• Journal of the korean academy of Pediatric Dentistry
• /
• v.31 no.3
• /
• pp.516-526
• /
• 2004

Polymerization shrinkage of photoinitiation type composite resin cause several clinical problems. The purpose of this study was to evaluate the shrinkage strain stress, linear polymerization shrinkage, compressive strength and microhardness of recently developed composite resins. The composite resins were divided into four groups according to the contents of matrix and filler type. Group I : $Denfil^{TM}$(Vericom, Korea) with conventional matrix, Group II : $Charmfil^{(R)}$(Dentkist, Korea) with microfiller and nanofller mixture, Group III : $Filtek^{TM}$ Z250(3M-ESPE, USA) TEGDMA replaced by UDMA and Bis-EMA(6) in the matrix, and Group IV : $Filtek^{TM}$ Supreme(3M-ESPE, USA) using pure nanofiller. Preparation of acrylic molds were followed by filling and curing with light gun. Strain gauges were attached to each sample and the leads were connected to a strainmeter. With strainmeter shrinkage strain stress and linear polymerization shrinkage was measured for 10 minutes. The data detected at 1 minute and 10 minutes were analysed statistically with ONE-way ANOVA test. To evaluate the mechanical properties of tested materials, compressive hardness test and microhardness test were also rendered. The results can be summarized as follows : 1. Filling materials in acrylic molds showed initial temporary expansion in the early phase of polymerization. This was followed by contraction with the rapid increase in strain stress during the first 1 minute and gradually decreased during post-gel shrinkage phase. After 1 minute, there's no statistical differences of strain stress between groups. The highest strain stress was found in group IV and followed by group III, I, II at 10 minutes-measurement(p>.05). In regression analysis of strain stress, group III showed minimal inclination and followed by group II, I, IV during 1 minute. 2. In linear polymerization shrinkage test, the composite resins in every group showed initial increase of shrinkage velocity during the first 1 minute, followed by gradually decrease of shrinkage velocity. After 1 minute, group IV and group III showed statistical difference(p<.05). After 10 minutes, there were statistical differences between group IV and group I, III(p<.05) and between group II and group III(p<.05). In regression analysis of linear polymerization shrinkage, group II showed minimal inclination and followed by group IV, III, I during 1 minute. 3. In compressive strength test, group III showed the highest strength and followed by group II, IV, I. There were statistical differences between group III and group IV, I(p<.05). 4. In microhardness test, upper surfaces showed higher value than lower surfaces in every group(p<.05).

• Electrical & Electronic Materials
• /
• v.6 no.4
• /
• pp.354-360
• /
• 1993

열수축성 튜브 제조에 적합한 조성을 얻기 위하여 PVC의 방사선가교에 대하여 검토하였다. 중합도가 각각 다른 PVC에 가소제, 가교제를 변화시켜 배합한 혼합물을 방사선 가교시켰을 때 가교도는 가교제, 가소제, 중합도 및 조사선량이 증가됨에 따라 증가되었다. 가교제로서는 삼관능성 단량체가 높은 가교효율을 나타내었다. 가교 PVC 필름의 열수축성은 연신배율과 수축 온도를 높여줌으로써 증가되었으나 가교제 및 가소제의 증가량에 의한 열수축성의 증가는 나타내지 않았고 저중합도 PVC의 열수축성은 극히 저조하였다.

• Journal of the korean academy of Pediatric Dentistry
• /
• v.30 no.1
• /
• pp.102-109
• /
• 2003

The purpose of this study was to evaluate the linear polymerization shrinkage(%) and microhardness of composite resin(Z-100, 3M, USA) according to 2-step light curing method. Conventional light curing unit(Curing Light 2500, 3M USA) and 2-step light curing unit(Elipar Highlight, ESPE, Germany) were used as light source. The strain gauge method was used for determination of polymerization shrinkage(%). Samples were divided by 3 groups according to light curing methods (Group I : $450mW/cm^2$, 40sec, Group II : $650mW/cm^2$, 40sec, Group III : $150mW/cm^2$, 10sec & $650mW/cm^2$, 30sec). Preparations of acrylic molds were followed by filling and curing. Strain gauges attached to each sample were connected to a strainmeter. Measurements were recorded at each second for the total of 10 minutes including the periods of light application. And microhardness of each group after 24hours from light irradiation were measured. Obtained data were analyzed statistically using Ore-way ANOVA and/or Scheffe test. The results of the present study can be summarized as follows: 1. Composite resin in acrylic molds showed the initial expansion at the early phase of polymerization. This was followed by the contraction with the rapid increase in volume during the first 60 seconds and gradually diminished as curing process continued. 2. The lowest linear polymerization shrinkage(%) was found in group III followed by group I, II during the measuring periods. 3. Group III using 2-step curing method showed statistically significant reduction of linear polymerization shrinkage(%) compared with group I, II at 1 minute and 10 minutes from light irradiation(p<0.05). 4. The microhardness values of each group not revealed significant difference.

• Journal of the korean academy of Pediatric Dentistry
• /
• v.43 no.4
• /
• pp.365-373
• /
• 2016

Composites are the most useful restorative material. However, composites have some disadvantages such as polymerization shrinkage, long working time, and susceptibility to water and contamination, which are stood out more especially when treating children. To solve these problems, bulk-fill composites have been developed. The aim of this study is to compare mechanical properties of bulk-fill and conventional composites. Bulk-fill composites (SureFil SDR flow (SDR), Tetric N-Ceram bulk fill (TBF)) and conventional composites (Filtek Z-350 (Z-350), Unifil Flow (UF), Unifil Loflo Plus (UL)) were used. The Vickers hardness tester was used to measure the microhardness of materials, and Fourier transform infrared spectroscopy was used to measure the degree of conversion. Polymerization shrinkage was measured by using a linometer. Flexural and compressive properties were measured by using the universal testing machine. Data were statistically analyzed by ANOVA and Scheffe's post hoc test. The level of significance was set to p < 0.05. Most conventional composites showed higher microhardness than bulk-fill composites. However, bulk-fill composites showed a higher top/bottom microhardness ratio than conventional composites. Bulk-fill composites showed a higher top/bottom degree of conversion ratio than conventional composites. The polymerization shrinkage was highest in UL and lowest in Z-350. The polymerization shrinkage of flowable composites was higher than that of non flowable composites. The compressive properties were highest in Z-350 and lowest in SDR and UL. In terms of flexural properties, Z-350 was the highest. However, none of the bulk-fill composites exhibited mechanical properties as good as those of conventional composites. Nonetheless, the ratio of microhardness and degree of conversion, which are important properties of bulk filling, were higher in bulk-fill composites. Therefore, the bulk-fill composites might be considered suitable restorative materials in pediatric dentistry.

• Journal of the korean academy of Pediatric Dentistry
• /
• v.35 no.1
• /
• pp.18-29
• /
• 2008

The purpose of this study was to compare the polymerization shrinkage of several filling methods using strain gauges. In this study, a light-emitting diode(LED) curing unit(Elipar Freeligh2, 3M EPSE, USA) and plasma arc lamp(PAL) curing unit(Flipo, LOKKI, France) were used for curing, Filtek $Z350^{TM}$(3M EPSE, USA) composite resin was used for the cavity filling. Sixty permanent bicuspid teeth, that were extracted for orthodontic treatment, were studied. The cavities were prepared on the occlusal surface and were filled using the following methods : 1) bulk filling, 2) parallel filling, 3) oblique filling The strain was recorded on the buccal, lingual, mesial and distal surfaces and the strain values were computed into stress values. The shear bond strength of each filling method was tested using a Micro Universal Testing machine. The results can be summarized as follows: 1. In the strain changes, all LED and PAL curing groups showed an increase on the buccal surface and a slow decrease as time elapsed. 2. In the strain changes of the mesial and distal surfaces, the decreases and increases were shown repeatedly and reduced as time elapsed. 3. There were no significant statistical strain changes among filling methods in the LED or PAL curing groups. 4. There were significant statistical strain changes between the LED and PAL curing groups on the buccal surface(p<0.05). 5. From the shear bond strength results, in the LED curing group, filling method 3 showed lower surface stress than filling method 1 and 2(p<0.05). In the PAL curing group, there were no significant statistical strain changes between each filling method. 6. The surface stress of each group was lower than the shear bond strength.

• Restorative Dentistry and Endodontics
• /
• v.28 no.4
• /
• pp.348-353
• /
• 2003

The purpose of present study was to evaluate the polymerization shrinkage stress and amount of linear shrinkage of composites and compomers for posterior restoration. For this purpose, linear polymerization shrinkage and polymerization stress were measured. For linear polymerization shrinklage and polymerization stress measurement, custom made Linometer (R&B, Daejon, Korea) and Stress measuring machine was used (R&B, Daejon, Korea). Compositers and compomers were evaluated: Dyract AP (Dentsply Detrey, Gumbh. German) Z100 (3M Dental Products, St. Paul. USA) Surefil (Dentsply Caulk, Milford, USA) Pyramid (Bisco, Schaumburg, USA) Synergy Compact (Coltene, Altstatten, Switzerland), Heliomolar (Vivadent/Ivoclar, Liechtenstein), and Compoglass (Vivadent Ivoclar/Liechtenstein) were used. 15 measurements were made for each material. Linear polymerization shrinkage or polymerization stress for each material was compared with one way ANOVA with Tukey at 95% levels of confidence. For linear shrinkage: Heliomolar, Surefil

• Polymer(Korea)
• /
• v.30 no.2
• /
• pp.135-139
• /
• 2006

To evaluate the dental restorative application of polymer composites filled with hydroxyapatite (HAP) which is an inorganic component of human bone material, dental properties of the polymer composites were investigated. A visible light system was utilized to activate the acrylate resin matrix of the composites. Maximum loading percentage of HAP in composite was 65 wt% and the depth of cure was 6.0 mm which can be applicable for dental restoration. With increasing the HAP content, degree of conversion of polymer composites was slightly decreased, however, polymerization shrinkage value was not varied. Diametral tensile strength value was enhanced with an increase of HAP content, however, there was no strict trend between flexural strength and HAP concentration. Anyhow, polymer composites prepared herein have superior mechanical properties sufficient specifications applicable to dental materials.

• Journal of the korean academy of Pediatric Dentistry
• /
• v.46 no.1
• /
• pp.1-9
• /
• 2019

The aim of this study was to compare the degree of conversion and polymerization shrinkage of low and high viscosity bulk-fill giomer-based and resin-based composites. Two bulk-fill giomer (Beautifil Bulk Restorative (BBR), Beautifil Bulk Flowable (BBF)), two bulk-fill (Tetric N-Ceram Bulk-fill (TBF), SureFil SDR flow (SDR)) and two conventional resin composites (Tetric N-Ceram (TN), Tetric N-flow (TF)) were selected for this study. The degree of conversion was measured by using Fourier transform infrared spectroscopy. Polymerization shrinkage was measured with the linometer. For all depth, BBR had the lowest degree of conversion and SDR had the highest. At 4 mm, the degree of conversion of low and high viscosity bulk-fill giomer resin composites was lower than that of bulk-fill resin composites (p < 0.05). At the depth between 2 mm and 4 mm, there were significant difference with TBF, TN and TF (p < 0.05), while no significant difference in the degree of conversion was measured for BBR, BBF and SDR. Polymerization shrinkage of six resin composites decreased in the following order: TF > SDR > BBF > TBF > TN and BBR (p < 0.05). Polymerization shrinkage of bulk-fill giomer resin composites was lower than that of bulk-fill resin composites (p < 0.05). From this study, it is found that the bulk-fill giomer resin composites and TBF were not sufficiently cured in 4 mm depth. The degree of conversion of low and high viscosity bulk-fill giomer resin composites was significantly lower than bulk-fill resin composites in both 2 mm and 4 mm depths. Therefore, such features of bulk-fill giomer resin composites should be carefully considered in clinical application.

• Proceedings of the Korean Society of Dyers and Finishers Conference
• /
• 2011.11a
• /
• pp.28-28
• /
• 2011

최근 초경량 직물에 나일론 Spiral Crimp 신축소재에 많이 사용되어지는 Mechanical 신축성 직물이 시판되고 있으나 신축특성의 저하, 품질 저하의 문제점이 대두되고 있어 아직까지 본격적으로는 상용화되지 못하고 있고 국내외적으로 아직까지 나일론 세섬사 Spiral Crimp 신축소재개발과 관련된 기술개발은 전무한 실정이다. 따라서 본 연구에서는 현재까지 국내외적으로 개발되지 못한 스포츠 아웃도어용 경량직물의 Mechanical 신축성 초경량 직물을 개발하기 위해서 중합단계에서 나일론 개질 폴리머를 개발하고, 수축 특성이 서로 다른 2종의 나일론 폴리머를 이용하여 side by side 형태로 세섬 복합방사와 사가공 및 연신 단계에서 2d급 Spiral Crimp 및 Super Bulky특성이 우수한 신축성 소재를 개발하여 이들의 구조와 물성을 조사 검토하여 이를 실제 현장에 자료를 제공하는 것을 목적으로 하였다.

• Polymer(Korea)
• /
• v.33 no.2
• /
• pp.153-157
• /
• 2009

The resin matrix in the dental composite is generally composed of 2,2-bis[4-(2-hydroxy-3-methacryloyloxy propoxy) phenyl] propane (Bis-GMA) as a base resin and triethylene glycol dimethacrylate (TEGDMA) as a diluent for the reduction of viscosity. The applications of dental composite were often limited in dentistry due to the relatively large amounts of volumetric shrinkage during polymerization and water uptake caused by the addition of TEGDMA to the resin matrix. In this study, in order to solve problems stemmed from the TEGDMA by reducing amount of diluent added to resin matrix, diethylene glycol dimethacrylate (DEGDMA) and ethylene glycol dimethacrylate (EGDMA) were explored as new diluents. A decrease in the volumetric shrinkage and an increase in the mechanical strength were observed by replacing TEGDMA in the dental composite to DEGDMA (or EGDMA). Reduction in the mechanical strength of the dental composite containing DEGDMA (or EGDMA), was not serious in comparison with that of the dental composite containing TEGDMA after water uptake.