• Title/Summary/Keyword: 제3계

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Development of Alkoxysilane Mixed Solution as Stone Preservation and Consolidation Materials (알콕시 실란계 석재 보존 및 강화제 개발)

  • Kim, Eun-Kyung;Park, Seong-Yong;Cho, Hyun-Dong;Won, Jong-Ok;Do, Jin-Young;Kim, Sa-Dug
    • Journal of Conservation Science
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    • v.21
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    • pp.21-32
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    • 2007
  • Low-viscosity alkoxysilanes that polymerize into the porous network of decayed stone by a sol-gel process are widely used as stone consolidants. During drying, the gel network contracts due to capillary pressure generated by solvent evaporation. We have prepared tetraethoxysilane mixed solution containing methyltrisilane, ethyl trisilane and (3-glycidyloxypropyl)trimethoxysilane having epoxy ring in order to reduce the shrinkage happened inside the stone porous structure during the gel formation. Mixed solutions were applied into sandstone and granites and characterized by FT-IR, SEM. The gelation time, water uptake, contact angles were measured and compared with those of the commercial stone conservation materials.

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Study on Polymerization Condition of Water-based Acrylic Adhesion (수분산성 아크릴계 점착제 중합 조건에 관한 연구)

  • Lee, Haeng Ja;Jang, Suk Hee;Chang, Sang Mok;Kim, Jong Min
    • Korean Chemical Engineering Research
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    • v.48 no.5
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    • pp.609-614
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    • 2010
  • In this study, emulsion polymerizations for synthesizing acrylic pressure-sensitive adhesive(PSA) were carried out using 2-ethylhexyl acrylate(2-EHA), n-butyl acrylate(n-BA), methyl metacrylate(MMA) as fundamental monomers and acrylic acid(AAc) as a functional monomer in the presence of anionic SLS (sodium lauryl sulfate). To obtain the optimized synthetic condition in the polymerization, we analyzed the polymerization variables such as the effect of surfactant concentration and hydrophilic lipophilic values(HLB). At the same time, the final adhesive properties were also analyzed by the function of the initiator concentration and buffer concentration. In the results, the most stable emulsion was obtained at the surfactant concentrations between 3 and 5 wt%. It was also determined the effect of HLB value of nonionic surfactant and the initiator concentrations on the gel content. Stable emulsion is obtained using the surfactant having HLB value of 12.3. The rate of emulsion polymerization was increased at the initiator concentration greater than 1 wt%, but the stability of the emulsion was decreased. Finally, the effect of the buffer concentrations on the pH and the conversion of the acrylic emulsion product were experimentally measured. At the sodium bicarbonate concentration above 0.4 wt%, the buffer infulence was apparent. The buffer effect was fully acceptable at the concentrations between 0.6 and 0.8 wt% regardless of the monomer composition.

A Study on CSFs in the 4th Industrial Revolution (제4차 산업혁명의 성공요인에 관한 연구)

  • Sung, Tae kyung
    • Journal of Service Research and Studies
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    • v.10 no.1
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    • pp.69-83
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    • 2020
  • The purposes of this study is to identify the critical success factors for the 4th industrial revolution through literature review and to empirically evaluate the validity of these factors through questionnaires from executives engaging in the industries of the 4th industrial revolution. Literature review identifies leadership, change management, top management support, strategic fit, training, empowerment, teamwork, organizational culture, communication, and project management as ten critical success factors, Questionnaires were administered to CIOs and CEOs in the industries belong to the 4th industrial revolution. Response rate was 64.4% which shows quite high participation. Respondents rated strategic fit as the most important factor, followed by top management support, leadership, change management, project management, teamwork, communication, training, organizational culture, and empowerment. To successfully pursue the 4th industrial revolution, the followings are recommended. (1) detailed and refined execution strategy, (2) establishment of effective network among government, public companies, research institutes, universities, and industries, (3) strategic and long-term plan, (4) differentiated execution strategy from other countries and global cooperation system.

Study of Adhesion Phenomena of Alkoxysilane-type Consolidants on Fresh Granites (알콕시 실란계 석재 강화제의 화강암 점착 특성 연구)

  • Kim, Eun-Kyung;Son, Seung-Hwan;Won, Jong-Ok;Kim, Jeong-Jin;Kim, Sa-Dug
    • Journal of Conservation Science
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    • v.23
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    • pp.1-10
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    • 2008
  • Consolidants based on tetraethoxysilane (TEOS) such as alkoxysilanes have been widely used for the consolidation of decaying stone heritages. Low-viscosity alkoxysilanes penetrate inside the decaying stone and polymerize within the porous structure of the decaying stone, significantly increasing the cohesion of the material. However, TEOS-based consolidants suffer from practical drawbacks, such as crack formation of the gel during the drying phase due to the developed capillary force, which is typical for TEOS-based consolidants. We prepared new consolidants TEOS-based consolidants containing flexible (3-glycidoxypropyl)trimethoxysilane (GPTMS) and silica nanoparticles (or polyhedral oligomeric silsesquioxanes (POSS)) in order to reduce capillary force development during gel drying. Since the consolidants should have a good interaction with the component of the stone in order to connect the isolate grains of decaying stone, the adhesion interaction of the developed consolidants on the surface of the granite was macroscopically investigated by the ISO 2409 cross cutting test. The adhesion interaction decreased with the addition of silica nanoparticle and POSS while it increased with the addition of GPTMS in TEOS solution.

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Short Aramid Fiber Reinforced Polyethylene and Epoxy Composity- I. Studies on the Curing Acceleration of Epoxy/Amine System by Differential Scanning Calorimeter (Aramid단섬유보강 고기능폴리에틸렌 및 에폭시 복합재료 제조- I.DSC에 의한 에폭시/아민계의 경화 촉진 연구)

  • Ha, Chan Sik;Lim, Seung Ha;Kim, Byung Kyu;Chin, Young Jo;Cho, Won Jei
    • Applied Chemistry for Engineering
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    • v.3 no.1
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    • pp.111-118
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    • 1992
  • The curing acceleration of epoxy/amine system was investigated by using differential scanning calorimeter(DSC), The epoxy, diglycidylether of bisphenol A (DGEBA) was cured with methylene dianiline (MDA) with or without accelerators. Two kinds of accelerators were tested for the study ; tris(dimethylaminomethyl)phenol (DMP - 30) and 3 - (3,4 - dichlorophenyl)-1, 1-dimethylurea (DIURON). Heats of reaction and glass transition temperatures ($T_g$) of the cured epoxy system were analyzed by DSC along with the estimation of activation energy by the dynamic DSC studies. It was found that DMP - 30 is more effective accelerator than DIURON which showed faster curing and lower activation energy.

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Interview - 제25회 한용교포장인상 수상자

  • (사)한국포장협회
    • The monthly packaging world
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    • s.347
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    • pp.82-86
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    • 2022
  • (사)한국포장협회(회장 임경호)는 지난 2월 18일 '제32차 정기총회 및 포장인의 날'에 (사)한국포장협회 회장상과 공로상, 그리고 한용교포장인상을 수여했다. 이번 제25회 한용교포장인상 시상식에서는 연구개발 부문에 박세철 (주)아이피씨 기술연구소 소장이, 수출진흥 부문에 최봉규 (주)천일 대표이사가 수상의 영광을 안았고, 장학생 부문에서는 대구대학교 식품공학과의 박정우 학생과 연세대학교 패키징학과의 신동훤 학생이 장학금을 수여받았다. 한편 제3회 (사)한국포장협회 회장상은 이현철 (주)서일 소장이 수상했고 공로상은 신동윤 율촌화학(주) 회장이 수상했다. 다음 인터뷰를 통해 제25회 한용교포장인상 수상자들의 활약상을 살펴본다.

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ROLE OF NITRIC OXIDE AND DISTRIBUTION OF NITRIC OXIDE SYNTHASE IN THE GUSTATORY SYSTEM (미각계에서 산화질소의 역할과 산화질소 합성효소의 분포)

  • Kim, Young-Jae;Kim, Won-Jae;Ryu, Sun-Youl
    • Journal of the Korean Association of Oral and Maxillofacial Surgeons
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    • v.26 no.3
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    • pp.262-269
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    • 2000
  • 말초 미각계 및 중추 미각계에서 산화질소의 역할과 그것의 합성효소의 존재는 아직 규명되지 않고 있다. 본 연구는 말초미각계인혀와 미각구심성신경 그리고 중추미각계인 뇌간고속핵에서 산화질소 합성효소의 분포 및 면역조직화학 방법과 고삭신경의 extracellular recording 뇌간고속핵 절편 whole cell patch 방법으로 조사하였다. 신경성 산화질소 합성효소는 혀의 전방에 위치한 심상유두와 유곽유두에 약하게 존재하였으며 미뢰주위와 결체조직에 존재하는 신경섬유 및 혀의 상피층에 풍부하게 존재하였다. 혀에 소금물을 가하여 증가된 고삭신경의 복합전위는 산화질소 유리제인 SNP에 의해 증가되었으며 내인성 산화질소 합성효소 억제제인 L-NAME와 soluble guanylate cyclase 억제제인 ODQ에 의해 억제되었다. 문측 연수에 존재한 문측 고속핵과 진전핵에서 nNOS가 풍부하게 존재하였다. 문측 고속핵의 신경들은 안정막전위가 $-48{\pm}52mV$였고 활동전위의 크기는 $74{\pm}11mV$였다. SNP에 의해 뇌간 고속핵 신경들이 탈분극되었으며 current clamp하였을 때 활동전압의 빈도가 증가하였다. 또한 SNP에 의한 문측 고속핵의 탈분극과 활동전압 빈도증가는 L-NAME와 ODQ에 의해 감소되었다. 이상의 실험결과는 산화질소 합성효소가 혀와 뇌간고속핵에 존재하며 여기서 유리된 내인성 산화질소가 말초성 및 중추성 미각기전에 관여하리라 사료된다.

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Robust Centralized Servocontroller Design for a Rotor System Supported by Magnetic Bearings (자기베어링 지지 로터계를 위한 견실한 중앙집중식 서보제어기 설계)

  • 김종원
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.6
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    • pp.1141-1149
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    • 1992
  • This paper presents a robust centralized control scheme for a magnetic bearing system which supports a rigid rotor at both shaft ends in the radial direction. The negative stiffness element and the inductive force associated with bearing magnetic field are considered in the dynamic model of the system. For this model, the controllability and observability are examined, and then a robust control theory is applied to design two types of multi-input multi-output servocontrollers. A general servocompensator is embedded in the first one and a centralized PID controller is suggested as a second one. By simulation study, the performance of two types of servocontrollers are compared in the aspects of disturbance rejection, reference tracking and the robustness limit.

Compensation of Unbalanced Source Voltage using Symmetrical Component Method (대칭좌표계를 이용한 불평형 전원전압의 보상)

  • Yun Min-Sung;Lee Woo-Cheol;Hyun Dong-Seok
    • Proceedings of the KIPE Conference
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    • 2004.07b
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    • pp.673-676
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    • 2004
  • 본 논문은 3상 입력전원의 불평형과 고조파문제를 대칭 좌표계를 통해 각각 정상분과 역상분으로 분리하여 동기 회전 좌표계 상에서 보상할 수 있는 알고리즘을 제안하였다. 동기 회전 좌표계 상에서 보상이 이루어지므로 UPQC와 같은 다양한 목적의 능동전력필터에 쉽게 적용될 수 있다 제안된 알고리즘의 타당성을 뒷받침하기 위해 시뮬레이션을 수행 하였다.

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Prediction and model1ing of changes of freshwater ecoystem (담수역 생태계의 부영양화 및 녹조 연구)

  • 이원호;신윤근;김영길
    • Proceedings of the Korean Society of Coastal and Ocean Engineers Conference
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    • 2000.09a
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    • pp.88-90
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    • 2000
  • 새만금 담수호의 생태계의 변화를 예측하기 위하여, 대상해역 인근의 저염수역에서 부영양화 및 미소조류 생태계에 관한 연구를 계획하였다. 이는 새만금호의 미소조류 생태계 변화와 부영양화의 과정을 완화시킬 수 있는 길을 모색하기 위한 3개년 연구계획으로서, 제 1년차 연구의 현장 조사 및 자료분석 결과를 보고한다. (중략)

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