• The Journal of Engineering Geology
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• v.12 no.4
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• pp.471-484
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• 2002

Alluviums in the Keum River watershed cover an areal extent of $3,029{\;}\textrm{km}^2$ and contain about 8.1 billion tons of groundwater. However, the waters are severely polluted by nitrate, possibly due to the application of nitrogen fertilizer (>250 N kg/ha) on agricultural land. This paper aims to elucidate the pollution status and behaviors of nitrate in alluvial groundwaters in the Keum River watershed area, based on regional hydrogeochemical study. Most of the collected samples (n = 186) are polluted by nitrate (average = 42.2 mg/L, maximum = 295 mg/L). About 29% of the samples have the nitrate concentrations exceeding Korean Drinking Water Standard (44 mg/L $NO_3$). The distribution of nitrate concentrations in the study area is largely dependant on geochemical environments of alluvial aquifers. In particular, the decrease of redox potential of alluvial groundwaters showed a good correlation with the decreases of nitrate, iron, and manganese concentrations. Thus, the change of redox state in alluvial aquifers, likely reflecting their sedimentary environments, controls both the behavior and fate of nitrogen compounds and their natural attenuation (denitrification) in aquifers. A carbon-rich, silty layer within alluvium strata forms a reducing condition and possesses a buffering capacity on nitrate pollution.

• Proceedings of the Korea Water Resources Association Conference
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• 2020.06a
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• pp.282-282
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• 2020

본 연구는 여수시 농어촌지역에 대하여 지하수 함양특성, 개발가능량 산정 및 오염부하량 등의 조사를 통해서 체계적인 지하수자원의 보전관리(안)을 수립하기 위해 수행되었다. 연구지역은 여수시 화양면, 소라면 2개 면을 포함하는 농어촌 용수구역(여소지구)으로, 여소지구의 총면적은 130.68 ㎢이며, 이 중 임야면적은 81.57 ㎢, 경지면적은 32.98 ㎢ 이고, 경지면적은 논 15.37 ㎢, 밭 17.42 ㎢, 시설재배 0.19 ㎢로 구성되어 있다. 여소지구의 30년 강수평균은 1,454.08 mm/년이며, 지하수 함양량은 국가지하수관리 기본계획(국토교통부, 2019) 및 전라남도 지하수관리계획(전라남도, 2009) 보고서를 참고하여 평균값인 11.28%로 산정한 결과, 21,279 천㎥/년으로 분석되었다. 또한, 지하수연보(국토교통부, 2018)의 세부용도별 이용량을 활용하여 지하수 이용량을 산정한 결과, 2,638.35 천㎥/년이었으며, 강수량, 함양률 및 면적 값을 고려하여 지하수 개발가능량을 산정한 결과, 16,387.57 천㎥/년, 개발가능량 대비 이용량은 16.11%로 확인되었다. 여소지구의 질산성질소 항목은 총 181개소(경지면적 0.2 ㎢당 1점)에 대해 분석한 결과, 전체 평균값은 6.67 mg/L이었으며, 농업용수 수질기준(20 mg/L)을 초과한 관정은 8개소(6%)로 확인되었다. DRASTIC을 이용한 오염취약성 지수는 평균값이 119.57점으로 나타나 오염취약성이 낮은 것으로 분석되었다. 신고·허가된 축사 시설을 기준으로 점오염원 조사결과, 단위면적당 시설수(오염원밀도)는 3.12 개소/㎢로 조사되었으며, 인구, 가축 및 토지이용 등 인자별을 고려하여 오염부하량을 산출한 결과, 단위면적당 오염부하량은 75.30 kg/day/㎢로 확인되었다. 행정구역별로 7가지 지표를 반영하여 관심, 주의, 경계 및 심각 4단계로 기준을 설정하여 지하수관리 필요지역을 선정하였다. 수량 측면은 개발가능량 대비 이용량, 단위면적당 이용량 및 관정밀 3가지 지표를 적용하였고, 수질 측면은 질산성질소 평균, 오염취약성 지수, 오염원밀도 및 단위면적당 오염부하량 4가지 지표를 적용하여 선정하였다. 지하수관리 필요지역을 분석한 결과, 전체 18개 리 중에서 14개 리에서 수량관리 12개리에서 수질관리 필요지역이 나타났다. 수량관리 필요지역은 지하수 취수량 조정 및 관리 확충 등의 대책방안이 마련되어야 하며, 수질관리 필요지역은 주변 오염원관리 및 수질검사 강화 등의 대책방안이 필요할 것으로 판단된다.

• Korean Journal of Ecology and Environment
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• v.37 no.4 s.109
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• pp.431-435
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• 2004

A nitrate-contaminated groundwater was hydrogeochemically investigated to estimate the factors controlling groundwater quality in an alluvial fan area. Even though monthly groundwater levels increased with monthly rainfalls, the monthly $NO_3^--N$ concentrations in groundwater showed a small variation, mostly exceeding a maximum contaminant level of 10 mg $L^{-1}$ in environmental quality standards for groundwater during 2003. The 2003 annual groundwater recharge was 1,730 mm =20,056 mm-18,326 mm. Where 20,056 mm and 18,326 mm are annual sum of daily increase and decrease in ground water level. However, the annual sum of increase in ground water level (20,056 mm) was approximately 10 times higher than annual rainfall. Moreover, the annual sum of daily ground water level decrease (-18,326mm) showed that a large amount of groundwater was discharged with $NO_3^-$-contamination. Hydrogeochemically, a large amount of groundwater input and output through the alluvial fan area were observed after rainfall with a considerably high concentration of $NO_3^-$. Consequently, this alluvial fan area including forest area reflects on the evidence under the condition of 'nitrogen excess' or 'nitrogen saturation'. In addition, such a large amount of groundwater outflow can cause environmental damage in surface water, associated with $NO_3^-$- contamination. This study also expects that this hydrogeochemical data will be useful for water management.

• Journal of Soil and Groundwater Environment
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• v.7 no.4
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• pp.77-86
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• 2002

Surfactant enhanced in-situ soil flushing was performed to remediate the soil and groundwater at an oil contaminated site, where had been used as a military vehicle repair area for 40 years. A section from the contaminated site (4.5 m $\times$ 4.5 m $\times$ 6.0 m) was selected for the research, which was composed of heterogeneous sandy and silt-sandy soils with average $K_d$ of 2.0$\times$$10^{-4}$cm/sec. Two percent of sorbitan monooleate (POE 20) and 0.07% of iso-prophyl alcohol were mixed for the surfactant solution and 3 pore volumes of surfactant solution were injected to remove oil from the contaminated section. Four injection wells and two extraction wells were built in the section to flush surfactant solution. Water samples taken from extraction wells and the storage tank were analyzed on a gas-chromatography (GC) for TPH concentration in the effluent with different time. Five pore volumes of solution were extracted while TPH concentration in soil and groundwater at the section were below the Waste Water Discharge Limit (WWDL). The effluent TPH concentration from wells with only water flushing was below 10 ppm. However, the effluent concentration using surfactant solution flushing increased to 1751 ppm, which was more than 170 times compared with the concentration with only water flushing. Total 18.5 kg of oil (TPH) was removed from the soil and groundwater at the section. The concentration of heavy metals in the effluent solution also increased with the increase of TPH concentration, suggesting that the surfactant enhanced in-situ flushing be available to remove not only oil but heavy metals from contaminated sites. The removal efficiency of surfactant enhanced in-situ flushing was investigated at the real contaminated site in Korea. Results suggest that in-situ soil flushing could be a successful process to remediate contaminated sites distributed in Korea.

• Journal of Soil and Groundwater Environment
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• v.11 no.6
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• pp.8-17
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• 2006

Laboratory scale experiments were performed to investigate the removal efficiency of the in-situ chemical oxidation method and the air-sparging method for diesel contaminated soil and groundwater. Two kinds of diesel contaminated soils (TPH concentration : 2,401 mg/kg and 9,551 mg/kg) and groundwater sampled at Busan railroad station were used for the experiments. For batch experiments of chemical oxidation by using 50% hydrogen peroxide solution, TPH concentration of soil decreased to 18% and 15% of initial TPH concentration. For continuous column experiments, more than 70% of initial TPH in soil was removed by using soil flushing with 20% hydrogen peroxide solution, suggesting that most of diesel in soil reacted with hydrogen peroxide and degraded into $CO_2$ or $H_2O$ gases. Batch experiment for the air-sparging method with artificially contaminated groundwater (TPH concentration : 810 mg/L) was performed to evaluate the removal efficiency of the air-sparging method and TPH concentration of groundwater decreased to lower than 5 mg/L (waste water discharge tolerance limit) within 72 hours of air-sparging. For box experiment with diesel contaminated real soil and groundwater, the removal efficiency of air-sparging was very low because of the residual diesel phase existed in soil medium, suggesting that the air-sparging method should be applied to remediate groundwater after the free phase of diesel in soil medium was removed. For the last time, the in-situ box experiment for a unit process mixed the chemical oxidation process with the air-sparging process was performed to remove diesel from soil and groundwater at a time. Soil flushing with 20% hydrogen peroxide solution was applied to diesel contaminated soils in box, and subsequently contaminated groundwater was purified by the air-sparging method. With 23 L of 20% hydrogen peroxide solution and 2,160 L of air-sparging, TPH concentration of soil decreased from 9,551 mg/kg to 390 mg/kg and TPH concentration of groundwater reduced to lower than 5 mg/L. Results suggested that the combination process of the in-situ hydrogen peroxide flushing and the air-sparging has a great possibility to simultaneously remediate fuel contaminated soil and groundwater.

• Proceedings of the Korea Water Resources Association Conference
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• 2012.05a
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• pp.423-427
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• 2012

지하수 관측이란 지하수위 하강, 수질오염 등 지하수 장해로부터 지하수를 보전 관리하고 대책을 수립하기 위하여 정기적 및 장기적으로 지하수위, 수질 등 부존된 지하수 특성의 상태와 변화하는 추이를 관찰하여 측정하는 행위를 말한다. 지하수는 지하의 보이지 않는 지층구조에서 매우 천천히 유동하므로 수위하강 및 수질오염 발생을 늦게 인지할 경우 원상회복이 불가능할 수 있고, 지하수 장해를 인지한 이후의 대처과정에서도 기존의 관측자료가 없거나 부족할 경우에는 원인분석과 대책수립이 지연되거나 불가능할 수 있으므로 지하수관리에 있어 관측정호를 설치하고 정기적으로 지하수의 부존 및 유동특성, 배경수질 등의 지하수 관측은 기본적이며 필수적인 요소이다. 따라서 지하수 관측망을 설치하고 운영하기 위해서는 관측 목적을 명확히 정의하고 관측 프로그램이 이를 만족시키도록 구성되어야하며 시간적, 공간적으로 지하수가 변동되는 것을 고려하여 관측 지역 대수층의 유형과 특성 등이 완전히 파악되어야 한다. 필요시 기존 관정을 활용하여 관측하며 관측 항목, 관측 유형, 위치측량 및 관측 주기 등은 관측의 목적에 부합되도록 한다. 관측 데이터의 생성, 전송 및 분석 진행과정 등이 완벽하게 정립되어 데이터의 생성에서부터 활용까지 체계화되어야 하고 지하수와 지표수는 연계된 단일 수자원으로서 지하수 관측은 지표수 관측과 연계되어 설계되고 분석되어야 한다. 또한 취득된 데이터의 정확성은 지속적으로 검토 확인되어야 하며 전문가의 능력을 활용하여 관련 자료의 분석이 이루어지고 데이터의 정도를 높이기 위한 후속조치들이 병행되어야 한다. 그리고 지하수위, 수질 등 관측 자료가 자연적인 지하수 유동 체계에 의하여 변화되는 것이라고 인식될 경우에는 관측 시스템 전반을 재평가하여 보다 효율적인 관측 시스템으로 발전시켜야 한다.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 1997.05a
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• pp.87-91
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• 1997

• Proceedings of the KSEEG Conference
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• 2001.04a
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• pp.33-34
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• 2001

• Journal of Soil and Groundwater Environment
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• v.13 no.1
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• pp.77-91
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• 2008

In this study, we developed a technique of applying DRASTIC, which is the most widely used tool for estimation of groundwater vulnerability to the aqueous phase contaminant infiltrated from the surface, and a groundwater flow model jointly to assess groundwater contamination potential. The developed technique is then applied to Buyeo-eup area in Buyeo-gun, Chungcheongnam-do, Korea. The input thematic data of a depth to water required in DRASTIC model is known to be the most sensitive to the output while only a few observations at a few time schedules are generally available. To overcome this practical shortcoming, both steady-state and transient groundwater level distributions are simulated using a finite difference numerical model, MODFLOW. In the application for the assessment of groundwater vulnerability, it is found that the vulnerability results from the numerical simulation of a groundwater level is much more practical compared to cokriging methods. Those advantages are, first, the results from the simulation enable a practitioner to see the temporally comprehensive vulnerabilities. The second merit of the technique is that the method considers wide variety of engaging data such as field-observed hydrogeologic parameters as well as geographic relief. The depth to water generated through geostatistical methods in the conventional method is unable to incorporate temporally variable data, that is, the seasonal variation of a recharge rate. As a result, we found that the vulnerability out of both the geostatistical method and the steady-state groundwater flow simulation are in similar patterns. By applying the transient simulation results to DRASTIC model, we also found that the vulnerability shows sharp seasonal variation due to the change of groundwater recharge. The change of the vulnerability is found to be most peculiar during summer with the highest recharge rate and winter with the lowest. Our research indicates that numerical modeling can be a useful tool for temporal as well as spatial interpolation of the depth to water when the number of the observed data is inadequate for the vulnerability assessments through the conventional techniques.

• Journal of Radiation Protection and Research
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• v.26 no.2
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• pp.79-86
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• 2001

This study presents the quantitative exposure assessment of indoor radon released from groundwater. Most of the Indoor radon comes directly from soil beneath the basement or foundation. Recently, radon in groundwater releases to indoor air whenever the water is used and contributes to the total inhalation risk from indoor air. This study first develops a mathematical model to describe the transfer and distribution of radon released from groundwater in a house. Then, daily human exposures through inhalation or such radon are estimated with the model for an male adult based on two sets of exposure scenarios. The results obtained from the study would help increase the understanding of risk assessment issues associated with the indoor radon released from groundwater.