• Resources Recycling
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• v.31 no.4
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• pp.49-55
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• 2022

In this study, the heavy metal ions (of Pb, Cd, Cr, and Hg) in wastewater were removed using a spent Li₂O-Al₂O₃-SiO₂-based crystallized glass previously used as an induction top plate material. Changes in the removal efficiency of heavy metals according to different reaction parameters, such as the amount of zeolite used as a heavy-metal adsorbent, adsorption time, initial concentration of the heavy metals, and pH of the initial solution, were investigated. As the amount of zeolite added increased, the heavy-metal removal efficiency also increased. Adsorption time had a considerable influence on adsorption characteristics, and the removal efficiency of all heavy metals increased with increasing adsorption time. In the case of Cd, the removal efficiency was greatly improved depending on the adsorption time. The initial concentration of the heavy-metal solution did not affect the removal efficiency; however, the initial pH of the heavy-metal solution affected the removal efficiency. More specifically, the removal efficiency of Cd increased while that of Pb and Cr decreased with increasing pH. The adsorption characteristics of Hg were not significantly affected by pH.

• Economic and Environmental Geology
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• v.38 no.2 s.171
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• pp.135-142
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• 2005

In order to investigate the contamination level and seasonal variation of heavy metals and evaluate the bioavailability of toxic elements, environmental geochemical survey was undertaken at the Dogok Au-Ag-Cu mine area. The main pollution sources in the area were suggested as tailings, mine waste materials and mine water. Elevated levels of $140{\cal}mg/{\cal}kg{\;}As,{\;}107{\cal}mg/{\cal}kg{\;}Cd,{\;} 3017{\cal}mg/{\cal}kg{\;}Cu,{\;}12926{\cal}mg/{\cal}kg{\;}Pb,{\;}9094{\cal}mg/{\cal}kg$ Zn(before rainy season) were found in mine tailings. Concentrations of heavy metals in farmland soils exceeded normal level in nature soil (Bowen, 1979). The highest level of heavy metals was found in water samples near the mine tailing dumps regarded as a main pollution source of toxic elements in the area. These concentrations decreased to downstream due to the effect of dilution. From the results of sequential extraction analyses for tailings and soils, non-residual forms of heavy metals were found, which indicate the contamination to be progressing by continuing weathering and oxidation. Cadmium and Zn would be of the highest mobility in all samples. The bioavailability of Cd, Cu, Zn and As using SBET analysis from paddy soils was $53.3{\%},{\;}46.5{\%},{\;}41.0{\%}$ and $37.0\%$, respectively. The farmland soil sample(S3) showed the highest total concentration and bioavailability of heavy metals.

• Journal of the Korean Chemical Society
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• v.53 no.6
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• pp.793-804
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• 2009

In this study, high school students' perceptions of chemically ill-defined ‘heavy metals’ were examined through questionnaires. Nineteen classes of 11th graders (N = 611) were divided into two groups according to completion of 'Chemistry I', which were 10 science-classes and 9 liberal art-classes and compared each other. Three terms of students' cognition and definition, impact on the formation of their cognition, and their chemical knowledge of 'heavy metals' were analyzed by SPSS. The findings revealed that most of students recognized ‘the heavy metal’ as the metal which causes to be accumulated on any living thing and is hazardous in human body regardless of different major between liberal art and science. Mass media and school instruction were found to be the greatest impact on the formation of these cognitions. Especially, school instruction had more effects on students majoring in science than students majoring in liberal art, which bring the result that students in science-classes have more misconception about the definition of 'heavy metals' with human toxicant regardless of metal species and its content in human body and physical density due to the ill-defined terminology of the textbook than students in liberal art-classes do. It is interesting that students in science-classes understood hazard and chemical structure of 'heavy metals' better, while students in liberal art-classes answered the question better about hazardous properties of heavy metals.

• Microbiology and Biotechnology Letters
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• v.20 no.6
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• pp.693-698
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• 1992

The resistant effect of several heavy metal ions to Serratia marcescens strain P was studied by the method of minimal inhibitory concentration(MIC), and testing for their metal biosorption. S. marcescens strain P showed a good survival in the presence of high concentrations of some metal ions, namely cadmium, lead, iron, magnesium, and manganese. Copper had the most inhibitory effect among tested. The MIC value was ranged from 0.79 to 1.58 mM. Cells of S. marcescens strain P exhibit an abnormally long lag phase when incubated in high concentrations of zinc and cadmium. Pigment production was reduced by zinc and cadmium, but enhanced by lead and iron. S. marcescens strain P was resistant to ampicillin, tetracycline, cefamandole and chloramphenicol with minimal inhibitory concentration of 128 $\mu$g/ml, 32 $\mu$g/ml, 256 $\mu$g/ml, and 8 $\mu$g/ml, respectively. The kinetics study of biosorptive uptake by S. marcescens strain P revealed that 16.59% of cadmium and 35.38% of lead were eliminated from the media.

• Economic and Environmental Geology
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• v.36 no.1
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• pp.17-25
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• 2003

Researches were carried out to investigate the characteristics and concentration of heavy metal elements of stream water through Dongmyoung abandoned metal mine and soil adjacent to the mine. The pH range of water was 5.9∼7.1 that implies the water environment was acidic to neutral. The contents and distribution aspects of heavy metals in water samples varied with geochemical characteristics of element, but the concentration of heavy metals has the tendency of increase closer to the mine in general. The results of soil analysis show that total heavy metal concentration of agricultural soil near mine was far lower than those of ore tailing and dumping site. Therefore, the effects of the abandoned mine on stream water and agricultural products were supposed to be insignificant, particularly because the portion of absorbed carbonates and reducible fractions among total heavy metal concentration was relatively lower than the other. Since, however total heavy metal concentrations of mining site were relatively higher than those of adjacent region, there is a possibility of heavy metal difussion when the chemical environment of the site changes due to migration of surface and underground water. It is suggested that the preventive measures for water and soil pollution by the heavy metals would be considered around the region.

• Journal of the Korea Organic Resources Recycling Association
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• v.21 no.3
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• pp.53-63
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• 2013

It is well known that problem for contaminated soil with heavy metals is mainly produced from agricultural land around abandoned metal mine and the cost to solve them is much higher than those of water and air pollution in addition, it takes much more time to clarify the contaminated soil. Until now, economical and practical many techniques to remediate contaminated soils with heavy metals have been developed and proposed. Therefore, in this study, characteristic, merit and weakness for various techniques which are developing and commercializing recently in domestic/foreign country will be reviewed.

• Clean Technology
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• v.18 no.4
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• pp.341-346
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• 2012

Many researchers have studied that many processes to effectively remove heavy metals in water/wastewater. Especially, among many processes, physical and chemical processes are relatively simple and obtain high treatment efficiency for removal heavy metals compared with biological treatment. Recently, interests in physical and chemical methods are sharply increasing again because of dangerousness for radioactive element. In this study, various physical and chemical processes such as chemical precipitation, ion-exchange, electrodialysis, and membrane separation are introduced.

• Ecology and Resilient Infrastructure
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• v.7 no.1
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• pp.63-71
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• 2020

Various types of amendments have been studied for heavy metal stabilization in soil. However, researches on the effect of amendments on alkali soil and their effects on the plants at various edible parts are insufficient. The aim of this study was to evaluate the stabilization efficiency of heavy metals and their transfer into edible parts of food crops. Abandoned mine area was selected and 3 types of amendments (lime stone, LS; steel slag, SS; acid mine drainage sludge, AMDS) was applied with 3% (w/w). in field. After 6 month aging, Chinese cabbage (leafy), bok choy (leafy), garlic (root) and red pepper (fruit) were transplanted and cultivated. For chemical assessment, total concentration and bioavailability using Mehlich-3 solution were determined. For biological assessment, fresh weight and heavy metal uptakes were analyzed. It was revealed that AMDS reduced bioavailability most effectively, resulting in the decrease in heavy metal concentration in edible parts of all crops. When explaining the heavy metal uptake of plants, the bioavailability was more appropriate than the total contents of soil heavy metals. Therefore, bioavailability-based further research and management practices should be carried out continuously for the sustainable environment management, safe crop production, and human health risk reduction.

• Proceedings of the KSEEG Conference
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• 2002.04a
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• pp.31-33
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• 2002

• Korean Journal of Environmental Agriculture
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• v.23 no.2
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• pp.92-98
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• 2004

The adsorption and desorption of Pb, Cd, Co, Zn, Cr, Co, Ni, and Mo on the waste Undaria sp. were studied. Except for Pb. the mono adsorption rate for all heavy metals were lower than that of the heavy metals mixed. However, the adsorption capacity of the heavy metals by 1g of biosorption, in mixed heavy metals increased According to FT-IR analysis of the biosorbent after heavy metal biosorption, the replacement of the functional group by the heavy metals ions could be confirmed and the inverted peaks became larger after heavy metals adsorption. The adsorption equilibrium of heavy metals was reached in about 1 hour. The equilibrium parameters were determined based on Langmuir and Freundlich isotherms. The affinity of metals on the biosorbent decreased in the following order: Pb>Cu>Cr>Cd>Co. The desorption rate decreased in the following sequence: NTA>$H_2SO_4$>HCl>EDTA. The desorption rate of heavy metals by NTA increased with increase in the concentration from 0.1 to 0.3% but the desorption rate became constant beyond 0.3%. Therefore, it represented that desorption rate of heavy metals was suitable under optimized condition ($30^{\circ}C$, pH 2 and 0.3% NTA solution) and was fast with 80% or more the uptake occurring within 10 min of contact time.