• Journal of the Earthquake Engineering Society of Korea
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• v.1 no.3
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• pp.29-35
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• 1997

The megastructure combined with the modular concept is an effcient structural system adequate for ultra-tail buildings for the future. An ingeneous structural control system can be developed by separating the internal subframe in one or many modules from the external megaframe, thus taking advantage of the effect of tuned mass dampers without adding any aditional mass. This so called mega-subcontrol system is generally modeled by a 20DF system for parametric study and for finding optimal values of the parameters. In this study the equation of motion for the system is obtained frist and the preconditions for the simplified modeling are investigated. Finally the optimal value for the subsreucture strffness is fomputed with given mass and damping ratios and transfer functions for responses are abtained for white noise ground exitation to verify the effectiveness of the mega-subcontrol system.

• Journal of the Korean earth science society
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• v.32 no.6
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• pp.586-594
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• 2011

Gravity Recovery and Climate Experiment (GRACE), launched in April, 2002, makes it possible to monitor Earth's mass redistribution with its time-varying gravity observation. GRACE provides monthly gravity solutions as coefficients of spherical harmonics, and thus ones need to convert the gravity spectrum to gravity grids (or mass grids) via the spherical harmonics. GRACE gravity solutions, however, include spatial alias error as well as noise, which requires to suppress in order to enhance signal to noise ratio. In this study, we present the GRACE data processing procedures and introduce some applications of time-varying gravity, which are studies of terrestrial water storage changes, Antarctic and Greenland ice melting, and sea level rise. Satellite missions such as GRACE will continue up to early 2020, and they are expected to be an essential resource to understand the global climate changes.

• Analytical Science and Technology
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• v.27 no.6
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• pp.292-299
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• 2014

Iopromide is an X-ray contrast agent that has been detected frequently with high concentration level in surface waters. Structural characterization of degradation products and measurement of degradation efficiency of iopromide by an electron beam irradiation were performed. For the fortified sample with iopromide, electron beam irradiation (UELV-10-10S, klysotrn, 10 MeV, 1 mA and 10 kW) was performed. The chemical structures of I_D_665 and I_D_663, which are degradation products of iopromide, were proposed by interpretation of mass spectra and chromatograms by LC/ESI-MS/MS. The mass fragmentation pathways of mass spectra in tandem mass spectrometry were also proposed. Iopromide was degraded 30.5~98.4% at dose of 0.3~5 kGy, and 97.8~30% in the concentration range $0.5{\sim}100{\mu}g/kg$ at electron beam dose of 0.3 kGy, respectively. Thus, increased degradation efficiency of iopromide by electron beam irradiation was observed with a higher dose of electron beam and lower concentration.

• Journal of the Korean Chemical Society
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• v.47 no.2
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• pp.137-146
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• 2003

3-Hydroxybenzopyran[3,2-c]-[1]-benzopyran-6,7-diones (3) and 3-methoxycarbonylcoumarin (4) were prepared via condensation of 1 with resorcinol in the presence of sodium methoxide. The chemical behavior of 3 towards acetic anhydride, alkyl halides and diazonium chloride is described. The electron impact ionization mass spectra of compounds 4,5 and 6a,b show a weak molecular ion peak and a base peak of m/z 89, m/z 280. m/z 91 and m/z 120 resulting from a cleavage fragmentation respectively. The molecular ion of compounds 3, 6b, and 7a is a base peak of m/z 280, m/z 366 and m/z 488 respectively. Compound 7a give a characteristic fragmentation pattern with a two very stable fragmentation of m/z 383 and m/z 77.

• Bulletin of the Society of Naval Architects of Korea
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• v.11 no.2
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• pp.23-40
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• 1974

Semisubmersible 해양석유시추선의 기본설계에 필요한 파랑중(波浪中)에서 운동(運動)을 계산(計算)하는 이론적방법(理論的方法)을 제시하고 "MOHOLE"과 "SEDCO 1350-F" 석유시추선들의 운동(運動)을 해석하였다. 이 규칙파에서 운동계산을 불규칙해양파(波)에 적용하는 응용해석을 보여주었다. 현재 이론적 방법으로는 6자유도(自由度)의 운동을 해양파의 어떤 방향에 대해서도 정확히 계산할 수 있으며 계산의 정확성은 수조(水槽)에서의 모형선의 운동측정치와 실선(實船)의 운동측정치와 비교하여 증명되었다. 또 현재의 방법은 종전에 개발된 방법보다 더 일반적(一般的)인 경우를 다룰 수 있으며 결과치도 더 정확하다. 극소운동특성을 갖는 해양석유시추선과 부체(浮體)해양구조물의 설계는 경비가 비싸고 시간이 많이 드는 모형실험보다는 유체역학적(流體力學的) Parameters를 신속 정확히 자주 변경 검토해야 하는 기본설계단계에서는 정확한 이론적인 전자계산기에 의한 계산방법이 절실히 필요하다. 예상(豫想)과 같은 부가질량(附加質量)과 감쇠력(減衰力)은 Resonance 운동주기에서만 운동에 영향을 준다. 해양구조물에 작용하는 파력(波力)은 Froude-Krilov force, 부가질량(附加質量) 및 감쇠력(減衰力)과 Restoring force로 구성했으며 규칙파(規則波)에서의 6자유도(自由度) 운동방정식은 본 논문에 제시된 실험측정치(値)와 실험으로 정확도가 증명된 이론치(値)의 부가질량과 감쇠력 계수(係數)를 써서 풀었다. 규칙파(規則波)에서의 계산된 운동을 Pierson Moskowitz 해양파(海洋波) 스펙트럼과 linear superposition principle에 의해 불규칙해양파(不規則海洋波)에서의 운동을 계산하는데 사용했다. 불규칙파(不規則波)에서의 운동은 운동스펙트럼과 통계적 운동치로 나타냈다. 현재의 계산방법은 실제 기본설게에 사용되어 왔으며, 다른 응용분야는 파랑중(波浪中)에서의 파면(波面)과 Deck간(間)의 Clearance, 계류선(係留線)의 동장력(動張力)계산의 기본 Data 및 기본설계의 Draft 등 Parameters를 통(通)한 Optimum Design 등(等)이다. 파(波)의 한 방향(方向)에 대(對)한 전자계산기(電子計算機)(IBM 370 또는 CDC 6400)에 의한 운동계산은 10초(秒)미만밖에 안걸린다. 또 현재의 계산방법은 해양석유시추선뿐 아니라 이와 비슷한 부체(浮體)해양구조물과 Pipe-laying선(船) 또 Supply Boat설계(設計)에도 쓰여지고 있다.

• Analytical Science and Technology
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• v.21 no.4
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• pp.245-258
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• 2008

Five triterpenic acids as marker compounds were extracted and isolated from Prunellae Spica by column chromatography and reversed-phase high-performance liquid chromatography (HPLC), and their purity was determinated by HPLC (purity ${\geq}90%$). Molecular weight and elemental compositions of the five marker compounds were determined by fast atom bombardment high-resolution mass spectrometry (FAB-HRMS). The structural determination of the five marker compounds was carried out fast atom bombardment collision-induced dissociation tandem mass spectrometry (FAB-CID-MS/MS). The collision-induced dissociation (CID) of protonated molecules $[M+H]^+$ and deprotonated molecules $[M-H]^-$ produced diverse product ions due mainly to retro Diels-Alder reaction (RDA), dehydration and decarboxylation. Moreover, the CID-MS/MS spectra of the $[M-H]^-$ ions were observed charge-remote fragmentation (CRF) patterns. On the basis of interpretation of CID-MS/MS spectra, structural elucidation of triterpenic acids isolated from Prunellae Spica was clearly performed.

• Journal of the Korean Chemical Society
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• v.32 no.6
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• pp.536-542
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• 1988

A nickel(Ⅱ) complex, Ni(IAA-NBz) (IAA-NBz') with ligand, N-benzylisonitrosoacetyl acetone imine (H-IAA-NBz) has been synthesized. This complex is very stable at room temperature and has cis-form and trans-form isomers. The ratio of nickel (Ⅱ) ion and ligand combined is 1 : 2. The elemental analysis, ir, nmr. electronic spectra and mass spectra have been studied. It is suggested from these studies that the isonitroso group of one ligand, H-IAA-NBz coordinates to nickel(Ⅱ)ion through the nitrogen atom to form five-membered ring, while that of the other ligand, H-IAA-NBz coordinates to nickel (Ⅱ) ion through the oxygen atom to form six-membered ring in square-planar complex.

• Journal of the Korean Applied Science and Technology
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• v.33 no.2
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• pp.286-292
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• 2016

1, 2-Hexanediol galactoside (HD-gal) has been synthesized from 1, 2-hexanediol (HD), a cosmetic preservative, using recombinant Escherichia coli ${\beta}$-galactosidase (${\beta}$-gal) at the high lactose concentration (300 g/l). To confirm the molecular structure of synthesized HD-gal, NMR ($^1H$- and $^{13}C$-) spectroscopy and mass spectrometry of HD-gal were conducted. $^1H$ NMR spectrum of HD-gal showed multiple peaks corresponding to the galactocyl group, which is an evidence of galactocylation on HD. Downfield proton peaks at ${\delta}_H$ 4.44 ppm and multiple peaks from ${\delta}_H$3.96~3.58 ppm were indicative of galactocylation on HD. Up field proton peaks at ${\delta}_H$ 1.60~1.35 ppm and 0.92 ppm showed the presence of $CH_2$ and $CH_3$ protons of HD. $^{13}C$ NMR spectrum revealed the presence of 21 carbons suggestive of ${\alpha}$- and ${\beta}$-anomers of HD-gal. Among 12 carbon peaks from each anomers, the 3 peaks at dC 68.6, 60.9 and 13.2 ppm were assigned to be overlapped showing only 21 peaks out of total 24 peaks. The mass value (protonated HD-gal, m/z = 281.1601) from mass spectrometry analysis of HD-gal, and $^1H$ and $^{13}C$ NMR spectral data were in well agreement with the expecting structure of HD-gal. For further study, the minimum inhibitory concentrations (MICs) of HD-gal against bacteria will be investigated, and, in addition, cytotoxicity to human skin cells of HD-gal will be examined. It is expected that it will eventually be able to develop a new cosmetic preservative, which have low cytotoxicity against human skin cell and maintains antimicrobial effect.

• Journal of the Earthquake Engineering Society of Korea
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• v.6 no.4
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• pp.65-73
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• 2002

It has been recognized that the damage control must become a more explicit design consideration. In an effort to develop design methods based on performance it is clear that the evaluation of the nonlinear response is required. The methods available to the design engineer today are nonlinear time history analyses, monotonic static nonlinear analyses, or equivalent static analyses with simulated nonlinear influences. Some building codes propose the capacity spectrum method based on the nonlinear static analysis(pushover analysis) to determine the earthquake-induced demand given by the structure pushover curve. These procedures are conceptually simple but iterative and time consuming with some errors. This paper presents a nonlinear direct spectrum method(NDSM) to evaluate seismic performance of structures, without iterative computations, given by the structural initial elastic period and yield strength from the pushover analysis, especially for MDF(multi degree of freedom) systems. The purpose of this paper is to investigate the accuracy and confidence of this method from a point of view of various earthquakes and unloading stiffness degradation parameters. The conclusions of this study are as follows; 1) NDSM is considered as practical method because the peak deformations of nonlinear system of MDF by NDSM are almost equal to the results of nonlinear time history analysis(NTHA) for various ground motions. 2) When the results of NDSM are compared with those of NTHA. mean of errors is the smallest in case of post-yielding stiffness factor 0.1, static force by MAD(modal adaptive distribution) and unloading stiffness degradation factor 0.2~0.3.

• Journal of the Korean Chemical Society
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• v.28 no.4
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• pp.244-250
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• 1984

Separation and identification of the polycyclic aromatic compounds (PAC) from pyrolysis products of cellulose and lignin were performed using a combination of acid-base solvent partitioning and silicic acid column chromatography with fused-silica capillary column gas chromatography/ mass spectrometry. Sixteen PAC were positively identifited by retention indices and mass spectra data. Both materials produced the same kinds of PAC. But lignin produced much more PAC than cellulose. Almost no highly carcinogenic heterocyclic PAC containing nitrogen and sulfur were produced.