• Title/Summary/Keyword: 중간체

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Synthesis of Borosilicate Zeotypes by Steam-assisted Conversion Method (수증기 쪼임법에 의한 제올라이트형 보로실리케이트 제조방법)

  • Mansour, R.;Lafjah, M.;Djafri, F.;Bengueddach, A.
    • Journal of the Korean Chemical Society
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    • v.51 no.2
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    • pp.178-185
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    • 2007
  • Intermediate pentasil borosilicate zeolite-like materials have been crystallized by a novel method named steam-assisted conversion, which involves vapor-phase transport of water. Indeed, amorphous powders obtained by drying Na2O.SiO2.B2O3.TBA2O gels of various compositions using different boron sources are transformed into crystalline borosilicate zeolite belonging to pentasil family structure by contact with vapors of water under hydrothermal conditions. Using a variant of this method, a new material which has an intermediate structure of MFI/MEL in the ratio 90:10 was crystallized. The results show that steam and sufficiently high pH in the reacting hydrous solid are necessary for the crystallization to proceed. Characterization of the products shows some specific structural aspects which may have its unique catalytic properties. X-ray diffraction patterns of these microporous crystalline borosilicates are subjected to investigation, then, it is shown that the product structure has good crystallinity and is interpreted in terms of regular stacking of pentasil layers correlated by inversion centers (MFI structure) but interrupted by faults consisting of mirror-related layers (MEL structure). The products are also characterized by nitrogen adsorption at 77 K that shows higher microporous volume (0.160 cc/g) than that of pure MFI phase (0.119 cc/g). The obtained materials revealed high surface area (~600 m2/g). The infrared spectrum reveals the presence of an absorption band at 900.75 cm-1 indicating the incorporation of boron in tetrahedral sites in the silicate matrix of the crystalline phase.

Design and Construction of the Cultivating Weeder for a 3-Wheel Riding Type Cultivating Vehicle (3륜 승용관리기용 중경제초기 설계 제작)

  • Choi, Il Soo;Choi, Yong;Lee, Beom Seob;Ji, Keum Bae;Yun, Young Tae;Yoo, Soo Nam
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2017.04a
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    • pp.77-77
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    • 2017
  • 현재 국내의 경우 4륜 승용관리기가 개발되었으나 성능 미비와 편이성 부족으로 승용관리기 및 부속 작업기 보급이 매우 저조한 상태이다. 3륜 승용관리기는 작업기 복부 장착으로 작업의 정밀도, 편이성, 관측의 용이성 향상과 함께 지상고 제고, 차폭 조절, 조향 등의 성능 개선을 기할 수 있다. 국내에서는 3륜 승용관리기용 복부 장착 부속작업기가 거의 개발되어 있지 않으며, 특히 두류 재배에 있어서 일관기계화 작업을 위한 관리작업기의 개발은 매우 필요한 실정이다. 승용관리기에 의한 중경제초는 잡초방제는 물론 물 빠짐과 토양 속 통기가 좋아지고, 지온 조절, 쓰러짐 방지, 부정근 발생을 조장하여 콩의 생육과 결실을 좋게 함으로써 수량이 증가되는 효과가 있다. 따라서 본 연구는 3륜 승용관리기에 적합한 복부장착형의 중경제초기를 설계 제작하였다. 3륜 승용관리기용 중경제초기는 승용관리기의 복부 PTO에서의 구동력 전달을 위한 연결 조인트, 중간축, 기어 및 체인 전동기구, 구동축으로 구성된 동력전달부, 중경제초를 위한 5개의 로타리 날과 후방 1개의 제초날로 구성된 3조의 작업날, 경심 조절을 위한 바퀴, 다양한 조간거리에 적응을 위한 조간조정 나사부, 흙의 비산 방지를 위한 로타리 날 커버 및 케이스, 3륜 승용관리기에의 부착을 위한 프레임 및 부착보조 작업기 이동용 바퀴장치 등으로 구성 설계 제작하였다. 로타리 날은 기존 시판 관리기용 로타리 중경 날을 사용하였는데 진행방향에 역으로 회전하도록 하였고, 날의 회전반경은 약 330 mm, 조당 경운 폭은 약 250 mm, 최대 경심 100 mm로 설계하였다. 조간거리의 조절범위는 수동나사에 의하여 620~900 mm 범위로 무단조절 할 수 있도록 하였다. 중경제초기는 3륜 승용 관리기 복부의 평행링크에 부착되므로 작업기의 이동 및 부착 편이성을 위하여 이동용 바퀴를 설치하였다. 제작된 중경제초기의 크기는 길이${\times}$${\times}$높이가 $660{\times}2072{\times}880mm$, 중량은 약 200 kg으로 제작되었다.

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Design and Construction of the Cultivating Hiller for a 3-Wheel Riding Type Cultivating Vehicle (3륜 승용관리기용 중경배토기 설계 제작)

  • Choi, Il Soo;Choi, Yong;Lee, Beom Seob;Ji, Keum Bae;Yun, Young Tae;Yoo, Soo Nam
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 2017.04a
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    • pp.76-76
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    • 2017
  • 4륜 승용관리기는 보통 후방이나 전방에 작업기를 장착하여 작업하나 3륜 승용관리기는 작업기를 복부에 장착함으로 작업의 정밀도, 편이성, 관측의 용이성 향상과 함께 지상고 제고, 차폭 조절, 조향 등의 성능 개선을 기할 수 있다. 국내에서는 3륜 승용관리기용 복부 장착 부속작업기가 거의 개발되어 있지 않으며, 특히 두류 재배에 있어서 일관기계화 작업을 위한 관리작업기의 개발이 매우 필요한 실정이다. 승용관리기의 중경배토기에 의한 작업은 기존 인력에 의한 작업보다 약 87%의 노력을 절감할 수 있으며, 잡초방제 효과도 인력에 비하여 크게 떨어지지 않고, 수량도 증가하는 것으로 보고되고 있다. 따라서 본 연구는 3륜 승용관리기에 적합한 복부장착형의 중경배토기를 설계 제작하였다. 3륜 승용관리기용 중경배토기는 승용관리기의 복부 PTO에서의 구동력 전달을 위한 연결 조인트, 중간축, 기어 및 체인 전동기구, 구동축으로 구성된 동력전달부, 4개의 로타리 날과 후방 1개의 배토날로 구성된 3조의 작업날, 로타리 날과 배토날의 경심 조절을 위한 3조의 바퀴, 흙의 비산 방지를 위한 로타리날 커버 및 케이스, 다양한 조간거리에 적응을 위한 조간조정 나사부, 3륜 승용관리기에의 부착을 위한 프레임 및 부착보조 작업기 이동용 바퀴장치 등으로 구성 설계 제작하였다. 로타리 날과 배토날은 기존 시판 관리기용 날을 사용하였다. 로타리 날은 진행방향으로 회전하도록 하였으며, 날의 회전반경은 약 330 mm, 조당 경운 폭은 약 230 mm 설계하였다. 최대 경심은 100 mm이며, 조간거리의 조절범위는 수동 나사에 의하여 620~900 mm 범위로 무단조절 할 수 있도록 하였다. 중경제초기는 3륜 승용 관리기 복부의 평행링크에 부착되므로 작업기의 이동 및 부착 편이를 위하여 이동용 바퀴를 설치하였다. 제작된 중경배토기의 크기는 길이${\times}$${\times}$높이가 $660{\times}2072{\times}880mm$, 중량은 약 200 kg으로 제작되었다.

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Occurrence and Formation Environment of Boron Deposits in Turkey (터키 붕소광상의 부존특성 및 형성환경)

  • Koh, Sang-Mo;Lee, Bum Han;Lee, Gilljae;Cicek, Murat
    • Economic and Environmental Geology
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    • v.47 no.5
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    • pp.541-549
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    • 2014
  • The annual borate production in Turkey is about 3 million tons, which occupies approximately 61 percent of total annual world production. Turkey has five boron deposits including Bigadic, Emet, Kestelek, Kirka, and Sultancayir. At present, Bigadic, Emet, and Kirka deposits are operating. Kirka boron deposit is distributed within volcanoclatic sedimentary group as mainly layered, rarely brecciated and massive types. Major borate is borax associated with colemanite and ulexite. They show a horizontal symmetrical zonation from Na borate (borax) in the center of deposit to Na-Ca borate (ulexite) and Ca-borate (colemanite) in margin. Bigadic boron deposit is known as the largest colemanite deposit in the world. This deposit occurs as two borate bearing horizons in Miocene volcanoclastic sedimentary group. Thickness ranges from several meters to 100 meter with a length of several hundreds meters. Borate ore bodies which are mainly composed of colemanite and ulexite are alternated with claystone, mudstone, tuff and layered limestone as lenticular shape. Sultancayir boron deposit is mainly distributed within gray limestone. Main borate minerals of this deposit are pandermite and ulexite. Pandermite and ulexite occur as colloform aggregate and small veinlet, respectively. Turkish boron deposits are evaporite deposit which were formed in Miocene playa-lake environment. Boron was supplied to the deposits by the volcanic and hydrothermal activities.

Varietal Differences and Time Course Changes in Greenness Values in Rice Leaf (벼 엽록도값의 품종간 차이와 생육기간중 경시적 변화)

  • 홍광표;김영광;정완규;손길만;송근우;최용조;최진용
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.48 no.6
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    • pp.479-483
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    • 2003
  • Knowledge of N accumulation during the vegetative growth stage of rice (Oryza sativa L.) is useful for determining the need for topdressing fertilizer N at panicle initiation and booting stage. The chlorophyll content showing SPAD threshold values generated by a simple and portable diagnostic instrument, chlorophyll meter, enables implement the measures of greenness and/or relative chlorophyll contents of leaves. Two-year field experiment was conducted to evaluate the possible application of the chlorophyll meter for N diagnosis in transplanted paddy rice. The chlorophyll meter threshold values (SPAD reading) were taken from uppermost fully expanded leaves at 10days interval from 10 days after transplanting. SPAD readings and N contents of rice leaf blade were closely related at the maximum tillering stage. SPAD readings during growth period showed M-shaped distribution, sharply finished to drop at 20 days after heading date. As N fertilizer increased, the SPAD readings increased. The SPAD readings showed more critical and clear difference in immature paddy field than in ordinary paddy field, where the former soil showed higher response to N fertilizer topdressed. Based on the PAD readings for obtaining an optimum sink size bearing the maximum grain yield, N fertilizer to be dressed at the panicle initiation stage is to be adjusted within the SPA$\times$tillers value range 888 in ordinary paddy, and 800 in immature paddy vice. Among the cultivars tested, Huckhyangbyeo, Jinpumbyeo, Ansungbyeo, Sobibyeo, Manpungbyeo, Sangmibyeo, Jinbongbyeo, showed high SPAD values, whereas the cultivars, Nonghobyeo, Saechuchungbyeo, Hwabongbyeo, Mananbyeo, did low values and others intermediate SPAD threshhold values.

Sterol Composition of Rice Bran Oil (미강유중(米糠油中)의 Sterol조성(組成))

  • Jeong, Tae-Myoung;Yang, Min-Suk;Hah, Bong-Suk
    • Applied Biological Chemistry
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    • v.27 no.2
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    • pp.119-128
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    • 1984
  • The unsaponifiable from rice bran oil was fractionated into 4-desmethyl-'4-monomethyl- and 4, 4-dimethylsterol (triterpene alcohol) fraction by thin layer chromatography (TLC), and sterol composition of the each fraction was analyzed by gas liquid chromatography(GLC). The sterol peaks not well separated by GLC were further fractionated by $AgNO_3-TLC$, then analyzed using GLC. Each components in the three sterol fractions were identified by GLC and gas chromatography-maps spectrometry. As the results, ten sterols were confirmed as 4-desmethylsterol, nine as 4-monomethylsterol and four as 4, 4-dimethylsterol. Such uncommon phytosterols in higher plants as fucosterol, 24-ethyllophenol, 4${\alpha}$-methylstigmasta-7, 25-dienol and 28-isocitrostadienol were detected in rice bran oil and the biosynthetic pathways of the phytosterols were deduced with all the identified sterols.

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Design of GPS Receiving Antenna Installed in a Missile's Warhead (미사일 탑재형 GPS 안테나 설계)

  • Lee Jong-Min;Woo Jong-Myung
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.17 no.9 s.112
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    • pp.900-912
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    • 2006
  • A GPS receiving antenna installed in the missile's warhead is designed and fabricated at a center frequency 1.575 GHz. The circular shaped antenna is installed in the middle of the warhead where the antenna's patch and the ground plane are connected with a hollow cylindrical shaped short pin. Using the dual feeding and phase difference method, an omni-directional radiation pattern which direction is normal to the missile's axis(H-plane) is obtained. The optimized diameters of the circular patch and the cylindrical ring typed shorting pin of the GPS receiving antenna which use the FR4.material(dielectric constant $\varepsilon_r=4.6$) are 59.5 mm and 14 mm, respectively. The cylindrical body with diameter 100 mm and height 500 mm is attached to the lower part of the warhead in order to complete the missile figure. The radiation patterns are measured by changing the angle and phase between the dual feeding points. When the phase difference of dual feeding is $100^{\circ}$ and the angle between the dual feeding points is $100^{\circ}$, the nearly omni-directional radiation pattern in the H-plane is obtained. In this case, the antenna gain is -5.55 dBd and the relative level difference between the maximum and the minimum radiation intensity is 3.98 dB.

Genetic Diversity and Genetic Structure of Acer pseudosieboldianum Populations in South Korea Based on AFLP Markers (AFLP 마커를 이용한 당단풍나무 집단의 유전다양성과 유전구조)

  • Ahn, Jiyoung;Hong, Kyung-Nak;Baek, Seung-Hoon;Lee, Min-Woo;Lim, Hyo-In;Lee, Jei-Wan
    • Journal of Korean Society of Forest Science
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    • v.105 no.4
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    • pp.414-421
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    • 2016
  • Fourteen Acer pseudosieboldianum populations in South Korea were used to estimate genetic diversity, genetic differentiation and genetic relationships using seven AFLP primer combinations. The average of effective alleles ($A_e$), the proportion of polymorphic loci (%P) and Shannon's diversity index (I) was 1.4, 82.2% and 0.358, respectively. The expected heterozygosity ($H_e$) under Hardy-Weinberg equilibrium was 0.231 and the expected heterozygosity (Hj) from Bayesian inference was 0.253. The level of genetic diversity was moderate compared to those of Genus Acer and lower than those of other species having similar ecological niche and life history. The inbreeding coefficient within populations ($F_{IS}$) from Bayesian method was 0.712 and it could be influenced by selfing or biparental inbreeding to induce homozygote excess. The level of genetic differentiation was 0.107 from AMOVA (${\Phi}_{ST}$) and 0.110 from Bayesian method (${\Phi}^{II}$). The genetic differentiation was lower than those of other species having similar ecological niche and life history. Ulleungdo population had the lowest level of genetic diversity and was genetically the most distinct population from others in the study. We consider that founder effect and genetic drift might be occurred to reduce genetic diversity and then the geographical isolation might interrupt gene flow to aggravate it.

The cultivate characteristics and the wood rotting ability and type of the Kuehneromyces mutabilis Sing. et A. H. Smith (무리우산버섯균의 배양적 특징과 목재부후 특성 파악)

  • Yun, Dae-Ryoung;Chai, Jyung-Ki
    • Journal of Mushroom
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    • v.2 no.4
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    • pp.192-199
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    • 2004
  • The mycelial mass of K. mutabilis greatly increased at pH 5.5~6.0 but decreased pH 6.0. The linear mycelial growth wsa mostly supported on sawdust of Quercus accutisima and the mycelial density wsa high on sawdust of Q. accutisima and corn cob. Much mycelial distribution could be showen in ray parenchyma cell and ray tracheid. Severe degradation of ray parenchyma cell was found but little degradation of ray tracheid cell was found. The dry weight loss wsa 5.9% after agar-block test. And the pH wsa acidified from 6.07 to 4.31 and hot water extractives was decreased after degradation of Q. serrata sawdust by K. mutabilis.

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Identification of Stictodora lari (Heterophyidae) metacercariae encysted in the brackish water fish, Acanthogobius flavimanus (문절망둑(Acanthogobius flavimanus)에서 얻은 Stictodora lari 피낭유충의 동정)

  • 채종일;박상규
    • Parasites, Hosts and Diseases
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    • v.27 no.4
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    • pp.253-260
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    • 1989
  • Metacercariae of the genus Stictodora encysted in the head tissue of Acanthogobius navimanus (the gobies) caught at Sachun-gun, Kyongnam Province, were identified to be Stictodora Zari Yamaguti, 1939 (Trematoda: Heterophyidae), a new parasite fauna in Korea. The metacercariae were 0.39∼,0.43 mm by 0.32∼0.35 mm in size, long elliptical, and with a thin and transparent cyst wall. Total 200 metacercariae were collected from 50 gobies. In order to obtain adult worms two kittens and a Puppy were infected each with 34∼100 metacercariae, and total 33 adults were recovered between the day 4 and day 8 post-infection. The S. sari adults measured 0.95∼1.18 mm long and 0.26∼0.32 mm wide and the eggs in uteri 0.028∼0.033 mm by 0.017∼0.020 mm. The most characteristic morphological feature of these flukes was the presence of a gonotyl and gonotyl spines arranged in two groups; densely crowded group of 30~40 spines and linearly-arranged one of 30∼40 spines, together of which made a comma(or reversed comma) shape along the lateral margin of the gonotyl. It has been proved by this study that 5. sari is distributed in southern coasts of Korea.

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