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Suppression of Abnormal Grain Growth in $BaTiO_3$ ($BaTiO_3$계에서의 비정상 입자 성장의 억제)

  • 최시영;강석중;이병기
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2001.11a
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    • pp.36-36
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    • 2001
  • $BaTiO_3$는 현재 전기 전자 부속 산업엣 필수적인 재료로서, multilayer capacitor,positive temperature coefficient(PTC) resistor, grain-boundary battier layer capacitor(GBBLC)등에 쓰이고 있다. $BaTiO_3$의 전기적 특성을 최대화하기 위해서는 미세구조가 최적화 되어야만 하는데 일반적으로 수 마이트로 이내의 작고 균일한 크기의 입자크기가 바람직하다. 그러나 $BaTiO_3$계에서 화학양론의 조성이 정확하게 일치하지 않거나 $La^{3+}$$Nb^{5+}$같은 첨가제가 들어가지 않으면 비정상 입자 성장은 자발적으로 일어난다. 그러나 첨가제는 $BaTiO_3$의 강자성 특성에 영향을 주게 되므로 첨가제 없이 비정상 입자 성장을 억제할 수 있는 것이 바람직한 방법이며, 이 것이 본 실험의 목표이다. 본 실험에서는 0.4-mol%-$TiO_2$가 첨가된 $BaTiO_3$ 분말을 디스크 형태로 성형하여 $H_2$ 분위기, 1250에서 5시간동안 열처리한 후, 공기 중, 1300도에서 48시간까지 소결한 후 미세조직을 관찰하였다. 소결 전에 $H_2$ 분위기에서 열처리를 함으로서 초기 입자 크기는 증가하게 되고 이로 인한 계의 성장 구동력 감소로 비정상 입자 성장이 억제되었으며 균일하고 미세한 입자 크기를 가지는$BaTiO_3$ 소결체를 얻을 수 있었다. 또한 비정상이 억제되지 않은 $BaTiO_3$의 유전 특성보다 우수한 유전 특성을 나타내었다. 본 실험을 통해서 첨가제를 사용하지 않고 우수한 유전 특성을 가지는 미세한 균일한 입자의 $BaTiO_3$를 제조하는 새로운 기술을 개발하였다.

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Water Repellent Characteristics According to the Surface Properties of Cement Mortar Mixed with Water-soluble Water Wepellent (표면 성상에 따른 수용성 발수제 혼입 시멘트 모르타르의 발수특성)

  • Kang, Suk-Pyo;Kang, Hye-Ju;Hong, Seong-Uk;Yang, Seung-Hyeon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.6
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    • pp.42-49
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    • 2020
  • This paper is a basic study to improve durability by imparting hydrophobicity to the surface and sphere of cement-based materials. A cement mortar to which a silane/siloxane-based mixed water repellent was added was prepared, and its initial hydration performance, flow performance, and compressive strength were measured. In addition, after the surface was abraded, the water contact angle and water absorption were measured. The flow of cement mortar to which the water repellent was added was found to decrease up to 1.5% in the addition amount of the water repellent agent, and increased at 3.0% in the addition amount. It was found that the setting time of the cement paste was delayed in both the initial setting and the termination when the water repellent was added. It was found that the compressive strength decreased from 3.0% of the maximum added amount of the water repellent to a maximum of 30%. The contact angle was found to increase when the water repellent was added to the cement mortar, and the contact angle after surface polishing was found to be larger than before surface polishing. The addition of the water repellent showed hydrophobicity not only on the surface but also on the surface and cross section damaged by polishing. The water absorption rate was found to decrease when the water repellent was added to the cement mortar, and the water absorption rate after surface polishing was found to be greater than before surface polishing.

Adhesive Properties of Emulsion PSA Polymerized Using Tween Series Nonionic Surfactants (Tween계 비이온 계면활성제를 이용하여 중합한 에멀션점착제의 접착물성)

  • Lim, Tae Kyun;Lee, Myung Cheon
    • Korean Chemical Engineering Research
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    • v.52 no.3
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    • pp.289-293
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    • 2014
  • In making emulsion type pressure sensitive adhesive (PSA), environmentally friendly Tween series nonionic surfactants were used to find out the possibility of substituting the traditional nonyl-phenyl nonionic surfactant (NP-40) by comparing their adhesive properties. Results exhibited that the PSA used Tween series nonionic surfactants showed much better adhesive properties in peel strength and holding power than that used NP-40.

Estimation of the Target Water Quality Achievement for 3rd Stage Total Maximum Daily Loads(TMDLs) in Yeongsan River (영산강 3단계 수질오염총량관리제의 목표수질 달성전망 평가)

  • Park, Sung Chun;Oh, Chang Yeol;Moon, Byoung Seok;Gwak, Pil Jeong;Kim, Jeong Soo
    • Proceedings of the Korea Water Resources Association Conference
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    • 2017.05a
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    • pp.523-527
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    • 2017
  • 우리나라의 수질오염총량관리제는 지역의 발전 계획과 하천의 수질을 연계시켜 목표수질을 달성하는 범위 내에서 개발을 허용한다는 것을 기본으로 하여 1999년 "한강수계상수원수질개선및주민지원등에관한법률"에 의해 처음 시행되었다. 그러나 한강수계보다 늦게 2004년에 도입된 낙동강, 금강, 영산강 섬진강 수계에서는 의무제 총량으로 우리나라에서 처음 도입되어 지난 12년간 시행되었으며 충청북도와 강원도를 제외한 한강수계에서도 2013년 6월부터 의무제 총량이 도입되었다. 1단계 수질오염총량관리제는 BOD만을 관리항목으로 설정하여 관리한 반면 2011년부터 2015년까지 시행하는 2단계 수질오염총량관리제는 부영양화 방지를 위해 총인항목을 포함하여 관리항목을 설정하여 관리하였으며, 2016년에 시작하여 2020년까지 시행하는 3단계수질오염총량관리제는 2단계에서와 같은 관리항목을 설정하여 시행하고 있다. 본 연구에서는 3단계 영산강수계의 수질오염총량관리제 목표수질의 달성전망을 평가하기 위하여 3단계 기본계획에서 활용한 QUAL-MEV 모델을 이용하였으며, 2012년 수질자료를 보정자료로, 2015년 수질자료를 검증자료로 활용하여 구축하고 2020년의 영산강수계 8개 단위유역의 말단지점에 대하여 목표수질의 달성을 평가하였다. 그 결과 BOD는 영본A, 영본B지점에서 각각 목표수질을 21%, 8%를 초과하며 T-P는 영본A지점에서 30%를 초과하여 목표수질을 달성하지 못할 것으로 예측되었다. 영산강수계 3단계 수질오염총량관리제의 성공을 위하여 영본A, 영본B지점의 목표수질 달성을 위한 추가 수질개선계획의 수립이 필요한 것으로 판단된다.

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Evaluating Shrinkage Characteristic of Ternary Grout for PSC Bridge Using Expansive Additive and Shrinkage Reducing Agent (팽창재 및 수축저감제를 이용한 PSC 교량용 3성분계 그라우트의 수축특성 평가)

  • Yuan, Tian-Feng;An, Gi-Hong;Ryu, Gum-Sung;Koh, Kyoung-Taek;Yoon, Young-Soo
    • Journal of the Korea Concrete Institute
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    • v.28 no.5
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    • pp.519-525
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    • 2016
  • This paper reports on analyzing the free and restrained shrinkage characteristic of ternary grout used cementitious admixture. In this study, the cementitious admixture was used such as fly ash, ziricania silica fume by combination of expansive additive (a, b) and shrinkage reducing agent. And a number of basic performance tests were conducted to investigate bleeding, volume change, fluidity and compressive strength behavior. According to the results, within appropriate mixing ratio, even the fluidity is not influenced by expansive additive and shrinkage reducing agent, the resistant properties of bleeding, volume change, shrinkage and compressive strength are increased. Comparing with plain grout, the free shrinkage reduced by a minimum of 29% which specimens are added expansive additive and shrinkage reducing agent. The combination of expansive additive a and shrinkage reducing agent is the most effective for reduction of shrinkage. And increasing the mixing ratio of expansive additive and shrinkage reducing agent extended cracking time. Nevertheless, combined addition of expansive additive a 2.0% and shrinkage reducing agent 0.50% has best shrinkage reduction behavior and not appeared cracking. From the above, the mixing ratio of 2.0% of expansive additive a and 0.50% of shrinkage reducing agent is high performance ternary grout for PSC bridge.

Application Of $P_2O_5$-ZnO-RO System With Glass Network Former to Transparent Dielectric ($P_2O_5$-ZnO-RO계에 유리형성제 첨가에 의한 투명유전체의 응용)

  • 차명룡;전재삼;정병해;김형순
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.213-213
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    • 2003
  • 저온소성 가능하며 저 융점유리인 고 투과율의 Pb-free 조성으로서 PDP(Plasma Display panel)의 투명유전체에 응용하고자 P$_2$O$_{5}$-ZnO-RO 계인 인산염 유리의 열적, 광학적성질을 연구하였다. 이 삼원계인 인산염유리계를 PDP의 투명 유전체에 응용하기에는 열적특성에서 문제점이 제기되어, (30-50)P$_2$O$_{5}$ - (20-50)ZnO - (15-45) RO (mol%)계에 유리망목형성제인 A1$_2$O$_3$, SiO$_2$, B$_2$O$_3$등을 첨가하여 열적성질 및 소성후 투광성 등을 조사하였다. 열적특성은 DTA와 TGA를 이용하여 유리전이점(Tg) 및 선팽 창계수(CTE)와 연하점(Ts) 을 측정하였으며, 투광성은 500-58$0^{\circ}C$에서 1시간동안 소성하여 UV-visible spectrometer을 이용하였다 그 결과로, 380-46$0^{\circ}C$의 Tg와 8-$10^{-6}$K의 CTE 및 70-80%의 광투과율을 나타내었다. 이러한 결과는 P$_2$O$_{5}$-ZnO-RO계는 PDP의 투명유전체에 적용하기에는 상당히 높거나 낮은 Tg를 형성하였지만 유리형성제를 수 mol%을 첨가함으로써 적절한 Tg점과 높은 투과율을 얻을 수 있었다.수 있었다.

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A Study on Reactivity of Zinc-Based Sorbents (아연계흡수제의 반응특성 규명연구)

  • 연장희;이영우;이창근
    • Journal of Energy Engineering
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    • v.7 no.1
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    • pp.24-34
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    • 1998
  • In this research, effects of the types and amounts of binders and additives on desulfurization and regeneration reactivities of zinc titanate were investigated. Bentonite and kaolinite were used as binders and Mo-based, Ni-based, and Cu-based compounds were used as additives. A thermogravimetric analyzer (TGA) was utilized to investigate reactivities of desulfurization and regeneration for each sorbent. Two-cycle reactions of desulfurization-regeneration were performed in the TGA reactor. Results of XRD analysis showed that all sorbents had the crystalline phases of $Zn_2TiO_2$ and $Zn_2Ti_3O_8$ irrespective of the type and amount of binder and additive. Kaolinite-bound sorbents gave higher surface areas than bentonite-bound ones and the surface areas and pore volumes of sorbents increased with amount of binder increased. It was found that the most suitable temperatures for desulfurization and regeneration were 680$^{\circ}$C and 730$^{\circ}$C, respectively, and the sorbent prepared by the addition of 3 mol% CuO showed the best performance in terms of desulfurization and regeneration. Nio-added sorbents had good regenerability whereas $MoO_3-based$ sorbents showed poor performance. In cycle experiments in a fixed bed reactor 3 mol% CuO-added sorbents showed high reactivity.

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A study on the zinc oxide crystalline powder synthesized by zinc chloride solution and sodium-based alkali precipitants (염화아연 수용액과 나트륨계 알칼리 침전제 종류에 따라 합성한 산화아연 결정 분말에 대한 연구)

  • Dae-Weon Kim;Dae-Hwan Jang;Bo-Ram Kim
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.33 no.1
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    • pp.15-21
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    • 2023
  • To prepare zinc oxide powder, three types of sodium-based alkali precipitants such as NaOH, Na2CO3, NaOH/NaHCO3 were compared to the differences in the manufacturing process of zinc oxide powder from zinc precipitate products like intermediates with the consideration of thermodynamic reaction. The prepared zinc precipitate products by the reaction with the sodium-based alkali precipitant were confirmed to respectively hydroxy zinc chloride (Zn5(OH)8Cl2·H2O) and zinc carbonate hydroxide (Zn5(OH)6(CO3)2·H2O) from XRD analysis. Zinc oxide particles were compared in heat treatment at 800℃ according to sodium-based alkali precipitants. The mixed NaOH and NaHCO3 of alkali precipitant reaction was contributed to synthesize the more uniform zinc oxide particles.

A Study on the Performance of COMS CPS during LEOP (천리안 위성의 LEOP기간 동안의 추진계 성능 연구)

  • Chae, Jong-Won;Han, Cho-Young;Yu, Myoung-Jong
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.40 no.3
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    • pp.258-263
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    • 2012
  • In this paper the Chemical Propulsion Subsystem of COMS is briefly explained and some telemetries acquired by a series operations of CPS during the Launch and Early Operation Phase of COMS are presented. The pressure and temperature of pressurant tank telemetries are compared with the results of the developed computer program. The changes in pressure are due to the two major phases. The first one is the initialization phases of CPS composed of the venting phase to vent the helium gas in the pipe network from the downstream of the propellant tanks to the thrusters for safety, the priming phase to fill the vented pipe network with oxidizer and fuel respectively and then the pressurization phase to pressurize the ullage of propellant tank to regulated pressure. And the other is the apogee engine firings in which COMS CPS is in the orbit raising phase to use helium as a pressurant to keep the pressure of propellant tank as the liquid apogee engine get fired until COMS reached to the target orbit. This program can be applicable to prepare basis design data of the next Geostationary Satellite CPS.

3th Green Packaging Contest (제3회 그린패키징 공모전)

  • (사)한국포장협회
    • The monthly packaging world
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    • s.249
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    • pp.108-118
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    • 2014
  • 환경부가 주최하고 (사)한국환경포장진흥원이 주관하는 제3회 그린패키징 공모전 시상식이 12월 9일 엘타워 엘하우스홀에서 열렸다. 그린패키징 공모전은 우수한 친환경 포장기술 및 디자인을 발굴, 시상함으로써 친환경 포장에 대한 인식 및 관심을 제고하여 관련 학생 및 종사자들의 사기진작과 기술개발 의욕을 고취시킨다는 목적 아래 금번 제3회를 맞고 있다. 특히 친환경 포장과 관련한 신기술 개발을 촉진함으로써 자원 절약과 녹색 성장에 기여한다는 취지를 갖고 있다. 제3회 그린패키징 공모전에서는 일반 부문 10개 업체 16점이 수상의 영예를 안았으며, 학생부문에서도 5개교 12점이 수상했다. 본 고에서는 제3회 그린패키징 공모전 수상작들을 살펴보도록 한다.

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