• Title/Summary/Keyword: 지하수의 오염

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Effects of Paper Mill Sludge Application on Early Growth of Acer palmatum Thunb. and Soil Physicochemical Properties of Forest Nursery (제지슬러지의 시용이 묘포의 단풍나무 초기생장과 토양의 이화학적 특성에 미치는 영향)

  • Park, Hyun;Lee, Don Koo
    • Korean Journal of Soil Science and Fertilizer
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    • v.31 no.1
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    • pp.39-45
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    • 1998
  • As a basic research for developing a sludge application technique in forestry, this study was conducted to investigage a reasonable amount and period of sludge to be applied onto forest nursery of Acer palmatum Thunb. The paper mill sludge was used for the study, and ammonium nitrate was treated to some of them to reduce the C/N ratio lower than 40. The maximum amount of applied sludge was 7ton/ha/year, and they were spread on spring and on late summer. The sludge application did not stimulate early growth of the trees during a year. Since there was no significant changes in soil chemical properties, the amount of applied sludge was thought to be too little to result in a significant role for tree growth. However, the soil water showed significant increase of Cu when the activated sludges were applied during late summer. Thus, the time of application need to be determined cautiously with considering the risk of ground water contamination. In conclusion, if we set a goal from the view point of long-term concept such as forest productivity rather than to get a short-term product, the uncomposted sludge in small amount during growing season might be considered to be applied on forest nursery.

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Effect of Rice Straw and Woodchip Application on Greenhouse Soil Properties and Vegetable Crops Productivity (볏짚과 파쇄목 시용이 시설하우스 토양 성질과 작물 수량에 미치는 영향)

  • Seo, Young-Ho;Lim, Soo-Jeong;Kim, Seung-Kyeong;Jung, Yeong-Sang
    • Korean Journal of Soil Science and Fertilizer
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    • v.40 no.1
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    • pp.4-11
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    • 2007
  • There have been increasing concerns about decreasing crop productivity due to salt accumulation in greenhouse soils. The objective of the study was to investigate the impact of rice straw and woodchip application to a salt accumulated greenhouse soil on crop productivity and soil quality. The application of rice straw (RS) and woodchip (W) increased tomato yield and decreased blossom-end rot, and increased yield of Chinese cabbage compared with standard recommended fertilization ($204-103-122kg\;ha^{-1}\;N-P_2O_5-K_2O$ for tomato and $222-64-110kg\;ha^{-1}\;N-P_2O_5-K_2O$ for Chinese cabbage), while less soil residual nitrate, phosphatephosphorus, and potassium. In addition to the organic material application, fertilization reduction based on soil testing may also contribute to relatively low level of soil residual nutrients. Application of the organic material reduced soil bulk density presumably because of improved soil aggregation and structure, and increased biomass C and dehydrogenase activity. In comparison to rice straw, woodchip application resulted in higher crop yield, less amount of soil residual nitrate and lower soil EC, and greater biomass and dehydrogenase activity. The results obtained in this study indicateshowed that woodchip amendment along with reduced fertilization based on soil testing can be one of essential management practices for salt accumulated greenhouse soils.

Development of a Groundwater Quality Sampling Method for Livestock Excreta Survey (가축분뇨실태조사를 위한 지하수 오염현황조사 지점 선정 방법 개발)

  • Kim, Deok-Woo;Ryu, Hong-Duck;Baek, Unil;Kim, Sunjung;Shin, Dong Seok;Lee, Jae Gwan;Chung, Eu Gene
    • Journal of Environmental Science International
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    • v.28 no.1
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    • pp.37-54
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    • 2019
  • The groundwater quality through livestock excreta survey based on "Act of the management and use of livestock excreta" was investigated by selecting sampling sites within 1 km of the farmland without considering hydrogeological units. However, these sites can be affected by various pollution sources such as chemical fertilizers and livestock excretions. Additionally, the effects of pollution sources on groundwater quality in the sites cannot be clearly distinguished from naturally occurring backgrounds. In this study, a method was developed to select the sampling sites for groundwater quality through livestock excreta survey in order to understand the effects of pollution sources especially livestock excreta. First, the concentrations of nitrate within the radius of 200 m, 300 m, 500 m and 750 m, respectively, from the farms regarded as pollution sources in hydrogeological units were compared in 2016-2017. All the nitrate concentrations at 200 - 500 m from the farms exceeded a background concentration, 13.3 mg/L. Those at 750 m and the background concentrations measured by the Ministry of Environment were comparable. Therefore, the appropriate radius was suggested as 500 m for livestock excretions survey. In this study, the areas within 500 m from the farms could be considered under the influence of livestock excretions, while those beyond 500 from the pollution sources as background in hydrogeological units. The developed method was validated by applying it to the sites selected based on both administrative divisions and watersheds for livestock excretion survey. The average densities for the developed method were 0.82 and 0.39 points/km2, respectively, which were considered as appropriate levels according to those of the European Environmental Agency.

Pre-grouting for CHI of EPB shield TBM in difficult grounds: a case study of Daegok-Sosa railway tunnel (복합지반 EPB TBM 커터교체를 위한 그라우팅 수행 사례)

  • Kang, Sung-Wook;Chang, Jaehoon;Lee, Jae-Won;Kim, Dae-Young;Shin, Young-Jin
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.23 no.5
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    • pp.281-302
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    • 2021
  • Railway projects have been consistently increasing in Korea. In relation to this trend, the mechanized tunneling using Tunnel Boring Machine (TBM) is preferably applied for mining urban areas and passing under rivers. The TBM tunneling under difficult grounds like mixed faces with high water pressure could require ground improvements for stable TBM advance or safe cutter head intervention (CHI). In this study, pre-grouting works for CHI in Daegok-Sosa railway project are presented in terms of the grouting zone design, the executions and the results, the lessons learned from the experience. It should be mentioned that the grouting from inside TBM was carried out several times and turned out to be inefficient in the project. Therefore, grouting experiences from the surface are highlighted in this study. Jet grouting was implemented on CHI points on land, while permeation grouting off shore in the Han River, which mostly allow to access the cutter head of TBM in free air with stable faces. The results of CHI works have been analyzed and the lesson learned are suggested.

Application of land cover and soil information for improvement of HSPF modeling accuracy (HSPF 예측 정확도 제고를 위한 토지피복 및 토양 특성 자료의 활용)

  • Kang, Yooeun;Kim, Jaeyoung;Seo, Dongil
    • Journal of Korea Water Resources Association
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    • v.55 no.10
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    • pp.823-833
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    • 2022
  • This study aims to improve the runoff modeling accuracy of a basin using Hydrological Simulation Program-FORTRAN (HSPF) model by considering nonhomogeneous characteristics of a basin. By entering classified values according to the various types of land cover and soil to the parameters in HSPF-roughness coefficient (NSUR), infiltration (INFILT), and evapotranspiration (LZETP)- the heterogeneity of the Yongdam Dam basin was reflected in the model. The results were analyzed and compared with the one where the parameters were set as a single value throughout the basin. The flow rate and water quality simulation results showed improved results when classified parameters were used by land cover and soil type than when single values were used. The parameterization changed not only the flow rate, but also the composition ratio of each hydrologic components such as surface runoff, baseflow, and evapotranspiration, which shows the impact of the value set to a parameter on the entire hydrological process. This implies the importance of considering the heterogeneous characteristics of the land cover and soil of the basin when setting the parameters in a model.

Evaluation of Environmental Stability and Durability of Cementitious Mixed Soil (시멘트계 혼합토의 환경안정성 및 내구성 평가)

  • Oh, Sewook;Bae, Wooseok;Kim, Hongseok
    • Journal of the Korean GEO-environmental Society
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    • v.23 no.9
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    • pp.17-23
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    • 2022
  • Using cement as a road subbase is economical, easily modified and supplemented and has excellent road pavement quality control. In addition, cement adheres well to sandy soils without adhesion, and it plays a role of permanently preserving adhesion in viscous soils with adhesion, so it can be widely applied as stable treatment with the advantages of increased strength, reduced compressibility. and improved durability. However, while cement is excellent in terms of strength for a road subbase, the material properties mean that it is difficult to maintain and reinforce when cracks or fractures occur due to dry shrinkage, and the pH increases in the ground due to hexavalent chromium eluting from cement. which can cause environmental problems such as groundwater contamination. Therefore, this study evaluates the usability of alternatives in the road base layer such as environmentally cementitious stabilizer and on-site soil generated from the site. We intend to reduce the environmental damage and evaluate the durability. To evaluate the applicability of the site, Environmental stability test and freeze-thaw test and wetting-drying test was conducted to evaluate the strength characteristics of alternative materials on the road through the limited performance evaluation of environmentally cementitious stabilizer. The test ranges were set at mixing ratios of 10%, 20%, and 30% and ages of three days, and 28 days old to evaluate the early strength and reference strength according to the mixing ratio of the environmentally cementitious stabilizer.

Status and Management Strategy of Pesticide Use in Golf Courses in Korea (우리나라 골프장의 농약사용 실태 및 관리방안)

  • Kim, Dongjin;Yoon, Jeongki;Yoo, Jiyoung;Kim, Su-Jung;Yang, Jae E.
    • Journal of Applied Biological Chemistry
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    • v.57 no.3
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    • pp.267-277
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    • 2014
  • Objective of this paper is to assess the available data on the pesticide uses and regulations in the golf courses, and provide the nationwide systematic management options. Numbers of golf courses in Korea are rapidly increasing from 2000s and reached at 421 sites by the end of 2011. Accordingly pesticide usage has been increased with years in direct proportion to the increasing number of golf courses. Amounts of pesticide applied in 2011 were 118,669 kg as of an active ingredient and were in the orders of fungicides (54.9%) > insecticides (24.4%) > herbicides (13.3%) > growth regulators (0.1%). Average pesticide usages in 2011 were 280.9 kg per golf course and $5.4kg\;ha^{-1}$. Frequencies of the residual pesticide detections in green and turf were higher than those in fairway and soil, respectively. Residue of highly toxic pesticides was not detected in golf courses. Ministry of Environment in 2010 has developed the 'golf course pesticide monitoring and management system' which is the advanced online registry for kind and amount of pesticides applied in each golf course. This system is intended for monitoring of the pesticide uses and residual levels and protecting the environmental pollution from pesticides in the golf course. In 2009, management of pesticides in the golf courses became the task of Ministry of Environment, being merged from many federal agency and ministries. The protocol for the site-specific best management practices, on which to base results from the risk assessment, should be set for pesticides in the golf to minimize the environmental impacts.

Quantification of kerosene and Diesel in Mixed Petroleum Fuels for Environmental Sample Characterization (다종유류 오염 환경매체에서의 유류 분리.정량에 관한 연구(I) - 등유, 경유 정량을 중심으로 -)

  • 이군택;이민효
    • Journal of Korea Soil Environment Society
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    • v.5 no.2
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    • pp.23-31
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    • 2000
  • The objective of this study was to develop an effective separation and quantification method for kerosene and diesel in a mixed petroleum fuel (gasoline, kerosene, and diesel) contaminated environmental samples. This investigation was directed to prove the hypothesis that if the source of petroleum fuels were identical, the peak-area ratios of a reference n-alkane to other n-alkane peaks should be a constant even at the different concentrations. In addition, experimental recovery rates were determined to select the reference peaks of kerosene and diesel for peak area ratio measurements. The experimental results showed that the peak area ratios were constant among the samples having different concentrations when the ratios were calculated from areas of $C_{l3}$, $C_{l4}$, and $C_{15}$ peaks for kerosene and $C_{l6}$ and $C_{l7}$ peak for diesel as reference n-alkane peaks. The recovery rates were evaluated by comparing the relative peak area ratios of each reference peaks after making pairs of the kerosene and diesel reference peaks in the samples contained a known amount of gasoline, kerosene, and diesel. The recovery rates(%) Were 107.0$_{{\pm}20.6}$/86.6/ sub $\pm$15.9/ for kerosene- $C_{13}$/diesel- $C_{16}$, 99.6$\pm$$_{17.2}$/86.6$_{{\pm}15.9}$ for kerosene- $C_{14}$/diesel- $C_{16}$, 73.9/$\pm$14.4//86.6$_{{\pm}sub 15.9}$ for kerosene- $C_{15}$ /diesel- $C_{16}$, 109.4$_{{pm}0.8}$/75.9$_{{pm}4.7}$ for kerosene- $C_{13}$/diesel- $C_{17}$, 107.4$_{{pm}7.9}$/75.9$_{{pm}4.7}$ for kerosene- $C_{14}$/diesel- $C_{17}$, and 95.7$_{{pm}4.6}$ /75.9/$\pm$14.6//75.9$_{{pm$}4.7}$ for kerosene- $C_{15}$ /diesel- $C_{17.}$ The above experimental results confirm that all of the reference peak pairs of kerosene and diesel are applicable to the quantitative analysis for the mixed fuel contaminated samples, but the kerosene- $C_{15}$ /diesel- $C_{l7}$ peaks are recommended since the pair has a lower standard deviation than the other pairs.s..s.s.s..s..s.s.s.s.s.

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Vertical Distribution of Heavy Metals in Paddy Soil Near Abandoned Metal Mines (폐금속광산 주변 논토양 중 중금속의 수직분포 특성)

  • Jung, Goo-Bok;Kim, Won-Il;Park, Kwang-Lai;Yun, Sun-Gang
    • Korean Journal of Environmental Agriculture
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    • v.20 no.4
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    • pp.297-302
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    • 2001
  • To compare the relationship between the vertical distribution of heavy metals in paddy soil and soil pH near four abandoned metal mines, 40 paddy surface soils $(0{\sim}15\;cm)$ and 12 soils with soil depths ($0{\sim}20$, $20{\sim}40$, $40{\sim}60$, $60{\sim}80$ and $80{\sim}100$ cm) were collected. Both total and extractable heavy metal contents in soils were analyzed after acid digestion $(HNO_3:HClO_4:H_2SO_4)$ and 0.1 N-HCl extraction, respectively. The 0.1 N-HCl fraction ratio over total contents of Cd, Cu, Pb, and Zn were 57, 30, 23, and 19% respectively. Vertical distribution of heavy metals varied considerably among the different mines. In Choil mine, there was no difference in concentrations of all the metals with soil layers. However, Cu and Pb contents in Gahak mime were high at $0{\sim}20\;cm$ depth, and Zn was high at $0{\sim}40\;cm$ depth. In Sinyemi mine, Cd and Cu contents were high at $0{\sim}40\;cm$ depth. Cd, Cu, and Pb contents in Okcheon mine were high through all soil profiles up to 100 cm soil depth. The 0.1 N-HCl fraction ratio over total contents of heavy metals with soil layers were very high at $0{\sim}20\;cm$ depth. As soil depth increased, fraction ratio of heavy metals decreased at the high soil pH (Gahak, Sinyemi, and Choil mines). However, the ratios of Cd, Cu, and Pb in Okcheon mine, having a relatively lower soil pH than other sites, were relatively similar through all the soil profiles up to 100 cm soil depth. Therefore, it was estimated that the mobility and availability of heavy metals in soils were affected by soil pH.

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Evaluation of 1,1,2-trichloroethylene Removal Efficiency Using Composites of Nano-ZnO Photocatalyst and Various Organic Supports (다양한 유기계 지지체와 광촉매 Nano-ZnO 복합체를 활용한 1,1,2-trichloroethylene 제거 효율 평가)

  • Jang, Dae Gyu;Ahn, Hosang;Kim, Jeong Yeon;Ahn, Chang Hyuk;Lee, Saeromi;Kim, Jong Kyu;Joo, Jin Chul
    • Journal of Korean Society of Environmental Engineers
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    • v.36 no.11
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    • pp.771-780
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    • 2014
  • In this study, the various organic supports (i.e., silicone, acrylonitrile-butadiene-styrene, epoxy, and, butadiene rubber) with great sorption capacity of organic contaminants were chosen to develop nano-ZnO/organic composites (NZOCs) and to prevent the detachment of nano-ZnO particles. The water resistance of the developed NZOCs were evaluated, and the feasibility of the developed NZOCs were investigated by evaluating the removal efficiency of 1,1,2-trichloroethylene (TCE) in the aqueous phase. Based on the results from water-resistance experiments, long-term water treatment usage of all NZOCs was found to be feasible. According to the FE-SEM, EDX, and imaging analysis, nano-ZnO/butadiene rubber composite (NZBC) with various sizes and types of porosity and crack was measured to be coated with relatively homogeneously-distributed nano-ZnO particles whereas nano-ZnO/silicone composite (NZSC), nano-ZnO/ABS composite (NZAC), and nano-ZnO/epoxy composite (NZEC) with poorly-developed porosity and crack were measured to be coated with relatively heterogeneously-distributed nano-ZnO particles. The sorption capacity of NZBC was close to 60% relative to the initial concentration, and this result was mainly attributed to the amorphous structure of NZBC, hence the hydrophobic partitioning of TCE to the amorphous structure of NZBC intensively occurred. The removal efficiency of TCE in aqueous phase using NZBC was close to 99% relative to the initial concentration, and the removal efficiency of TCE was improved as the amount of NZBC increased. These results stemmed from the synergistic mechanisms with great sorption capability of butadiene rubber and superior photocatalytic activities of nano-ZnO. Finally, the removal efficiency of TCE in aqueous phase using NZBC was well represented by linear model ($R^2{\geq}0.936$), and the $K_{app}$ values of NZBC were from 2.64 to 3.85 times greater than those of $K_{photolysis}$, indicating that butadiene rubber was found to be the suitable organic supporting materials with enhanced sorption capacity and without inhibition of photocatalytic activities of nano-ZnO.