• Title/Summary/Keyword: 증해

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Utilization of Pine Bark(Part 6) -Alkaline Sulfite-Anthraquinone Cooking of Underground Bark and Characterization of the Spent Liquor- (소나무 수피의 총합적 이용(제6보) -미분쇄 수피의 알칼리성 아황산염-안트라퀴논 증해와 증해폐액의 특성-)

  • 문성필;박성천
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.32 no.4
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    • pp.66-73
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    • 2000
  • Alkaline sulfite-anthraquinone(AS-AQ) cooking process has been applied to unground pine bark. The properties of the spent liquor such as molecular weight distributions, sulfonic equivalent weights, degree of sulfonation, phenolic hydroxyl groups and kaolin dispersing ability have been investigated to evaluate the possibility of using this liquor as concrete additives or binders. In the case of ground bark meal, more than 90% delignification was achieved at the optimal cooking conditions. However, applying these conditions on unground bark the delignification was slightly retarded. The decrease in the degree of delignification may be attributed to less penetration and diffusion of chemicals during the cooking of the bark. Increasing the cooking temperature only by $5^{\circ}C$ improved the delignification of the bark and about 90% delignification can be achieved. These results indicate that bark can be used successfully during AS-AQ cooking without any mechanical or physical pretreatment. The properties of lignin or polyphenol sulfonates in the spent liquor after AS-AQ cooking of the bark were compared with Sunflo-R, which is commercial lignosulfonate(CLS) prepared from wood. The weight average molecular weights(Mws) estimated by gel-filteration chromatography was found to be ranging from 1,200~1,800. These are considerably lower than those in CLS. Lignin or polyphenol sulfonates in the spent liquor of bark and CLS have similar degree of sulfonation, but the phenolic hydroxyl group was 1.8 times higher than CLS. Moreover, the dispersing abilities of the spent liquors were better than that of CLS, especially after 0.1% addition to kaolin suspension.

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Studies on the Pulping Characteristics of Larchwood (Larix leptolepis Gordon) by Alkaline Process with Additives (첨가제(添加劑) 알칼리 법(法)에 의한 일본 잎갈 나무의 펄프화(化) 특성(特性)에 관(關)한 연구(硏究))

  • Lim, Kie-Pyo;Shin, Dong-Sho
    • Journal of the Korean Wood Science and Technology
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    • v.7 no.2
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    • pp.3-30
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    • 1979
  • Larch ($\underline{Larix}$ $\underline{leptolepis}$ GORDON), one of the major afforestation species in Korea in view of its growing stock and rate of growth, is not favored as a raw material for pulp due to its low yield of pulp and difficulties with bleaching arising from the high content of extractives in wood, and the high heartwood ratio and the active phenolics, respectively. The purpose of this study is to investigate the characteristics of firstly pulping with various additives of cellulose protector for the yield of pulp, and secondly bleaching with oxygen for chlotination-alkali extraction of five stage-sequence to reduce chlorine compounds in bleaching effluents. The kraft cooking liquor for five age groups of larchwood was 18 percent active alkali with 25 percent sulfidity and 5 : 1 liquor-to-wood ratio, and each soda liquor for sap-and heart-wood of the 15-year-old larchwood was 18 percent alkali having one of the following cellulose protectors as the additive; magnesium sulfate ($MgSO_4$, 2.5%), zinc sulfate ($ZnSO_4$, 2.5%), aluminium sulfate ($Al_2(SO_4)_3$, 2.5%), potasium iodide (KI, 2.5%), hydroquinone (HQ, 2.5%), anthraquinone (AQ, 0.1%) and ethylene diamine (EDA, 2.5%). Then each anthraquinone-soda liquor for the determination of suitable cooking condition was the active alkali level of 15, 17 and 19 percent with 1.0, 0.5 and 0.1 percent anthraquinone, respectively. The cooking procedure for the pulps was scheduled to heat to 170$^{\circ}C$ in 90 minutes and to cook 90 minutes at the maximum temperature. The anthraquinone-soda pulps from both heartwood and sapwood of 15-year-old larchwood prepared with 0.5 percent anthraquinone and 18 percent active alkali were bleached in a four-stage sequency of OCED. (O: oxygen bleaching, D: chlorine dioxide bleaching and E: alkali extraction). In the first stage oxygen in atmospheric pressure was applied to a 30 percent consistency of pulp with 0.1 percent magnesium oxide (MgO) and 3, 6, and 9 percent sodium hydroxide on oven dry base, and the bleached results were compared pulps bleached under the conventional CEDED (C: chlorination). The results in the study were summarized as follows: 1. The screened yield of larch kraft pulp did not differ from particular ages to age group, but heartwood ratio, basic density, fiber length and water-extractives contents of wood and the tear factor of the pulp increased with increasing the tree age. The total yield of the pulp decreased. 2. The yield of soda pulp with various chemicals for cellulose protection of the 15-year-old larchwood increased slightly more than that of pure soda pulp and was slightly lower than that of kraft pulp. The influence of cellulose protectors was similar to the yield of pulps from both sapwood and heartwood. The effective protectors among seven additives were KI, $MgSO_4$ and AQ, for which the yields of screened pulp was as high as that of kraft pulp. Considering the additive level of protector, the AQ was the most effective in improving the yield and the quality of pulp. 3. When the amount of AQ increased in soda cooking, the yield and the quality of the pulp increased but rejects in total yield increased with decreasing the amount of active alkali from 19 to 15 percent. The best proportion of the AQ seemed to be 0.5 percent at 17 percent active alkali in anthraquinone-soda pulping. 4. On the bleaching of the AQ-soda pulp at 30 percent consistency with oxygen of atomospheric pressure in the first stage of the ODED sequence, the more caustic soda added, the brighter bleached pulp was obtained, but more lignin-selective bleaching reagent in proportion to the oxygen was necessary to maintain the increased yield with the addition of anthraquinone. 5. In conclusion, the suitable pulping condition for larchwood to improve the yield and quality of the chemical pulp to the level for kraft pulp from conventional process seemed to be. A) the selection of young larchwood to prevent decreasing in yield and quality due to the accumulation extractives in old wood, B) the application of 0.5 percent anthraquinone to the conventional soda cooking of 18 percent active alkali, and followed, C) the bleaching of oxygen in atmospheric pressure on high consistency (30%) with 0.1 percent magnesium oxide in the first stage of the ODED sequence to reduce the content of chlorine compounds in effluent.

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Preparation of Concrete Admixtures from Pine Bark Wasts(III) -Improvement of Strength Properties on Cement Mortar Using ASAQ Cooking Spent Liquor with Surfactants- (폐 소나무 수피로부터 콘크리트 혼화제의 제조(III) -ASAQ 증해폐액에 계면활성제 첨가에 의한 시멘트 모르터의 강도 특성 개선-)

  • 박성천;문성필;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.04b
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    • pp.751-754
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    • 1998
  • The study was carried out the efficiency of spent liquor(BSL) obtained from alkaline sulfite-anthraquinone cooking of pine bark added various surfactants. By adding surfactant to alkaline, weak alkaline, nertralized BSL, the dispersing ability of cement was remarkably improved. It was shown that the rate of water-reducing was 20~22%. The most superior efficiency surfactant was MTG. When BSL, MBSL and ABSL were added to MTG, the improvement of early and later strength was clear and also exhibited the superior properties of strength compared to PLAIN. Therefore, is a possibility that BSL will be used instead of melamine-base admixtures.

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Preparation of Concrete Admixtures from Pine Bark Wasts(II) -Conversion of Spent Liquor Obtained from Alkaline Sulfite- Anthraquinone(ASAQ) Cooking of Pine Bark Waste to Normal and Accelerating Concrete Admixtures- (폐 소나무 수피로부터 콘크리트 혼화제의 제조(II) - 소나무 수피 ASAQ증해 폐액의 표준형 및 촉진형 콘크리트 혼화제로의 전환 -)

  • 박성천;문성필;문소현;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.04b
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    • pp.747-750
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    • 1998
  • The application of spent liquor(BSL) obtained from alkaline sulfite-anthraquinone cooking of pine bark to cement mortar significantly improved the water-reducing ability and decreased the rate of cement hardening. However, the compressive and flexural strength of BSL addition to cement mortar were lower than that of PLAIN. The application of 0.2% antifoamer to BSL slightly decreased water-reducing ability, but remarkably improved the compressive and flexural strength of cement mortar. On the other hand, BSL decreased the rate of hardening of cement, which exhibited the protperties of the lignosulfonated based retarding water-reducing type. but the setting time of cement could be controlled by addition of Na2CO3 could be used to convert BSL to normal or accelerating concrete admixtures.

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Utilization of Pine Bark(II) -Characterization of Mg- and Na-base Acid Sulfite Cooking- (소나무 수피(樹皮)의 총합적(總合的) 이용(利用)(II) -Mg- 및 Na-base 산성(酸性) 아황산염(亞黃酸鹽) 증해(蒸解) 특성(特性)-)

  • Mun, Sung-Phil;Kim, Jae-Phil
    • Journal of the Korean Wood Science and Technology
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    • v.22 no.1
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    • pp.34-39
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    • 1994
  • Effects of Mg-base acid sulfite and Mg- or Na-base bisulfite on pine bark cooking were examined. In the presence of 75 % free acid at 145 $^{\circ}C$, the rate of cooking and delignification was improved with the increase of total acid. However, the delignification could not be achieved by 50 % or more under these cooking conditions. When cooked with 50~65 % free acid and at 155~165 $^{\circ}C$, the rate of cooking and delignification was remarkably improved. Thus, the bark was delignified up to 73 % when cooked for 2 hours in the presence of 50 % free acid and 24 % total acid. Na-base bisulfite was slightly more effective than Mg-base bisulfite for cooking, giving 76 % delignification of pine bark. However, there was no significant difference in selectivity of delignification between Na- and Mg-base bisulfite cooking.

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Manufacturing and Feed Value Evaluation of Wood-Based Roughage Using Lumber from Thinning of Oak and Pitch Pine (참나무류와 리기다소나무 간벌재를 이용한 목질 조사료 제조 및 사료가치 평가)

  • Kim, Seok Ju;Lee, Sung-Suk;Baek, Youl Chang;Kim, Yong Sik;Park, Mi-Jin;Ahn, Byeong Jun;Cho, Sung-Taig;Choi, Don-Ha
    • Journal of the Korean Wood Science and Technology
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    • v.43 no.6
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    • pp.851-860
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    • 2015
  • The objective of this study was to manufacture the wood based roughage using lumber from thinning of oak and pitch pine (Pinus rigida). And the study also aimed to investigate a feed value evaluation of wood based roughages. To investigate the optimization condition of steam-digestion treatment for roughage, the wood chips of oak and pitch pine were steam-digestion treated at $160^{\circ}C$ under pressure 6 atm depending on treatment times (60 min, 90 min and 120 min) followed by the content of essential oils analyzed. The essential oil content of steam-digestion treated roughages for 90 min and 120 min were under 0.1 mL/kg. The evaluation of feed value was carried out from steam-digestion treated roughages for 90 min through feed chemical composition analysis, NRC (National research Council) modeling, ruminal degradability analysis and relative economic value analysis. The feed chemical compositions including DM (dry mater), CP (crude protein), EE (ether extract), NDF (neutral detergent fiber), ADF (acid detergent fiber), ADL (acid detergent lignin), NFC (nonfiber carbohydrate) in oak roughage were 95.4, 1.36, 3.11, 90.05, 83.85, 17.33, 6.50%, respectively, and in pitch pine roughage were 94.37, 1.33, 5.48, 87.89, 86.88, 30.56, 6.32%, respectively. Both roughages showed low level of protein and very high level of NDF. The TDN (total digestible nutrient) levels using NRC (2001) model in oak and pitch pine roughages were 40.55, 31.22%, respectively. The ruminal in situ dry matter degradability was higher in oak roughage (23.84%) than in pitch pine roughage (10.02%). The economic values of oak and pitch pine rough-ages were 235, and 210 \, respectively.

Difference of the Chemical Compositions Between Petroleum Ether Extract and its Tall Oil in Pitch Pine, Pinus Rigida Mill (리기다소나무재(材)의 유기용매(有機溶媒) 추출물(抽出物)과 그 tall oil 간의 조성(組成)의 차이(差異))

  • Ko, Sang-Woon;Ahn, Won-Yung
    • Journal of the Korean Wood Science and Technology
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    • v.16 no.2
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    • pp.79-89
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    • 1988
  • This experiment was carried out to investigate the difference of compositions between petroleum ether extract and its tall oil in Pinus rigida Mill. xylem and to obtain the basic data on effective extraction and its utilization of by-product, resin and fatty acid, when pulp making. After both petroleum ether extract from wood meal and its tall oil in pitch pine were separated to the resin and fatty acid by using DEAE-Sephadex and aluminum oxide column, these were analyzed with gas chromatograph. The results obtained were as follows: 1. Fatty acids contained as ester form in living trees were varied by peroxide of organic solvent in petroleum ehter extraction and cooking chemicals in cooking. 2. Pimaric-type acid was eluted earlier than abietic-type acid in resin acids and the fewer the carbons, the earlier the elution in fatty acids. 3. The retention time of SE-30 column was even smaller than that of OV-101 column but the relative retention time obtained by using methyl pimarate and methyl stearate as internal standard was nearly identical. 4. Both petroleum ether extract and tall oil mainly consisted of resin acids, expecially abietic-type acid. 5. Tall oil had more fatty acid but less resin acid than petroleum ether extract. Also, the content of unidentified materials was increased owing to the isomerization and the shift of double bond position in unsaturated fatty acids by high temperature and cooking chemicals when cooking.

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Magnesium Sulfate Resistance of Geopolymer Incorporating Evaporated Rice Husk Powder (증해추출 왕겨분말을 혼입한 지오폴리머의 황산마그네슘 저항성에 관한 연구)

  • Cho, Seung-Bi;Kim, Young-Su
    • Journal of the Korea Institute of Building Construction
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    • v.22 no.6
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    • pp.663-672
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    • 2022
  • The purpose of this study is to evaluate the magnesium sulfate resistance of a geopolymer mixed with rice husk powder. General concrete, silica fume mixed concrete, and binary blended geopolymer were selected as comparison targets to confirm the magnesium sulfate resistance, and sulfate deterioration was calculated using the compressive strengths with ages. In addition, the weight change rate and the relative dynamic coefficient of the geopolymer were comparatively analyzed, and the degree of etteringite formation was confirmed using X-ray diffraction analysis. the experiment, the geopolymer mixed with 10% rice husk powder showed 10.8% higher compressive strength than concrete with silica fume when submerged for 56 days. Also, the geopolymer mixed with rice husk powder showed a small weight change rate of 0.9 to 1.45%. composition after immersion in magnesium sulfate through X-ray diffraction analysis, it was observed that a small amount of ettringite was dispersed in the geopolymer containing rice husk powder. Thus, there is a high correlation with the corrosion resistance of magnesium sulfate

Utilization of Pine Bark(I) -Chemical Compositions and Characterization of Ca-base Acid Sulfite Cooking of Pine Bark- (소나무 수피(樹皮)의 총합적(總合的) 이용(利用)(I) -수피(樹皮)의 화학적(化學的) 조성(組成)과 Ca-base 산성(酸性) 아황산염(亞黃酸鹽) 증해(蒸解) 특성(特性)-)

  • Mun, Sung-Phil;Kim, Jae-Phil
    • Journal of the Korean Wood Science and Technology
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    • v.22 no.1
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    • pp.28-33
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    • 1994
  • The chemical compositions of pine bark from mechanical pulp industry were determined, and effect of Ca base acid sulfite on bark cooking was investigated under various conditions. The pine bark was composed of 39.5 % alkali extractives, 50.3 % lignin, and a small amount of carbohydrate. The contents of alkali extractives and lignin were remarkably higher than those of pine wood. The bark was composed of high content of arabinose and xylose, while the wood was composed of high content of mannose. When pine bark was cooked with 75 % free acid at 145 $^{\circ}C$, the rate of cooking and delignification was improved with the increase of total acid, but it was very difficult to delignify the bark by 50 % and over under these conditions. In the presence of 60~65 % free acid and at 155~165 $^{\circ}C$, initial cooking rate, delignification, and delignification selectivity were considerably increased, but condensation reaction of lignin was considerable at the end of cooking. Therefore, it was shown that pine bark was very difficult to delignify by the Ca-base acid sulfite cooking.

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Investigation of the Effects of Environment Friendly Digestion Process on the Rice Hull (왕겨의 고도활용을 위한 친환경 고온고압 증해처리 효과)

  • Lee, Young-Ju;Jung, Woong-Ki;Sung, Yong-Joo
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2011.04a
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    • pp.139-150
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    • 2011
  • The effects of the high pressure and the high temperature digesting process with water on the properties of rice hull were investigated in this work. Two temperature condition such as $160^{\circ}C$ and $180^{\circ}C$ and thee treatment time such as 15 min, 30 min and 45 min were applied for this treatment. The pH of extract after the digestion process decreased as the temperature and the treatment time of the digestion were increased. The ash content and lignin content were not decreased by the the digestion. The structure of rice hull after digestion treatment became more weak, the better efficiency of the fiberization with PFI-Mill was shown for the digestion treated rice hull with the higher temperature and the longer treatment time.

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