• Title/Summary/Keyword: 지구온난화물질

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Copper-Based Electrochemical CO2 Reduction and C2+ Products Generation: A Review (구리 기반 전극을 활용한 전기화학적 이산화탄소 환원 및 C2+ 화합물 생성 기술)

  • Jiwon Heo;Chaewon Seong;Vishal Burungale;Pratik Mane;Moo Sung Lee;Jun-Seok Ha
    • Journal of the Microelectronics and Packaging Society
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    • v.30 no.4
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    • pp.17-31
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    • 2023
  • Amidst escalating global warming fueled by indiscriminate fossil fuel consumption, concerted efforts are underway worldwide to mitigate atmospheric carbon dioxide (CO2) levels. Electrochemical CO2 reduction technology is recognized as a promising and environmentally friendly approach to convert CO2 into valuable hydrocarbon compounds, deemed essential for achieving carbon neutrality. Copper, among the various materials used as CO2 reduction electrodes, is known as the sole metal capable of generating C2+ compounds. However, low conversion efficiency and selectivity have hindered its widespread commercialization. This review highlights diverse research endeavors to address these challenges. It explores various studies focused on utilizing copper-based electrodes for CO2 reduction, offering insights into potential solutions for advancing this crucial technology.

A prediction study on the number of emergency patients with ASTHMA according to the concentration of air pollutants (대기오염물질 농도에 따른 천식 응급환자 수 예측 연구)

  • Han Joo Lee;Min Kyu Jee;Cheong Won Kim
    • Journal of Service Research and Studies
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    • v.13 no.1
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    • pp.63-75
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    • 2023
  • Due to the development of industry, interest in air pollutants has increased. Air pollutants have affected various fields such as environmental pollution and global warming. Among them, environmental diseases are one of the fields affected by air pollutants. Air pollutants can affect the human body's skin or respiratory tract due to their small molecular size. As a result, various studies on air pollutants and environmental diseases have been conducted. Asthma, part of an environmental disease, can be life-threatening if symptoms worsen and cause asthma attacks, and in the case of adult asthma, it is difficult to cure once it occurs. Factors that worsen asthma include particulate matter and air pollution. Asthma is an increasing prevalence worldwide. In this paper, we study how air pollutants correlate with the number of emergency room admissions in asthma patients and predict the number of future asthma emergency patients using highly correlated air pollutants. Air pollutants used concentrations of five pollutants: sulfur dioxide(SO2), carbon monoxide(CO), ozone(O3), nitrogen dioxide(NO2), and fine dust(PM10), and environmental diseases used data on the number of hospitalizations of asthma patients in the emergency room. Data on the number of emergency patients of air pollutants and asthma were used for a total of 5 years from January 1, 2013 to December 31, 2017. The model made predictions using two models, Informer and LTSF-Linear, and performance indicators of MAE, MAPE, and RMSE were used to measure the performance of the model. The results were compared by making predictions for both cases including and not including the number of emergency patients. This paper presents air pollutants that improve the model's performance in predicting the number of asthma emergency patients using Informer and LTSF-Linear models.

Assessment of Climate Change Impacts on Stream and Lake Water Quality (미래 기후변화가 하천 및 호소수질에 미치는 영향 평가)

  • Park, Jong-Yoon;Joh, Hyung-Kyung;Shin, Hyung-Jin;Yu, Yung-Seak;Jang, Cheol-Hee;Kim, Seong-Joon
    • Proceedings of the Korea Water Resources Association Conference
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    • 2011.05a
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    • pp.48-48
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    • 2011
  • 본 연구에서는 미래 기후변화가 하천 및 호소수질에 미치는 영향을 평가하고자 유역 수문-수질 모의가 가능한 SWAT(Soil and water assessment tool) 모형과 호소수질 모의가 가능한 WASP(Water Quality Simulation Program) 모형을 연계운영하여 충주호를 포함하는 충주댐 유역($6,642.0km^2$)에 적용하였다. 이를 위해 IPCC(Intergovernmental panel on climate change)에서 제공하는 A1B 배출시나리오를 포함하는 MIROC3.2 hires 모형의 결과로부터 충주댐 유역의 총 6개 기상관측소에 대한 과거 30년(1997~2006) 실측자료를 바탕으로 미래 온도와 강수에 대한 편이보정(Bias correction) 및 Change Factor Method로 상세화(Downscaling)하여 미래 기후자료(2020s, 2050s, 2080s)를 생산하였다. 미래 연평균 온도는 기준년도인 2000년에 비해 최대 $+4.8^{\circ}C$(2080s)의 온도증가를 보였으며, 강수량의 경우 여름과 가을 강수량이 다소 감소하였으나 연평균 강수량은 최대 +34.4%(2080s) 증가하는 것으로 전망되었다. 먼저, SWAT 모형을 이용한 기후변화에 따른 댐 유입량은 39.8%(2080s) 증가는 것으로 분석되었으며 유역의 유출특성 변화로 인한 유사량은 지표유출변화에 기인하여 봄과 겨울에 증가하는 경향과 함께 -14.5%(2020s) ~ +27.3%(2080s)의 변화를 보이는 것으로 분석되었다. 영양물질에 대한 오염부하량은 2080s에서 T-N이 증가추세를 보이며 최대 87.3% 까지 증가하는 반면, T-P는 유사량과 유사한 변화패턴을 보이며 최대 48.4%까지 감소하는 것으로 분석되었다. 호소수질 모델링을 위한 충주호의 Segment 구성은 충주댐1 지점에서부터 충주댐4 지점까지 전체 수표면적 $65.7km^2$에 대하여 상층과 하층 총 760개로 구성하였으며, SWAT 모형에 의한 충주호 유입하천 소유역에서의 미래 유출 및 영양물질 자료를 WASP 모형의 초기값으로 입력하여 수체 내의 BOD, Chl-a, T-N, T-P 변화 분석을 실시하였다. 이와 같이 지구 온난화에 의한 기후변화는 강우특성 변화에 따른 가뭄과 홍수 등 극한 기상현상의 발생, 유역 물순환 체계 변화를 야기 시키므로서 수자원 부존량 변화에 영향을 미칠 뿐만 아니라 기온상승에 따른 수온변화, 비점오염물질의 거동에도 변화를 초래하여 하천 및 호소 수질에 큰 영향을 미칠 것으로 판단된다.

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Removal of tar and particulate from gasification process using pre-coating technology (바이오매스 가스화 공정의 생성가스 중 타르 및 입자 제거를 위한 pre-coating 기술 연구)

  • Kim, Joon-Yub;Choi, Byoung-Kwon;Jo, Young-Min;Kim, Sang-Bum
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.12
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    • pp.804-815
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    • 2019
  • Due to the depletion and environmental problems of fossil fuel, biomass has arisen as an alternative energy source. Biomass is a renewable and carbon-neutral source. However, it is moister and has lower energy density. Therefore, biomass needs thermal chemical conversion processes like gasification, and it does not only produce a flammable gas, called 'syngas', which consists of CO, H2, and CH4, but also some unwanted byproducts such as tars and some particulates. These contaminants are condensed and foul in pipelines, combustion chamber and turbine, causing a deterioration in efficiency. Thus this work attempted to find a method to remove tars and particles from syngas with a filter which adopts a pre-coating technology for preventing blockage of the filter medium. Hydrated limestone powder and activated carbon(wood char) powder were used as the pre-coat materials. The removal efficiency of the tars was 86 % and 80 % with activated carbon(wood char) coating and hydrated limestone coating, respectively.

A Study on Applicability of Hydrofluoroethers as CFC-Alternative Cleaning Agents (CFC 대체 산업세정제로의 HFEs의 적용가능성 연구)

  • Min, Hye-Jin;Shin, Jin-Ho;Bae, Jae-Heum;Kim, Hong-Gon;Lee, Hyun-Joo
    • Clean Technology
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    • v.14 no.3
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    • pp.184-192
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    • 2008
  • Fluoride-type cleaning agents such as 2,2,2-trifluoroethanol (TFEA) and hydrofluoroethers (HFEs) do not destroy ozone in the stratosphere and have low global warming potential compared to hydrofluorocarbons(HFCs) and hydrochlorofluorocarbons (HCFCs). Especially, HFEs which have no flash point are paid attention as next generation type of cleaning agents for chlorofluorocarbons (CFCs) since they are safe in handling and have excellent penetration ability compared to hydrocarbon cleaning agents with low flash point. Here, the physical properties and cleaning abilities of fluoride-type cleaning agents such as TFEA, HFE-7100, HFE-7200, HFE-476mec, HFE-449mec-f, AE-3000 and AE-3100E and silicide-type cleaning agents such as trifluoroetoxytrimethylsilane (TFES) and hexamethyldisilazane (HMDS) were measured and compared with those of ozone destruction substances such as CFC-113 and 1,1,1-trichloroethane. They were also compared with toxic methylene chloride (MC) and isopropyl alcohol (IPA) which are now being used as an alternative cleaning agents. As a result, TFEA and HFEs had lower cleaning ability for removal of various soils compared to chloride-type cleaning agents, but they showed excellent cleaning ability fur fluoride-type soils. TFES and HMDS also showed excellent cleaning ability for silicide-type soils.

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CFD Analysis on the Internal Reaction in the SNCR System (SNCR 시스템 내부의 물질 반응에 관한 전산해석적 연구)

  • Koo, Seongmo;Yoo, Kyung-Seun;Chang, Hyuksang
    • Clean Technology
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    • v.25 no.1
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    • pp.63-73
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    • 2019
  • Numerical analysis was done to evaluate the chemical reaction and the reduction rate inside of selective non-catalytic reduction to denitrification in combustion process. The $NO_X$ reduction in selective non-catalytic reduction is converted to not only nitrogen but also nitrous oxide. Simultaneous $NO_X$ reduction and nitrous oxide generation suppressing is required in selective non-catalytic reduction because nitrous oxide influences the global warming as a greenhouse gas. The current study was performed compare the computational analysis in the same temperature and amount of NaOH, and in comparison with the previous research experiments and confirmed the reliability of the computational fluid dynamics. Additionally, controlling the addition amount of NaOH to predict the $NO_X$ reduction efficiency and nitrous oxide production. Numerical analysis was done to check the mass fraction of each material in the measurement point at the end of selective non-catalytic reduction. Experimental Value and simulation value by numerical analysis showed an error of up to 18.9% was confirmed that a generally well predicted. and it was confirmed that the widened temperature range of more than 70% $NO_X$ removal rate is increased when the addition amount of NaOH. So, large and frequent changes of the reaction temperature waste incineration facilities are expected to be effective.

Reinforcement of Refrigerant Gas Regulations in EU and Implications for Carbon Neutrality (EU의 냉매가스 규제 강화와 탄소중립에의 시사점)

  • Dong Koo Kim
    • Environmental and Resource Economics Review
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    • v.31 no.4
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    • pp.777-799
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    • 2022
  • This study examined the latest EU regulatory strengthening trends for refrigerant gases with very large global warming potential (GWP) and derived implications for carbon neutrality. The European Commission recently unveiled an amendment that significantly strengthens the F-gas Regulation. This study presented the meaning of the main contents related to refrigerants in the amendment by comparing them with the current regulations. The main contents of the amendment include drastically reducing the maximum amount of HFCs that can be placed on the market, strengthening regulations related to HFCs allocation, adding products and equipment that use high GWP refrigerants, adding regulated F-gas and updating the GWP of existing gases, and other stricter regulatory designs. This movement of the EU will affect the policy stance of advanced countries such as the United States and Japan, and Korea's policy will also be further strengthened. Therefore, it will be inevitable for related industries to change to next-generation refrigerant gas. Meanwhile, this study also analyzed the latest policy trends related to per- and polyfluoralkyl substances (PFAS) regulation, which were not noted in previsou studies on refrigerants and F-gas. If PFAS's registration of REACH restricted substances, which are being promoted by five European countries, is made, it will have a very big impact on the industry regarding refrigerant gas. In addition, it will be inevitable to thoroughly review each country's greenhouse gas reduction strategies related to F-gas materials, including refrigerants.

Recent Development of Thermo-chemical Conversion Processes with Fluidized Bed Technologies (유동층 공정을 이용한 열화학적 전환 공정의 최신 개발 동향)

  • Hyun Jun Park;Seung Seok Oh;Olusola Nafiu Olanrewaju;Jester Lih Jie Ling;Chul Seung Jeong;Han Saem Park;See Hoon Lee
    • Korean Chemical Engineering Research
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    • v.61 no.1
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    • pp.8-18
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    • 2023
  • Increasing of energy demand due to the rapid growth of global population and the development of world economy has inevitably resulted in the continuously increase of fossil fuel usage in the world. However, highly dependence on fossil fuels has necessarily brought about critical environmental issues and challenges such as severe air pollutions and rapid global warming. In order to settle these environmental and energy problems, clean energy generations in the conventional combustion processes have widely adapted in the world. In particular, novel thermochemical conversion processes such as pyrolysis and gasification have rapidly been applied for generating clean energy. Fluidized bed technologies having advantages such as various fuel use, easy continuous operation, high heat and material transfer, isothermal operation, and lower operation temperature are widely adopted and used because they are suitable for thermochemical energy conversion. The latest research trends and important findings in the thermo-chemical conversion process with fluidized bed technologies are summarized in this review. Also, the need for research such as layered materials and substances to reduce fine dust (biomass, natural resource waste, etc.) was suggested. Through this, it is intended to increase interest and understanding in fluidized bed technology and to present directions for solving future challenges in fluidized bed process technology development.

Building of Prediction Model of Wind Power Generationusing Power Ramp Rate (Power Ramp Rate를 이용한 풍력 발전량 예측모델 구축)

  • Hwang, Mi-Yeong;Kim, Sung-Ho;Yun, Un-Il;Kim, Kwang-Deuk;Ryu, Keun-Ho
    • Journal of the Korea Society of Computer and Information
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    • v.17 no.1
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    • pp.211-218
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    • 2012
  • Fossil fuel is used all over the world and it produces greenhouse gases due to fossil fuel use. Therefore, it cause global warming and is serious environmental pollution. In order to decrease the environmental pollution, we should use renewable energy which is clean energy. Among several renewable energy, wind energy is the most promising one. Wind power generation is does not produce environmental pollution and could not be exhausted. However, due to wind power generation has irregular power output, it is important to predict generated electrical energy accurately for smoothing wind energy supply. There, we consider use ramp characteristic to forecast accurate wind power output. The ramp increase and decrease rapidly wind power generation during in a short time. Therefore, it can cause problem of unbalanced power supply and demand and get damaged wind turbine. In this paper, we make prediction models using power ramp rate as well as wind speed and wind direction to increase prediction accuracy. Prediction model construction algorithm used multilayer neural network. We built four prediction models with PRR, wind speed, and wind direction and then evaluated performance of prediction models. The predicted values, which is prediction model with all of attribute, is nearly to the observed values. Therefore, if we use PRR attribute, we can increase prediction accuracy of wind power generation.

Environmental impact evaluation and improvement measure of incineration plant by life cycle assessment (전과정평가를 이용한 소각시설의 환경영향평가 및 개선방안)

  • Kim, Hyeong-Woo;Kim, Kyeong-Ho;Park, Hung-Suck
    • Journal of the Korea Organic Resources Recycling Association
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    • v.21 no.4
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    • pp.88-100
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    • 2013
  • This study evaluated the direct and indirect environmental impacts of various unit operations of a industrial waste incineration plant by using the life cycle assessment tool and reviewed the improvement plan. During the incineration process, the direct environmental impact was decreased with decrease in emission of various air pollutants by incorporating an air pollution prevention facilities. However, an increase in indirect environmental impacts was observed as a consequence of resources and energy of consumption at the various operational facilities. Consequently, quantitative direct and indirect impact were 89.1%, 10.9%, respectively. The environmental impact analysis of system revealed the highest impact of incineration followed by the impacts of other unit processes such as semidry reactor, and bag-filter. The various air pollutants and ashes generated during the incineration process caused the most significant environmental impact. Among the various categories of environmental impact, global warming accounted the highest impact(more than 85%) followed by eutrophication, and abiotic depletion. As a result of the avoided impact by the utilization of heat generated during the waste incineration process, using an incineration heat for steam and electricity obtained the impact reduction of 45.5%, 19.8%. So, during siting of new incineration plant, the utilization of steam generated from the waste combustion is highly considered to reduce the environmental impact.