• Title/Summary/Keyword: 중금속 함량

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장풍광산 폐광석의 중금속오염 연구와 pH변화가 중금속의 용출거동에 미치는 영향평가

  • 이인경;이평구;최상훈
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.04a
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    • pp.385-388
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    • 2003
  • 폐광석에 함유되어 있는 총중금속함량을 측정하기 위한 전함량분석과 중금속을 다량 함유한 폐광석이 산성환경에 노출되어 있을 경우 중금속의 지화학적 거동을 파악하기 위해 산도를 변화시키면서 용출실험을 실시하였다. 전함량분석과 용출실험을 종합한 결과, 중금속 및 미량원소의 용출거동 특성을 크게 As-Co-Fe 형태와 Cu-Mn-Cd-Zn형태와 Pb로 구분할 수 있었다. As-Co-Fe의 용출특성은 약산성의 환경에서는 용출이 미약하나, 최종 pH 1.5이하의 강산성환경에서는 용출량이 급격하게 증가하며, Cu-Mn-Cd-Zn형태에서는 최초로 용해되는 pH가 5.0-3.0으로 As-Co-Fe 보다 다소 높았다. Pb는 다른 형태에 비해 상당히 적게 용출되었다 최종 용출된 함량과 관계없이 초기 용출이 발생하는 pH값을 기준으로 한 각 원소의 상대적인 이동성은 Mn =Zn>Cd=Cu>>Fe=Co>As>Pb 순서이며, 산성비는 Zn, Mn 및 Cu를 쉽게 용출시켜 이동도를 증가시킬 것으로 판단된다.

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Heavy Metal Contents of Compost from Household Food Waste (음식쓰레기 퇴비화과정 중 중금속함량 변화)

  • Seo, Jeoung-Yoon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.4 no.1
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    • pp.23-31
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    • 1996
  • The heavy metal concentration in mixed and separately collected household food waste, and their compost during the composting period was analysed. The mixed and separately collected food waste had Cd content of 8 mg/kg in spring and its content of 13 mg/kg in winter respectively. Its content was higher than by-product compost limit value(5 mg Cd/kg). Cd concentration in separately collected food waste in a house was higher in January, February, April and May than by-product compost limit value (5 mg Cd/kg). When Cd concentration in the initial composting material was higher than 5 mg/kg, its concentration in the compost of household food waste during the composting period was higher than by-product compost limit value, but it was not accumulated in the compost during the composting period. Fly ash was added to separately collected household food waste to adjust its moisture content for composting. Its addition had moisture conditioning and Cd concentration reducing effect in the compost. The average one month composted fresh compost from the mixed collected household food waste was matured in a pile out of doors for 7 months with turning the pile once a month and its heavy metal concentration was examined. Accumulation of the heavy metals in the compost did not occur during the composting period, because they were washed out during the rainfall.

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Contents of Heavy Metals in Soils of the Kum-Ho River Basin (금호강류성 하상토양중 중금속함량)

  • 문효노;장봉기;김두희
    • Journal of environmental and Sanitary engineering
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    • v.5 no.1
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    • pp.1.1-14
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    • 1990
  • This study was conducted to investigate the contents of heavy metals in soils of the Kumho river basin, by analyzing soils according to the distance from edge of the river and to the soil layers. The contents of heavy metals in soils showed highly in its downstream. Namely there was shown a remarkably high contents of these heavy metals in the Kum-ho bridge areas where Kongdan stream joins Dalseo stream, such as 39.52ppm for zinc, 35.92ppm for copper, 97.90ppm for iron, 102.45ppm for manganese, 13.92ppm for lead, respectively, and 0.48ppm for cadmium. However, the heavy metals contents in soils around Kangchang bridge tended to gradually decrease in its contents, probably because its main soils consisting of sand. Based on their soil layers, the average contents of these heavy metals in the surface soils were higher than one of the subsurface soil. Its contents according to the distance from the river edge indicated some difference every individual area. Nevertheless, its contents showed lower contents in the area far away from the edge. And its contents tended to again increase in the outside bank. In addition, a remarkable positive correlation is shorten between individual heavy metals, except correlation between iron and lead. Also cadmium just shows reverses correlation in the statistics. With respect to comparison between soil layers, there was a remarkable positive correlation between surface layers and subsurface layers. Considering the above results, it seems that the pollution of river bed's soil is in proportion to it of stream.

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Effects of Copper and Zinc on Germination, Chlorophyll and Organic Compounds in Seedling of Rice (Oryza sativa L.) (구리와 아연 처리가 벼의 발아, 유묘의 엽록소와 유기산 함량에 미치는 영향)

  • Kim, Sang-Kuk;Lee, Sang-Chul;Min, Gi-Gun;Lee, Seong-Phil;Choi, Boo-Sull;Yeo, Soo-Kab
    • Korean Journal of Soil Science and Fertilizer
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    • v.31 no.1
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    • pp.51-55
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    • 1998
  • The experiment was conducted to elucidate the growth response of rice seedling to heavy metals, copper and zinc. The copper and zinc concentration in rice seedling was 50mg/l and 100mg/l, respectively. Germination. chlorophyll and organic compounds were investigated in seedling of rice with or without heavy metals. Root growth and germination were inhibited at 50mg/l Cu and at 100mg/l compared to control and such reduction in growth was more remarkable at 100mg/l Zn than at 50mg/l Cu. Chlorophyll content was slightly reduced at both 50mg/l Cu and 100mg/l Zn. Malic acid was remarkably increased at 50mg/l Cu compared with that at Zn 100mg/l regardless of rice cultivars. The content of organic acids such as succinic, citric, and malic acid and free proline was increased with treatment of copper and zinc.

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Analysis of Heavy Metals in Annual Rings of Pinus thunbergii at Air Polluted Area (대기오염지역(大氣汚染地域)의 해송(海松) 연륜(年輪) 속의 중금속(重金屬) 분석(分析))

  • Kim, Jong-Kab;O, Ki-Chel
    • Journal of Korean Society of Forest Science
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    • v.88 no.4
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    • pp.429-437
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    • 1999
  • Heavy metals(Cd, Cu, Pb and Zn) in tree rings of P. thunbergii growing at Onsan Industrial Complex of air polluted area were analyzed to study the condition of heavy metal pollution. The tree ring width began to decrease after operation of factories and decreased abruptly at Onsan Industrial Complex after 1991. Cd contents in tree rings showed 119.4ppb to 867.0ppb level and suddenly increased after 1991. Cu contents showed 309.5ppb to 3686.8ppb, and Pb contents 911.33ppb to 7997.1ppb and fluctuations of those were high after operation of factories. Zn contents showed the highest level of 3528.7ppb to 23826.7ppb and largely ascended after 1960, and increased suddenly after 1992, as compared to former tendency. On the other hand, heavy metal contents in tree rings of P. thunbergii at Gosung of non-air polluted area were far lower than Onsan I. C., and there was a wide difference between both areas after 1990. On the heavy metal contents accumulated in bark of P. thunbergii of both areas, it was higher to 10 times in Cd, 1,000 times in Cu, 285 times in Pb and 133 times in Zn contents at Onsan than at Gosung. In the heavy metal analysis for circle plate and cores, heavy metal contents in cores were generally higher than those in disk and Pb contents showed specially high difference, but pattern of variation by tree age showed a similar tendency.

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Environmental Contamination and Bioavailability Assessment of Heavy Metals in the Vicinity of the Dogok Au-Ag-Cu Mine (도곡(Au-Ag-Cu)광산 주변지역의 중금속 원소들의 환경오염특성 및 생체흡수도 평가)

  • Lee Sung-Eun;Lee Jin-soo;Chon Hyo-Taek
    • Economic and Environmental Geology
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    • v.38 no.2 s.171
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    • pp.135-142
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    • 2005
  • In order to investigate the contamination level and seasonal variation of heavy metals and evaluate the bioavailability of toxic elements, environmental geochemical survey was undertaken at the Dogok Au-Ag-Cu mine area. The main pollution sources in the area were suggested as tailings, mine waste materials and mine water. Elevated levels of $140{\cal}mg/{\cal}kg{\;}As,{\;}107{\cal}mg/{\cal}kg{\;}Cd,{\;} 3017{\cal}mg/{\cal}kg{\;}Cu,{\;}12926{\cal}mg/{\cal}kg{\;}Pb,{\;}9094{\cal}mg/{\cal}kg$ Zn(before rainy season) were found in mine tailings. Concentrations of heavy metals in farmland soils exceeded normal level in nature soil (Bowen, 1979). The highest level of heavy metals was found in water samples near the mine tailing dumps regarded as a main pollution source of toxic elements in the area. These concentrations decreased to downstream due to the effect of dilution. From the results of sequential extraction analyses for tailings and soils, non-residual forms of heavy metals were found, which indicate the contamination to be progressing by continuing weathering and oxidation. Cadmium and Zn would be of the highest mobility in all samples. The bioavailability of Cd, Cu, Zn and As using SBET analysis from paddy soils was $53.3{\%},{\;}46.5{\%},{\;}41.0{\%}$ and $37.0\%$, respectively. The farmland soil sample(S3) showed the highest total concentration and bioavailability of heavy metals.

Effect of municipal sewage sludge application on the change of physico-chemical properties and contents of heavy metals in soils (도시하수(都市下水)Sludge의 시용(施用)이 토양이화학성(土壤理化學性) 및 중금속(重金屬) 이동 (移動)에 미치는 영향(影響))

  • Choi, Jyung;Chang, Sang-Moon;Lee, Dong-Hoon;Choi, Choong-Ryeol;Park, Seon-Do
    • Korean Journal of Environmental Agriculture
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    • v.17 no.2
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    • pp.170-173
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    • 1998
  • This study was conducted to investigate the effect of municipal sludge application on the change of physico-chemical properties and contents of heavy metals in soils. The application of the sludge resulted in increasing the content of total nitrogen, available phosphate,exchangeable K, Ca, Mg, and the soil porosity and permeability but soil hardness was reduce. It is clear that application of municipal sewage sludge would not due to increase in the heavy metals content in soil because of the lower concentration of heavy metal in the sludge. Totally it is evident that municipal sewage sludge application should play an important role in improving soil physico-chemical properties.

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Evaluation of Heavy Metal Contents in Mudflat Solar Salt, Salt Water, and Sea Water in the Nationwide Salt Pan (전국 염전에서 생산된 갯벌천일염, 함수 및 해수의 중금속 함량 평가)

  • Kim, Hag-Lyeol;Yoo, Young-Joo;Lee, In-Sun;Ko, Gang-Hee;Kim, In-Cheol
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.41 no.7
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    • pp.1014-1019
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    • 2012
  • This study was conducted to evaluate the heavy metal contents of mudflat solar salt, salt water, and sea water produced in the nationwide salt pan. In mudflat solar salt, moisture contents were significantly different (p<0.001) between regions, ranging from 7.357% to 14.862%. Arsenic (As) content ranged from 0.007 ppm to 0.497 ppm, cadmium (Cd) from 0.000 ppm to 0.101 ppm, plumbum (Pb) from 0.000 ppm to 0.191 ppm, hydrargyrum (Hg) from 0.006 ppb to 0.180 ppb, and copper (Cu) from 0.039 ppm to 4.794 ppm between regions, which were significantly different (p<0.001). Further, As, Cd, Pb, and Hg contents of sea and salt water were not in excess of their criterion points. Our results suggest that heavy metal contents of mudflat solar salt, salt water, and sea water produced in the nationwide salt pan were at safe levels. However, continuous management of heavy metal contamination, such as PVC met, is still necessary.

Atomic Absorption Spectrophotometric Analysis of Heavy Metals in the Soils of Paddy Fields Around Industrial Areas (원자흡광법에 의한 공업단지(경인${\cdot}$전북)주변답 토양중의 중금속함량분석에 관한 연구)

  • Park Seung Heui
    • Korean journal of applied entomology
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    • v.18 no.1 s.38
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    • pp.49-53
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    • 1979
  • Paddy lands around industrial areas in Gyeonggi and Jeonbuk provinces are increasingly concerned about pollution by heavy metals. This stimulated the quantitative analysis of copper, zinc, lead and cadmium in the soil from the aress concerned. Results obtained are summarized as follows: 1. Heavy metal contents of the soil from Sue-Myun, Siheung-Gun, Gyunggi province were 20.95 ppm of Cu, 226.46 ppm of Zn, 84.17 ppm of Pb, and 2.62 ppm of Cd, respectively. Those of Anyang, Kimpo, and Jeonbuk areas were as low as the natural background levels, about 10 ppm. 2. The contentration of heavy metals of the river valley soils tended to increase from upper stream to the lower. This seemed to be caused by the fact tat disposed water from plants flows to the lower stream and metals contained in the water accummlate in the soils around the lower stream. 3. Cadmium content was exceptionally lower than 0.2 ppm in all the areas tested. The present concentartion of cadmium is not of the extent to which any injury could occur to rice plants.

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포장재중금속함량권장기준및시험방법고시

  • Korea Packaging Association INC.
    • The monthly packaging world
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    • s.162
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    • pp.124-141
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    • 2006
  • 환경부는 포장재의 중금속 함량 권장기준 마련을 위한「제품의 포장재질∙포장방법에 관한 기준 등에 관한 규칙」이 개정됨에 따라 규제대상 중금속의 종류∙농도 및 시험방법 등을 마련하기위해 제정안을 입법 예고 했다. 본 고에서는 주요 내용을 살펴보도록 한다.

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