting coefficients, we obtain a new global stiffness and mass matrix. With the optimal weighting coefficients minimizing grid dispersion and grid anisotropy, we can reduce the number of grid points required per wavelength to 4 for a $1\%$ upper limit of error. We confirm the accuracy of our weighted-averaging finite-element method through accuracy analyses for a homogeneous and a horizontal-layer model. By synthetic data example, we reconfirm that our method is more efficient for simulating a geological model than previous finite-element methods.

• Proceedings of the Korean Vacuum Society Conference
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• 1999.07a
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• pp.77-77
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• 1999

박막시료의 분석에는 RBS, XPS, SIMS, AES 등이 주로 이용되고 있으며, 특히 RBS는 비교체가 필요없고 정량성이 좋다는 장점 때문에 중요하다. 그러나 RBS는 원리적으로 경원소에 대한 감도가 낮아 기판원소보다 무거운 질량을 갖는 원소의 분석에만 이용되는 것이 보통이다. 이러한 단점을 보완하기 위해 본 연구에서는 수년전부터 RBS와 비슷한 원리를 갖고 같은 장비를 이용하여 수행이 가능한 경원소 분석법인 TOF-ERDA(Time of Flight Elastic Recoil detection)을 개발하여 실용화 하였다. 본 연구실에서 보유하고 있는 미국 NEC사의 5SDH 가속기는 최대 가속전압이 1.7MV로 Cl5+ 이온을 사용하는 경우 10 MeV가 최대 가속에너지가 된다. 이런 정도의 에너지 범위에서는 TOF spectrometer의 시간분해능이 아주 높을 필요가 없고 비교적 작은 가속기로도 분석이 가능하며, 수소의 검출효율이 우수하다는 점 등 많은 장점이 있다. 그러나 한편으로는 분석가능한 깊이가 수천 $\AA$ 정도로 제한되고 질량 분해능도 수십 MeV 내지 100MeV 이상의 고에너지 이온빔을 이용하는 경우에 비해 떨어진다는 단점이 있다. 또한 묵운 원소의 분석이 불가능하기 때문에 경원소의 분석에 국한하여 적용하고 무거운 원소에 대해서는 RBS를 병용하게 된다. 본 연구에서는 일본 이화학연구소의 선형가속기인 RILAC으로부터 얻은 40MeV Ar 이온 및 138 MeV Xe 이온을 이용하여 TOF-ERDA 시스템을 제작하였다. 그러기 위해서 고에너지 이온의 비행시간을 측정하는 목적으로 높은 시간 분해능을 갖는 시간 검출기를 설계, 제작하였다. 또한 표적함 밑에는 회전원판이 있어 시간검출기 및 에너지 검출기가 중앙의 시료홀더를 중심으로 회전이 가능하도록 되었다. 회전은 표적함 밖에서 원격조정 가능하다. 이렇게 함으로써 검출각을 임의로 바꾸면서 측정이 가능하도록 하였다. 제작된 분석시스템의 성능을 확인하기 위해 YBaCuO 초전도 박막을 측정하였으며 그 결과를 그림에 나타낸다. 저 에너지 ERDA에서는 나타나기 힘든 Ba, Y, Cu 등의 무거운 원소의 피크들이 분명히 나타남을 확인할 수 있다.